Pub Date : 2025-07-10DOI: 10.1007/s12648-025-03706-w
Amlan Jyoti Borah, Anurup Gohain Barua
Many a scientific study was carried out on the in vivo bioluminescence emission of the firefly. In those studies, the wavelength peaks of different species of firefly were documented at fixed positions—showing no variation. Here we record steady state emission spectra of the Indian species of firefly Asymmetricata circumdata at its normal flashing temperature. An observation of the spectra of different specimens of this summer species recorded over three years reveals that positions of the peaks are not the same; these differ by 9 nm. This non-negligible difference points towards slight changes in the structure of, or in the localised microenvironment around, the enzyme catalyst luciferase in this species itself.
{"title":"Variation in the emission-peak position of the firefly Asymmetricata circumdata","authors":"Amlan Jyoti Borah, Anurup Gohain Barua","doi":"10.1007/s12648-025-03706-w","DOIUrl":"10.1007/s12648-025-03706-w","url":null,"abstract":"<div><p>Many a scientific study was carried out on the in vivo bioluminescence emission of the firefly. In those studies, the wavelength peaks of different species of firefly were documented at fixed positions—showing no variation. Here we record steady state emission spectra of the Indian species of firefly <i>Asymmetricata circumdata</i> at its normal flashing temperature. An observation of the spectra of different specimens of this summer species recorded over three years reveals that positions of the peaks are not the same; these differ by 9 nm. This non-negligible difference points towards slight changes in the structure of, or in the localised microenvironment around, the enzyme catalyst luciferase in this species itself.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 13","pages":"4945 - 4948"},"PeriodicalIF":1.7,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-09DOI: 10.1007/s12648-025-03695-w
Raziye Ertuğrul Uyar
This study investigates the dielectric properties of an Au/SnO2/p-InP (MOS) capacitor through admittance measurements over a broad frequency and temperature range. The experimental results demonstrate the dependence of capacitance and conductance on temperature, frequency, and applied bias voltage. Key findings reveal a temperature-dependent capacitance behavior where capacitance decreases under reverse bias due to carrier freezing and increases under forward bias due to carrier activation. In the forward bias region, the capacitance also exhibits a decreasing trend with increasing frequency, which is attributed to the limited response of interface states at higher frequencies. The dielectric constant and loss increase with temperature but decrease at higher frequencies as a result of the reduced ability of dipoles to follow the alternating field. The ac conductivity behavior is consistent with a short-range hopping mechanism, where both temperature and frequency contribute to enhanced conductivity. The results align with the correlated barrier hopping (CBH) conduction model. This work provides a comprehensive analysis of the frequency- and temperature-dependent electrical characteristics of MOS capacitors, thereby addressing existing gaps in the literature. The findings are important for the design and optimization of semiconductor devices and sensor technologies, improving electronic performance in various applications.
{"title":"Effect of frequency and temperature on dielectric properties of Au/SnO2/p-InP (MOS) capacitor","authors":"Raziye Ertuğrul Uyar","doi":"10.1007/s12648-025-03695-w","DOIUrl":"10.1007/s12648-025-03695-w","url":null,"abstract":"<div><p>This study investigates the dielectric properties of an Au/SnO<sub>2</sub>/p-InP (MOS) capacitor through admittance measurements over a broad frequency and temperature range. The experimental results demonstrate the dependence of capacitance and conductance on temperature, frequency, and applied bias voltage. Key findings reveal a temperature-dependent capacitance behavior where capacitance decreases under reverse bias due to carrier freezing and increases under forward bias due to carrier activation. In the forward bias region, the capacitance also exhibits a decreasing trend with increasing frequency, which is attributed to the limited response of interface states at higher frequencies. The dielectric constant and loss increase with temperature but decrease at higher frequencies as a result of the reduced ability of dipoles to follow the alternating field. The ac conductivity behavior is consistent with a short-range hopping mechanism, where both temperature and frequency contribute to enhanced conductivity. The results align with the correlated barrier hopping (CBH) conduction model. This work provides a comprehensive analysis of the frequency- and temperature-dependent electrical characteristics of MOS capacitors, thereby addressing existing gaps in the literature. The findings are important for the design and optimization of semiconductor devices and sensor technologies, improving electronic performance in various applications.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 13","pages":"5057 - 5067"},"PeriodicalIF":1.7,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-08DOI: 10.1007/s12648-025-03691-0
Nadim Mahamud Nobin, Lokman Ali, Khairul Alam
High-entropy alloys (HEAs) are designed by combining chemical elements in equal or nearly equal amounts to create strong, ductile materials. Some attributes of HEAs can be modified by doping elements that are chosen based on the working environments. This study examines the impact of (Al) addition on the mechanical properties of ({Al}_{x}{(CoCrFeNi)}_{1-x}) high-entropy alloys (HEAs) through molecular dynamics (MD) simulations. We examined a variety of mechanical properties, including yield strength, lattice distortion, elastic constants, elastic moduli, anisotropy, and melting point. Increasing the (Al) content in ({Al}_{x}{(CoCrFeNi)}_{1-x}) HEAs there was noticeable influences on strength and ductility which directly alters the mechanical properties of this alloys. The calculations of melting points indicate that incorporating (Al) contents significantly influence thermal properties, leading to increased melting points. Our findings emphasize the importance of understanding these effects, as they can provide useful insights for the design and progress of HEAs with superior mechanical properties appropriate for a variety of technological applications.
{"title":"Enhanced mechanical properties achieved through Al addition in ({Al}_{x}{(CoCrFeNi)}_{1-x}) high entropy alloys","authors":"Nadim Mahamud Nobin, Lokman Ali, Khairul Alam","doi":"10.1007/s12648-025-03691-0","DOIUrl":"10.1007/s12648-025-03691-0","url":null,"abstract":"<div><p>High-entropy alloys (HEAs) are designed by combining chemical elements in equal or nearly equal amounts to create strong, ductile materials. Some attributes of HEAs can be modified by doping elements that are chosen based on the working environments. This study examines the impact of <span>(Al)</span> addition on the mechanical properties of <span>({Al}_{x}{(CoCrFeNi)}_{1-x})</span> high-entropy alloys (HEAs) through molecular dynamics (MD) simulations. We examined a variety of mechanical properties, including yield strength, lattice distortion, elastic constants, elastic moduli, anisotropy, and melting point. Increasing the <span>(Al)</span> content in <span>({Al}_{x}{(CoCrFeNi)}_{1-x})</span> HEAs there was noticeable influences on strength and ductility which directly alters the mechanical properties of this alloys. The calculations of melting points indicate that incorporating <span>(Al)</span> contents significantly influence thermal properties, leading to increased melting points. Our findings emphasize the importance of understanding these effects, as they can provide useful insights for the design and progress of HEAs with superior mechanical properties appropriate for a variety of technological applications.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 13","pages":"4949 - 4960"},"PeriodicalIF":1.7,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12648-025-03691-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-08DOI: 10.1007/s12648-025-03658-1
L. Darbali, B. Nmaila, L. B. Drissi, R. Ahl Laamara, K. Htoutou
We investigated the magnetic properties of an Ising diluted nanotube with a mixed-spin (1/2,3/2) hexagonal core-shell structure, using a combination of effective field theory (EFT) and probability distribution techniques. The study uniquely explored the effects of disorder in both the core and shell in relation to the uniaxial anisotropy (D_z) and core-shell exchange interactions (R_{cs}). Additionnaly, the research highlighted a diverse range of compensation behaviors (Q-, R-, S-, N-, L-, and P-types) based on Néel’s classification. To invoke the enegetic aspect, we studied also the internal energy, the magnetic susceptibiliy and the free energy. The discovery of triple hysteresis loops under specific parameter conditions, added a significant new dimension to the understanding of such systems.
{"title":"Bond-dilution effects on magnetic and hysteretic properties of mixed spin-(1/2,3/2) Ising ferrimagnetic nanotube","authors":"L. Darbali, B. Nmaila, L. B. Drissi, R. Ahl Laamara, K. Htoutou","doi":"10.1007/s12648-025-03658-1","DOIUrl":"10.1007/s12648-025-03658-1","url":null,"abstract":"<div><p>We investigated the magnetic properties of an Ising diluted nanotube with a mixed-spin (1/2,3/2) hexagonal core-shell structure, using a combination of effective field theory (EFT) and probability distribution techniques. The study uniquely explored the effects of disorder in both the core and shell in relation to the uniaxial anisotropy <span>(D_z)</span> and core-shell exchange interactions <span>(R_{cs})</span>. Additionnaly, the research highlighted a diverse range of compensation behaviors (Q-, R-, S-, N-, L-, and P-types) based on Néel’s classification. To invoke the enegetic aspect, we studied also the internal energy, the magnetic susceptibiliy and the free energy. The discovery of triple hysteresis loops under specific parameter conditions, added a significant new dimension to the understanding of such systems.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 12","pages":"4533 - 4548"},"PeriodicalIF":1.7,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This paper presents the design of a highly birefringent and highly nonlinear photonic crystal fiber based on sulfur-based glass (As2Se3). The structure incorporates two elliptical air holes and four circular air holes of different sizes at the fiber core. Using the full vector finite element method (FEM) with anisotropic perfectly matched layers, the birefringence characteristics, nonlinear properties, dispersion, and beat length in the wavelength range of 1.2–1.8 μm are investigated by tuning the structural parameters of the fiber. The results show that the birefringence of the photonic crystal fiber reaches 0.172 at 1.55 μm wavelength, while the nonlinear coefficients in the X-polarization direction are 149.31 m−1 W−1, and the nonlinear coefficients in the Y-polarization direction are 215.41 m−1 W−1. In addition, the PCF dispersion is normal in this band range and shows positive dispersion in the X-polarization direction and negative dispersion in the Y-polarization direction. Photonic crystal optical fibers based on the sulfur-based glass As2Se3 have a simple structure and show significant potential for applications in various fields, such as optical coherence tomography (OCT) and super-resolution imaging technology in the medical field, optical sensors, and optical communications.
{"title":"Design of highly birefringent, highly nonlinear photonic crystal fibers based on the sulfur glass As2Se3","authors":"Hua Wang, Xinyi Zhang, Chengen Zhang, Jingya Zhao, Zhiliang Chen, Silei Wang, Shuqing Yan, Pibin Bing","doi":"10.1007/s12648-025-03686-x","DOIUrl":"10.1007/s12648-025-03686-x","url":null,"abstract":"<div><p>This paper presents the design of a highly birefringent and highly nonlinear photonic crystal fiber based on sulfur-based glass (As<sub>2</sub>Se<sub>3</sub>). The structure incorporates two elliptical air holes and four circular air holes of different sizes at the fiber core. Using the full vector finite element method (FEM) with anisotropic perfectly matched layers, the birefringence characteristics, nonlinear properties, dispersion, and beat length in the wavelength range of 1.2–1.8 μm are investigated by tuning the structural parameters of the fiber. The results show that the birefringence of the photonic crystal fiber reaches 0.172 at 1.55 μm wavelength, while the nonlinear coefficients in the X-polarization direction are 149.31 m<sup>−1</sup> W<sup>−1</sup>, and the nonlinear coefficients in the Y-polarization direction are 215.41 m<sup>−1</sup> W<sup>−1</sup>. In addition, the PCF dispersion is normal in this band range and shows positive dispersion in the X-polarization direction and negative dispersion in the Y-polarization direction. Photonic crystal optical fibers based on the sulfur-based glass As<sub>2</sub>Se<sub>3</sub> have a simple structure and show significant potential for applications in various fields, such as optical coherence tomography (OCT) and super-resolution imaging technology in the medical field, optical sensors, and optical communications.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 13","pages":"5239 - 5253"},"PeriodicalIF":1.7,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the present paper, the FeAlBSn nano-composite was synthesized using powder metallurgy technique in order to investigate the effect of milling time on its structural and magnetic properties. Comprehensive characterization was conducted using X-ray diffraction (XRD), scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectrometry (EDS), and vibrating sample magnetometry (VSM). XRD analysis of the initial powder (0 h) revealed distinct peaks that correspond to the elements Fe, Al, B, and Sn. Upon 20 h of milling, progressive solid-state reactions and structural transformations led to the formation of multiple intermetallic phases, including FeB, Fe2B, FeAl, AlB2, AlB12, FeSn, Fe2Sn2, Fe2Sn, and Fe2AlB2. The average crystallite size decreased from 54 to 13 nm, accompanied by an increase in lattice strain from 0.08% to 0.6%. SEM–EDS analysis confirmed significant morphological refinement and uniform elemental distribution, with the mean particle size reducing from ~ 40 µm to ~ 10 µm after milling. In addition, Magnetic measurements revealed a significant dependence on milling time, with coercivity (Hc), remanent magnetization (Mr), and squareness ratio (Mr/Ms) reached 220.74 Oe, 1.66 emu/g, and 0.15, respectively, after 20 h. However, saturation magnetization (Ms) decreased considerably from 103.28 emu/g (0 h) to 11.16 emu/g (20 h), indicating the formation of weakly magnetic or non-magnetic intermetallic phases. These findings highlight the impact of mechanical milling on tailoring the structural and magnetic properties of FeAlBSn nanocomposite for advanced applications.
{"title":"Structural and magnetic behaviour of FeAlBSn nanocomposite synthesized via powder metallurgy process","authors":"Abderrahmane Younes, Abdessabour Benamor, Abderahim Abada, Rachid Amraoui","doi":"10.1007/s12648-025-03696-9","DOIUrl":"10.1007/s12648-025-03696-9","url":null,"abstract":"<div><p>In the present paper, the FeAlBSn nano-composite was synthesized using powder metallurgy technique in order to investigate the effect of milling time on its structural and magnetic properties. Comprehensive characterization was conducted using X-ray diffraction (XRD), scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectrometry (EDS), and vibrating sample magnetometry (VSM). XRD analysis of the initial powder (0 h) revealed distinct peaks that correspond to the elements Fe, Al, B, and Sn. Upon 20 h of milling, progressive solid-state reactions and structural transformations led to the formation of multiple intermetallic phases, including FeB, Fe<sub>2</sub>B, FeAl, AlB<sub>2</sub>, AlB<sub>12</sub>, FeSn, Fe<sub>2</sub>Sn<sub>2</sub>, Fe<sub>2</sub>Sn, and Fe<sub>2</sub>AlB<sub>2</sub>. The average crystallite size decreased from 54 to 13 nm, accompanied by an increase in lattice strain from 0.08% to 0.6%. SEM–EDS analysis confirmed significant morphological refinement and uniform elemental distribution, with the mean particle size reducing from ~ 40 µm to ~ 10 µm after milling. In addition, Magnetic measurements revealed a significant dependence on milling time, with coercivity (Hc), remanent magnetization (Mr), and squareness ratio (Mr/Ms) reached 220.74 Oe, 1.66 emu/g, and 0.15, respectively, after 20 h. However, saturation magnetization (Ms) decreased considerably from 103.28 emu/g (0 h) to 11.16 emu/g (20 h), indicating the formation of weakly magnetic or non-magnetic intermetallic phases. These findings highlight the impact of mechanical milling on tailoring the structural and magnetic properties of FeAlBSn nanocomposite for advanced applications.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 13","pages":"5069 - 5076"},"PeriodicalIF":1.7,"publicationDate":"2025-07-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145560972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-05DOI: 10.1007/s12648-025-03684-z
Bushra M ALHasni, E. M. Ahmed
The PbO–SiO2 system has a wide range of industrial applications, including optical glasses, optoelectronics, and radiation shielding. In this study, the structure of lead-silicate glasses was investigated using molecular dynamics (MD) simulations with Buckingham-type rigid ion potentials combined with Coulomb interactions. Three glass compositions, xPbO–(100 − x)SiO2 with x = 50, 60, and 65 mol%, were examined. In the simulated structures, Si4+ ions are tetrahedrally coordinated with oxygen atoms, with an average coordination number of four. The PbO4 units serve as the fundamental structural motifs in lead-silicate glasses. The number of Pb–Pb nearest neighbors follows a statistical model in which modifier cations (Pb2+) bond to non-bridging oxygens (Onb), and M(Onb)n polyhedra are primarily connected via corner-sharing. The Pb–Pb partial pair distribution function, TPbPb(r), exhibits a peak height that increases with PbO concentration, as expected. The distribution of Qn species varies systematically with silica content, reflecting the depolymerization of the silicate network upon the addition of lead oxide. All structural models demonstrate good agreement with experimental data and Reverse Monte Carlo (RMC) modeling results, including parameters such as short-range order, average bond lengths, bond angle distributions, and Qn species distributions.
{"title":"The short and medium range structure of lead silicate glasses","authors":"Bushra M ALHasni, E. M. Ahmed","doi":"10.1007/s12648-025-03684-z","DOIUrl":"10.1007/s12648-025-03684-z","url":null,"abstract":"<div><p>The PbO–SiO<sub>2</sub> system has a wide range of industrial applications, including optical glasses, optoelectronics, and radiation shielding. In this study, the structure of lead-silicate glasses was investigated using molecular dynamics (MD) simulations with Buckingham-type rigid ion potentials combined with Coulomb interactions. Three glass compositions, xPbO–(100 − x)SiO<sub>2</sub> with x = 50, 60, and 65 mol%, were examined. In the simulated structures, Si<sup>4+</sup> ions are tetrahedrally coordinated with oxygen atoms, with an average coordination number of four. The PbO<sub>4</sub> units serve as the fundamental structural motifs in lead-silicate glasses. The number of Pb–Pb nearest neighbors follows a statistical model in which modifier cations (Pb<sup>2+</sup>) bond to non-bridging oxygens (Onb), and M(Onb)<sub>n</sub> polyhedra are primarily connected via corner-sharing. The Pb–Pb partial pair distribution function, T<sub>PbPb(r)</sub>, exhibits a peak height that increases with PbO concentration, as expected. The distribution of Q<sup>n</sup> species varies systematically with silica content, reflecting the depolymerization of the silicate network upon the addition of lead oxide. All structural models demonstrate good agreement with experimental data and Reverse Monte Carlo (RMC) modeling results, including parameters such as short-range order, average bond lengths, bond angle distributions, and Q<sup>n</sup> species distributions.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 13","pages":"5077 - 5085"},"PeriodicalIF":1.7,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-05DOI: 10.1007/s12648-025-03690-1
Belqees Hassan, Muhammad Irfan, Emad M. Ahmed, Shams A. M. Issa, Hesham M. H. Zakaly
Solid-state energy storage devices hold significant potential owing to their superior safety features, increased energy density, and minimized packaging needs, positioning them as ideal candidates for extensive energy storage systems. The sustainable development of contemporary infrastructure significantly depends on clean and efficient transportation solutions, with lithium-ion batteries (LIBs) leading this transformative shift. This study investigates the structural, mechanical, electronic, and optical properties of Li10GeP2Se12 through first-principles density functional theory (DFT) to assess its potential as a solid electrolyte in Li-metal batteries and supercapacitors. The evaluation of mechanical stability was conducted utilizing the IR-Elast code, resulting in a bulk modulus (B) of 110.5 GPa, a shear modulus (G) of 80.2 GPa, a Young’s modulus (E) of 229.3 GPa, and a Poisson’s ratio (v) of 0.25. The computed Pugh’s ratio (B/G) of 1.09 suggests a moderate level of ductility accompanied by significant mechanical strength. The electronic structure analysis indicates that Li10GeP2Se12 functions as a semiconductor, exhibiting a direct band gap of around 2.1 eV. This characteristic positions it well for use in optoelectronic and energy storage applications. Calculations of optical properties indicate a significant dielectric constant of ε1 (0) ≈ 5.1 and a peak refractive index of around 2.2 in the low-energy region. The material demonstrates significant absorption peaks in the ultraviolet range at approximately 9.8 eV and marked optical anisotropy across various polarization directions. These properties underscores the promise of Li10GeP2Se12 as a versatile material for solid-state lithium batteries and integrated optoelectronic energy devices.
{"title":"Recent advancements and challenges in deploying lithium-ion batteries as economical energy storage devices: first-principles calculations of lithium triphoselenium Li10GeP2Se12","authors":"Belqees Hassan, Muhammad Irfan, Emad M. Ahmed, Shams A. M. Issa, Hesham M. H. Zakaly","doi":"10.1007/s12648-025-03690-1","DOIUrl":"10.1007/s12648-025-03690-1","url":null,"abstract":"<div><p>Solid-state energy storage devices hold significant potential owing to their superior safety features, increased energy density, and minimized packaging needs, positioning them as ideal candidates for extensive energy storage systems. The sustainable development of contemporary infrastructure significantly depends on clean and efficient transportation solutions, with lithium-ion batteries (LIBs) leading this transformative shift. This study investigates the structural, mechanical, electronic, and optical properties of Li<sub>10</sub>GeP<sub>2</sub>Se<sub>12</sub> through first-principles density functional theory (DFT) to assess its potential as a solid electrolyte in Li-metal batteries and supercapacitors. The evaluation of mechanical stability was conducted utilizing the IR-Elast code, resulting in a bulk modulus (B) of 110.5 GPa, a shear modulus (G) of 80.2 GPa, a Young’s modulus (E) of 229.3 GPa, and a Poisson’s ratio (v) of 0.25. The computed Pugh’s ratio (B/G) of 1.09 suggests a moderate level of ductility accompanied by significant mechanical strength. The electronic structure analysis indicates that Li<sub>10</sub>GeP<sub>2</sub>Se<sub>12</sub> functions as a semiconductor, exhibiting a direct band gap of around 2.1 eV. This characteristic positions it well for use in optoelectronic and energy storage applications. Calculations of optical properties indicate a significant dielectric constant of ε<sub>1</sub> (0) ≈ 5.1 and a peak refractive index of around 2.2 in the low-energy region. The material demonstrates significant absorption peaks in the ultraviolet range at approximately 9.8 eV and marked optical anisotropy across various polarization directions. These properties underscores the promise of Li<sub>10</sub>GeP<sub>2</sub>Se<sub>12</sub> as a versatile material for solid-state lithium batteries and integrated optoelectronic energy devices.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 13","pages":"5045 - 5055"},"PeriodicalIF":1.7,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-04DOI: 10.1007/s12648-025-03679-w
Farhad Ali, Muhammad Furqan
This research work presents a complete classification of Friedmann–Robertson–Walker (FLRW) spacetimes based on Noether symmetries. Various classes are analyzed for flat, open, and closed universe models. According to this classification we have various forms of cosmic scale factor b(t). Different sets of Noether symmetries are reported for different classes of FLRW universe. We obtained different classes of the said spacetime along with their Noether symmetries and the corresponding conservation laws. The main objective of this research is to find all possible forms of the scale factor b(t) and discuss their physical significance.
{"title":"Complete classification of Friedmann–Robertson–Walker spacetime","authors":"Farhad Ali, Muhammad Furqan","doi":"10.1007/s12648-025-03679-w","DOIUrl":"10.1007/s12648-025-03679-w","url":null,"abstract":"<div><p>This research work presents a complete classification of Friedmann–Robertson–Walker (FLRW) spacetimes based on Noether symmetries. Various classes are analyzed for flat, open, and closed universe models. According to this classification we have various forms of cosmic scale factor <i>b</i>(<i>t</i>). Different sets of Noether symmetries are reported for different classes of FLRW universe. We obtained different classes of the said spacetime along with their Noether symmetries and the corresponding conservation laws. The main objective of this research is to find all possible forms of the scale factor <i>b</i>(<i>t</i>) and discuss their physical significance.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 13","pages":"4935 - 4944"},"PeriodicalIF":1.7,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-03DOI: 10.1007/s12648-025-03676-z
Syeda Noureen
This study investigates the role of electromagnetic wave dynamics in heating the lower corona and upper chromosphere in M-type stars, which possess a non-relativistic, weakly magnetized, and partially degenerate electron-ion plasma environment. Kinetic modeling is used to investigate the behavior of low-frequency (Alfvén) and high-frequency (R and L) waves. The results demonstrate that R and L waves are found to transfer energy more effectively to the active magnetic corona, in contrast to Alfvén waves, which are primarily limited to the upper chromospheric region where they can deposit energy locally. Additionally, the effect of ion cyclotron frequency and propagation length on wave energy transfer and coronal heating in M stars is studied, which may be facilitated by a wave-dependent energy redistribution mechanism. Although this model assumes a completely ionized plasma that fits the upper chromosphere and corona, the impact of partial ionization in deeper layers could be important and needs further study. This study lays the foundation for understanding M-star magnetic activity and encourages future research that incorporates more complex plasma conditions.
{"title":"Electromagnetic wave dynamics and coronal heating in M stars","authors":"Syeda Noureen","doi":"10.1007/s12648-025-03676-z","DOIUrl":"10.1007/s12648-025-03676-z","url":null,"abstract":"<p>This study investigates the role of electromagnetic wave dynamics in heating the lower corona and upper chromosphere in M-type stars, which possess a non-relativistic, weakly magnetized, and partially degenerate electron-ion plasma environment. Kinetic modeling is used to investigate the behavior of low-frequency (Alfvén) and high-frequency (R and L) waves. The results demonstrate that R and L waves are found to transfer energy more effectively to the active magnetic corona, in contrast to Alfvén waves, which are primarily limited to the upper chromospheric region where they can deposit energy locally. Additionally, the effect of ion cyclotron frequency and propagation length on wave energy transfer and coronal heating in M stars is studied, which may be facilitated by a wave-dependent energy redistribution mechanism. Although this model assumes a completely ionized plasma that fits the upper chromosphere and corona, the impact of partial ionization in deeper layers could be important and needs further study. This study lays the foundation for understanding M-star magnetic activity and encourages future research that incorporates more complex plasma conditions.</p><p>. </p>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"99 13","pages":"4911 - 4933"},"PeriodicalIF":1.7,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}