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DEM study on the force chain evolution of biaxial compression of pebble bed 卵石床双轴压缩力链演变的 DEM 研究
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-26 DOI: 10.1016/j.nme.2024.101717
Wang Jian , Liu Mingzong , Deng Haishun , Lei Mingzhun

Li4SiO4 and Li2TiO3 are granular materials in the pebble bed of fusion reactors, and their physical parameters and mechanical properties directly affect the working status and structural design of the pebble bed. The force chain can be employed to intuitively describe the mechanical properties of the pebble bed in the particle aggregate. Based on the discrete element method, we conducted a numerical study on the evolution characteristics of the force chain of Li4SiO4 and Li2TiO3 pebble beds under biaxial compression and explored the friction coefficient and pebble bed effect of the aspect ratio on the force chain distribution. The results revealed that as the particle friction coefficient increased, the force chain tended to be isotropically distributed, indicating that the friction mechanism was more conducive to a uniform distribution of the force chain. During compression, the average coordination number of the pebble bed increased with the friction coefficient. The Li2TiO3 particles had larger gravity than the Li4SiO4 pebble bed therefore, the Li2TiO3 pebble bed accounted for more force chains in the vertical direction. When the aspect ratio of the pebble bed was less than 0.5 or greater than 2.5, the distribution of force chains exhibited strong anisotropy. Conversely, when the pebble bed aspect ratio ranged between 0.5 and 2.5, the distribution of force chains tended towards an isotropic trend. Moreover, the number of force chains in each direction varied with changes in the aspect ratio of the pebble bed, characterized by a high concentration at the edges and a lower concentration in the middle. The results can provide an in-depth understanding of the force chain distribution and evolution characteristics in the pebble bed and provide a theoretical basis for designing and analyzing tritium breeding pebble beds.

Li4SiO4和Li2TiO3是聚变反应堆卵石床中的颗粒材料,其物理参数和力学性能直接影响卵石床的工作状态和结构设计。采用力链可以直观地描述颗粒集合体中卵石床的力学性能。基于离散元方法,我们对双轴压缩下 Li4SiO4 和 Li2TiO3 卵石床的力链演化特征进行了数值研究,并探讨了摩擦系数和卵石床长宽比对力链分布的影响。结果发现,随着颗粒摩擦系数的增大,力链趋于各向同性分布,表明摩擦机制更有利于力链的均匀分布。在压缩过程中,卵石床的平均配位数随摩擦系数的增加而增加。Li2TiO3 颗粒的重力大于 Li4SiO4 卵石床,因此 Li2TiO3 卵石床在垂直方向上的力链更多。当卵石床的长宽比小于 0.5 或大于 2.5 时,力链的分布表现出很强的各向异性。相反,当卵石床的纵横比在 0.5 和 2.5 之间时,力链的分布趋向于各向同性。此外,各方向的力链数量随卵石床纵横比的变化而变化,其特点是边缘集中度高,中间集中度低。研究结果可以深入了解鹅卵石床的力链分布和演化特征,为设计和分析氚孕育鹅卵石床提供理论依据。
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引用次数: 0
Structural integrity evaluation of the DTT plasma facing unit using detailed CFD and thermo-mechanical analyses 利用详细的 CFD 和热机械分析对 DTT 等离子体面层装置进行结构完整性评估
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-26 DOI: 10.1016/j.nme.2024.101715
Patrik Tarfila , Oriol Costa Garrido , Boštjan Končar , Emanuela Martelli , Francesco Giorgetti , Selanna Roccella

A new Divertor Tokamak Test (DTT) facility is currently being built in Italy to investigate different divertor configurations under different plasma scenarios. The divertor and in particular its target, consisting of Plasma Facing Units (PFUs), is exposed to high heat loads due to plasma fluence. In this paper, the structural integrity of the PFU is evaluated for a reference Single Null (SN) divertor configuration under three different plasma scenarios. A comprehensive structural integrity analysis has been carried out in three stages. In the first stage, computational fluid dynamic (CFD) analyses of the divertor’s PFU with a cooling channel were performed at three different heat loads corresponding to three plasma scenarios. The temperature fields calculated by the CFD analyses were then used as input for the second stage, in which thermo-mechanical simulations were performed to predict the stresses and displacements in the PFU. Due to the high local heat loads, high stresses or even yielding are expected in the PFU’s structural components. Therefore, in the third stage, the structural integrity of critical cross-sections has been verified using the Structural Design Criteria for In-vessel Components (SDC-IC). It has been demonstrated that structural components of the PFU are able to withstand the expected loads, although some non-structural components experienced yielding while not exceeding the critical values.

意大利目前正在建造一个新的岔道托卡马克试验(DTT)设施,以研究不同等离子体情况下的不同岔道配置。分流器,尤其是由等离子体面罩单元(PFU)组成的目标,会因等离子体通量而承受高热负荷。本文评估了在三种不同等离子体情况下参考单空(SN)分流器配置的 PFU 结构完整性。全面的结构完整性分析分三个阶段进行。第一阶段,在三种不同的热负荷(对应三种等离子体情况)下,对带有冷却通道的分流器 PFU 进行了计算流体动力学(CFD)分析。然后将 CFD 分析计算出的温度场作为第二阶段的输入,进行热机械模拟以预测 PFU 中的应力和位移。由于局部热负荷较高,预计 PFU 的结构部件会出现高应力甚至屈服。因此,在第三阶段,使用舱内部件结构设计标准(SDC-IC)验证了关键截面的结构完整性。结果表明,尽管一些非结构部件出现了屈服,但并未超过临界值,PFU 的结构部件能够承受预期载荷。
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引用次数: 0
Numerical study and experimental validation of heat transfer capacity of flat-type divertor for fusion reactor 核聚变反应堆平面型岔流器传热能力的数值研究与实验验证
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-25 DOI: 10.1016/j.nme.2024.101716
Nanyu Mou , Mingxiang Lu , Mingchi Feng , Shuai Huang , Le Han , Damao Yao

The divertor must simultaneously withstand unprecedented high heat fluxes of up to 20 MW/m2 and high-energy neutron irradiation of 14-MeV during fusion reactor operation. Accordingly, it is necessary to simultaneously meet the excellent heat dissipation capacity of the divertor and maintain good material performance in harsh neutron irradiation environments. The flat-type divertor demonstrates better heat transfer performance compared to monoblock divertor. Nevertheless, under the condition of a heat flux of 20 MW/m2, the heat transfer and thermal fatigue performance of flat-type divertor using advanced materials are still unidentified. In this study, we conducted a thorough analysis of the heat transfer capabilities and thermal fatigue characteristics of potassium-doped tungsten (KW)/Cu/Oxide dispersion strengthened copper (ODS-Cu)/reduced activation ferritic/martensitic (RAFM) divertor mockup adopts hypervaportron (HV) structure by numerical simulations combined with experiments. The numerical results indicate that the flat-type KW/Cu/ODS-Cu/RAFM divertor mockup expresses excellent heat transfer capacity. The contact area between the edge of the fins and the bottom surface of the ODS-Cu heat sink induces a significant increase in water flow velocity to ∼15 m/s. The peak temperature of loaded KW surface is only ∼985 °C under the flow rate of 5 t/h and inlet temperature of 20 °C. During the high heat flux tests, the prepared flat-type divertor mockup successful endured 1000 cycles of 20 MW/m2 with the peak temperature of 883 °C, and the surface temperature experienced a fluctuation of 2.4 % during the thermal fatigue tests. This study can provide a strong data reference and technical support for the development of fusion reactors, and is of great significance in advancing the commercialization of fusion energy.

在聚变反应堆运行期间,分流器必须同时承受前所未有的高达 20 MW/m2 的高热通量和 14-MeV 的高能中子辐照。因此,在恶劣的中子辐照环境中,既要满足分流器出色的散热能力,又要保持良好的材料性能。与单体分流器相比,扁平型分流器具有更好的传热性能。然而,在热通量为 20 MW/m2 的条件下,使用先进材料的扁平型分流器的传热和热疲劳性能仍未确定。在本研究中,我们通过数值模拟结合实验,对采用超蒸气管(HV)结构的掺钾钨(KW)/氧化物分散强化铜(ODS-Cu)/还原活化铁素体/马氏体(RAFM)分流器模型的传热能力和热疲劳特性进行了深入分析。数值结果表明,平面型 KW/Cu/ODS-Cu/RAFM 分流器模型具有出色的传热能力。鳍片边缘与 ODS-Cu 散热器底面之间的接触面积使水流速度显著增加到 ∼15 m/s。在流量为 5 吨/小时、入口温度为 20 °C的条件下,加载 KW 表面的峰值温度仅为 985 °C。在高热通量试验中,制备成功的平板式分流器模拟件承受了1000次20 MW/m2的循环,峰值温度为883 ℃,在热疲劳试验中表面温度波动为2.4%。这项研究可为聚变堆的发展提供有力的数据参考和技术支持,对推进聚变能的商业化具有重要意义。
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引用次数: 0
Effect of electronic excitations on hydrogen behavior in tungsten 电子激发对钨中氢行为的影响
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-23 DOI: 10.1016/j.nme.2024.101714
X.B. Ye , Z.H. He , D.D. Li

The interaction between ions should be greatly modified under electronic excitation states, subsequently altering the interactions between materials. We perform a series of first-principles calculations to predict the solution and diffusion behaviors of interstitial hydrogen (H) in tungsten (W) under various electronic excitations. Qualitatively, the solution, diffusion, and trapping behaviors of H in W under various electronic excitation states are basically consistent with those in the ground state. However, it can be found that the solution energy and the migration energy barrier of H decreases as increasing the electronic temperature of system. The Pearson correlation coefficient study shows that there exists a perfect negative correlation between the lattice constant of W and H solution energy induced by lattice distortion. Besides, electronic excitations also make the binding energy of multiple H atoms decrease. That is, when the same number of H atoms are added to the vacancy, the binding energy decreases with increasing the electronic temperature of system. Based on these calculation results, we can infer that electronic excitations make dissolved H atoms more active in W system. This may, to some extent, allow dissolved H to migrate around and not aggregate so easily, thus reducing the production of H bubbles. Therefore, in quantitative terms, the electronic excited states have a certain effect on the H behavior in W.

在电子激发态下,离子之间的相互作用会发生很大变化,从而改变材料之间的相互作用。我们进行了一系列第一性原理计算,以预测钨(W)中间隙氢(H)在各种电子激发下的溶解和扩散行为。从定性上看,各种电子激发态下氢在钨中的溶解、扩散和捕获行为与基态基本一致。但可以发现,H 的溶解能和迁移能垒随着体系电子温度的升高而降低。皮尔逊相关系数研究表明,W 的晶格常数与晶格畸变引起的 H 的溶解能之间存在完美的负相关。此外,电子激发也会使多个 H 原子的结合能降低。也就是说,当空位中加入相同数量的 H 原子时,结合能会随着体系电子温度的升高而降低。根据这些计算结果,我们可以推断出电子激发使溶解的 H 原子在 W 系统中更加活跃。这可能在一定程度上使溶解的 H 原子向四周迁移,不那么容易聚集,从而减少 H 气泡的产生。因此,从数量上看,电子激发态对 H 在 W 中的行为有一定的影响。
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引用次数: 0
A real-sized start-up monitoring module prototype for comprehensive test and irradiation campaigns of miniaturized neutron detectors according to the IFMIF-DONES baseline 用于根据 IFMIF-DONES 基准对微型中子探测器进行全面测试和辐照活动的实际尺寸启动监测模块原型
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-23 DOI: 10.1016/j.nme.2024.101712
Santiago Becerril-Jarque , Álvaro Marchena , Andrés Roldán Aranda , Pablo Araya , Roberto García Baonza , Agustín García , Jorge Aguilar , Luis Fernández , Urszula Wiacek , Rafal Prokopowicz , Jesús Castellanos , David Rapisarda

The key system to know the neutron and gamma fields during the commissioning at IFMIF-DONES facility will be the STart-Up Monitoring Module (STUMM), which will include tens of very sophisticated and miniaturised detectors providing crucial information about the radiation fields. In particular, there will be MFCs (micro-fission chambers), ICs (Ionisation Chambers), SPNDs (Self-Powered Neutron Devices) and GTs (Gamma Thermometers).

The current state-of-the-art does not provide answers about the performance of the detectors in the very specific working conditions inside the IFMIF-DONES Test Cell, as a very high spatial density of detectors inside the STUMM vessel, an extremely harsh environment with neutron flux up to 5·1014n/cm2/s and the need of long mineral cables (>30 m) to drive the very weak current signals from the irradiation area to the closest electronics cubicles available in the facility.

Except for the extremely high neutron flux provided by IFMIF-DONES, all the other very critical conditions can be replicated by means of a 1:1 scaled prototype of the STUMM (STUMM-PROTO), which will be subjected to comprehensive testing and irradiation campaigns in order to increase the knowledge about the performance of the detectors above mentioned.

The present work shows the wide range of capabilities offered by STUMM-PROTO as well as the current status of its construction and some first notions about the experimental campaigns to be implemented.

在 IFMIF-DONES 调试期间,了解中子和伽马场的关键系统是启动监测模块 (STUMM),其中包括数十个非常精密的微型探测器,提供有关辐射场的重要信息。特别是 MFC(微裂变室)、IC(电离室)、SPND(自供电中子设备)和 GT(伽马温度计)。由于 STUMM 容器内探测器的空间密度非常高,环境极其恶劣,中子通量高达 5-1014n/cm2/s,而且需要用长矿物电缆(30 米)将非常微弱的电流信号从辐照区传输到设施内最近的电子设备间,因此,目前的先进技术无法解释探测器在 IFMIF-DONES 试验舱内非常特殊的工作条件下的性能。除了IFMIF-DONES提供的极高中子通量外,所有其他非常关键的条件都可以通过一个1:1比例的STUMM原型(STUMM-PROTO)来复制,该原型将接受全面的测试和辐照活动,以增加对上述探测器性能的了解。
{"title":"A real-sized start-up monitoring module prototype for comprehensive test and irradiation campaigns of miniaturized neutron detectors according to the IFMIF-DONES baseline","authors":"Santiago Becerril-Jarque ,&nbsp;Álvaro Marchena ,&nbsp;Andrés Roldán Aranda ,&nbsp;Pablo Araya ,&nbsp;Roberto García Baonza ,&nbsp;Agustín García ,&nbsp;Jorge Aguilar ,&nbsp;Luis Fernández ,&nbsp;Urszula Wiacek ,&nbsp;Rafal Prokopowicz ,&nbsp;Jesús Castellanos ,&nbsp;David Rapisarda","doi":"10.1016/j.nme.2024.101712","DOIUrl":"10.1016/j.nme.2024.101712","url":null,"abstract":"<div><p>The key system to know the neutron and gamma fields during the commissioning at IFMIF-DONES facility will be the STart-Up Monitoring Module (STUMM), which will include tens of very sophisticated and miniaturised detectors providing crucial information about the radiation fields. In particular, there will be MFCs (micro-fission chambers), ICs (Ionisation Chambers), SPNDs (Self-Powered Neutron Devices) and GTs (Gamma Thermometers).</p><p>The current state-of-the-art does not provide answers about the performance of the detectors in the very specific working conditions inside the IFMIF-DONES Test Cell, as a very high spatial density of detectors inside the STUMM vessel, an extremely harsh environment with neutron flux up to 5·10<sup>14</sup>n/cm<sup>2</sup>/s and the need of long mineral cables (&gt;30 m) to drive the very weak current signals from the irradiation area to the closest electronics cubicles available in the facility.</p><p>Except for the extremely high neutron flux provided by IFMIF-DONES, all the other very critical conditions can be replicated by means of a 1:1 scaled prototype of the STUMM (STUMM-PROTO), which will be subjected to comprehensive testing and irradiation campaigns in order to increase the knowledge about the performance of the detectors above mentioned.</p><p>The present work shows the wide range of capabilities offered by STUMM-PROTO as well as the current status of its construction and some first notions about the experimental campaigns to be implemented.</p></div>","PeriodicalId":56004,"journal":{"name":"Nuclear Materials and Energy","volume":"40 ","pages":"Article 101712"},"PeriodicalIF":2.3,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2352179124001352/pdfft?md5=0b7fa9c437da34dba1b1c90fccd781df&pid=1-s2.0-S2352179124001352-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141848393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sputtering fabrication of isolated W nanocolumns: A possible alternative as plasma facing material for nuclear fusion reactors 用溅射法制造隔离的 W 纳米柱:核聚变反应堆等离子体面材料的可能替代品
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-19 DOI: 10.1016/j.nme.2024.101704
R. Gonzalez-Arrabal, Y. Mendez-González, J.M. Perlado

Isolated tungsten nanocolumns (W-NCs) have been reported to exhibit a higher radiation resistance than coarse grained W samples, under radiation conditions similar to those that plasma facing materials would face in both magnetic and inertial confinement nuclear fusion approaches (MCF and ICF, respectively). This is so, because their ability to release He via the free surfaces and, the strong reduction of the sputtering yield under KeV Ar and D irradiation as well as, flattening of its angular dependence. The latter is very important for the divertor location in MCF.

In this work, we investigate the capabilities of sputtering (an easy control, environmentally friendly, versatile, scalable and low-cost technique) to fabricate isolated W nanocolumns. We study the influence of sputtering parameters (plasma power and deposition angle) on the morphology, density and microstructure of the deposited coatings. Results show that stable α-phase 3D isolated W-NCs are produced at low plasma power (<100 W) and high deposition angles (θ ≥ 75°).

据报道,在与磁约束核聚变和惯性约束核聚变方法(分别为 MCF 和 ICF)中面向等离子体的材料类似的辐射条件下,孤立的钨纳米柱(W-NCs)比粗颗粒钨样品表现出更高的抗辐射能力。之所以如此,是因为它们能够通过自由表面释放 He,而且在 KeV Ar 和 D 的辐照下,溅射产率大大降低,其角度依赖性也趋于平缓。在这项工作中,我们研究了利用溅射(一种易于控制、环境友好、用途广泛、可扩展且成本低廉的技术)制造孤立 W 纳米柱的能力。我们研究了溅射参数(等离子功率和沉积角度)对沉积涂层的形态、密度和微观结构的影响。结果表明,在低等离子体功率(<100 W)和高沉积角(θ ≥ 75°)条件下,可以制备出稳定的 α 相三维孤立 W 纳米柱。
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引用次数: 0
Irradiation effects on copper oxide superconductors including high-entropy REBCO(HE-REBCO) 辐照对包括高熵 REBCO(HE-REBCO)在内的氧化铜超导体的影响
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-19 DOI: 10.1016/j.nme.2024.101709
Kota Sakurai , Aichi Yamashita , Yoshikazu Mizuguchi , Kiyohiro Yabuuchi , Naoko Oono-Hori

Polycrystalline specimens of copper oxide superconductors YBa2Cu3O7-δ(YBCO), Y0.39Sm0.30Eu0.31Ba2Cu3O7-δ(ME-REBCO), Y0.18La0.24Nd0.14Sm0.14Eu0.15Gd0.15Ba2Cu3O7-δ (HE-REBCO) were irradiated with 1 MeV-He ions at room temperature. Magnetization measurement using superconducting quantum interference device (SQUID) and microstructure observation using transmission electron microscope (TEM) were conducted before and after irradiation. The improvement of properties in HE-REBCO and degradations in YBCO, ME-REBCO were suggested by SQUID measurement. HE-REBCO had smaller irradiation defects and volume fractions although disappearance of twin boundaries due to tetragonal transition occurred in peak-damage area as well as YBCO. These defects work as optimal flux pinning centers leading to improve properties in HEREBCO.

在室温下用 1 MeV-He 离子辐照了氧化铜超导体 YBa2Cu3O7-δ(YBCO)、Y0.39Sm0.30Eu0.31Ba2Cu3O7-δ(ME-REBCO)、Y0.18La0.24Nd0.14Sm0.14Eu0.15Gd0.15Ba2Cu3O7-δ(HE-REBCO)的多晶试样。在辐照前后使用超导量子干涉装置(SQUID)进行了磁化测量,并使用透射电子显微镜(TEM)观察了微观结构。SQUID 测量结果表明,HE-REBCO 的性能有所改善,而 YBCO 和 ME-REBCO 的性能有所下降。HE-REBCO 的辐照缺陷和体积分数较小,但在峰值损伤区和 YBCO 中,由于四方转变导致孪晶边界消失。这些缺陷可作为最佳磁通钉中心,从而改善 HEREBCO 的性能。
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引用次数: 0
Microstructural and mechanical properties of Al-base coated EUROFER-97 铝基涂层 EUROFER-97 的微结构和机械性能
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-18 DOI: 10.1016/j.nme.2024.101711
Liberato Volpe, Tamsin Whitfield, Luke Hewitt, Joven Lim

Coolant-facing alloys in a tokamak will face harsh environments due to the synergistic effect of flowing coolant, dynamic mechanical loading, ionising radiation, and tritium embrittlement. Reduced activation ferritic/martensitic (RAF/M) EUROFER-97 is the primary candidate as the structural alloy for the breeder blanket to be used in DEMO reactor. Under fusion-like conditions, coatings are required to improve both its corrosion properties and act as a tritium permeation barrier (TPB) layer. In this study, Al-base self-passivating coatings have been investigated as possible solution to provide protection against corrosion and act as TPB layer. The aim of this study was to assess the adhesion properties between different self-passivating Al-base coatings as electroplated and chemical vapour deposited (CVD) coatings on a RAF/M EUROFER-97 under strain. These studies showed the high ductility of pure electroplated Al-coatings, whereas both CVD coatings cracked under the applied strain.

由于流动冷却剂、动态机械负载、电离辐射和氚脆性的协同作用,托卡马克中的冷却剂面合金将面临恶劣的环境。还原活化铁素体/马氏体(RAF/M)EUROFER-97 是 DEMO 反应堆所用增殖毯结构合金的主要候选材料。在类核聚变条件下,需要使用涂层来改善其腐蚀性能,并充当氚渗透屏障(TPB)层。在这项研究中,对铝基自钝化涂层进行了调查,作为提供防腐蚀保护并充当氚渗透屏障层的可能解决方案。本研究的目的是评估 RAF/M EUROFER-97 上不同自钝化铝基涂层(电镀涂层和化学气相沉积(CVD)涂层)在应变条件下的附着特性。这些研究表明,纯电镀铝涂层具有很高的延展性,而两种化学气相沉积涂层在施加应变时都会开裂。
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引用次数: 0
New processing routes for Zr-based ODS ferritic steels Zr 基 ODS 铁素体钢的新加工路线
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-17 DOI: 10.1016/j.nme.2024.101713
M. Oñoro , E. Salas-Colera , S.R. Parnell , V. Martin-Diaconesu , D. Alba Venero , T. Leguey , V. de Castro , M.A. Auger

In this work, Zr addition is proposed to refine the nanoparticle dispersion in an ODS RAF steel of composition Fe-14Cr-2W-0.3Zr-0.24Y (wt.%). Three batches of material are obtained using pre-alloyed atomized powder, where yttrium is directly introduced in the melt, and manufactured through three different processing routes. First route is based on the newly developed STARS route that aims to avoid subsequent mechanical alloying. The second route explores the impact of mechanical alloying in pre-oxidized powders. The third route uses mechanically alloyed powders without the pre-oxidation process. The ODS-powders were individually consolidated by hot isostatic pressing and later hot rolled. The obtained materials were characterized by small-angle neutron scattering (SANS) and X-ray absorption spectroscopy (XAS) techniques. SANS and XAS analysis point out the absence of oxide nanoparticles in the material based on the STAR route. SANS analysis confirms that the mechanically alloyed materials do exhibit the presence of nanoparticles. These are identified as Zr-O-rich nanoprecipitates by XAS and the calculated A-ratio by SANS is linked with the phase Y2Zr2O7. Their radii are in the range of 3–3.6 nm. XAS results show that mechanical alloying minimizes the initial differences regarding the oxidation state between the ODS powders with and without pre-oxidation.

在这项工作中,建议添加 Zr 以细化成分为 Fe-14Cr-2W-0.3Zr-0.24Y (wt.%) 的 ODS RAF 钢中的纳米粒子分散。我们使用预合金化雾化粉末(钇直接进入熔体)获得了三批材料,并通过三种不同的加工路线进行生产。第一种工艺基于新开发的 STARS 工艺,旨在避免后续的机械合金化。第二条路线是探索预氧化粉末中机械合金化的影响。第三种方法使用机械合金粉末,而不使用预氧化工艺。ODS 粉末通过热等静压单独固结,然后进行热轧。获得的材料通过小角中子散射(SANS)和 X 射线吸收光谱(XAS)技术进行表征。SANS 和 XAS 分析表明,基于 STAR 路线的材料中不存在氧化物纳米颗粒。SANS 分析证实,机械合金材料中确实存在纳米颗粒。根据 XAS 和 SANS 计算的 A 比率,这些纳米颗粒与 Y2Zr2O7 相联系在一起,被确定为富含 Zr-O 的纳米沉淀物。它们的半径在 3-3.6 纳米之间。XAS 分析结果表明,机械合金化可最大限度地减少预氧化和未预氧化 ODS 粉末之间的初始氧化态差异。
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引用次数: 0
Investigation of mechanical characteristics of hot-pressed sintered tungsten based advanced shielding materials 热压烧结钨基先进屏蔽材料的机械特性研究
IF 2.3 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2024-07-15 DOI: 10.1016/j.nme.2024.101710
Xiang Geng , Qiang Qi , Wu Wang , Tom Guo , Yubo Cai , Shouxi Gu , Qingjun Zhu , Hai-Shan Zhou , Songlin Liu , Guang-Nan Luo

This research aims to investigate the application of the hot pressing (HP) sintering process in the fabrication of W-B-Fe-Cr-C advanced shielding materials and analyze the relationship between their microstructure and mechanical properties. The findings reveal that the HP sintering process can effectively produce reactive sintered boride (RSB) materials with high density and engineering application size. The results indicate that the residual stress in RSB-HP improves its bending strength to some extent. Residual stress and granular structure are both related to phase aggregation during sintering. Microstructural analysis has unveiled the granular organizational characteristics and the pathways of crack propagation within the RSB-HP. These discoveries hold significant importance for comprehending the potential of the HP sintering process in the context of nuclear fusion shielding material preparation and provide a scientific foundation for further optimizing the sintering process and performance of RSB materials.

本研究旨在探讨热压(HP)烧结工艺在制造 W-B-Fe-Cr-C 高级屏蔽材料中的应用,并分析其微观结构与机械性能之间的关系。研究结果表明,热压烧结工艺能有效生产出具有高密度和工程应用尺寸的反应烧结硼化物(RSB)材料。结果表明,RSB-HP 中的残余应力在一定程度上提高了其抗弯强度。残余应力和颗粒结构都与烧结过程中的相聚集有关。微结构分析揭示了 RSB-HP 中的颗粒组织特征和裂纹扩展途径。这些发现对于理解 HP 烧结工艺在核聚变屏蔽材料制备方面的潜力具有重要意义,并为进一步优化 RSB 材料的烧结工艺和性能奠定了科学基础。
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Nuclear Materials and Energy
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