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Comparison of Novel Raman Techniques for Fiber Forensics 光纤取证中新型拉曼技术的比较
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-07-28 DOI: 10.3390/opt4030032
Benjamin R. Anderson, N. Gese, H. Eilers
We have proposed three novel Raman techniques to expand capabilities for non-destructive dyed-fiber forensics: THz Raman spectroscopy (TRS), integrating-cavity-enhanced Raman spectroscopy (ICERS), and deep-UV Raman spectroscopy (DUVRS). In this study, we report on our attempts to apply these techniques to a variety of dyed-nylon fibers and report on the results of each technique, with a particular focus on the dyes Acid Red 337 and Acid Yellow 49. We find that none of the dyes tested had discernible THz peaks but that they do impact the peak positions of the host fabric’s THz spectrum. For ICERS, we find that light absorption overwhelms any possible cavity enhancement, making the technique unusable for most dyed fabrics when using UV/VIS excitation. However, NIR excitation may still prove beneficial, but a new cavity material (with a higher NIR reflectance) is needed. Finally, we tested DUVRS but found that, for all the dyed fibers tested, the DUV excitation resulted in rapid photodegradation, making the technique unusable for non-destructive forensics.
我们提出了三种新的拉曼技术来扩展非破坏性染色纤维取证的能力:太赫兹拉曼光谱(TRS),集成腔增强拉曼光谱(ICERS)和深紫外拉曼光谱(DUVRS)。在这项研究中,我们报告了我们将这些技术应用于各种染色尼龙纤维的尝试,并报告了每种技术的结果,特别关注染料酸性红337和酸性黄49。我们发现测试的染料都没有可识别的太赫兹峰,但它们确实影响了宿主织物的太赫兹光谱的峰值位置。对于ICERS,我们发现光吸收压倒了任何可能的腔增强,使得该技术在使用UV/VIS激发时无法用于大多数染色织物。然而,近红外激发可能仍然是有益的,但需要一种新的腔体材料(具有更高的近红外反射率)。最后,我们测试了DUVRS,但发现,对于所有测试的染色纤维,DUV激发导致快速光降解,使该技术无法用于非破坏性取证。
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引用次数: 0
Frequency Response Analysis of FAU, LTA and MFI Zeolites Using UV-Vis and Electrochemical Impedance Spectroscopy 紫外可见光谱和电化学阻抗光谱分析FAU、LTA和MFI沸石的频率响应
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-07-28 DOI: 10.3390/opt4030033
F. N. Murrieta-Rico, J. Antúnez-García, R. Yocupicio-Gaxiola, Armando Reyes Serrato, V. Petranovskii, M. Xiao, O. Sergiyenko, W. Flores-Fuentes, J. Rodríguez-Quiñonez
Zeolites are porous materials that have cavities interconnected by channels. These crystalline materials are composed of Si-O tetrahedral structures, and according to the assembly of such tetrahedral structures, specific crystalline structures are obtained. Until now, it has been said that there are more than 245 different zeolitic frameworks, and since each one has a specific distribution of pores and cavities, each kind of zeolite has a specific area-to-volume ratio. As a result of the type of zeolite structure, the zeolite can exhibit specific properties, i.e., electrical or optical. Moreover, the physical properties of zeolites can be modified after the inclusion of another chemical species in their structure or in their voids, which can result in tuning a zeolite for specific applications. In this work, synthetic zeolites of types LTA, FAU and MFI are characterized by a number of methods. In particular, the data from UV-Vis spectroscopy are analyzed, and the effect of crystalline structure on properties such as optical bandgap, refractive index, absorption coefficient, incident photon frequency, and extinction coefficient is studied.
沸石是一种多孔材料,其孔洞通过通道相互连接。这些晶体材料由Si-O四面体结构组成,根据这种四面体结构的组装,可以得到特定的晶体结构。到目前为止,据说有超过245种不同的沸石骨架,并且由于每种沸石都有特定的孔和空腔分布,因此每种沸石都有特定的面积体积比。由于沸石结构的类型不同,沸石可以表现出特定的性质,即电学或光学性质。此外,在沸石的结构或空隙中加入另一种化学物质后,沸石的物理性质可以被改变,这可以使沸石适应特定的应用。本文采用多种方法对LTA型、FAU型和MFI型分子筛进行了表征。特别对紫外可见光谱数据进行了分析,研究了晶体结构对光学带隙、折射率、吸收系数、入射光子频率和消光系数等性能的影响。
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引用次数: 0
Thermal Effects on Optical Chirality, Mechanics, and Associated Symmetry Properties 热效应对光手性、力学和相关对称性的影响
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-07-17 DOI: 10.3390/opt4030030
Hyoung-In Lee, Tanvi P. Vaidya, Ram Prakash Dwivedi
A review is provided here about the thermal effects on optical chirality. To this goal, chiral objects dispersed in an embedding fluid are examined for their magnetoelectric coupling. Thermal effects on several chiral meta-atoms and their ensembles are examined. To this goal, DNA-like helical structures are examined in detail. The mechanical aspect of thermo-elasticity is reviewed along with transverse deformations while drawing analogies from condensed-matter physics. In this respect, the chirality-induced spin selection is reviewed along with the temperature-mediated electron–phonon interactions. A wide range of materials, such as polymers and biological cells, are also examined for temperature effects. A transition temperature delineating a sign flip in the chirality parameter is identified as well. Chirality-associated functionalities such as ratchet motions, switching, and modulations are investigated for their respective thermal effects. Issues of fabricating chiral meta-atoms are also discussed.
本文综述了热对光学手性的影响。为此,研究了分散在嵌入流体中的手性物体的磁电耦合。研究了几种手性元原子及其系综的热效应。为此,对dna样螺旋结构进行了详细的研究。热弹性的力学方面与横向变形一起进行了回顾,同时从凝聚态物理中进行了类比。在这方面,回顾了手性诱导的自旋选择以及温度介导的电子-声子相互作用。广泛的材料,如聚合物和生物细胞,也被检查温度的影响。还确定了描述手性参数中符号翻转的转变温度。手性相关的功能,如棘轮运动,开关和调制研究各自的热效应。还讨论了手性元原子的制备问题。
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引用次数: 0
IOL Power Calculation in an Unusual Long Fellow Eye: A Case Report 异长眼人工晶体度数计算一例
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-07-03 DOI: 10.3390/opt4030029
Umberto Camellin, F. Franchina, A. Meduri, P. Aragona
Background: Intra-Ocular Lens (IOL) power calculation in long eyes remains challenging despite the availability of new formulas and biometers. This case report shows that optimization of the A-constant in the first eye can reduce postoperative refractive error in the second eye, even in the case of an IOL with negative power. This report aimed to describe a case in which this method was used to calculate IOL power to reduce postoperative refractive error in a long fellow eye. As far as we know, this is the first paper reporting the use of the optimized constant in the first eye to reduce postoperative error in the second eye in the case of a negative IOL. Case presentation: A highly myopic patient with nuclear cataracts underwent phacoemulsification cataract surgery (PCS) in both eyes. The axial length (AL) was 39.42 mm in the right eye and 37.45 mm in the left eye. All biometric data were obtained via low-coherence reflectometry using an OA-2000 biometer (Tomey, Nagoya, Japan). First, an IOL power calculation using the Barrett II formula and PCS was performed in the shorter eye. To evaluate the postoperative refractive error, the optimized A-constant in the left eye was estimated using the Camellin-Calossi formula. The new A-constant was then used for the right eye IOL power calculation using the same formula. The prediction error (PE) in the left eye was −0.23 D with the Barrett II formula. The optimized A-constant method using the Camellin-Calossi formula in the fellow eye gave −0.28 D of PE. Conclusions: The A-constant optimization for very long eyes, using data from the first operated eye, may be useful to reduce refractive prediction error in the second eye in very long eyes, as well as in the case of IOL power with negative values.
背景:尽管有了新的配方和生物计,长眼的人工晶状体(IOL)度数计算仍然具有挑战性。本病例报告表明,优化第一只眼的a -常数可以减少第二只眼的术后屈光不正,即使是在人工晶状体为负度数的情况下。本报告旨在描述一个用这种方法计算人工晶状体度数以减少长眼术后屈光不正的病例。据我们所知,这是第一篇报道在人工晶状体阴性的情况下,在第一只眼使用优化常数来减少第二只眼的术后误差的论文。病例介绍:高度近视伴核性白内障患者行双眼超声乳化白内障手术。眼轴长(AL)右眼39.42 mm,左眼37.45 mm。所有生物特征数据均通过使用OA-2000生物计(Tomey,名古屋,日本)的低相干反射法获得。首先,使用Barrett II公式和PCS计算短眼人工晶状体度数。为评价术后屈光不正,采用Camellin-Calossi公式计算左眼最佳a常数。新的a常数用同样的公式计算右眼人工晶状体度数。Barrett II公式对左眼的预测误差(PE)为- 0.23 D。采用Camellin-Calossi公式优化后的a -常数法对眼PE值为- 0.28 D。结论:超长眼a常数优化方法可有效降低超长眼及人工晶状体度数为负值时第二眼屈光预测误差。
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引用次数: 0
Near-Field Single-Scattering Calculations of Aerosols: Sensitivity Studies 气溶胶的近场单散射计算:敏感性研究
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-06-14 DOI: 10.3390/opt4020028
N. A. Arreyndip, K. Kandler, Aryasree Sudharaj
We model the effects of the photosensitive parameters of aerosols on their optical properties to provide a solid framework for further experimental and theoretical studies. A spherical dust particle is used to study the effects of the ambient medium, size, surface roughness, wavelength, and imaginary part of the complex refractive index. Five Gaussian random spheres with different aspect ratios are simulated to study the dependence of aerosol light scattering properties on particle shape distribution. To investigate the influence of composition, we model two typical kaolinite-like particles (pure and composite) collected from Southwest Sahara, with 0 and 2% hematite at different mixing states. Using the method of discrete-dipole approximation in DDSCAT, a comparative study is performed with the Mueller matrix elements, scattering, absorption, extinction efficiencies, single scattering albedo, and linear depolarization ratio as indicators. For single, microscopic dust particles, near-field calculations are carried out. The results show that the intensity of backscattering and the scattering efficiency decreases in water compared to dry air. Light in the visible range is more efficient for aerosol scattering experiments. A small number of impurities in the sample will increase its absorbing properties, but, in general, the scattering efficiencies strongly depend on the single-particle mixing state. Smaller particles with a diameter comparable to the wavelength of incident light show higher scattering efficiencies but lower backscattering intensities than larger particles, while surface roughness is shown to strongly alter the polarizability of the particle but has a negligible effect on its single-scattering albedo. Moreover, different shapes have a strong effect on the degree of linear polarization, but, in general, using the spherical over elliptic shape model can underestimate the scattering efficiencies by up to 4%. Finally, variation in the imaginary part of the complex RI can underestimate the single scattering albedo by up to 35.8%.
我们模拟了气溶胶的光敏参数对其光学性质的影响,为进一步的实验和理论研究提供了坚实的框架。用球形尘埃粒子研究了环境介质、粒径、表面粗糙度、波长和复折射率虚部的影响。模拟了5个不同长径比的高斯随机球,研究了气溶胶光散射特性与粒子形状分布的关系。为了研究成分的影响,我们模拟了从西南撒哈拉收集的两种典型的高岭石样颗粒(纯和复合),在不同的混合状态下含有0%和2%的赤铁矿。利用离散偶极近似的方法,以Mueller矩阵元素、散射、吸收、消光效率、单散射反照率和线性退极化比为指标,进行了比较研究。对于单个微尘粒子,进行近场计算。结果表明,与干燥空气相比,水中的后向散射强度和散射效率有所降低。可见光范围内的光对气溶胶散射实验更有效。样品中少量杂质会增加其吸收性能,但一般来说,散射效率强烈依赖于单颗粒混合状态。直径与入射光波长相当的小颗粒比大颗粒具有更高的散射效率,但后向散射强度较低,而表面粗糙度会强烈改变颗粒的极化率,但对其单次散射反照率的影响可以忽略不计。此外,不同的形状对线极化程度有很强的影响,但一般来说,使用球形比椭圆形状模型可以低估散射效率高达4%。最后,复RI虚部的变化对单次散射反照率的低估可达35.8%。
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引用次数: 0
Effect of Higher Order Aberrations and Intraocular Scatter on Optical Quality Based on an Optical Eye Model 基于光学眼模型的高阶像差和眼内散射对光学质量的影响
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-05-26 DOI: 10.3390/opt4020027
Feng Rao, X. Zhao, Ming Zhang, Yan Wang
The impact of intraocular scatter and higher order aberrations (HOAs) on ocular optical quality was investigated. An optical eye model was constructed using the measured ocular aberrations, corneal surfaces, axial length, and scatter fraction, and the impact of HOAs and scatter on modulation transfer functions (MTFs) was studied based on the newly established optical eye model. For uniform intraocular scatter, the monochromatic and polychromatic MTF decreased as the HOAs or scatter fractions increased independently at each spatial frequency, which implied that both were essential for visual quality. In addition, the scatter effect on MTF was more significant for the eye with less HOA. The combined deterioration effect of these two factors on the MTF was less than their summation, suggesting a potential compensatory mechanism between HOAs and scatter.
研究了眼内散射和高阶像差(HOAs)对眼光学质量的影响。利用测量的眼像差、角膜表面、眼轴长度和散射分数建立光学眼模型,并在此基础上研究了hoa和散射对调制传递函数(mtf)的影响。对于均匀的眼内散射,单色和多色MTF随着hoa或散射分数在每个空间频率上的独立增加而减少,这意味着两者对视觉质量都是必不可少的。此外,散射效应对MTF的影响在HOA较小的眼中更为显著。这两个因素对MTF的综合恶化效应小于它们的总和,表明hoa和散射之间存在潜在的补偿机制。
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引用次数: 0
Tunability of the Optical Properties of Transition-Metal-Based Structural Phase Change Materials 过渡金属基结构相变材料光学性质的可调性
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-05-24 DOI: 10.3390/opt4020026
Sheheera Irfan, Yasir A. Haleem, M. Irshad, Muhammad Farooq Saleem, M. Arshad, Muhammad Habib
Phase transitions are an intriguing yet poorly understood aspect of transition-metal-based materials; these phase transitions can result in changes to the refractive index, absorption coefficient, and other optical properties of the materials. Transition-metal-based materials exist in a variety of crystalline phases and also have metallic, semi-metallic, and semi-conducting characteristics. In this review, we demonstrate that alloyed W- and Mo-based dichalcogenides enable phase transitions in structures, with phase transition temperatures that are tunable across a wide range using various alloy models and modern DFT-based calculations. We also analyze the tuning the optical bandgap of the metal oxide nanoparticles through doping of the transition metal in a manner that is suitable for optical switching and thermal imaging. After the introduction and a brief illustration of the structures and their exceptional properties, we discuss synthetic methodologies and their application as part of important strategies toward the enhanced performance of transition-metal-based dichalcogenides and oxides. In the end, our conclusion highlights the prospects of 2D materials as phase transition materials due to their advantages in terms of scalability and adaptability.
相变是过渡金属基材料的一个有趣但鲜为人知的方面;这些相变会导致材料的折射率、吸收系数和其他光学性质的变化。过渡金属基材料存在于多种晶相中,也具有金属、半金属和半导体特性。在这篇综述中,我们证明了合金W和mo基二硫族化物能够在结构中实现相变,并且使用各种合金模型和现代基于dft的计算可以在很大范围内调节相变温度。我们还分析了通过掺杂过渡金属来调整金属氧化物纳米粒子的光学带隙的方法,使其适合于光开关和热成像。在介绍和简要说明了这些化合物的结构及其特殊性质之后,我们讨论了合成方法及其应用,作为提高过渡金属基二硫族化合物和氧化物性能的重要策略的一部分。最后,我们的结论强调了二维材料作为相变材料的前景,因为它们在可扩展性和适应性方面具有优势。
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引用次数: 0
Disinfection of Transparent Screens by Side-Coupled UVA LED Radiation 侧耦合UVA LED辐射对透明屏幕的消毒
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-05-15 DOI: 10.3390/opt4020023
Ben Sicks, Anna-Maria Gierke, Florian Sommerfeld, Martin Klein, M. Hessling
(1) Background: Applications using touch screens are increasingly deployed in medical facilities, as well as in public areas. When touching the display with fingers, potentially pathogenic microorganisms such as methicillin-resistant Staphylococcus aureus (MRSA) can be transmitted. An automated process to decontaminate the device in between users would be highly useful. (2) Methods: Thin glass plates were superficially contaminated with the non-pathogenic Staphylococcus carnosus in a controlled manner. Subsequently, UVA radiation of 400 or 380 nm was laterally coupled into the glass plate, which acted as a light guide. Contact agar plates recorded the change in the staphylococci concentration over time. Additionally, the UVA radiation emitted by the glass plates was measured and the potential risk to humans assessed. (3) Results: Staphylococci concentration decreased as a result of UVA radiation for both wavelengths. At 400 nm, it took about 7.5 h and at 380 nm about 1 h until a reduction of 90% was reached. To meet higher disinfection requirements, disproportionately longer irradiation times were necessary. The potential UVA irradiation of humans in front of the glass pane was about 35 µW/cm2 or less and posed no risk to humans. (4) Conclusions: Side-coupled UVA radiation is in principle capable of safely automatically disinfecting microorganisms on touch screens. However, the required irradiation times are still in the hour range, so that a rapid disinfection within a minute or less is not yet possible with the presented setup. However, higher UVA intensities might reduce the current disinfection durations.
(1)背景:使用触摸屏的应用越来越多地部署在医疗设施和公共场所。当用手指触摸显示器时,可能会传播潜在的致病微生物,如耐甲氧西林金黄色葡萄球菌(MRSA)。在用户之间对设备进行消毒的自动化过程将非常有用。(2)方法:控制非致病性胭脂红葡萄球菌污染薄玻璃板表面。随后,将400或380 nm的UVA辐射侧向耦合到玻璃板中,玻璃板起到导光作用。接触琼脂板记录葡萄球菌浓度随时间的变化。此外,测量了玻璃板发出的长波紫外线辐射,并评估了对人类的潜在风险。(3)结果:两种波长的UVA辐射均导致葡萄球菌浓度下降。在400 nm处,大约需要7.5 h,在380 nm处大约需要1 h,直到还原达到90%。为了满足更高的消毒要求,需要更长的辐照时间。人体在玻璃板前受到的潜在UVA辐射约为35 μ W/cm2或更低,对人体没有风险。(4)结论:侧耦合UVA辐射原则上能够安全自动消毒触摸屏上的微生物。然而,所需的辐照时间仍在小时范围内,因此,目前的装置尚不可能在一分钟或更短时间内进行快速消毒。然而,较高的UVA强度可能会缩短当前的消毒时间。
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引用次数: 0
Self-Contained Reference Sensors to Reduce Nuisance Alarm Rate in φ-OTDR-Based Fence Intrusion Detection System 基于φ- otdr的围栏入侵检测系统中自包含参考传感器降低骚扰报警率
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-05-15 DOI: 10.3390/opt4020024
Hailiang Zhang, Hui Dong, D. Hu, Jun Hong Ng
Nuisance alarm rate (NAR) is one of the key performance parameters in a phase-sensitive optical time domain reflectometry (φ-OTDR)-based fence intrusion detection system. Typically, the vibrations caused by ambient environmental conditions, such as heavy rain, strong wind, and passing vehicles, easily result in many nuisance alarms. Significant research efforts have been undertaken to suppress the NAR. In this paper, we propose to utilize short segments of the sensing fiber as reference sensors for significant reduction in the NAR in φ-OTDR for the first time, to the best of our knowledge. According to our field trial results, the proposed approach can reduce the NAR by more than 90%. The proposed approach is very simple, practical, and cost-effective, which can be easily integrated with the existing methods of reducing NAR and act as an additional level of decision-making algorithm for triggering alarms.
妨害报警率(NAR)是基于相位敏感光时域反射法(φ-OTDR)的围栏入侵检测系统的关键性能参数之一。通常,由环境条件引起的振动,如大雨、强风和过往车辆,很容易导致许多滋扰警报。已经进行了大量的研究工作来抑制NAR。在本文中,据我们所知,我们首次提出利用传感光纤的短段作为参考传感器,以显著降低φ-OTDR中的NAR。根据我们的现场试验结果,该方法可以将NAR降低90%以上。所提出的方法非常简单、实用且具有成本效益,可以很容易地与现有的减少NAR的方法集成,并作为触发警报的额外决策算法。
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引用次数: 0
Advanced Raman Spectroscopy Based on Transfer Learning by Using a Convolutional Neural Network for Personalized Colorectal Cancer Diagnosis 基于卷积神经网络迁移学习的先进拉曼光谱在个体化结直肠癌诊断中的应用
3区 物理与天体物理 Q1 Materials Science Pub Date : 2023-04-27 DOI: 10.3390/opt4020022
D. Kalatzis, E. Spyratou, M. Karnachoriti, M. Kouri, S. Orfanoudakis, Nektarios Koufopoulos, A. Pouliakis, N. Danias, I. Seimenis, A. Kontos, E. Efstathopoulos
Advanced Raman spectroscopy (RS) systems have gained new interest in the field of medicine as an emerging tool for in vivo tissue discrimination. The coupling of RS with artificial intelligence (AI) algorithms has given a boost to RS to analyze spectral data in real time with high specificity and sensitivity. However, limitations are still encountered due to the large amount of clinical data which are required for the pre-training process of AI algorithms. In this study, human healthy and cancerous colon specimens were surgically resected from different sites of the ascending colon and analyzed by RS. Two transfer learning models, the one-dimensional convolutional neural network (1D-CNN) and the 1D–ResNet transfer learning (1D-ResNet) network, were developed and evaluated using a Raman open database for the pre-training process which consisted of spectra of pathogen bacteria. According to the results, both models achieved high accuracy of 88% for healthy/cancerous tissue discrimination by overcoming the limitation of the collection of a large number of spectra for the pre-training process. This gives a boost to RS as an adjuvant tool for real-time biopsy and surgery guidance.
先进的拉曼光谱(RS)系统作为一种新兴的体内组织识别工具在医学领域引起了新的关注。RS与人工智能(AI)算法的耦合使得RS能够实时分析光谱数据,具有较高的特异性和灵敏度。然而,由于人工智能算法的预训练过程需要大量的临床数据,因此仍然遇到了局限性。在本研究中,从升结肠的不同部位手术切除人类健康和癌结肠标本,并通过RS进行分析,开发了一维卷积神经网络(1D-CNN)和一维resnet迁移学习(1D-ResNet)网络两种迁移学习模型,并使用Raman开放数据库对其进行评估,用于包括病原体光谱的预训练过程。结果表明,两种模型都克服了在预训练过程中采集大量光谱的限制,实现了88%的健康/癌组织识别准确率。这促进了RS作为实时活检和手术指导的辅助工具。
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引用次数: 3
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Progress in Optics
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