Glass and Ceramics最新文献

A technology for facing material based on mechanically activated cullet modified with potassium hydroxide was developed. The phase composition, macro- and microstructure of the facing material were studied. It was found that the structure of the composite modified with potassium hydroxide is represented in the interpore space by needle-shaped and columnar crystals of potassium silicates. Physicomechanical characteristics of facing material were investigated.

An energy-efficient synthesis of highly porous ceramic materials based on Sc₂O₃ was conducted using a combination of compaction and technological combustion methods with the participation of active binders. Using XRF (x-ray phase analysis), SEM (scanning electron microscopy), and EDA (energy dispersive analysis) methods, it was found that the investigated material has a morphology based on Sc₂O₃ and thortveitite Sc₂Si₂O₇ that is highly developed, multi-level, and microstructural. The basic characteristics of the material’s pore space (porosity, pore size, specific surface area, permeability, etc.) were determined by means of mercury porosimetry and alternative methods.

The influence of the technological glass-melting parameters of the selected composition in the SrO–Al₂O₃–P₂O₃–SiO₂–F system on the value of the refractive index and the amount of fluorine remaining in the glass structure post-melting was investigated. The lowering of the melting temperature combined with tableting of the charge [batch] increases fluorine absorption in the glass up to 17 wt.% at the same time, and the value of the refractive index reduction to n_D = 1.49. It was experimentally established that in the multicomponent glass selected for glass-ionomer cements with two glass-forming oxides (SiO₂ and P₂O₂) and a high Al₂O₃ content, each wt.% of fluorine reduces the refractive index by about 3.5 × 10 ^–4 units.

A method has been developed for securing an optical fiber in a quartz connector by using sodium polysilicate hydrogel formed in a cylindrical gap between a connector and an optical fiber by means of alkaline decomposition of the quartz surfaces of manufactured components. The conditions for the thermal decomposition of hydrogel are determined, and it is shown that hydrogel decomposition with cellular structure formation is possible at temperatures below the thermal decomposition temperature of the polymer coating of the optical fiber. The hydrogel formation conditions and the thermal properties of the hydrogel are determined. Conclusions regarding the suitability of the proposed method for securing an optical fiber in a quartz connector are drawn.

The influence of the modification of glass in the strontium-aluminum-boron-silicate system (SABS) on technological and physicochemical properties was investigated. Introducing two alkalis into the glass makeup significantly lowered the melting temperature, from 1500 to 1450°C, which effected changes in the properties of the glass. On introducing alkalis in amounts up to 5 mol.% the thermal linear expansion coefficient (LTEC) decreased from 58 to 50 (α × 10 ^{– 7} K^{– 1}) and the refractive index n_D from 1.551 to 1.528. However, alkaline components adversely affect the hydrolytic resistance of the glass, transferring it from hydrolytic class I to II. The solution to this problem was to: (1) employ the polyalkaline effect, (2) maintain high radiopacity of the glass by introducing a small amount of highly effective radiopaque barium oxide into the makeup and significant strontium oxide reduction, and (3) increase the aluminum oxide content, which ordinarily increases the chemical resistance of the glass. The result was improved melting properties on lower melting temperatures and glass with high values of x-ray contrast (about 550%), light transmission (T = 90%), refractive index values n_D = 1.530 and LTEC = 56 (α × 10 ^{– 7} K^{– 1}) were obtained while maintaining chemical stability with respect to water the corresponding hydrolytic class I.

It was found that the high decomposition temperature of amorphous Al(OH)₃ makes it possible to sinter corundum ceramics directly from aluminum hydroxide, bypassing the stage of its preliminary thermal dehydration. Using the cold isostatic pressing method at 200, 600, and 1000 MPa, compacts with densities of 62, 69, and 79% of the theoretical value were obtained. The temperature dependence of the shrinkage of amorphous Al(OH)₃ compacts was studied as a function of the cold isostatic pressing pressure. An area of intense shrinkage was discovered in the range 1050 – 1150°C, which coincides with both the temperature of complete decomposition of amorphous Al(OH)₃ and the transition γ → α-Al₂O₃.

The local Abrio method of birefringence assessment was applied for the first time to strengthened glasses, and it was used to investigate the micro-stress distribution in float glass subjected to ion-exchange strengthening. It is demonstrated that the thickness of the stressed layer can be determined with great precision, and a correlation is found between the depth of the stressed layer and the penetration depth of potassium cations in the course of ion exchange.

The effect of the eutectic additive of the system Li₂O–B₂O₃ on the sintering process and the dielectric properties of Li₂MgTi₃O₈-based ceramics was studied. It was found that the introduction of an additive in amounts 10.0 – 15.0% promotes sintering of ceramics by means of a liquid-phase mechanism. Li₂MgTi₃O₈-based ceramic, containing a sintering additive in the amount 15.0% and fired at 900°C, demonstrates the following property levels: average density ρ_av = 3.04 g/cm³, open porosity P_o = 5.7%, relative dielectric constant ε_r = 19.0, and dielectric loss tangent tan δ = 0.028. The lowered sintering temperature of the ceramic will allow the manufacture of different electronic components based on it, using low-temperature co-firing ceramic (LTCC) technology, and the a specified level of dielectric properties will allow the miniaturization of devices.