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Depth-resolved deuterium retention profiles in displacement-damaged tungsten measured via picosecond-laser-induced ablation quadrupole mass spectrometry 利用皮秒激光诱导烧蚀四极杆质谱法测量位移损伤钨中的深度分辨氘保留谱
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2026-01-09 DOI: 10.1016/j.nme.2026.102059
C. Kawan , S. Brezinsek , E. Wüst , T. Dittmar , T. Schwarz-Selinger , M. Rasinski , S. Möller , L. Gao , Ch. Linsmeier
<div><div>Tungsten (W) is the most promising plasma-facing material candidate for future deuterium–tritium (D–T) fusion reactors due to its favorable properties, such as low sputtering yield, low chemical reactivity, high melting point, and low intrinsic fuel retention. However, highly energetic neutrons from DT fusion reactions can cause displacement damage in the W lattice and enhance fuel retention. This affects the tritium cycle requirements and nuclear safety, as a tritium inventory builds up in the vessel. Therefore, diagnostics are required to quantify the D and T content in-situ in the plasma-facing and structural materials. Laser-induced Ablation Quadrupole Mass Spectrometry (LIA-QMS) is a promising method for quantifying fuel content with good spatial and depth resolution. LIA-QMS can be simultaneously applied with Laser-induced Breakdown Spectroscopy (LIBS). Combining both techniques provides the high depth resolution of LIBS with the quantification capabilities of LIA-QMS. This study compares D depth profiles recorded with pico-second LIA-QMS with Nuclear Reaction Analysis (NRA) with <span><math><msup><mrow></mrow><mrow><mn>3</mn></mrow></msup></math></span>He beam on a displacement-damaged W sample. The comparison reveals the depth profiling capabilities, strengths, and weaknesses of LIA-QMS using picosecond lasers. A set of similarly self-damaged (10.8 MeV W<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span> irradiated) ITER-grade W samples from PLANSEE was gently loaded with D in a low-temperature plasma at 370 K. The D concentration was varied by subsequent annealing of the samples at different temperatures in a vacuum after the D decoration. The ratio between D<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> and HD, both contributing to the total D content, increases from 1:1 to 1:5, starting at the surface and extending to <span><math><mrow><mn>4</mn><mspace></mspace><mi>μ</mi><mi>m</mi></mrow></math></span>, with increasing depth. LIA-QMS shows a similarly high sensitivity (<span><math><mo><</mo></math></span>0.05 at<span><math><mtext>%</mtext></math></span> D at a 15 nm average ablation rate (AAR)) as NRA (around 150-400 nm resolution). ps-LIA-QMS can be calibrated via a known amount of reference gas injections and deviates from the NRA results by a factor of 1.7 across all samples, which also includes non-volatile species. The laser-induced crater surface stays relatively flat for up to <span><math><mrow><mn>4</mn><mspace></mspace><mi>μ</mi><mi>m</mi></mrow></math></span> until surface structures start dominating the crater’s surface under the given laser parameters. <span><math><mi>μ</mi></math></span>-NRA in and around the craters shows complete removal of D inside the laser crater. Thermal effects due to the ps-pulses within the crater floor are indicated, but could not be quantified yet. In conclusion, this study shows a good agreement between ps-LIA-QMS, a p
钨(W)具有低溅射率、低化学反应性、高熔点和低固有燃料滞留等优点,是未来氘-氚(D-T)聚变反应堆最有前途的面向等离子体材料候选材料。然而,来自DT聚变反应的高能量中子会引起W晶格的位移损伤,并增强燃料的保留。这影响了氚循环要求和核安全,因为氚库存在容器中积累。因此,诊断需要在等离子体表面和结构材料中原位量化D和T含量。激光诱导烧蚀四极杆质谱法(LIA-QMS)具有良好的空间分辨率和深度分辨率,是一种很有前途的燃料含量定量方法。LIA-QMS可与激光诱导击穿光谱(LIBS)同时应用。结合这两种技术提供了LIBS的高深度分辨率和LIA-QMS的定量能力。本研究比较了皮秒LIA-QMS与3He束核反应分析(NRA)在位移损伤W样品上记录的D深度剖面。通过比较,揭示了使用皮秒激光的LIA-QMS的深度剖面能力、优点和缺点。一组来自PLANSEE的类似自损伤(10.8 MeV W3+辐照)的iter级W样品在370 K低温等离子体中缓慢加载D。经过D修饰后,对样品进行不同温度的真空退火处理,得到不同浓度的D。随着深度的增加,D2和HD对总D含量的贡献比例从1:1增加到1:5,从地表开始,延伸到4μm;LIA-QMS显示出与NRA(约150-400 nm分辨率)相似的高灵敏度(在15 nm平均消融率(AAR)下,% D时<;0.05)。ps-LIA-QMS可以通过已知的参比气体注入量进行校准,并且在所有样品中与NRA结果的偏差为1.7倍,其中也包括非挥发性物质。在给定的激光参数下,激光诱导的陨石坑表面保持相对平坦达4μm,直到表面结构开始主导陨石坑表面。μ-NRA显示激光撞击坑内部的D被完全去除。由于陨石坑底部的ps脉冲的热效应被指出,但还不能量化。综上所述,本研究表明,作为一种潜在的原位法,ps-LIA-QMS与参考的非原位法NRA在D的定量上具有良好的一致性。这为研究烧蚀过程中粒子壁相互作用的开放性问题铺平了道路。
{"title":"Depth-resolved deuterium retention profiles in displacement-damaged tungsten measured via picosecond-laser-induced ablation quadrupole mass spectrometry","authors":"C. Kawan ,&nbsp;S. Brezinsek ,&nbsp;E. Wüst ,&nbsp;T. Dittmar ,&nbsp;T. Schwarz-Selinger ,&nbsp;M. Rasinski ,&nbsp;S. Möller ,&nbsp;L. Gao ,&nbsp;Ch. Linsmeier","doi":"10.1016/j.nme.2026.102059","DOIUrl":"10.1016/j.nme.2026.102059","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Tungsten (W) is the most promising plasma-facing material candidate for future deuterium–tritium (D–T) fusion reactors due to its favorable properties, such as low sputtering yield, low chemical reactivity, high melting point, and low intrinsic fuel retention. However, highly energetic neutrons from DT fusion reactions can cause displacement damage in the W lattice and enhance fuel retention. This affects the tritium cycle requirements and nuclear safety, as a tritium inventory builds up in the vessel. Therefore, diagnostics are required to quantify the D and T content in-situ in the plasma-facing and structural materials. Laser-induced Ablation Quadrupole Mass Spectrometry (LIA-QMS) is a promising method for quantifying fuel content with good spatial and depth resolution. LIA-QMS can be simultaneously applied with Laser-induced Breakdown Spectroscopy (LIBS). Combining both techniques provides the high depth resolution of LIBS with the quantification capabilities of LIA-QMS. This study compares D depth profiles recorded with pico-second LIA-QMS with Nuclear Reaction Analysis (NRA) with &lt;span&gt;&lt;math&gt;&lt;msup&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;3&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/math&gt;&lt;/span&gt;He beam on a displacement-damaged W sample. The comparison reveals the depth profiling capabilities, strengths, and weaknesses of LIA-QMS using picosecond lasers. A set of similarly self-damaged (10.8 MeV W&lt;span&gt;&lt;math&gt;&lt;msup&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;3&lt;/mn&gt;&lt;mo&gt;+&lt;/mo&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/math&gt;&lt;/span&gt; irradiated) ITER-grade W samples from PLANSEE was gently loaded with D in a low-temperature plasma at 370 K. The D concentration was varied by subsequent annealing of the samples at different temperatures in a vacuum after the D decoration. The ratio between D&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; and HD, both contributing to the total D content, increases from 1:1 to 1:5, starting at the surface and extending to &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;μ&lt;/mi&gt;&lt;mi&gt;m&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, with increasing depth. LIA-QMS shows a similarly high sensitivity (&lt;span&gt;&lt;math&gt;&lt;mo&gt;&lt;&lt;/mo&gt;&lt;/math&gt;&lt;/span&gt;0.05 at&lt;span&gt;&lt;math&gt;&lt;mtext&gt;%&lt;/mtext&gt;&lt;/math&gt;&lt;/span&gt; D at a 15 nm average ablation rate (AAR)) as NRA (around 150-400 nm resolution). ps-LIA-QMS can be calibrated via a known amount of reference gas injections and deviates from the NRA results by a factor of 1.7 across all samples, which also includes non-volatile species. The laser-induced crater surface stays relatively flat for up to &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;μ&lt;/mi&gt;&lt;mi&gt;m&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; until surface structures start dominating the crater’s surface under the given laser parameters. &lt;span&gt;&lt;math&gt;&lt;mi&gt;μ&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;-NRA in and around the craters shows complete removal of D inside the laser crater. Thermal effects due to the ps-pulses within the crater floor are indicated, but could not be quantified yet. In conclusion, this study shows a good agreement between ps-LIA-QMS, a p","PeriodicalId":56004,"journal":{"name":"Nuclear Materials and Energy","volume":"46 ","pages":"Article 102059"},"PeriodicalIF":2.7,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145977400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Charpy impact properties of EUROFER97-3 after neutron irradiation at 330 °C and 540 °C to damage doses of 21–23 dpa 在330°C和540°C中子辐照21-23 dpa损伤剂量下,EUROFER97-3的夏比冲击特性
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-02 DOI: 10.1016/j.nme.2026.102079
Vladimir Chakin, Carsten Bonnekoh, Ramil Gaisin, Rainer Ziegler, Michael Duerrschnabel, Michael Klimenkov, Bronislava Gorr, Michael Rieth
The reduced activation ferritic-martensitic (RAFM) EUROFER97-3 steel of two heat treatments (EUROFER97-3_1100/700 and EUROFER97-3_980/780) after irradiation in the BOR-60 fast reactor at temperatures of 330 °C and 540 °C, with damage doses ranging from 21.6 to 22.8 dpa showed big differences in the Charpy impact properties depending on the irradiation temperature. Significant drop in the upper shelf energy (USE) and shift of the ductile–brittle transition temperature (DBTT) occurred after irradiation at 330 °C. However, irradiation at 540 °C resulted in only minor changes in the USE and DBTT compared to the unirradiated reference state. Probably, these changes are attributed of the formation of radiation-induced defects and evolution in the phase structure.
在330℃和540℃条件下,损伤剂量在21.6 ~ 22.8 dpa范围内,经bor60快堆辐照后,还原活化铁素体-马氏体(RAFM) EUROFER97-3钢的Charpy冲击性能随辐照温度的变化有较大差异。在330℃辐照后,上架能(USE)显著下降,韧脆转变温度(DBTT)发生显著变化。然而,与未照射的参考状态相比,540°C照射仅导致USE和DBTT的微小变化。这些变化可能是由于辐射缺陷的形成和相结构的演变。
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引用次数: 0
Quantifying helium-bubble swelling in RAFM steels using TEM and the surface-step method 用透射电镜和表面步进法定量测定RAFM钢中的氦泡膨胀
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2026-03-03 DOI: 10.1016/j.nme.2026.102095
Sangeun Kim , Hyung-Ha Jin , Chang-hoon Lee , Sanghoon Noh , Sungjin Kwon , Dong Won Lee , Chansun Shin
In fusion-relevant environments where transmutation helium accumulates, He bubble formation can become a critical damage mechanism in reduced-activation ferritic/martensitic (RAFM) steels because it drives swelling and can degrade mechanical performance. Swelling is often assessed indirectly from surface-step height measurements and nanoindentation mapping, yet their quantitative relationship to the underlying bubble population remains unclear. Here, He bubbles in K-RAFM steels and a Eurofer97-like reference steel were quantified by cross-sectional TEM after 160 keV He implantation and post-irradiation annealing (PIA) at 300–500 °C. Bubble size distributions, number densities, and bubble-volume-fraction-based swelling were evaluated and directly compared with step-height- and hardness-based metrics. Bubble nucleation was most evident at 300–400 °C through an increase in number density, whereas pronounced coarsening at 500 °C led to a sharp increase in swelling. Step height reproduced the temperature-dependent swelling trend, while the nanoindentation hardening response was more closely linked to bubble number density than to bubble size. In addition, sequential H/He implantation revealed a clear He–H synergy, with a stronger enhancement of bubble density and swelling when H was implanted after He (He + H) than in the reverse order (H + He).
在与聚变相关的环境中,嬗变氦积聚,氦泡的形成可能成为低活化铁素体/马氏体(RAFM)钢的关键损伤机制,因为它会导致膨胀并降低机械性能。膨胀通常通过表面台阶高度测量和纳米压痕测绘间接评估,但它们与潜在气泡数量的定量关系尚不清楚。在300-500℃下,160 keV He注入和辐照后退火(PIA)后,用透射电镜定量了K-RAFM钢和类似eurofer97的参比钢中的He气泡。对气泡尺寸分布、气泡数量密度和气泡体积分数进行评估,并与基于台阶高度和硬度的指标进行直接比较。在300-400℃时,气泡成核最明显,数量密度增加,而在500℃时,明显的粗化导致膨胀急剧增加。台阶高度再现了温度依赖的膨胀趋势,而纳米压痕硬化响应与气泡数密度的关系比与气泡尺寸的关系更密切。此外,顺序H/He注入显示出明显的He - H协同作用,在He (He + H)之后注入H比在相反的顺序(H + He)之前注入H对气泡密度和膨胀的增强更强。
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引用次数: 0
Self-blocking driven interstitial confinement at metallic grain boundaries 金属晶界自阻塞驱动的间隙约束
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2025-12-11 DOI: 10.1016/j.nme.2025.102044
Qilong Cao , Fangqing Qian , Xiaolin Li , Panpan Wang , He Tong , Yange Zhang , Yichun Xu , Xianping Wang , C.S. Liu , Xiang-Yan Li
Grain boundaries (GBs) serve as critical microstructural features in determining the radiation resistance of nanocrystalline metals through their capacity to absorb radiation-induced defects, particularly self-interstitial atoms (SIAs) and vacancies (Vs). Nevertheless, the fundamental mechanism governing SIA dynamics near GBs that dominate defect–GB interactions remain inadequately elucidated. This knowledge gap is primarily due to the fact that the time scale of SIA diffusion and its segregation towards GBs is significantly smaller than that of other events, leading to its preferential segregation to GBs and decoupling from other defects. In this study, we employ combined molecular statics and dynamics simulations to systematically investigate the atomic-scale behavior of SIA and its cluster (SIAn) states near GBs in three body-centered cubic metals (tungsten, molybdenum and iron), while concurrently exploring potential V annihilation mechanisms associated with these processes. We propose a “self-blocking” mechanism governing the behavior of the SIAn near GBs at low temperatures. As accumulated SIAns progressively occupy GB trapping sites, subsequent incoming clusters experience spatial confinement within the near-boundary region. These constrained SIAns exhibit intermediate energy states between bulk configuration states and fully GB-trapped states. Crucially, the partially constrained SIAns demonstrate two distinctive features of an enhanced V annihilation volume exceeding that of GB-trapped clusters by several times (attributed to their preserved bulk-like atomic configurations) and long-range repulsive interactions with bulk SIAs (potentially modifying defect-trapping dynamics of GBs). This self-blocking phenomenon implies both a saturation threshold for GB defect absorption capacity and an extended boundary zone facilitating V–SIA recombination. The spatially confined annihilation pathway near GBs provides a potential channel for eliminating bulk defects at low temperatures, offering new insights into the atomic-scale self-healing processes in nanocrystalline materials.
晶界(GBs)是决定纳米晶金属抗辐射能力的关键微观结构特征,通过它们吸收辐射诱导缺陷的能力,特别是自间隙原子(SIAs)和空位(Vs)。然而,控制缺陷-缺陷相互作用的gb附近SIA动力学的基本机制仍然没有充分阐明。这种知识差距主要是由于SIA扩散及其向GBs偏析的时间尺度明显小于其他事件,导致其优先向GBs偏析并与其他缺陷解耦。在这项研究中,我们采用分子静力学和动力学模拟相结合的方法,系统地研究了三种体心立方金属(钨、钼和铁)在GBs附近SIA及其簇态(SIAn)的原子尺度行为,同时探索了与这些过程相关的潜在V湮灭机制。我们提出了一种“自阻塞”机制来控制低温下GBs附近的SIAn行为。当累积的sis逐渐占据GB捕获位点时,随后进入的簇在近边界区域内经历空间限制。这些受约束的原子表现出介于体态和完全gb捕获态之间的中间能态。至关重要的是,部分约束的SIAs表现出了两个显著的特征:增强的V湮灭体积比gb捕获的簇多几倍(归因于它们保留了块状原子构型),以及与本体SIAs的远程排斥相互作用(可能改变gb的缺陷捕获动力学)。这种自阻塞现象意味着存在GB缺陷吸收能力的饱和阈值和有利于V-SIA复合的扩展边界区。GBs附近的空间受限湮灭路径为在低温下消除体缺陷提供了一个潜在的通道,为纳米晶体材料的原子尺度自愈过程提供了新的见解。
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引用次数: 0
Primary and secondary metallic PFC damage induced by runaway electron dissipation in FTU FTU中失控电子耗散引起的一次和二次金属PFC损伤
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-19 DOI: 10.1016/j.nme.2026.102089
M. De Angeli , P. Tolias , S. Ratynskaia , D. Ripamonti , M. Iafrati , G. Maddaluno , G. Daminelli , E. Fortuna-Zalesna
Runaway electron (RE) interaction with plasma-facing components (PFCs) has been documented to lead to deep volumetric melting and thermal shock driven material explosions followed by extensive wall cratering. This work reports a post-mortem FTU investigation that covers the primary localized RE-induced damage directly caused by beams striking poloidal or toroidal molybdenum (Mo)-based limiters and the subsequent secondary non-localized RE-induced damage inflicted on nearby limiter tiles by the mechanical impact of fast up to 1  km/s solid debris violently ejected during the direct RE-PFC interaction. Early indications on the resilience of tin liquid limiters to RE incidence are also presented.
失控电子(RE)与等离子体面组件(pfc)的相互作用导致深度体积熔化和热冲击驱动的材料爆炸,随后是广泛的壁坑。这项工作报告了一项事后FTU调查,该调查涵盖了由光束撞击极向或环向钼基限制器直接引起的主要局部re诱导损伤,以及在RE-PFC直接相互作用期间剧烈抛射的快速固体碎片对附近限制器瓦造成的随后的二次非局部re诱导损伤。还提出了锡液限制剂对稀土发生率的回弹性的早期迹象。
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引用次数: 0
Dust deposition on plasma-facing substrates extracted from the WEST Tokamak 从西托卡马克提取的等离子体表面衬底上的尘埃沉积
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2026-01-03 DOI: 10.1016/j.nme.2025.102056
Nathan Nelson , Céline Martin , Cécile Arnas , Andrea Campos , Elodie Bernard , Chijin Xiao , Lénaïc Couëdel , West Team
Dust particles deposited during the first phase of operation of the WEST tokamak were collected and analysed from substrates positioned at four distinct poloidal locations along the inner wall. Among various particle types composed of materials present in the vacuum vessel, previously unreported tungsten molten splashes exhibiting highly distinctive “stethoscope-like” morphologies were discovered. These unusual tungsten particles were found in large numbers exclusively on substrates located closest to the lower divertor. They display a well-defined log-normal size distribution, with average lengths ranging from 0.75 to 1.5 µm, and a clear angular alignment pointing predominantly away from the divertor. This directional distribution provides compelling evidence that they were ejected from the lower divertor region. Additionally, more conventional tungsten ellipsoidal particles were identified across all four poloidal positions. These ellipsoids were most abundant near the divertor and exhibited progressively more elongated shapes and less distinct alignment patterns with increasing distance, suggesting a common origin but different transport histories. Their size distributions are also log-normal, with average diameters between 100 and 200 nm. The characteristics of both particle types (distribution, size scaling, and directionality) suggest a common origin in molten tungsten droplets expelled from the lower divertor, most likely as a result of arcing events.
在WEST托卡马克第一阶段运行期间沉积的尘埃颗粒被收集和分析,这些尘埃颗粒来自位于内壁四个不同极向位置的基板。在真空容器中存在的各种由材料组成的颗粒类型中,发现了以前未报道的钨熔融飞溅,表现出高度独特的“听诊器样”形态。这些不寻常的钨颗粒大量出现在靠近下分流器的底物上。它们显示出明确的对数正态尺寸分布,平均长度范围为0.75至1.5 μ m,并且明显的角度对准主要指向远离导流器。这种定向分布提供了令人信服的证据,表明它们是从较低的分流区喷出的。此外,在所有四个极向位置上都可以识别出更传统的钨椭球体颗粒。这些椭球体在转向器附近最为丰富,随着距离的增加,椭球体的形状逐渐变长,排列模式越来越不明显,表明它们有共同的起源,但不同的运输历史。它们的尺寸分布也是对数正态分布,平均直径在100到200纳米之间。两种颗粒类型的特征(分布、尺寸尺度和方向性)表明,它们的共同起源是由下部分流器喷出的熔融钨液滴,很可能是电弧事件的结果。
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引用次数: 0
Overview of advanced plasma-facing materials testing for Fusion Pilot Plants at DIII-D DIII-D聚变中试工厂先进等离子体表面材料测试概述
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2026-01-14 DOI: 10.1016/j.nme.2026.102064
Jonathan Coburn , Florian Effenberg , Mary Alice Cusentino , Chase Hargrove , Mykola Ialovega , Maria Morbey , Lauren Nuckols , Žana Popović , Zachary Bergstrom , Shawn Zamperini , Tyler Abrams , Dmitry Rudakov , Shota Abe , Shane Evans , Tatsuya Hinoki , Ryan Hood , Eric Lang , Charlie Lasnier , Ulises Losada , Claudio Marini , Weicheng Zhong
Characterization and testing of advanced plasma-facing materials (PFMs) for Fusion Pilot Plants (FPP) is being conducted at the DIII-D National Fusion Facility through the ongoing two-year FPP Candidate Materials Thrust. Year one tested 17 novel materials utilizing the Divertor Materials Evaluation System (DiMES), with samples analyzed pre- and post-experiment via SEM, EDS, and confocal microscopy. Repeatable reference discharges were developed to ensure uniformity between experiments, including a new strike-point rastering scenario to provide more uniform heat/particle flux across DiMES during ELMing H-mode discharges. Various sample geometries and temperatures were used to achieve FPP-relevant conditions, including samples angled 10° towards the incident plasma flux and pre-heating up to 500 °C.
The first exposure of liquid lithium (Li) capillary porous structures in a tokamak demonstrated uniform emission of Li vapor and suppression of Li droplets in H-mode when preheated to 350 °C. Dispersoid-strengthened W with 1 wt% TaC, TiC, and ZrC exposed to H-mode showed cracking and dispersoid ejection for all varieties except TiC, providing a clear down-selection. Ultra-high temperature ceramic materials TiB2 and ZrB2 showed minimal degradation under L-mode exposure. Silicon carbide (SiC) fiber composites showed arcing along edges, while CVD SiC remained pristine. Atmospheric plasma-sprayed W and SiC coatings endured H-mode exposure without macroscopic delamination; SiC exhibited granular ejection, while W showed increased outgassing. Additional W-based alloys were stress tested in H-mode, including Ni-based W heavy alloys, WfSiCf/W composites, W multi-principle element alloys, and functionally-graded W/SiC, to varying degrees of success.
DIII-D国家聚变设施正在通过正在进行的为期两年的FPP候选材料推力,对聚变中试工厂(FPP)的先进等离子体表面材料(pfm)进行表征和测试。第一年使用DiMES (Divertor materials Evaluation System)测试了17种新材料,并通过扫描电镜(SEM)、能谱仪(EDS)和共聚焦显微镜对实验前后的样品进行了分析。开发了可重复的参考放电以确保实验之间的均匀性,包括一个新的击点光栅场景,以在ELMing h模式放电期间提供更均匀的热/粒子通量。不同的样品几何形状和温度被用来达到fpp相关的条件,包括样品与入射等离子体通量成10°角,预热到500°C。首次在托卡马克中暴露液态锂(Li)毛细孔结构,当预热到350℃时,在h模式下Li蒸气均匀发射,Li液滴被抑制。添加1 wt% TaC、TiC和ZrC的弥散增强W在h模式下,除TiC外,所有品种均出现开裂和弥散弹射,提供了明确的向下选择。超高温陶瓷材料TiB2和ZrB2在l模式下的降解最小。碳化硅(SiC)纤维复合材料的边缘呈弧形,而CVD SiC则保持原始状态。大气等离子喷涂W和SiC涂层可承受h模式暴露而无宏观分层;SiC表现为颗粒状喷射,W表现为脱气增加。在h模式下对其他W基合金进行了应力测试,包括ni基W重合金、WfSiCf/W复合材料、W多元素合金和功能梯度W/SiC,均取得了不同程度的成功。
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引用次数: 0
A genetic algorithm to optimize the multi-group structure for the neutronic analyses of the ARC fusion reactor ARC聚变反应堆中子分析多群结构优化的遗传算法
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2026-01-27 DOI: 10.1016/j.nme.2026.102072
Alex Aimetta , Nicolò Abrate , Marco Caravello , Sandra Dulla , Antonio Froio , Mattia Massone
In the framework of the modeling of fusion reactors with deterministic neutronic codes, the choice of an appropriate energy grid for the generation of the multigroup nuclear properties is essential. In this work, a Genetic Algorithm is employed to optimize the energy grid employed in the nemoFoam multiphysics code to reproduce the results provided by the Monte Carlo code Serpent in terms of neutron flux, neutron power deposition and Tritium Breeding Ratio for the Affordable, Robust and Compact (ARC) fusion reactor. Different runs of the Genetic Algorithm are performed, with the aim of optimizing not only the quantities of interest separately, but also trying to combine them thanks to the definition of appropriate fitness functions. The optimization is performed starting from a pre-defined 86 groups energy grid, over which the nuclear properties and the reference quantities are evaluated with Serpent. The results show that it is not straightforward to optimize at the same time the energy grid for different quantities and that, in general, coarse energy grids are able to provide good results in nemoFoam for what concerns the ARC reactor, allowing to alleviate the computational burden of the neutronic evaluation too.
在具有确定性中子码的聚变反应堆建模框架中,选择合适的能量网格来生成多群核性质是至关重要的。在这项工作中,采用遗传算法来优化nemoFoam多物理场代码中使用的能量网格,以重现蒙特卡罗代码Serpent在可负担、稳健和紧凑(ARC)聚变反应堆的中子通量、中子功率沉积和氚增殖比方面提供的结果。对遗传算法进行不同的运行,目的不仅是单独优化感兴趣的数量,而且通过定义适当的适应度函数,尝试将它们组合在一起。从预定义的86组能量网格开始进行优化,并在此基础上使用Serpent评估核性质和参考量。结果表明,同时对不同数量的能量网格进行优化并不简单,总的来说,粗能量网格能够在nemoFoam中提供与ARC反应堆有关的良好结果,也可以减轻中子评估的计算负担。
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引用次数: 0
Simulations of beryllium castellation gap bridging during vertical displacement events 垂直位移事件中铍晶格间隙桥接的模拟
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2025-12-13 DOI: 10.1016/j.nme.2025.102048
L. Vignitchouk, JET Contributors
Multiphase Navier–Stokes simulations of castellated beryllium plates exposed to JET-like disruption plasma loads are performed to investigate melt transport in the vicinity of gaps and the formation of re-solidified bridges between adjacent castellation blocks. It is found that two-dimensional computations are able to predict whether bridging occurs and that they agree with experimental data in terms of characteristic melt infiltration depths and global material transport along the surface. However, three-dimensional set-ups appear to be necessary when estimates of the damaged component’s surface morphology are sought in cases where bridging does not occur. Comparisons with simplified shallow-water models confirm that such models are applicable to scenarios in which bridges have already been formed, although they tend to overestimate the net melt displacement.
采用多相Navier-Stokes模拟方法,研究了暴露在类似喷射射流的等离子体载荷下的壳状铍板在间隙附近的熔体输运以及相邻壳状块之间再固化桥的形成。发现二维计算能够预测桥接是否发生,并且在特征熔体渗透深度和沿表面的整体物质输送方面与实验数据一致。然而,在桥接不发生的情况下,当寻求损坏部件表面形态的估计时,三维设置似乎是必要的。与简化的浅水模型的比较证实,这种模型适用于桥梁已经形成的情况,尽管它们往往高估了净融化位移。
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引用次数: 0
Modification of chemical and mechanical properties of p-W-O coating after Magnum-PSI D2-N2 plasma exposure and its consequences for the analysis of LIBS spectra Magnum-PSI D2-N2等离子体辐照后p-W-O涂层化学力学性能的改变及其对LIBS光谱分析的影响
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-03-01 Epub Date: 2026-01-17 DOI: 10.1016/j.nme.2026.102065
Indrek Jõgi , Peeter Paris , Kaarel Piip , Jordy Vernimmen , Beata Tyburska-Pueschel , Sven Lange , Taivo Jõgiaas , Matteo Passoni , David Dellasega , Gabriele Alberti , Hennie van der Meiden
The present study investigated the effect of D2-N2 (7%) plasma exposure in Magnum-PSI on the D retention and chemical and mechanical properties of a porous W-O (p-W-O) coating. The variation of the chemical composition, crystalline phase and mechanical properties along the sample surface were determined by Nuclear Reaction Analysis (NRA), Rutherford Backscattering Spectroscopy (RBS), nanoindentation and Raman spectroscopy. These changes were compared to the Laser-Induced Breakdown Spectroscopy (LIBS) measurements. LIBS depth profiles of W and Mo were consistent with the profiles determined by NRA and RBS, showing a W-O layer, a thin W adhesion layer and a Mo substrate. Typically, the high D intensity was determined only during the first LIBS laser shot on a measurement spot, while the spatial distribution of D intensity determined by LIBS along the coating surface followed the D concentration determined by NRA. According to the Raman spectra, the investigated p-W-O coating corresponded to nanograins of W-O and the phase composition was relatively uniform along the coating surface. The elastic modulus of p-W-O coating was considerably lower than the modulus of Mo coating or bulk W coating and corresponded to the values found in other studies carried out with W-O mixtures. The elastic modulus of p-W-O coating decreased towards the edge of the coating. The study revealed that the modulus and the background intensity of the LIBS spectra had a negative correlation, suggesting that LIBS may be a suitable method for the estimation of the stiffness of tungsten co-deposits as a similar correlation is shown for other types of W coatings.
本研究研究了在Magnum-PSI中暴露D2-N2(7%)等离子体对多孔W-O (p-W-O)涂层的D保留和化学力学性能的影响。采用核反应分析(NRA)、卢瑟福后向散射光谱(RBS)、纳米压痕和拉曼光谱测定了样品表面化学成分、晶相和力学性能的变化。这些变化与激光诱导击穿光谱(LIBS)测量结果进行了比较。W和Mo的LIBS深度分布图与NRA和RBS测定的分布图一致,呈现W- o层、薄W附着层和Mo衬底。通常情况下,高D强度仅在第一次LIBS激光射入测点时产生,而LIBS测定的D强度沿涂层表面的空间分布遵循NRA测定的D浓度。拉曼光谱表明,所制备的p-W-O涂层与W-O纳米颗粒相对应,涂层表面相组成相对均匀。p-W-O涂层的弹性模量大大低于Mo涂层或块状W涂层的弹性模量,与W- o混合物的其他研究结果一致。p-W-O涂层的弹性模量沿涂层边缘逐渐减小。研究表明,LIBS光谱的模量与背景强度呈负相关,表明LIBS可能是估计钨共镀层硬度的合适方法,因为其他类型的W涂层也显示出类似的相关性。
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引用次数: 0
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Nuclear Materials and Energy
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