首页 > 最新文献

Quaternary Geochronology最新文献

英文 中文
Pysochron: A Python-based solution for calculating cosmogenic 26Al/10Be isochron burial ages Pysochron:一个基于python的计算宇宙成因26Al/10Be等时线埋藏年龄的解决方案
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-05-29 DOI: 10.1016/j.quageo.2025.101675
William E. Odom
Cosmogenic 26Al/10Be isochron burial dating is a powerful tool for dating sediment burial over the past several million years. By measuring in-situ 26Al and 10Be in a suite of samples from the same depth in a buried deposit, it is possible to quantify the inventory of cosmogenic nuclides produced after burial, date the burial of shallow sediments, identify sediment reworking, and calculate paleo-erosion rates. While this approach has been used to date materials around the world for over a decade, few published codes exist for performing 26Al/10Be isochron calculations. The isochron calculation options that are available typically rely on numerous files and libraries, rendering modification and troubleshooting difficult. Moreover, the widespread use of proprietary programming languages – and their associated addon packages – can place an additional financial burden on an already costly endeavor.
Pysochron (https://code.usgs.gov/recon/pysochron) provides a solution to these issues. In its base form, it exists as a single script that can be easily modified, upgraded, and shared. Because it was developed in an open-source environment, all required computational packages are available free of charge. A user-friendly interface allows rapid modification of calculation parameters, and an automated commentary on isochron results provides insights and recommendations. Pysochron has been validated with 40 published cosmogenic 26Al/10Be burial isochrons around the world, with burial ages ranging from ∼5 Ma to ∼180 ka. As such, it is a promising option for members of the cosmogenic nuclide community seeking a straightforward, cost-effective, and flexible solution to isochron burial dating challenges.
宇宙成因26Al/10Be等时线埋藏年代测定是测定过去几百万年沉积物埋藏年代的有力工具。通过原位测量埋藏矿床中相同深度的一组样品中的26Al和10Be,可以量化埋藏后产生的宇宙形成核素的库存,确定浅层沉积物的埋藏日期,确定沉积物的再加工,并计算古侵蚀速率。虽然这种方法已经在世界各地使用了十多年,但很少有公开的代码用于执行26Al/10Be等时线计算。可用的等时线计算选项通常依赖于大量文件和库,使得修改和故障排除变得困难。此外,专有编程语言及其相关插件包的广泛使用可能会给本已昂贵的工作增加额外的财务负担。Pysochron (https://code.usgs.gov/recon/pysochron)为这些问题提供了解决方案。在其基本形式中,它作为一个脚本存在,可以很容易地修改、升级和共享。因为它是在开源环境中开发的,所以所有必需的计算包都是免费的。用户友好的界面允许快速修改计算参数,对等时线结果的自动评论提供见解和建议。Pysochron已经用世界各地40条已发表的宇宙成因26Al/10Be埋藏等时线进行了验证,埋藏年龄从~ 5 Ma到~ 180 ka不等。因此,对于宇宙起源核素社区的成员来说,这是一个很有前途的选择,他们寻求一种简单、经济、灵活的解决方案来解决等时线埋藏测年的挑战。
{"title":"Pysochron: A Python-based solution for calculating cosmogenic 26Al/10Be isochron burial ages","authors":"William E. Odom","doi":"10.1016/j.quageo.2025.101675","DOIUrl":"10.1016/j.quageo.2025.101675","url":null,"abstract":"<div><div>Cosmogenic <sup>26</sup>Al/<sup>10</sup>Be isochron burial dating is a powerful tool for dating sediment burial over the past several million years. By measuring in-situ <sup>26</sup>Al and <sup>10</sup>Be in a suite of samples from the same depth in a buried deposit, it is possible to quantify the inventory of cosmogenic nuclides produced after burial, date the burial of shallow sediments, identify sediment reworking, and calculate paleo-erosion rates. While this approach has been used to date materials around the world for over a decade, few published codes exist for performing <sup>26</sup>Al/<sup>10</sup>Be isochron calculations. The isochron calculation options that are available typically rely on numerous files and libraries, rendering modification and troubleshooting difficult. Moreover, the widespread use of proprietary programming languages – and their associated addon packages – can place an additional financial burden on an already costly endeavor.</div><div>Pysochron (<span><span>https://code.usgs.gov/recon/pysochron</span><svg><path></path></svg></span>) provides a solution to these issues. In its base form, it exists as a single script that can be easily modified, upgraded, and shared. Because it was developed in an open-source environment, all required computational packages are available free of charge. A user-friendly interface allows rapid modification of calculation parameters, and an automated commentary on isochron results provides insights and recommendations. Pysochron has been validated with 40 published cosmogenic <sup>26</sup>Al/<sup>10</sup>Be burial isochrons around the world, with burial ages ranging from ∼5 Ma to ∼180 ka. As such, it is a promising option for members of the cosmogenic nuclide community seeking a straightforward, cost-effective, and flexible solution to isochron burial dating challenges.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"89 ","pages":"Article 101675"},"PeriodicalIF":1.7,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144196340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Radiocarbon and luminescence age estimate database for the Willandra Lakes Region World Heritage Area: a reliability-assurance assessment 威兰德拉湖区世界遗产区的放射性碳和发光年龄估算数据库:可靠性保证评估
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-05-14 DOI: 10.1016/j.quageo.2025.101678
Nathan R. Jankowski , Nicola Stern , Elizabeth Foley , Geraldine Jacobsen , Haidee Cadd , Tegan Smith , Willandra Lakes Region Aboriginal Advisory Group
The legacy of geochronological data gathered within the Willandra Lakes Region World Heritage Area over more than 60 years has produced a corpus of age estimates that are now of varying reliability as a result of improvements in laboratory, measurement, analytical, and reporting procedures. A database of all known radiocarbon and luminescence age estimates was compiled and the reliability of each age estimate was ranked from A (most reliable) to C (least reliable). A total of 128 of 269 radiocarbon, 138 of 339 optically stimulated luminescence (OSL), and 0 of 53 thermoluminescence ages were given a Rank A score. Using only Rank A OSL age estimates, a Bayesian modelled chronostratigraphic framework for the Lake Mungo lunette was developed for the Lower Mungo (56.2 ± 3.0 to 37.7 ± 1.0 ka), Upper Mungo (36.4 ± 1.1 to 34.1 ± 1.7 ka), Arumpo (25.1 ± 0.6 to 18.2 ± 0.5 ka), and Zanci (18.2 ± 0.5 to 17.2 ± 0.7 ka) Units. Three lacustrine phases were identified using Rank A radiocarbon ages on otoliths and mussel shell: system-wide high water ∼55–35 ka cal BP (continuing in the north until ∼30 ka cal BP); a short pulse reaching to Lake Outer Arumpo ∼29–24 ka cal BP; and a final saline phase at Lake Mungo ∼21–17 ka cal BP, whilst freshwater conditions were maintained throughout this period at Lake Mulurulu. Only 62 of 143 radiocarbon ages associated directly with archaeological features were given a Rank A score and because they are derived from a restricted range of site types, some with restricted temporal distributions, they are not a reliable basis for documenting the history of land use and occupancy. Continued research is needed to increase the number of reliable age estimates from depositional, palaeohydrological, and archaeological contexts in different landforms to produce a clearer understanding of both palaeoenvironmental change, and the history of land use and occupancy of this enduring cultural landscape.
60多年来,在威兰德拉湖区世界遗产区内收集的地质年代学数据产生了一个年龄估计语料库,由于实验室、测量、分析和报告程序的改进,这些数据现在具有不同的可靠性。一个包含所有已知放射性碳和发光年龄估计的数据库被编译,每个年龄估计的可靠性从A(最可靠)到C(最不可靠)排序。269个放射性碳年龄中有128个,339个光激发发光年龄中有138个,53个热释光年龄中有0个达到A级。仅使用Rank A OSL年龄估计,建立了Mungo湖lunette的下Mungo(56.2±3.0 ~ 37.7±1.0 ka)、上Mungo(36.4±1.1 ~ 34.1±1.7 ka)、Arumpo(25.1±0.6 ~ 18.2±0.5 ka)和Zanci(18.2±0.5 ~ 17.2±0.7 ka)单元的Bayesian模拟年代地层格架。利用耳石和贻贝壳的A级放射性碳年龄确定了三个湖相:全系统高水位~ 55-35 ka cal BP(在北部持续到~ 30 ka cal BP);短脉冲到达外阿仑坡湖~ 29-24 ka cal BP;在蒙哥湖(Lake Mungo)约21-17 ka cal BP为最终的咸水阶段,而在穆鲁鲁鲁湖(Lake Mulurulu)这一时期一直保持着淡水条件。在143个与考古特征直接相关的放射性碳年龄中,只有62个被评为a级,因为它们来自有限范围的遗址类型,其中一些具有有限的时间分布,它们不是记录土地使用和占用历史的可靠基础。需要继续开展研究,从不同地貌的沉积、古水文和考古背景中增加可靠的年龄估计,以更清楚地了解古环境变化以及这一持久文化景观的土地利用和占用历史。
{"title":"Radiocarbon and luminescence age estimate database for the Willandra Lakes Region World Heritage Area: a reliability-assurance assessment","authors":"Nathan R. Jankowski ,&nbsp;Nicola Stern ,&nbsp;Elizabeth Foley ,&nbsp;Geraldine Jacobsen ,&nbsp;Haidee Cadd ,&nbsp;Tegan Smith ,&nbsp;Willandra Lakes Region Aboriginal Advisory Group","doi":"10.1016/j.quageo.2025.101678","DOIUrl":"10.1016/j.quageo.2025.101678","url":null,"abstract":"<div><div>The legacy of geochronological data gathered within the Willandra Lakes Region World Heritage Area over more than 60 years has produced a corpus of age estimates that are now of varying reliability as a result of improvements in laboratory, measurement, analytical, and reporting procedures. A database of all known radiocarbon and luminescence age estimates was compiled and the reliability of each age estimate was ranked from A (most reliable) to C (least reliable). A total of 128 of 269 radiocarbon, 138 of 339 optically stimulated luminescence (OSL), and 0 of 53 thermoluminescence ages were given a Rank A score. Using only Rank A OSL age estimates, a Bayesian modelled chronostratigraphic framework for the Lake Mungo lunette was developed for the Lower Mungo (56.2 ± 3.0 to 37.7 ± 1.0 ka), Upper Mungo (36.4 ± 1.1 to 34.1 ± 1.7 ka), Arumpo (25.1 ± 0.6 to 18.2 ± 0.5 ka), and Zanci (18.2 ± 0.5 to 17.2 ± 0.7 ka) Units. Three lacustrine phases were identified using Rank A radiocarbon ages on otoliths and mussel shell: system-wide high water ∼55–35 ka cal BP (continuing in the north until ∼30 ka cal BP); a short pulse reaching to Lake Outer Arumpo ∼29–24 ka cal BP; and a final saline phase at Lake Mungo ∼21–17 ka cal BP, whilst freshwater conditions were maintained throughout this period at Lake Mulurulu. Only 62 of 143 radiocarbon ages associated directly with archaeological features were given a Rank A score and because they are derived from a restricted range of site types, some with restricted temporal distributions, they are not a reliable basis for documenting the history of land use and occupancy. Continued research is needed to increase the number of reliable age estimates from depositional, palaeohydrological, and archaeological contexts in different landforms to produce a clearer understanding of both palaeoenvironmental change, and the history of land use and occupancy of this enduring cultural landscape.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"89 ","pages":"Article 101678"},"PeriodicalIF":1.7,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144105129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterizing and dating authigenic phosphates from the sedimentary infill of Atapuerca archaeo-paleoanthropological cave sites (Spain) 西班牙Atapuerca古古人类洞穴遗址沉积填充物中自生磷酸盐的特征及年代测定
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-05-13 DOI: 10.1016/j.quageo.2025.101674
I. Campaña , M. Duval , A. Álvaro-Gallo , V. Guilarte , Q. Shao , A.I. Ortega , L.J. Arnold , M. Demuro , J.M. Bermúdez de Castro , E. Carbonell
We present the results of a characterization and dating study of eight authigenic apatite samples collected from various stratigraphic units of three cave sites across the Atapuerca complex, namely Gran Dolina, Galería Complex and Sima del Elefante. Characterization analyses using X-ray diffraction, X-ray fluorescence and Electron Spin Resonance (ESR) spectroscopy have been used to determine the nature and composition of the samples: seven of them are mostly made of hydroxyapatite, while one is composed of crandallite, and all show variable amounts of contamination by calcite and/or sediment. The timing of authigenic apatite formation, which results from the weathering of the limestone in a karstic environment, has been tentatively constrained through a combination of bulk and spatially resolved analyses using ESR and U-series methods. The dating results obtained enable the identification of various formation events during the Middle and Late Pleistocene at each site, around 170–180 ka and 110–120 ka in Gran Dolina, ∼250 ka and ∼40 ka in Galería Complex, and, possibly, ∼360 ka in Sima del Elefante. Importantly, all these ages are significantly younger than the depositional age of the host sediment, thus confirming the post-depositional nature of authigenic apatite. Additionally, the absence of age consistency across sites suggests that they have all experienced independent diagenetic events, which cannot be attributed to the overall karst dynamics of the Sierra de Atapuerca, but should rather be regarded as local processes.
Beyond the dating results, this study provides an overview of the potential and current limitations of ESR and U-series methods applied to Quaternary authigenic apatite. The main complication regarding the ESR method lies in the evaluation of the internal dose rate given the high uranium concentrations measured in the samples, and the absence of a directly related alpha efficiency value for this type of material. Laser ablation U-series analyses also highlight the methodological challenges caused by significant spatial heterogeneity of the U-series data across the apatite samples, which reflects the complexity, non-uniformity and long duration of apatite formation processes around the limestone blocks.
我们介绍了从阿塔普埃尔卡复合体(Gran Dolina复合体、Galería复合体和Sima del Elefante复合体)三个洞穴遗址的不同地层单元收集的8个自生磷灰石样本的表征和定年研究结果。利用x射线衍射、x射线荧光和电子自旋共振(ESR)光谱进行表征分析,确定了样品的性质和组成:其中7个样品主要由羟基磷灰石组成,而1个样品由菱辉石组成,所有样品都显示出不同数量的方解石和/或沉积物污染。自生磷灰石形成的时间是岩溶环境中石灰岩风化的结果,通过使用ESR和u系列方法的体积和空间分辨分析相结合,初步限制了磷灰石形成的时间。所获得的测年结果使每个地点能够确定中更新世和晚更新世的各种形成事件,在Gran Dolina约为170-180 ka和110-120 ka,在Galería复合体约为250 - 40 ka,并且可能在Sima del Elefante约为360 ka。重要的是,所有这些年龄都明显小于寄主沉积物的沉积年龄,从而证实了自生磷灰石的沉积后性质。此外,不同地点的年龄不一致表明它们都经历了独立的成岩事件,这不能归因于阿塔普埃卡山的整体岩溶动力学,而应被视为局部过程。除了测年结果之外,本研究还概述了ESR和u系列方法应用于第四纪自生磷灰石的潜力和目前的局限性。ESR方法的主要复杂之处在于,在样品中测得的铀浓度很高的情况下,对内剂量率的评估,以及对这类材料缺乏直接相关的α效率值。激光烧蚀u系列分析还强调了u系列数据在灰石样品中的显著空间异质性所带来的方法挑战,这反映了石灰石块周围磷灰石形成过程的复杂性、不均匀性和长时间。
{"title":"Characterizing and dating authigenic phosphates from the sedimentary infill of Atapuerca archaeo-paleoanthropological cave sites (Spain)","authors":"I. Campaña ,&nbsp;M. Duval ,&nbsp;A. Álvaro-Gallo ,&nbsp;V. Guilarte ,&nbsp;Q. Shao ,&nbsp;A.I. Ortega ,&nbsp;L.J. Arnold ,&nbsp;M. Demuro ,&nbsp;J.M. Bermúdez de Castro ,&nbsp;E. Carbonell","doi":"10.1016/j.quageo.2025.101674","DOIUrl":"10.1016/j.quageo.2025.101674","url":null,"abstract":"<div><div>We present the results of a characterization and dating study of eight authigenic apatite samples collected from various stratigraphic units of three cave sites across the Atapuerca complex, namely Gran Dolina, Galería Complex and Sima del Elefante. Characterization analyses using X-ray diffraction, X-ray fluorescence and Electron Spin Resonance (ESR) spectroscopy have been used to determine the nature and composition of the samples: seven of them are mostly made of hydroxyapatite, while one is composed of crandallite, and all show variable amounts of contamination by calcite and/or sediment. The timing of authigenic apatite formation, which results from the weathering of the limestone in a karstic environment, has been tentatively constrained through a combination of bulk and spatially resolved analyses using ESR and U-series methods. The dating results obtained enable the identification of various formation events during the Middle and Late Pleistocene at each site, around 170–180 ka and 110–120 ka in Gran Dolina, ∼250 ka and ∼40 ka in Galería Complex, and, possibly, ∼360 ka in Sima del Elefante. Importantly, all these ages are significantly younger than the depositional age of the host sediment, thus confirming the post-depositional nature of authigenic apatite. Additionally, the absence of age consistency across sites suggests that they have all experienced independent diagenetic events, which cannot be attributed to the overall karst dynamics of the Sierra de Atapuerca, but should rather be regarded as local processes.</div><div>Beyond the dating results, this study provides an overview of the potential and current limitations of ESR and U-series methods applied to Quaternary authigenic apatite. The main complication regarding the ESR method lies in the evaluation of the internal dose rate given the high uranium concentrations measured in the samples, and the absence of a directly related alpha efficiency value for this type of material. Laser ablation U-series analyses also highlight the methodological challenges caused by significant spatial heterogeneity of the U-series data across the apatite samples, which reflects the complexity, non-uniformity and long duration of apatite formation processes around the limestone blocks.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"89 ","pages":"Article 101674"},"PeriodicalIF":1.7,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144241540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
New chronological constraints on the history of the Kalahari Group from the Upper Ugab Valley, Namibia 对纳米比亚上乌加布山谷喀拉哈里族历史的新时间限制
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-05-09 DOI: 10.1016/j.quageo.2025.101677
A. Kuzmenko , A. Torfstein , A. Hidy , Y. Geller , S. Vainer , A. Matmon
<div><div>The sedimentary fill of the Kalahari Basin, which extends across several countries in southern and central Africa, records landscape evolution processes and holds archeological evidence of early hominid occupation. Recent studies have demonstrated that the majority of the Kalahari Group sediments were deposited between the Pliocene and the recent present. However, due to limited access to natural outcrops in the flat Kalahari topography, the chronology of the sequence, mostly its earlier part, is not well constrained.</div><div>Here, we set out to study the geologic history of the Ugab drainage system, located in northern Namibia adjacent to the western margin of the Kalahari Basin. The evolution of the upper Ugab drainage system and the adjacent region of the Kalahari Basin were modulated by similar climatic and geologic conditions and processes. Furthermore, the continental water divide at the Ugab catchment headwaters is pushed eastward, further than any ephemeral river draining to the Atlantic Ocean. This geometry raises the possibility of a local drainage divide migration and implies that the upper part of the Ugab drainage system was part of the Kalahari Basin until captured westward to the Atlantic Ocean. Thus, the lower part of the sedimentary section exposed in the upper Ugab Valley may be a remnant of the eroded Kalahari Group. We report new chronological constraints on Kalahari Group units from the “Base Camp” outcrop in the upper Ugab Valley, using cosmogenic <sup>26</sup>Al and <sup>10</sup>Be dating in quartz and U-Th dating of carbonate cements and tufa. The study site is comprised of a ∼20 m thick cemented conglomerate sequence overlain by 20–25 m of carbonate and siliceous duricrusts. We developed a novel multi-stage numerical model for interpreting cosmogenic <sup>26</sup>Al and <sup>10</sup>Be data, following key stages of landscape evolution through a Monte Carlo simulation. This model reconstruction indicates that fluvial deposition of at least 70–100 m of sediments in the upper Ugab Valley had commenced most likely during the Miocene. Following sediment accumulation, surface stability was maintained for a mean most probable duration of 8.86 <sup>+6.82</sup>/<sub>-1.51</sub> Myr, and then followed by a short (<∼300 ka) erosional phase that removed a minimum of 32–53 m of the valley fill. Fine-grained sediments were then deposited during the Middle Pleistocene on top of the erosional surface and cemented by calcite and dolomite at a low gradient valley floor. The beginning of the final incision through the duricrust layer and the subsequent emergence of ground water springs are indicated by tufa deposits dated to 58.3 <sup>+22.2</sup>/<sub>-17.5</sub> ka. Quartzite samples from the re-exposed top of the conglomerate show simple cosmogenic exposure ages that range between 15.8 and 39.4 ka. Though the model suggests a gradual exposure, with at least two different incision rates over time, the overall exposure time i
喀拉哈里盆地的沉积填充物横跨非洲南部和中部的几个国家,记录了景观演变过程,并保存了早期人类居住的考古证据。最近的研究表明,喀拉哈里群的大部分沉积物沉积于上新世到近代之间。然而,由于喀拉哈里平原上的自然露头有限,该层序的年代学,主要是其早期部分,并没有得到很好的约束。在这里,我们开始研究Ugab排水系统的地质历史,它位于纳米比亚北部,毗邻喀拉哈里盆地的西部边缘。乌加布上游流域系统和毗邻的喀拉哈里盆地的演化受到相似的气候和地质条件和过程的调节。此外,乌加布集水区源头的大陆分水岭向东推进,比任何流入大西洋的短暂河流都要远。这种几何形状提出了局部排水分界线迁移的可能性,并暗示乌加布排水系统的上部是喀拉哈里盆地的一部分,直到向西进入大西洋。因此,乌加布河谷上部暴露的沉积剖面下部可能是喀拉哈里群侵蚀的残余物。我们利用石英的宇宙成因26Al和10Be测年以及碳酸盐胶结物和凝灰岩的U-Th测年,报道了Ugab山谷上“基地营”露头中卡拉哈里群单元的新年代学约束。研究地点由~ 20米厚的胶结砾岩层序组成,上面覆盖着20 - 25米的碳酸盐和硅质硬壳。我们开发了一种新的多阶段数值模型,用于解释宇宙成因26Al和10Be数据,通过蒙特卡罗模拟跟踪景观演化的关键阶段。该模型重建表明,Ugab河谷上游至少70-100米的沉积物的河流沉积很可能在中新世开始。在沉积物堆积之后,地表稳定维持了8.86 +6.82/-1.51 Myr的平均最可能持续时间,然后是一个短暂的(< ~ 300 ka)侵蚀阶段,该阶段至少移走了32-53 m的山谷填充物。在中更新世期间,细粒沉积物沉积在侵蚀面顶部,并在低梯度谷底被方解石和白云石胶结。凝灰岩沉积的年代为58.3 +22.2/-17.5 ka,表明了硬壳层最终切口的开始和地下水泉水的出现。砾岩顶部重新暴露的石英岩样品显示简单的宇宙成因暴露年龄在15.8 ~ 39.4 ka之间。虽然该模型表明,随着时间的推移,至少有两种不同的切割速率,逐渐暴露,但总体暴露时间在晚更新世。可能发生在中新世的沉积,以及第四纪早期基底粗粒砾岩的移除,都表明高能河流系统的存在,表明相对于现在的气候,更大的起伏和可能更湿润的气候条件。细粒硬壳经两个沉积单元向低能沉积和向高能切割转变,表明乌加布河谷上游可能存在局部排水重排和分区迁移。
{"title":"New chronological constraints on the history of the Kalahari Group from the Upper Ugab Valley, Namibia","authors":"A. Kuzmenko ,&nbsp;A. Torfstein ,&nbsp;A. Hidy ,&nbsp;Y. Geller ,&nbsp;S. Vainer ,&nbsp;A. Matmon","doi":"10.1016/j.quageo.2025.101677","DOIUrl":"10.1016/j.quageo.2025.101677","url":null,"abstract":"&lt;div&gt;&lt;div&gt;The sedimentary fill of the Kalahari Basin, which extends across several countries in southern and central Africa, records landscape evolution processes and holds archeological evidence of early hominid occupation. Recent studies have demonstrated that the majority of the Kalahari Group sediments were deposited between the Pliocene and the recent present. However, due to limited access to natural outcrops in the flat Kalahari topography, the chronology of the sequence, mostly its earlier part, is not well constrained.&lt;/div&gt;&lt;div&gt;Here, we set out to study the geologic history of the Ugab drainage system, located in northern Namibia adjacent to the western margin of the Kalahari Basin. The evolution of the upper Ugab drainage system and the adjacent region of the Kalahari Basin were modulated by similar climatic and geologic conditions and processes. Furthermore, the continental water divide at the Ugab catchment headwaters is pushed eastward, further than any ephemeral river draining to the Atlantic Ocean. This geometry raises the possibility of a local drainage divide migration and implies that the upper part of the Ugab drainage system was part of the Kalahari Basin until captured westward to the Atlantic Ocean. Thus, the lower part of the sedimentary section exposed in the upper Ugab Valley may be a remnant of the eroded Kalahari Group. We report new chronological constraints on Kalahari Group units from the “Base Camp” outcrop in the upper Ugab Valley, using cosmogenic &lt;sup&gt;26&lt;/sup&gt;Al and &lt;sup&gt;10&lt;/sup&gt;Be dating in quartz and U-Th dating of carbonate cements and tufa. The study site is comprised of a ∼20 m thick cemented conglomerate sequence overlain by 20–25 m of carbonate and siliceous duricrusts. We developed a novel multi-stage numerical model for interpreting cosmogenic &lt;sup&gt;26&lt;/sup&gt;Al and &lt;sup&gt;10&lt;/sup&gt;Be data, following key stages of landscape evolution through a Monte Carlo simulation. This model reconstruction indicates that fluvial deposition of at least 70–100 m of sediments in the upper Ugab Valley had commenced most likely during the Miocene. Following sediment accumulation, surface stability was maintained for a mean most probable duration of 8.86 &lt;sup&gt;+6.82&lt;/sup&gt;/&lt;sub&gt;-1.51&lt;/sub&gt; Myr, and then followed by a short (&lt;∼300 ka) erosional phase that removed a minimum of 32–53 m of the valley fill. Fine-grained sediments were then deposited during the Middle Pleistocene on top of the erosional surface and cemented by calcite and dolomite at a low gradient valley floor. The beginning of the final incision through the duricrust layer and the subsequent emergence of ground water springs are indicated by tufa deposits dated to 58.3 &lt;sup&gt;+22.2&lt;/sup&gt;/&lt;sub&gt;-17.5&lt;/sub&gt; ka. Quartzite samples from the re-exposed top of the conglomerate show simple cosmogenic exposure ages that range between 15.8 and 39.4 ka. Though the model suggests a gradual exposure, with at least two different incision rates over time, the overall exposure time i","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"89 ","pages":"Article 101677"},"PeriodicalIF":1.7,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143936184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessing the potential of a modified post-isothermal IRSL (pIt-IR) protocol to circumvent the problems posed by anomalous fading in polymineral fine grains 评估改进的等温后IRSL (pIt-IR)协议的潜力,以避免多矿物细颗粒中异常褪色所带来的问题
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-05-05 DOI: 10.1016/j.quageo.2025.101676
Nina Ataee, Helen M. Roberts, Geoff A.T. Duller
Attempts to find a ‘non-fading’ infrared stimulated luminescence (IRSL) signal have been ongoing in the past two decades, due to complications regarding measurement and application of anomalous fading as well as higher age uncertainty introduced by fading correction. In this research, the potential of the post-isothermal IRSL (pIt-IR) protocol to generate ages without the need for fading correction is investigated. Polymineral fine grain samples were collected from a sediment core from Lake Chew Bahir in Ethiopia which is supported by independent age control. The equivalent dose (De) values determined using the pIR50IR225 pIt-IR protocol are in agreement with the fading corrected pIRIR225 De values for the upper ∼40 mcd of the core (∼200 Gy), below which the pIR50IR225 pIt-IR De values underestimate the fading corrected pIRIR225 De values. This underestimation appears to be a consequence of the IR50 signal approaching field saturation since pIt-IR De determination depends on both IR50 and pIRIR225 signals. Increasing the measurement temperature of the first IR signal in the pIRIR225 pIt-IR protocol (from 50 to 150 °C, i.e. pIR150IR225 pIt-IR) appears to extend the upper limit of the pIt-IR protocol by producing De values that are consistent both with the fading corrected pIRIR225 De values (within 1σ uncertainties), and also in agreement with the ages of two known-age tephra (within 2σ uncertainties) down to ∼90 mcd of the core (∼450 Gy, ∼180 ka). This demonstrates that the pIt-IR protocol is capable of producing De values and ages that do not require fading correction as long as the first IRSL signal in the pIRIR225 pIt-IR protocol is not in field saturation. However, verification of the accuracy of the De values and ages generated using the pIt-IR protocol is provided by comparison of the fading corrected IR50 and corrected pIRIR225 De values/ages, which could otherwise be collected directly through more conventional pIRIR protocols that are shorter in duration than pIt-IR measurement sequences. This raises questions regarding the benefit of using a pIt-IR protocol rather than a pIRIR protocol for dating, the primary advantage of which remains circumvention of the problems posed by anomalous fading for sediments that are younger than the field saturation values of the first IR signal measured in a pIt-IR protocol.
在过去的二十年里,由于异常衰落的测量和应用以及衰落校正带来的更高年龄不确定性的复杂性,寻找“非衰落”红外激发发光(IRSL)信号的尝试一直在进行。在这项研究中,研究了等温后IRSL (pIt-IR)协议在不需要衰落校正的情况下产生年龄的潜力。从埃塞俄比亚的Chew Bahir湖沉积物岩心中采集了多矿物细粒样品,并进行了独立的年龄控制。使用pIR50IR225 pIt-IR方案确定的等效剂量(De)值与核心上~ 40 mcd (~ 200 Gy)的衰减校正pIRIR225 De值一致,在此以下,pIR50IR225 pIt-IR De值低估了衰减校正pIRIR225 De值。这种低估似乎是IR50信号接近场饱和的结果,因为pIt-IR De的确定取决于IR50和pIRIR225信号。提高pIRIR225 pIt-IR协议中第一个红外信号的测量温度(从50°C到150°C,即pIR150IR225 pIt-IR)似乎可以通过产生与衰减校正后的pIRIR225 De值(在1σ不确定度内)一致的De值,并与两个已知年龄的tephra(在2σ不确定度内)的年龄一致,从而扩展pIt-IR协议的上限,直至核心的~ 90 mcd (~ 450 Gy, ~ 180 ka)。这表明,只要pIRIR225 pIt-IR协议中的第一个IRSL信号不处于场饱和状态,pIt-IR协议就能够产生不需要衰落校正的De值和年龄。然而,通过比较衰落校正后的IR50和校正后的pIRIR225 De值/年龄,可以验证使用pIt-IR协议生成的De值和年龄的准确性,否则可以通过比pIt-IR测量序列更短的更传统的pIRIR协议直接收集De值/年龄。这就提出了关于使用pIt-IR协议而不是pIRIR协议进行测年的好处的问题,其主要优点仍然是避免了沉积物异常褪色所带来的问题,这些沉积物比pIt-IR协议中测量的第一个红外信号的现场饱和值更年轻。
{"title":"Assessing the potential of a modified post-isothermal IRSL (pIt-IR) protocol to circumvent the problems posed by anomalous fading in polymineral fine grains","authors":"Nina Ataee,&nbsp;Helen M. Roberts,&nbsp;Geoff A.T. Duller","doi":"10.1016/j.quageo.2025.101676","DOIUrl":"10.1016/j.quageo.2025.101676","url":null,"abstract":"<div><div>Attempts to find a ‘non-fading’ infrared stimulated luminescence (IRSL) signal have been ongoing in the past two decades, due to complications regarding measurement and application of anomalous fading as well as higher age uncertainty introduced by fading correction. In this research, the potential of the post-isothermal IRSL (pIt-IR) protocol to generate ages without the need for fading correction is investigated. Polymineral fine grain samples were collected from a sediment core from Lake Chew Bahir in Ethiopia which is supported by independent age control. The equivalent dose (D<sub>e</sub>) values determined using the pIR<sub>50</sub>IR<sub>225</sub> pIt-IR protocol are in agreement with the fading corrected pIRIR<sub>225</sub> D<sub>e</sub> values for the upper ∼40 mcd of the core (∼200 Gy), below which the pIR<sub>50</sub>IR<sub>225</sub> pIt-IR D<sub>e</sub> values underestimate the fading corrected pIRIR<sub>225</sub> D<sub>e</sub> values. This underestimation appears to be a consequence of the IR<sub>50</sub> signal approaching field saturation since pIt-IR D<sub>e</sub> determination depends on both IR<sub>50</sub> and pIRIR<sub>225</sub> signals. Increasing the measurement temperature of the first IR signal in the pIRIR<sub>225</sub> pIt-IR protocol (from 50 to 150 °C, i.e. pIR<sub>150</sub>IR<sub>225</sub> pIt-IR) appears to extend the upper limit of the pIt-IR protocol by producing D<sub>e</sub> values that are consistent both with the fading corrected pIRIR<sub>225</sub> D<sub>e</sub> values (within 1σ uncertainties), and also in agreement with the ages of two known-age tephra (within 2σ uncertainties) down to ∼90 mcd of the core (∼450 Gy, ∼180 ka). This demonstrates that the pIt-IR protocol is capable of producing D<sub>e</sub> values and ages that do not require fading correction as long as the first IRSL signal in the pIRIR<sub>225</sub> pIt-IR protocol is not in field saturation. However, verification of the accuracy of the D<sub>e</sub> values and ages generated using the pIt-IR protocol is provided by comparison of the fading corrected IR<sub>50</sub> and corrected pIRIR<sub>225</sub> D<sub>e</sub> values/ages, which could otherwise be collected directly through more conventional pIRIR protocols that are shorter in duration than pIt-IR measurement sequences. This raises questions regarding the benefit of using a pIt-IR protocol rather than a pIRIR protocol for dating, the primary advantage of which remains circumvention of the problems posed by anomalous fading for sediments that are younger than the field saturation values of the first IR signal measured in a pIt-IR protocol.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"88 ","pages":"Article 101676"},"PeriodicalIF":1.7,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143921853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Determining equivalent dose for optically stimulated luminescence (OSL) dating with physically meaningful dose response curves 用物理上有意义的剂量响应曲线确定光激发发光(OSL)测年的等效剂量
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-05-05 DOI: 10.1016/j.quageo.2025.101671
George Kitis , Georgios S. Polymeris , Jun Peng
Non-linear dose–response curves are common in many thermoluminescence (TL) and optically stimulated luminescence (OSL) dosimetric applications, especially in TL and OSL dating. In most cases, these calibration curves are characterized by saturating exponential expressions; consequently, the accuracy of equivalent dose De is highly dependent on the specific position along the saturating exponential curve. In the present work, accuracy is estimated through numerical simulations using novel analytical dose–response expressions based on the Lambert W function. These simulations are subsequently extrapolated to experimental OSL dose–response curves obtained from dating experiments. The De was estimated by solving the new dose–response expressions and the error σDe, arising from the uncertainty of the natural signal, was evaluated through analytical expressions derived using error propagation theory. Finally, an analytical expression was derived for the derivative of the dose–response function, and the accuracy of De correlated with the derivative at the point corresponding to the unknown dose. The newly derived analytical expressions, based on physical models, enable the determination of De in both linear and non-linear regions of the dose response curves (DRC). This model offers a significant advantage over other existing empirical expressions, whose results lack theoretical justification. The present study offers a general and objective method to identify samples potentially affected by De saturation, through direct evaluation of the derivative of the DRC.
非线性剂量响应曲线在许多热释光和光激发发光剂量学应用中很常见,特别是在热释光和光激发发光测年中。在大多数情况下,这些校准曲线的特征是饱和指数表达式;因此,当量剂量De的精度高度依赖于饱和指数曲线上的特定位置。在目前的工作中,通过使用基于Lambert W函数的新的解析剂量响应表达式的数值模拟来估计精度。这些模拟结果随后被外推到由测年实验获得的实验OSL剂量-响应曲线。通过求解新的剂量响应表达式估计了De,并利用误差传播理论导出的解析表达式对自然信号的不确定性引起的误差σDe进行了计算。最后,导出了剂量-响应函数导数的解析表达式,在未知剂量对应的点上,De的精度与导数相关。新导出的解析表达式,基于物理模型,可以在剂量响应曲线(DRC)的线性和非线性区域确定De。该模型比其他现有的经验表达式具有显著的优势,这些表达式的结果缺乏理论依据。本研究通过直接评估DRC的衍生物,提供了一种通用和客观的方法来识别可能受De饱和度影响的样品。
{"title":"Determining equivalent dose for optically stimulated luminescence (OSL) dating with physically meaningful dose response curves","authors":"George Kitis ,&nbsp;Georgios S. Polymeris ,&nbsp;Jun Peng","doi":"10.1016/j.quageo.2025.101671","DOIUrl":"10.1016/j.quageo.2025.101671","url":null,"abstract":"<div><div>Non-linear dose–response curves are common in many thermoluminescence (TL) and optically stimulated luminescence (OSL) dosimetric applications, especially in TL and OSL dating. In most cases, these calibration curves are characterized by saturating exponential expressions; consequently, the accuracy of equivalent dose <span><math><msub><mrow><mi>D</mi></mrow><mrow><mi>e</mi></mrow></msub></math></span> is highly dependent on the specific position along the saturating exponential curve. In the present work, accuracy is estimated through numerical simulations using novel analytical dose–response expressions based on the Lambert <span><math><mi>W</mi></math></span> function. These simulations are subsequently extrapolated to experimental OSL dose–response curves obtained from dating experiments. The <span><math><msub><mrow><mi>D</mi></mrow><mrow><mi>e</mi></mrow></msub></math></span> was estimated by solving the new dose–response expressions and the error <span><math><msub><mrow><mi>σ</mi></mrow><mrow><msub><mrow><mi>D</mi></mrow><mrow><mi>e</mi></mrow></msub></mrow></msub></math></span>, arising from the uncertainty of the natural signal, was evaluated through analytical expressions derived using error propagation theory. Finally, an analytical expression was derived for the derivative of the dose–response function, and the accuracy of <span><math><msub><mrow><mi>D</mi></mrow><mrow><mi>e</mi></mrow></msub></math></span> correlated with the derivative at the point corresponding to the unknown dose. The newly derived analytical expressions, based on physical models, enable the determination of <span><math><msub><mrow><mi>D</mi></mrow><mrow><mi>e</mi></mrow></msub></math></span> in both linear and non-linear regions of the dose response curves (DRC). This model offers a significant advantage over other existing empirical expressions, whose results lack theoretical justification. The present study offers a general and objective method to identify samples potentially affected by <span><math><msub><mrow><mi>D</mi></mrow><mrow><mi>e</mi></mrow></msub></math></span> saturation, through direct evaluation of the derivative of the DRC.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"88 ","pages":"Article 101671"},"PeriodicalIF":1.7,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143911735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Testing micro-aliquot SGC and LnTn methods for age determination up to 780 ka using coarse K-feldspar grains from Nihewan Basin, northern China 利用泥河湾盆地粗钾长石颗粒,对微等分SGC和LnTn法测定780ka年龄进行了试验
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-05-01 DOI: 10.1016/j.quageo.2025.101673
Shengxia Xu , Xue Rui , Yujie Guo , Bo Li
The Nihewan Basin in northern China is a key region for the study of Paleolithic archaeology of East Asia, due to the discovery of Paleolithic sites with ages spanning the entire Pleistocene. However, many Paleolithic sites assigned to the Middle to Late Pleistocene are still not dated or poorly dated, which affects our understanding the stone tool technology evolution in the Nihewan Basin. The post-infrared infrared stimulated luminescence (pIRIR) signal from potassium-rich feldspar grains can be applied to date Middle to Late Pleistocene sediments, as this signal has significantly lower fading rate. In this study, to establish a robust chronological framework of the Nihewan Paleolithic sites more effectively, a micro-aliquot (MA) standardised growth curve (SGC) was constructed for pIRIR dating. The established MA SGC was tested for sediments up to 780 ka, and the obtained MA SGC De results were compared with those from single-aliquot (SA) measurement. Results from a number of tests suggest that the disagreement between MA and SA results is due to a small amount of anomalous fading in dimmer grains, which can be corrected by Tn threshold. By projecting the weighted mean Ln/Tn ratios (after Tn threshold correction) onto the MA SGC, the obtained pIRIR ages increase from top to bottom, and the sample from just above the B/M boundary (∼780 ka) yielded an age of 725117+179 ka, which is consistent with the expected age. Our result suggested that the MA SGC method can reduce instrument time and has the potential to provide reliable age up to ∼700–800 ka in this region.
中国北方泥河湾盆地是东亚旧石器时代考古研究的重点地区,其旧石器时代遗址的发现跨越了整个更新世。然而,许多被划为中更新世至晚更新世的旧石器时代遗址仍然没有定年或定年不准确,这影响了我们对泥河湾盆地石器技术演变的认识。富钾长石颗粒的红外后红外激发发光(pIRIR)信号具有明显的低衰减速率,可用于中晚更新世沉积物。为了更有效地建立泥河湾旧石器时代遗址的可靠年代框架,本研究构建了微等分(MA)标准化生长曲线(SGC)用于pIRIR测年。建立的MA SGC对780 ka沉积物进行了测试,并将所得的MA SGC De结果与单等分(SA)测量结果进行了比较。大量试验结果表明,MA和SA结果之间的差异是由于较暗的晶粒中有少量的异常衰落,这可以通过Tn阈值来纠正。通过将加权平均Ln/Tn比值(Tn阈值校正后)投影到MA SGC上,得到的pIRIR年龄从上到下递增,而刚好在B/M边界(~ 780 ka)上方的样品的年龄为725−117+179 ka,与预期年龄一致。我们的结果表明,MA SGC方法可以减少仪器时间,并有可能在该地区提供高达~ 700-800 ka的可靠年龄。
{"title":"Testing micro-aliquot SGC and LnTn methods for age determination up to 780 ka using coarse K-feldspar grains from Nihewan Basin, northern China","authors":"Shengxia Xu ,&nbsp;Xue Rui ,&nbsp;Yujie Guo ,&nbsp;Bo Li","doi":"10.1016/j.quageo.2025.101673","DOIUrl":"10.1016/j.quageo.2025.101673","url":null,"abstract":"<div><div>The Nihewan Basin in northern China is a key region for the study of Paleolithic archaeology of East Asia, due to the discovery of Paleolithic sites with ages spanning the entire Pleistocene. However, many Paleolithic sites assigned to the Middle to Late Pleistocene are still not dated or poorly dated, which affects our understanding the stone tool technology evolution in the Nihewan Basin. The post-infrared infrared stimulated luminescence (pIRIR) signal from potassium-rich feldspar grains can be applied to date Middle to Late Pleistocene sediments, as this signal has significantly lower fading rate. In this study, to establish a robust chronological framework of the Nihewan Paleolithic sites more effectively, a micro-aliquot (MA) standardised growth curve (SGC) was constructed for pIRIR dating. The established MA SGC was tested for sediments up to 780 ka, and the obtained MA SGC D<sub>e</sub> results were compared with those from single-aliquot (SA) measurement. Results from a number of tests suggest that the disagreement between MA and SA results is due to a small amount of anomalous fading in dimmer grains, which can be corrected by T<sub>n</sub> threshold. By projecting the weighted mean L<sub>n</sub>/T<sub>n</sub> ratios (after T<sub>n</sub> threshold correction) onto the MA SGC, the obtained pIRIR ages increase from top to bottom, and the sample from just above the B/M boundary (∼780 ka) yielded an age of <span><math><mrow><msubsup><mn>725</mn><mrow><mo>−</mo><mn>117</mn></mrow><mrow><mo>+</mo><mn>179</mn></mrow></msubsup></mrow></math></span> ka, which is consistent with the expected age. Our result suggested that the MA SGC method can reduce instrument time and has the potential to provide reliable age up to ∼700–800 ka in this region.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"88 ","pages":"Article 101673"},"PeriodicalIF":1.7,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143928946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study the effect of irradiation, optical bleaching and heating on the thermal stability of OSL signals of quartz from dune sands in northern China 研究了辐照、光学漂白和加热对中国北方沙丘砂石英光释光信号热稳定性的影响
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-04-29 DOI: 10.1016/j.quageo.2025.101672
Zhijun Gong , Hong Yan , Ming Luo
Variability in the thermal stability of quartz OSL signals has been observed for Late Quaternary sediments in different geographic setting in China. In this study, quartz grains were extracted from the Taklimakan Desert and the Hunshandake sandy land and the thermal stability of their quartz OSL signals were further investigated. Firstly, quartz aliquots of Taklimakan Desert were measured by using pulse annealing tests. It was found that the quartz from the Taklimakan Desert exhibited highly variable pulse annealing curves, showing the significant differences in the thermal stability of quartz OSL signals. Secondly, laboratory irradiation, optical bleaching and heating experiments were designed to test their effects on the thermal stability of quartz OSL signals. To compare the thermal stability among different quartz aliquots more efficiently, the thermal remnant ratio (TRR) was used as the proxy for the thermal stability, which was measured by using the ratios of the remnant OSL signals measured after cut-heat to 280 °C to those measured after cut-heat to 240 °C in the simplified pulse annealing tests. For the quartz samples from the Taklimakan Desert, it was found that the operated cycles of dosing and bleaching have relatively insignificant effects on the TRR values of quartz OSL. For the effect of heating on TRR value, it is dependent on samples. When the initial TRR value of quartz OSL is significantly less than 0.9, heating to high temperatures (e.g. ≥400 °C) has significant effect on the TRR value of quartz OSL. When the initial TRR value of quartz OSL is equal to or larger than 0.9, the effect of heating on the TRR value is not obvious. Such results suggest that different heating history of quartz plays an important role in the thermal stability of the quartz OSL signal. Thirdly, the TRR values of quartz OSL of Taklimakan Desert were compared with those of Hunshandake sandy land. For the Taklimakan Desert, it was found that only a part of the quartz grains exhibit TRR values equal to or larger than 0.9. In comparison, the TRR values for the majority of quartz grains from the Hunshandake sandy land are equal to or larger than 0.9. Such results demonstrate the different heating histories of quartz grains between the Taklimakan Desert and the Hunshandake sandy land, i.e. only a part of quartz grains from the Taklimakan Desert suffered from high temperature heating, while the majority of quartz grains from the Hunshandake sandy land suffered from high temperature heating during geological past. The different heating histories of quartz grains between the Taklimakan Desert and the Hunshandake sandy land are consistent with the different geological settings of the two regions. Our studies suggest that the proxy (i.e. TRR) of the thermal stability of quartz OSL has advantages over luminescence sensitivity for distinguishing the provenance of sediments with different heating histories.
研究了中国不同地理环境下晚第四纪沉积物中石英OSL信号热稳定性的变化。本文以塔克拉玛干沙漠和浑善达克沙地为研究对象,对石英OSL信号的热稳定性进行了研究。首先,采用脉冲退火法测定了塔克拉玛干沙漠的石英等分。研究发现,塔克拉玛干沙漠石英的脉冲退火曲线变化很大,表明石英OSL信号的热稳定性存在显著差异。其次,设计了实验室辐照、光学漂白和加热实验,测试了它们对石英OSL信号热稳定性的影响。为了更有效地比较不同石英组分之间的热稳定性,采用热残余比(TRR)作为热稳定性的代表,用简化脉冲退火试验中切热至280°C后残余OSL信号与切热至240°C后残余OSL信号的比值来测量热残余比。对于塔克拉玛干沙漠石英样品,投加和漂白操作周期对石英OSL TRR值的影响相对不显著。加热对TRR值的影响与样品有关。当石英OSL的初始TRR值显著小于0.9时,加热至高温(如≥400℃)对石英OSL的TRR值有显著影响。当石英OSL的初始TRR值等于或大于0.9时,加热对TRR值的影响不明显。这些结果表明,石英的不同加热历史对石英OSL信号的热稳定性起着重要作用。第三,比较塔克拉玛干沙漠与浑善达克沙地石英OSL的TRR值。对于塔克拉玛干沙漠,只有部分石英颗粒的TRR值等于或大于0.9。浑善达克沙地大部分石英颗粒的TRR值均大于等于0.9。这些结果表明,塔克拉玛干沙漠和浑山达克沙地的石英颗粒的加热历史不同,即只有部分塔克拉玛干沙漠的石英颗粒经历了高温加热,而浑山达克沙地的大部分石英颗粒在地质历史中经历了高温加热。塔克拉玛干沙漠和浑善达克沙地石英颗粒的不同加热史与两地区不同的地质背景相一致。我们的研究表明,石英OSL热稳定性指标(即TRR)在区分不同加热历史的沉积物物源方面比发光灵敏度更有优势。
{"title":"Study the effect of irradiation, optical bleaching and heating on the thermal stability of OSL signals of quartz from dune sands in northern China","authors":"Zhijun Gong ,&nbsp;Hong Yan ,&nbsp;Ming Luo","doi":"10.1016/j.quageo.2025.101672","DOIUrl":"10.1016/j.quageo.2025.101672","url":null,"abstract":"<div><div>Variability in the thermal stability of quartz OSL signals has been observed for Late Quaternary sediments in different geographic setting in China. In this study, quartz grains were extracted from the Taklimakan Desert and the Hunshandake sandy land and the thermal stability of their quartz OSL signals were further investigated. Firstly, quartz aliquots of Taklimakan Desert were measured by using pulse annealing tests. It was found that the quartz from the Taklimakan Desert exhibited highly variable pulse annealing curves, showing the significant differences in the thermal stability of quartz OSL signals. Secondly, laboratory irradiation, optical bleaching and heating experiments were designed to test their effects on the thermal stability of quartz OSL signals. To compare the thermal stability among different quartz aliquots more efficiently, the thermal remnant ratio (TRR) was used as the proxy for the thermal stability, which was measured by using the ratios of the remnant OSL signals measured after cut-heat to 280 °C to those measured after cut-heat to 240 °C in the simplified pulse annealing tests. For the quartz samples from the Taklimakan Desert, it was found that the operated cycles of dosing and bleaching have relatively insignificant effects on the TRR values of quartz OSL. For the effect of heating on TRR value, it is dependent on samples. When the initial TRR value of quartz OSL is significantly less than 0.9, heating to high temperatures (e.g. ≥400 °C) has significant effect on the TRR value of quartz OSL. When the initial TRR value of quartz OSL is equal to or larger than 0.9, the effect of heating on the TRR value is not obvious. Such results suggest that different heating history of quartz plays an important role in the thermal stability of the quartz OSL signal. Thirdly, the TRR values of quartz OSL of Taklimakan Desert were compared with those of Hunshandake sandy land. For the Taklimakan Desert, it was found that only a part of the quartz grains exhibit TRR values equal to or larger than 0.9. In comparison, the TRR values for the majority of quartz grains from the Hunshandake sandy land are equal to or larger than 0.9. Such results demonstrate the different heating histories of quartz grains between the Taklimakan Desert and the Hunshandake sandy land, i.e. only a part of quartz grains from the Taklimakan Desert suffered from high temperature heating, while the majority of quartz grains from the Hunshandake sandy land suffered from high temperature heating during geological past. The different heating histories of quartz grains between the Taklimakan Desert and the Hunshandake sandy land are consistent with the different geological settings of the two regions. Our studies suggest that the proxy (i.e. TRR) of the thermal stability of quartz OSL has advantages over luminescence sensitivity for distinguishing the provenance of sediments with different heating histories.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"88 ","pages":"Article 101672"},"PeriodicalIF":1.7,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143895516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An evaluation of two cryptotephra quantification methods applied on lacustrine sediments with distant Laacher See tephra fallout 两种隐绦虫定量方法在湖泊沉积物中应用的评价
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-04-18 DOI: 10.1016/j.quageo.2025.101670
V. Meier , T. Hrstka , J. Ohser , J. Siquans , B. Brandstätter , G. Kletetschka , D. Vondrák
Detailed quantification of volcanic glass is crucial for improving the resolution of paleoenvironmental reconstructions and facilitating more accurate comparisons between distant sedimentary cryptotephra records. Here we present and evaluate two methods for the quantification of cryptotephra, shown on lake sediments from a site with distant Laacher See tephra fallout. Our methods initiate with delineating the extent and distribution of the cryptotephra layer within the sediments, accomplished through the integration of X-ray fluorescence (XRF) and computed tomography (medical- and μ-CT). The first quantification method involves the well-established process of shard extraction through stepwise density separation, followed by improved and statistically evaluated quantification introducing a new standardized marker. While the method itself is used widely for many years among cryptotephra researchers, we demonstrate how the new marker improves its precision for cryptotephra quantification, providing a robust, straightforward laboratory-based technique. Additionally, we introduce an innovative, software-based method that combines an SEM-based automated mineralogy analysis on thin sections with customized image analysis, which allows to study the area fraction of the glass phase, its depth-dependent variation, particle concentration with a focus on clustering behavior, depth-dependent particle count, total particle count, and particle size distribution within the glass phase. The significance of both methods lies in the efficiency and precision of cryptotephra quantification, enabling a deeper understanding of shard concentration and distribution. This study emphasizes the methodological innovations, offering improved tools for cryptotephra quantification, without focusing on detailed application-based analyses.
火山玻璃的详细量化对于提高古环境重建的分辨率和促进遥远沉积隐层记录之间更准确的比较至关重要。在这里,我们提出并评估了两种量化隐绦虫的方法,这些隐绦虫显示在遥远的Laacher地区的湖泊沉积物上。我们的方法首先通过x射线荧光(XRF)和计算机断层扫描(医学和μ ct)的整合来描绘沉积物中隐球菌层的范围和分布。第一种定量方法包括通过逐步密度分离的碎片提取过程,然后是引入新的标准化标记物的改进和统计评估定量。虽然该方法本身在隐隐体研究人员中广泛使用了多年,但我们展示了新的标记物如何提高其对隐隐体定量的精度,提供了一种强大的,直接的基于实验室的技术。此外,我们还引入了一种创新的基于软件的方法,该方法将基于sem的薄片自动矿物学分析与定制图像分析相结合,可以研究玻璃相的面积分数,其深度相关的变化,专注于聚类行为的颗粒浓度,深度相关的颗粒计数,总颗粒计数和玻璃相内的粒度分布。两种方法的意义在于隐隐phra量化的效率和精度,可以更深入地了解碎片的浓度和分布。本研究强调方法上的创新,为隐球菌量化提供改进的工具,而不是专注于基于应用的详细分析。
{"title":"An evaluation of two cryptotephra quantification methods applied on lacustrine sediments with distant Laacher See tephra fallout","authors":"V. Meier ,&nbsp;T. Hrstka ,&nbsp;J. Ohser ,&nbsp;J. Siquans ,&nbsp;B. Brandstätter ,&nbsp;G. Kletetschka ,&nbsp;D. Vondrák","doi":"10.1016/j.quageo.2025.101670","DOIUrl":"10.1016/j.quageo.2025.101670","url":null,"abstract":"<div><div>Detailed quantification of volcanic glass is crucial for improving the resolution of paleoenvironmental reconstructions and facilitating more accurate comparisons between distant sedimentary cryptotephra records. Here we present and evaluate two methods for the quantification of cryptotephra, shown on lake sediments from a site with distant Laacher See tephra fallout. Our methods initiate with delineating the extent and distribution of the cryptotephra layer within the sediments, accomplished through the integration of X-ray fluorescence (XRF) and computed tomography (medical- and μ-CT). The first quantification method involves the well-established process of shard extraction through stepwise density separation, followed by improved and statistically evaluated quantification introducing a new standardized marker. While the method itself is used widely for many years among cryptotephra researchers, we demonstrate how the new marker improves its precision for cryptotephra quantification, providing a robust, straightforward laboratory-based technique. Additionally, we introduce an innovative, software-based method that combines an SEM-based automated mineralogy analysis on thin sections with customized image analysis, which allows to study the area fraction of the glass phase, its depth-dependent variation, particle concentration with a focus on clustering behavior, depth-dependent particle count, total particle count, and particle size distribution within the glass phase. The significance of both methods lies in the efficiency and precision of cryptotephra quantification, enabling a deeper understanding of shard concentration and distribution. This study emphasizes the methodological innovations, offering improved tools for cryptotephra quantification, without focusing on detailed application-based analyses.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"88 ","pages":"Article 101670"},"PeriodicalIF":1.7,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143868298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dating earthworks with luminescence: Insights from the medieval ringfort of Den Burg, Texel (the Netherlands) 用发光测定土方工程的年代:来自特塞尔(荷兰)登堡中世纪环堡的见解
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2025-04-12 DOI: 10.1016/j.quageo.2025.101669
Roy van Beek , Elizabeth L. Chamberlain , Kirsten de Nooijer , Sander Gerritsen , Michiel Bartels , Jakob Wallinga
Ancient human-made earthworks such as mounds, middens, levees, raised or terraced fields, enclosures and forts are omnipresent in many areas across the globe. They may offer rich and important information on past societies. However, harvesting such data is significantly hampered by the general lack of robust earthwork chronologies. Dating earthworks is notoriously difficult due to a variety of factors, including a scarcity of closely datable archaeological finds, the frequent absence of suitable and relevant material for radiocarbon dating, and lacking or ambiguous historical sources. Luminescence dating may provide a solution for these problems because it enables direct dating of sediment, a ubiquitous and relevant material in earthwork construction. In this paper we focus on ringforts: circular or semi-circular defensive structures surrounded by earthen banks and ditches, which originated in the first millennium CE and appear to reflect major transformations in early historical societies. We present the results of a detailed luminescence study of a ringfort underlying the modern town centre of Den Burg, on the Wadden Isle of Texel in the Netherlands. We dated samples from different sedimentary contexts (bank and ditch infills) using both quartz optically stimulated luminescence (OSL) and feldspar single-grain post-infrared infrared stimulated luminescence (pIRIR). We analyze the results in the context of age interpretations based on other proxy data (radiocarbon dates, archaeological finds, historical evidence). This yields a new, robust dating chronology that changes the biography of the ringfort. The initial construction dates between 730 and 840 CE, making Den Burg the oldest known ringfort in the Low Countries. We reflect on the best practices for luminescence dating of earthworks and on archaeological implications for other ringforts in the Netherlands and beyond.
古代人造土方工程,如土墩、丘、堤防、高地或梯田、围场和堡垒,在全球许多地区无处不在。它们可以提供关于过去社会的丰富而重要的信息。然而,由于普遍缺乏可靠的土方工程年表,收集这些数据受到严重阻碍。由于各种因素,对土方工程进行测年是出了名的困难,包括缺乏精确测年的考古发现,经常缺乏合适和相关的放射性碳测年材料,以及缺乏或模糊的历史资料。发光测年可以为这些问题提供解决方案,因为它可以直接测定沉积物的年代,而沉积物是土方施工中普遍存在的相关材料。在本文中,我们将重点放在环堡:圆形或半圆形的防御结构,周围环绕着土岸和沟渠,起源于公元第一个千年,似乎反映了早期历史社会的重大转变。我们展示了对荷兰瓦登特塞尔岛登堡现代城镇中心的环堡进行详细发光研究的结果。我们使用石英光学激发发光(OSL)和长石单粒红外后红外激发发光(pIRIR)对不同沉积背景(河岸和沟渠填充)的样品进行了年代测定。我们在基于其他代理数据(放射性碳测年、考古发现、历史证据)的年龄解释背景下分析结果。这产生了一个新的、可靠的年代编年史,改变了ringfort的历史。最初的建造时间在公元730年到840年之间,使登堡成为低地国家已知的最古老的环堡。我们反思了土方工程发光定年的最佳实践,以及对荷兰及其他地区其他环堡的考古影响。
{"title":"Dating earthworks with luminescence: Insights from the medieval ringfort of Den Burg, Texel (the Netherlands)","authors":"Roy van Beek ,&nbsp;Elizabeth L. Chamberlain ,&nbsp;Kirsten de Nooijer ,&nbsp;Sander Gerritsen ,&nbsp;Michiel Bartels ,&nbsp;Jakob Wallinga","doi":"10.1016/j.quageo.2025.101669","DOIUrl":"10.1016/j.quageo.2025.101669","url":null,"abstract":"<div><div>Ancient human-made earthworks such as mounds, middens, levees, raised or terraced fields, enclosures and forts are omnipresent in many areas across the globe. They may offer rich and important information on past societies. However, harvesting such data is significantly hampered by the general lack of robust earthwork chronologies. Dating earthworks is notoriously difficult due to a variety of factors, including a scarcity of closely datable archaeological finds, the frequent absence of suitable and relevant material for radiocarbon dating, and lacking or ambiguous historical sources. Luminescence dating may provide a solution for these problems because it enables direct dating of sediment, a ubiquitous and relevant material in earthwork construction. In this paper we focus on ringforts: circular or semi-circular defensive structures surrounded by earthen banks and ditches, which originated in the first millennium CE and appear to reflect major transformations in early historical societies. We present the results of a detailed luminescence study of a ringfort underlying the modern town centre of Den Burg, on the Wadden Isle of Texel in the Netherlands. We dated samples from different sedimentary contexts (bank and ditch infills) using both quartz optically stimulated luminescence (OSL) and feldspar single-grain post-infrared infrared stimulated luminescence (pIRIR). We analyze the results in the context of age interpretations based on other proxy data (radiocarbon dates, archaeological finds, historical evidence). This yields a new, robust dating chronology that changes the biography of the ringfort. The initial construction dates between 730 and 840 CE, making Den Burg the oldest known ringfort in the Low Countries. We reflect on the best practices for luminescence dating of earthworks and on archaeological implications for other ringforts in the Netherlands and beyond.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"88 ","pages":"Article 101669"},"PeriodicalIF":1.7,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143842661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Quaternary Geochronology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1