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Developed and characterization of a novel Cd doped CeO2 nanofilm and application of methyl orange removed by photodegradation 新型掺镉 CeO2 纳米薄膜的开发与表征以及光降解去除甲基橙的应用
IF 1.6 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-08-10 DOI: 10.1007/s12648-024-03361-7
Müge Söyleyici Çergel, Ersin Demir, Sema Kurtaran
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引用次数: 0
Utilizing a forced Van der Pol-Rayleigh-Helmholtz oscillator under heptamodal-frequency operations in Casimir force measurement 在卡西米尔力测量中利用七模态频率操作下的强迫范德波尔-雷利-赫姆霍兹振荡器
IF 1.6 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-08-09 DOI: 10.1007/s12648-024-03359-1
Cagri Yilmaz
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引用次数: 0
The effects of temperature and pressure on optical properties of spherical core/shell/shell quantum dot 温度和压力对球形核/壳/壳量子点光学特性的影响
IF 1.6 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-08-09 DOI: 10.1007/s12648-024-03362-6
E. B. Al
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引用次数: 0
Q-switched and mode-locked pulsed laser with mechanically exfoliated V2ZnC MAX saturable absorber in erbium-doped all-fibre laser 在掺铒全光纤激光器中使用机械剥离 V2ZnC MAX 可饱和吸收体的 Q 值开关和模式锁定脉冲激光器
IF 1.6 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-08-09 DOI: 10.1007/s12648-024-03313-1
Kawther M. Musthafa, A. Hamzah, Ooi Wei Ling, A. Rosol, Norliza Mohamed, Sulaiman Wadi Harun
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引用次数: 0
Anisotropic star with a linear equation of state (EOS) 具有线性状态方程(EOS)的各向异性恒星
IF 2 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-08-06 DOI: 10.1007/s12648-024-03297-y
Rinkal Patel, B. S. Ratanpal, Ranjan Sharma

A new form of the equation of state (EOS) is considered to develop a model for describing the interior of a static, spherically symmetric, compact anisotropic star. The analytic solution is obtained using the Finch and Skea ansatz for the metric potential (g_{rr},) with a distinct geometric interpretation for the related background spacetime. The model parameters are fixed by matching the interior solution to the Schwarzschild exterior metric over the boundary of the star, together with the requirement that the radial pressure vanishes at the boundary. Data available for the pulsar 4U1802030 has been utilized to analyze the physical viability of the developed model. The model is shown to be stable.

研究考虑了一种新形式的状态方程(EOS),以建立一个描述静态、球面对称、紧凑的各向异性恒星内部的模型。解析解是利用芬奇和斯基亚方差的度量势 (g_{rr},)得到的,并对相关背景时空进行了独特的几何解释。模型参数是通过将内部解与恒星边界上的施瓦兹柴尔德外部度量相匹配来固定的,同时要求径向压力在边界处消失。利用脉冲星 4U1802030 的现有数据分析了所建立模型的物理可行性。结果表明该模型是稳定的。
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引用次数: 0
Effect of deposition cycle and annealing on the structural, optical, electrical, and photoluminescence properties of SnS films obtained from rapid S-SILAR technique 沉积周期和退火对快速 S-SILAR 技术获得的 SnS 薄膜的结构、光学、电学和光致发光特性的影响
IF 2 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-08-04 DOI: 10.1007/s12648-024-03349-3
Pawan Kumar, Gowrish K. Rao

In this paper, we present an optimized procedure for depositing SnS thin films using the rapid S-SILAR technique. We also analyze the effects of deposition cycles and post-deposition annealing on various film properties. XRD analysis indicates the presence of orthorhombic and cubic phases in the films. Energy dispersive X-ray analysis confirms near-optimal stoichiometry. SEM images depict the growth of closely spaced spherical granules. High optical absorption is observed in the mid-visible to NIR region, with the absorption edge shifting towards the NIR region after annealing. The bandgap values range from 1.6 eV to 1.9 eV, which is ideal for photovoltaic applications. PL spectra show three clusters of peaks corresponding to red and green emissions. Hall measurements confirm that both the as-deposited and annealed SnS films exhibit p-type conductivity, with a hole concentration on the order of 1015 cm−3.

本文介绍了利用快速 S-SILAR 技术沉积 SnS 薄膜的优化程序。我们还分析了沉积周期和沉积后退火对各种薄膜特性的影响。XRD 分析表明薄膜中存在正方和立方相。能量色散 X 射线分析证实了接近最佳的化学计量。扫描电子显微镜(SEM)图像描绘了紧密间隔的球形颗粒的生长过程。在中可见光到近红外区域观察到高光学吸收,退火后吸收边缘向近红外区域移动。带隙值在 1.6 eV 至 1.9 eV 之间,非常适合光伏应用。PL 光谱显示出三个峰群,分别对应于红色和绿色发射。霍尔测量证实,沉积和退火后的 SnS 薄膜都具有 p 型导电性,空穴浓度约为 1015 cm-3。
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引用次数: 0
Obliquely nonlinear solitary waves in magnetized electron–positron–ion plasma 磁化电子-正电子-离子等离子体中的斜非线性孤波
IF 2 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-08-04 DOI: 10.1007/s12648-024-03329-7
L. Nazziwa, I. Habumugisha, E. Jurua

This study focused on nonlinear ion-acoustic solitary structures (IASS) in a magnetized plasma system that is kappa distributed comprising electrons, positrons, and ions (e–p–i) using a fluid theory approach. A novel nonlinear inverse dispersion relation peculiar to this complex plasma environment was derived. The dispersive properties of ion-acoustic waves in magnetized e–p–i plasma environment were investigated considering the influence of various superthermal of electrons and positrons ((kappa _{e}~textrm{and} ~kappa _{p})), unperturbed positron to ion density ratio, p, electron to ion density ratio, ((delta )), ion to electron temperature ratio, ((sigma )). By numerically analyzing the impact of plasma properties, particularly the nonlinear dispersion characteristics in a magnetized e–p–i plasma. The influence of the external magnetic field (obliqueness) angle, (theta), which alters the frequency value of ((omega ^{2})). It was found that the values of (delta), the frequency (omega ^{2}) of IASS waves decreases with increasing (delta). This result has significant implications for understanding the dynamics of various astrophysical settings, such as the solar wind. However, when (delta > 0), the curves become more nonlinear, indicating the waves become more dispersive. Further, it is discovered that as the value of (theta) for (+~omega ^{2}) solution increases, the shape of the dispersion curve does not significantly change. In contrast, it is observed from the (-~omega ^{2}) solution that for all values of angle (theta), frequency decreases with increasing angle (theta). This is because the ion-acoustic mode is strong at the propagation angle at (theta = 0^{circ }) and weakens as the propagation angle increases, eventually disappearing at (theta = 90^{circ }). Thus, these findings provide an appreciable understanding of the dispersion characteristics of obliquely propagating IASS modes in a magnetized e–p–i plasma. In conclusion, our results provide important and new information on the interaction of plasma parameters in complex astronomical (natural) and laboratory (artificial) settings.

本研究采用流体理论方法,重点研究了由电子、正电子和离子(e-p-i)组成的卡帕分布磁化等离子体系统中的非线性离子声孤结构(IASS)。推导出了这种复杂等离子体环境特有的新型非线性反色散关系。考虑到电子和正电子的各种超热((kappa _{e}~textrm{and} ~kappa _{p})), 未受扰动的正电子与离子密度比,p, 电子与离子密度比,((delta )),离子与电子温度比,((sigma ))的影响,研究了磁化e-p-i等离子体环境中离子声波的色散特性。通过数值分析等离子体特性的影响,特别是磁化 e-p-i 等离子体中的非线性色散特性。外磁场(斜度)角(theta)的影响改变了频率值((omega ^{2}))。研究发现,随着 (delta) 的增大,IASS 波的频率 (omega ^{2})会减小。这一结果对于理解太阳风等各种天体物理环境的动力学具有重要意义。然而,当(delta > 0) 时,曲线变得更加非线性,表明波变得更加分散。此外,我们还发现,随着(+~omega ^{2})解的(theta)值的增加,色散曲线的形状并没有明显变化。相反,从(-~omega ^{2})溶液中可以观察到,在所有角度(theta)值下,频率都会随着角度(theta)的增大而降低。这是因为离子声学模式在传播角为(theta = 0^{circ } )时很强,随着传播角的增大而减弱,最终在(theta = 90^{circ } )时消失。因此,这些发现提供了对磁化 e-p-i 等离子体中斜向传播的 IASS 模式的弥散特性的理解。总之,我们的研究结果为复杂的天文(自然)和实验室(人工)环境中等离子体参数的相互作用提供了重要的新信息。
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引用次数: 0
Effect of heat treatment on structural, optical and magneto-dielectric properties of Co–Cu spinel nano ferrites 热处理对 Co-Cu 尖晶石纳米铁氧体结构、光学和磁介电特性的影响
IF 2 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-07-30 DOI: 10.1007/s12648-024-03283-4
Poorva Rani, Priyanka Godara, Ram Mehar Singh, Ashok Kumar

Here, we have investigated the impact of heat treatment on structural, morphological, optical and magneto-dielectric properties of Co0.5Cu0.5Fe2O4 spinel nanoferrites prepared by sol–gel auto-combustion method. The prepared samples were sintered at 700, 800, and 900 °C and then characterized by XRD, FTIR, SEM, UV–Vis spectroscopy, VSM and impedance analyser techniques. The obtained XRD patterns were refined with Full Prof Suite Software which confirmed the cubic spinel structure of the prepared sample and it was observed that crystallite size increases from 38 to 44 m with increase in sintering temperature and the same is confirmed by W–H plot also. The SEM micro graphs represent the morphological features of the prepared samples and average particle size was calculated by using the imageJ software, which ranges 47–126 nm with increase in temperature. The FTIR spectra confirmed the presence of tetrahedral and octahedral sites in the prepared samples. Various optical parameters were recorded using UV–Vis spectroscopy and it was found that optical band gap energy decreased from 3.976 to 3.832 eV, whereas refractive index increased from 2.262 to 2.283, and high frequency dielectric constant varied from 5.114 to 5.210 with rise in temperature which was due to decrease in grain boundary area and porosity. The magnetic studies were carried out at room temperature using VSM and it was found that magnetic parameters get improved with increase in sintering temperature. Dielectric measurements were made by impedance analyser in a frequency range of 20 Hz to 10 MHz which were in consonance with Maxwell–Wagner polarization and Koop’s theory.

在此,我们研究了热处理对溶胶-凝胶自燃烧法制备的 Co0.5Cu0.5Fe2O4 尖晶石的结构、形态、光学和磁介电特性的影响。制备的样品在 700、800 和 900 °C 下烧结,然后通过 XRD、傅立叶变换红外光谱、扫描电子显微镜、紫外可见光谱、VSM 和阻抗分析仪技术进行表征。用 Full Prof Suite 软件对所获得的 XRD 图谱进行了细化,证实了所制备样品的立方尖晶石结构,并观察到随着烧结温度的升高,结晶尺寸从 38 m 增加到 44 m,W-H 图也证实了这一点。SEM 显微图显示了制备样品的形态特征,并使用 imageJ 软件计算了平均粒度,随着温度的升高,粒度范围为 47-126 nm。傅立叶变换红外光谱证实了制备的样品中存在四面体和八面体位点。使用紫外可见光谱记录了各种光学参数,发现光带隙能从 3.976 eV 下降到 3.832 eV,折射率从 2.262 上升到 2.283,高频介电常数随着温度的升高从 5.114 变化到 5.210,这是由于晶界面积和孔隙率的减少。磁性研究是在室温下使用 VSM 进行的,结果发现磁性参数随着烧结温度的升高而提高。用阻抗分析仪在 20 Hz 至 10 MHz 的频率范围内进行了介电测量,结果与 Maxwell-Wagner 极化和 Koop 理论一致。
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引用次数: 0
Structural and optical properties of Cu:CdS thin films on soft polymer substrate 软聚合物基底上 Cu:CdS 薄膜的结构和光学特性
IF 2 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-07-30 DOI: 10.1007/s12648-024-03344-8
Sk. Faruque Ahmed, Mohibul Khan

The structural and optical properties of copper doped cadmium sulfide (Cu:CdS) thin films on flexible polyethylene terepthalate substrates have been presented. The hexagonal crystallite structure of as-deposited thin films was characterized by the X-ray diffraction technique. X-ray photoelectron spectroscopy has been used to study the chemical binding energy and compositional analysis of the deposited thin films. The surface morphology of the deposited thin films has been analysed by an atomic force microscope image. The optical and photoluminescence properties of deposited films have been studied by UV–Vis–NIR spectrophotometer and fluorimeter respectively. A linear shrinkage of lattice parameters has been observed in the CdS thin films with Cu doping because of the smaller ionic radius of Cu than that of Cd. The optical band gap energy of CdS thin films decreased initially with Cu doping due to s, p–d exchange interactions and then increased due to the reduction in crystallite size. The photoluminescence property of the Cu:CdS thin films has been studied at room temperature (30 °C). Photoluminescence spectra showed two emission peaks around 545 nm and 580 nm, respectively, the exact positions of which are dependent on the Cu at% in the thin films. The former is due to the band-band transition of CdS, and the second is due to sulphur vacancy.

本文介绍了在柔性聚对苯二甲酸乙二醇酯基底上掺杂铜的硫化镉(Cu:CdS)薄膜的结构和光学特性。X 射线衍射技术表征了沉积薄膜的六边形晶粒结构。X 射线光电子能谱被用来研究沉积薄膜的化学结合能和成分分析。原子力显微镜图像分析了沉积薄膜的表面形态。紫外-可见-近红外分光光度计和荧光计分别研究了沉积薄膜的光学和光致发光特性。由于铜的离子半径小于镉的离子半径,在掺入铜的 CdS 薄膜中观察到晶格参数的线性收缩。掺入 Cu 后,CdS 薄膜的光带隙能最初因 s、p-d 交换作用而降低,然后又因晶粒尺寸减小而升高。在室温(30 °C)下研究了 Cu:CdS 薄膜的光致发光特性。光致发光光谱分别显示出 545 nm 和 580 nm 附近的两个发射峰,其确切位置取决于薄膜中的铜含量。前者是由于 CdS 的带状转变,后者是由于硫的空位。
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引用次数: 0
Performance enhancement of FASnI3 perovskite photovoltaic cell through gradient re-arrangement of bulk defect and distinct charge transport layers 通过对块状缺陷层和不同电荷传输层进行梯度重排提高 FASnI3 包晶光伏电池的性能
IF 2 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-07-29 DOI: 10.1007/s12648-024-03350-w
Ramadevi Janapaneni, Deboraj Muchahary

This work deals with theoretical analysis of performance of a formamidinium tin iodide (FASnI3) based perovskite solar cell. The advantages of using FASnI3 over other perovskites include its low toxicity and environmental friendliness. While FASnI3 has slightly lower thermal and moisture stability compared to the inorganic CsSnI3, it offers better tunability of properties and higher power conversion efficiency (CE) potential. In PVSCs not only the surface defect but also the high concentration of Sn4+ creates huge bulk defect density inside the FASnI3 and limits the CE. The bulk defect is of two types (1) fixed ionic defects due to Sn4+ and (2) mobile ionic defects due to Sn interstitial and halide vacancy. With a goal to overcome the impact of fixed defect, we used a technique to gradient distribution of Sn4+ mediated bulk defects inside the absorber. The PVSC: ITO/PEDOT: PSS/FASnI3/C60/Au is simulated in OghmaNano where uniform distribution versus gradient distribution of defect inside FASnI3 are analyzed. The ~ 10 to 13% rise in CE is observed for the gradient distribution of defect and is attributed to the enhancement in electric field inside the device. Moreover, the impact of mobile ions on the performance of both uniform and gradient PVSCs is comprehensively analyzed and reported in this work. The analysis indicates that an ion density up to the order of 1022 m−3 has no significant impact on the performance of the PVSC. In addition, considering the pivotal role of charge transport layers, seven different materials such as MoO3, PEDOT: PSS, TCTA, V2O5, Li0.05Ni0.95O, SrCu2O2, and CuI are assessed for eligibility as HTAL in the proposed PVSC. Amongst those the CuI and C60 as HTAL and ETAL results in highest CE, FF, JSC and VOC of 20.64%, 69.09%, 1.14 V and 26.16 mA cm−2 respectively. The reported photovoltaic device with high CE is environment friendly and may be a potential candidate for solar energy harvesting.

这项研究对基于碘化甲脒锡 (FASnI3) 的过氧化物太阳能电池的性能进行了理论分析。与其他过氧化物相比,使用 FASnI3 的优势在于其低毒性和环保性。虽然 FASnI3 的热稳定性和湿稳定性略低于无机 CsSnI3,但它具有更好的特性可调性和更高的功率转换效率(CE)潜力。在 PVSC 中,不仅是表面缺陷,高浓度的 Sn4+ 也在 FASnI3 内部形成了巨大的体缺陷密度,从而限制了 CE。块状缺陷分为两类:(1)Sn4+ 导致的固定离子缺陷;(2)Sn 间隙和卤化物空位导致的移动离子缺陷。为了克服固定缺陷的影响,我们采用了一种技术,使吸收体内部由 Sn4+ 介导的块状缺陷呈梯度分布。PVSC:ITO/PEDOT:PSS/FASnI3/C60/Au 在 OghmaNano 中进行了模拟,分析了 FASnI3 内部缺陷的均匀分布与梯度分布。在缺陷梯度分布的情况下,CE 上升了 10% 到 13%,这归因于器件内部电场的增强。此外,本研究还全面分析并报告了移动离子对均匀和梯度 PVSC 性能的影响。分析表明,高达 1022 m-3 量级的离子密度对 PVSC 的性能没有显著影响。此外,考虑到电荷传输层的关键作用,七种不同的材料,如 MoO3、PEDOT:PSS、TCTA、V2O5、Li0.05Ni0.95O、SrCu2O2 和 CuI 等七种不同的材料被评估是否有资格作为 HTAL 用于拟议的 PVSC。其中,CuI 和 C60 作为 HTAL 和 ETAL,可获得最高的 CE、FF、JSC 和 VOC,分别为 20.64%、69.09%、1.14 V 和 26.16 mA cm-2。所报告的光伏器件具有高 CE 值,对环境友好,可能成为太阳能收集的潜在候选器件。
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引用次数: 0
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Indian Journal of Physics
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