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Structural Features and Properties of Metal Complexes in Ionic Liquids: Application in Alkylation Reactions 离子液体中金属配合物的结构特征和性质:在烷基化反应中的应用
Q3 Chemistry Pub Date : 2013-01-01 DOI: 10.1007/3418_2013_68
C. Chiappe, Tiziana Ghilardi, C. Pomelli
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引用次数: 6
Allylic Substitutions Catalyzed by Miscellaneous Metals 杂金属催化的烯丙基取代
Q3 Chemistry Pub Date : 2012-11-20 DOI: 10.1007/3418_2011_15
Jeanne‐Marie Begouin, Johannes E. M. N. Klein, Daniel Weickmann, B. Plietker
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引用次数: 27
Catalytic Oxidation and Deoxygenation of Renewables with Rhenium Complexes 铼配合物对可再生能源的催化氧化和脱氧
Q3 Chemistry Pub Date : 2012-01-01 DOI: 10.1007/978-3-642-28288-1_4
T. J. Korstanje, R. K. Gebbink
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引用次数: 18
Palladium-Catalysed Coupling Reactions 钯催化偶联反应
Q3 Chemistry Pub Date : 2012-01-01 DOI: 10.1007/3418_2012_32
J. G. Vries
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引用次数: 49
Pd-Catalyzed Telomerization of 1,3-Dienes with Multifunctional Renewable Substrates: Versatile Routes for the Valorization of Biomass-Derived Platform Molecules 用多功能可再生底物催化1,3-二烯的端粒化:生物质衍生平台分子增值的多种途径
Q3 Chemistry Pub Date : 2012-01-01 DOI: 10.1007/978-3-642-28288-1_2
P. Bruijnincx, R. Jastrzebski, P. Hausoul, R. K. Gebbink, B. Weckhuysen
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引用次数: 13
Transition-metal-catalyzed s-h and se-h bonds addition to unsaturated molecules 过渡金属催化的不饱和分子上的s-h和se-h键
Q3 Chemistry Pub Date : 2011-01-01 DOI: 10.1007/3418_2011_19
A. Ogawa
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引用次数: 39
Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation. 通过铱催化氢化和转移氢化形成C-C键。
Q3 Chemistry Pub Date : 2011-01-01 DOI: 10.1007/978-3-642-15334-1_5
John F Bower, Michael J Krische

The formation of C-C bonds via catalytic hydrogenation and transfer hydrogenation enables carbonyl and imine addition in the absence of stoichiometric organometallic reagents. In this review, iridium-catalyzed C-C bond-forming hydrogenations and transfer hydrogenations are surveyed. These processes encompass selective, atom-economic methods for the vinylation and allylation of carbonyl compounds and imines. Notably, under transfer hydrogenation conditions, alcohol dehydrogenation drives reductive generation of organoiridium nucleophiles, enabling carbonyl addition from the aldehyde or alcohol oxidation level. In the latter case, hydrogen exchange between alcohols and π-unsaturated reactants generates electrophile-nucleophile pairs en route to products of hydro-hydroxyalkylation, representing a direct method for the functionalization of carbinol C-H bonds.

通过催化氢化和转移氢化形成C-C键使得能够在不存在化学计量有机金属试剂的情况下添加羰基和亚胺。本文综述了铱催化的碳-碳键形成加氢反应和转移加氢反应。这些工艺包括羰基化合物和亚胺的乙烯化和烯丙基化的选择性原子经济方法。值得注意的是,在转移氢化条件下,醇脱氢驱动有机铱亲核试剂的还原生成,使羰基能够从醛或醇氧化水平添加。在后一种情况下,醇和π-不饱和反应物之间的氢交换在生成氢羟基烷基化产物的过程中产生亲电亲核试剂对,这代表了甲醇C-H键功能化的直接方法。
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引用次数: 245
Palladium(III) in Synthesis and Catalysis. 钯(III)的合成与催化。
Q3 Chemistry Pub Date : 2011-01-01 DOI: 10.1007/978-3-642-17429-2_6
David C Powers, Tobias Ritter

While the organometallic chemistry of Pd in its (0), (+II), and (+IV) oxidation states is well-established, organometallic Pd(III) chemistry remains widely unexplored. Few characterized Pd(III) complexes are known, which has inhibited detailed study of the organometallic chemistry of Pd(III). In this review, the potential roles of both mono- and dinuclear Pd(III) complexes in organometallic chemistry will be discussed. While not widely recognized, Pd in the (+III) oxidation state may play a significant role in a variety of known Pd-catalyzed reactions.

虽然Pd在(0),(+II)和(+IV)氧化态的有机金属化学已经建立,但有机金属Pd(III)化学仍然广泛未被探索。已知的Pd(III)配合物很少,这阻碍了Pd(III)有机金属化学的详细研究。本文将讨论单核和双核钯配合物在有机金属化学中的潜在作用。虽然不被广泛认识,但(+III)氧化态的Pd可能在各种已知的Pd催化反应中发挥重要作用。
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引用次数: 89
Chromo- and fluorogenic Organometallic Sensors 变色和荧光有机金属传感器
Q3 Chemistry Pub Date : 2010-01-01 DOI: 10.1007/978-3-642-01866-4_5
N. Fletcher, M. Lagunas
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引用次数: 10
Arsenic-Based Drugs: From Fowler's Solution to Modern Anticancer Chemotherapy 砷基药物:从福勒溶液到现代抗癌化疗
Q3 Chemistry Pub Date : 2010-01-01 DOI: 10.1007/978-3-642-13185-1_1
S. Gibaud, G. Jaouen
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引用次数: 65
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