{"title":"Structural Features and Properties of Metal Complexes in Ionic Liquids: Application in Alkylation Reactions","authors":"C. Chiappe, Tiziana Ghilardi, C. Pomelli","doi":"10.1007/3418_2013_68","DOIUrl":"https://doi.org/10.1007/3418_2013_68","url":null,"abstract":"","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"51 1","pages":"79-93"},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/3418_2013_68","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"51491707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jeanne‐Marie Begouin, Johannes E. M. N. Klein, Daniel Weickmann, B. Plietker
{"title":"Allylic Substitutions Catalyzed by Miscellaneous Metals","authors":"Jeanne‐Marie Begouin, Johannes E. M. N. Klein, Daniel Weickmann, B. Plietker","doi":"10.1007/3418_2011_15","DOIUrl":"https://doi.org/10.1007/3418_2011_15","url":null,"abstract":"","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"38 1","pages":"269-320"},"PeriodicalIF":0.0,"publicationDate":"2012-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/3418_2011_15","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"51491310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2012-01-01DOI: 10.1007/978-3-642-28288-1_4
T. J. Korstanje, R. K. Gebbink
{"title":"Catalytic Oxidation and Deoxygenation of Renewables with Rhenium Complexes","authors":"T. J. Korstanje, R. K. Gebbink","doi":"10.1007/978-3-642-28288-1_4","DOIUrl":"https://doi.org/10.1007/978-3-642-28288-1_4","url":null,"abstract":"","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"39 1","pages":"129-174"},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/978-3-642-28288-1_4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"51083169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Palladium-Catalysed Coupling Reactions","authors":"J. G. Vries","doi":"10.1007/3418_2012_32","DOIUrl":"https://doi.org/10.1007/3418_2012_32","url":null,"abstract":"","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"42 1","pages":"1-34"},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/3418_2012_32","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"51491413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2012-01-01DOI: 10.1007/978-3-642-28288-1_2
P. Bruijnincx, R. Jastrzebski, P. Hausoul, R. K. Gebbink, B. Weckhuysen
{"title":"Pd-Catalyzed Telomerization of 1,3-Dienes with Multifunctional Renewable Substrates: Versatile Routes for the Valorization of Biomass-Derived Platform Molecules","authors":"P. Bruijnincx, R. Jastrzebski, P. Hausoul, R. K. Gebbink, B. Weckhuysen","doi":"10.1007/978-3-642-28288-1_2","DOIUrl":"https://doi.org/10.1007/978-3-642-28288-1_2","url":null,"abstract":"","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"39 1","pages":"45-101"},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/978-3-642-28288-1_2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"51083117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Transition-metal-catalyzed s-h and se-h bonds addition to unsaturated molecules","authors":"A. Ogawa","doi":"10.1007/3418_2011_19","DOIUrl":"https://doi.org/10.1007/3418_2011_19","url":null,"abstract":"","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"1 1","pages":"325-360"},"PeriodicalIF":0.0,"publicationDate":"2011-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/3418_2011_19","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"51491328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2011-01-01DOI: 10.1007/978-3-642-15334-1_5
John F Bower, Michael J Krische
The formation of C-C bonds via catalytic hydrogenation and transfer hydrogenation enables carbonyl and imine addition in the absence of stoichiometric organometallic reagents. In this review, iridium-catalyzed C-C bond-forming hydrogenations and transfer hydrogenations are surveyed. These processes encompass selective, atom-economic methods for the vinylation and allylation of carbonyl compounds and imines. Notably, under transfer hydrogenation conditions, alcohol dehydrogenation drives reductive generation of organoiridium nucleophiles, enabling carbonyl addition from the aldehyde or alcohol oxidation level. In the latter case, hydrogen exchange between alcohols and π-unsaturated reactants generates electrophile-nucleophile pairs en route to products of hydro-hydroxyalkylation, representing a direct method for the functionalization of carbinol C-H bonds.
{"title":"Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.","authors":"John F Bower, Michael J Krische","doi":"10.1007/978-3-642-15334-1_5","DOIUrl":"10.1007/978-3-642-15334-1_5","url":null,"abstract":"<p><p>The formation of C-C bonds via catalytic hydrogenation and transfer hydrogenation enables carbonyl and imine addition in the absence of stoichiometric organometallic reagents. In this review, iridium-catalyzed C-C bond-forming hydrogenations and transfer hydrogenations are surveyed. These processes encompass selective, atom-economic methods for the vinylation and allylation of carbonyl compounds and imines. Notably, under transfer hydrogenation conditions, alcohol dehydrogenation drives reductive generation of organoiridium nucleophiles, enabling carbonyl addition from the aldehyde or alcohol oxidation level. In the latter case, hydrogen exchange between alcohols and π-unsaturated reactants generates electrophile-nucleophile pairs en route to products of hydro-hydroxyalkylation, representing a direct method for the functionalization of carbinol C-H bonds.</p>","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"34 2011","pages":"107-138"},"PeriodicalIF":0.0,"publicationDate":"2011-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/978-3-642-15334-1_5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30060307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2011-01-01DOI: 10.1007/978-3-642-17429-2_6
David C Powers, Tobias Ritter
While the organometallic chemistry of Pd in its (0), (+II), and (+IV) oxidation states is well-established, organometallic Pd(III) chemistry remains widely unexplored. Few characterized Pd(III) complexes are known, which has inhibited detailed study of the organometallic chemistry of Pd(III). In this review, the potential roles of both mono- and dinuclear Pd(III) complexes in organometallic chemistry will be discussed. While not widely recognized, Pd in the (+III) oxidation state may play a significant role in a variety of known Pd-catalyzed reactions.
{"title":"Palladium(III) in Synthesis and Catalysis.","authors":"David C Powers, Tobias Ritter","doi":"10.1007/978-3-642-17429-2_6","DOIUrl":"https://doi.org/10.1007/978-3-642-17429-2_6","url":null,"abstract":"<p><p>While the organometallic chemistry of Pd in its (0), (+II), and (+IV) oxidation states is well-established, organometallic Pd(III) chemistry remains widely unexplored. Few characterized Pd(III) complexes are known, which has inhibited detailed study of the organometallic chemistry of Pd(III). In this review, the potential roles of both mono- and dinuclear Pd(III) complexes in organometallic chemistry will be discussed. While not widely recognized, Pd in the (+III) oxidation state may play a significant role in a variety of known Pd-catalyzed reactions.</p>","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"503 ","pages":"129-156"},"PeriodicalIF":0.0,"publicationDate":"2011-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/978-3-642-17429-2_6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"29789959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2010-01-01DOI: 10.1007/978-3-642-01866-4_5
N. Fletcher, M. Lagunas
{"title":"Chromo- and fluorogenic Organometallic Sensors","authors":"N. Fletcher, M. Lagunas","doi":"10.1007/978-3-642-01866-4_5","DOIUrl":"https://doi.org/10.1007/978-3-642-01866-4_5","url":null,"abstract":"","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"28 1","pages":"143-170"},"PeriodicalIF":0.0,"publicationDate":"2010-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/978-3-642-01866-4_5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"51068694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2010-01-01DOI: 10.1007/978-3-642-13185-1_1
S. Gibaud, G. Jaouen
{"title":"Arsenic-Based Drugs: From Fowler's Solution to Modern Anticancer Chemotherapy","authors":"S. Gibaud, G. Jaouen","doi":"10.1007/978-3-642-13185-1_1","DOIUrl":"https://doi.org/10.1007/978-3-642-13185-1_1","url":null,"abstract":"","PeriodicalId":54425,"journal":{"name":"Topics in Organometallic Chemistry","volume":"32 1","pages":"1-20"},"PeriodicalIF":0.0,"publicationDate":"2010-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/978-3-642-13185-1_1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"51072607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}