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Excess Entropy of Metallic Glasses and Its Relation to the Glass-Forming Ability of Maternal Melts 金属玻璃的超熵及其与母熔体玻璃形成能力的关系
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-10 DOI: 10.1134/S0021364024602975
A. S. Makarov, R. A. Konchakov, G. V. Afonin, J. C. Qiao, N. P. Kobelev, V. A. Khonik

The excess entropy ΔS with respect to the maternal crystal state has been determined from calorimetric data for 30 metallic glasses. It has been shown that the excess entropy in the supercooled liquid state ΔSsql is a universal characteristic of a glass independent of its thermal treatment. Six parameters often used to estimate the glass-forming ability of supercooled melts have been calculated for the same metallic glasses. It has been shown that all six parameters increase with ΔSsql and the glass-forming ability of supercooled melts increases with their structural disorder. A possible mechanism to implement this relation has been discussed.

根据30种金属玻璃的量热数据,测定了母体晶体态的多余熵ΔS。研究表明,过冷液体状态下的过剩熵ΔSsql是玻璃的普遍特征,与热处理无关。本文对同一种金属玻璃的过冷熔体的玻璃成形能力进行了六个参数的计算。结果表明,6个参数均随ΔSsql的增大而增大,过冷熔体的非晶化能力随其结构无序度的增大而增大。讨论了实现这种关系的可能机制。
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引用次数: 0
Nanostructured Gd2O3:Yb Micropowder for Antibacterial Hyperthermia 纳米结构Gd2O3:Yb微粉用于抗菌热疗
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-10 DOI: 10.1134/S0021364024603233
D. P. Shcherbinin, D. V. Bulyga, I. N. Saraeva, E. R. Tolordava, A. A. Peunkov, D. M. Dolgintsev, A. N. Babkina, A. V. Ivanov, S. I. Kudryashov

A method has been proposed for photoinduced hyperthermia of pathogenic Gram-negative bacteria P. aeruginosa using Gd2O3:Yb micropowder. It is based on the possibility of laser excitation of anti-Stokes luminescence on ytterbium ions in the gadolinium oxide micropowder, which allows us, on the one hand, to heat the powder to the required temperature and, on the other hand, to accurately control the powder temperature using remote luminescent thermometry. It has been demonstrated that the long-term irradiation of the Gd2O3:Yb micropowder with 1035-nm nanosecond laser radiation changes the shape of anti-Stokes luminescence spectra associated with micropowder heating in the range from 27 to 63°C. The application of the proposed photoinduced hyperthermia method to a mixture of solutions of the Gd2O3:Yb micropowder and P. aeruginosa bacteria demonstrates a decrease in the bacterial population by 90%.

提出了一种利用Gd2O3:Yb微粉对致病性革兰氏阴性细菌铜绿假单胞菌进行光致热治疗的方法。它是基于激光激发氧化钆微粉中的镱离子产生反斯托克斯发光的可能性,这使得我们一方面可以将粉末加热到所需的温度,另一方面可以通过远程发光测温来精确控制粉末温度。结果表明,在27 ~ 63℃范围内,用1035 nm纳秒激光对Gd2O3:Yb微粉进行长期照射,会改变微粉加热后的反斯托克斯发光光谱形状。将提出的光致热疗方法应用于Gd2O3:Yb微粉和铜绿假单胞菌的混合物溶液中,结果表明细菌数量减少了90%。
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引用次数: 0
Compensation of the Effect of the Imperfection of the Nuclotron/JINR Lattice on the Proton Polarization near an Integer Spin Resonance (Brief Review) 核/JINR晶格缺陷对整数自旋共振附近质子极化影响的补偿(综述)
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-10 DOI: 10.1134/S0021364024603695
Yu. N. Filatov, A. M. Kondratenko, N. N. Nikolaev, Yu. V. Senichev, M. A. Kondratenko, S. V. Vinogradov, E. D. Tsyplakov, A. I. Chernyshov, A. V. Butenko, S. A. Kostromin, V. P. Ladygin, E. M. Syresin, E. A. Butenko, I. L. Guryleva, A. A. Melnikov, A. E. Aksentev

A number of open questions remain in the manipulation of the spins of colliding beams, which is a key aspect in the operation of polarized beam colliders such as the Nuclotron-based ion collider facility (JINR, Dubna, Russia) and the electron ion collider (BNL, United States). The spin transparency regime, which is the only realistic regime to control the deuteron polarization, has not yet been approved experimentally. With the existing configuration of the JINR accelerator complex, a pilot spin transparency experiment could be performed on a proton beam in the Nuclotron synchrotron. The dynamics of the proton beam polarization during the fast crossing of spin resonance guided by spin navigators based on regular orbit-steerer dipoles has been analyzed in this work. A scheme has been designed to compensate the coherent action of Nuclotron lattice imperfections on spin. In this scheme, the spin field induced by lattice imperfections is determined from the adiabatic deviation of spins in the resonance region, taking into account the synchrotron energy modulation. Integer-resonance strengths can be compensated down to the limits conditioned by orbital beam emittances. The numerical simulation of the proposed spin compensator has confirmed that the spin transparency regime in an imperfect Nuclotron lattice with a strongly distorted closed orbit can be experimentally verified.

在对撞光束的自旋操纵方面仍然存在一些悬而未决的问题,这是偏振光束对撞机操作的一个关键方面,例如基于核子的离子对撞机设施(俄罗斯杜布纳JINR)和电子离子对撞机(美国BNL)。自旋透明机制是控制氘核极化的唯一可行机制,但尚未得到实验证实。利用JINR加速器综合体的现有配置,可以在核同步加速器的质子束上进行自旋透明实验。本文分析了基于规则轨道转向偶极子的自旋导航仪引导下质子束自旋共振快速穿越过程中的极化动力学。设计了一种补偿原子核晶格缺陷对自旋相干作用的方案。在该方案中,考虑同步加速器能量调制,由晶格缺陷引起的自旋场由共振区自旋的绝热偏差确定。整数共振强度可以补偿到轨道束发射所限定的极限。该自旋补偿器的数值模拟证实了具有强畸变闭合轨道的不完全原子核晶格中的自旋透明状态可以通过实验得到验证。
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引用次数: 0
Effect of Electron-Deficient Substitution on the Spin Dynamics in FeGa3 缺电子取代对FeGa3自旋动力学的影响
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-10 DOI: 10.1134/S0021364024603476
A. V. Tkachev, S. V. Zhurenko, M. R. Bikmukhametova, M. S. Likhanov, A. V. Shevelkov, A. A. Gippius

The nuclear quadrupole resonance study of the electron-deficient substitution in the promising thermoelectric material FeGa3 resulting in the poorly studied Fe0.92Re0.08Ga3 and Fe0.92Mn0.08Ga3 compounds has been carried out. The doping of compounds of this structure type promotes the study of the dependence of the thermoelectric characteristics on the electronic structure and finally makes it possible to increase the thermoelectric efficiency, which is very important for applications. Both compounds exhibit pronounced signatures of the formation of an additional acceptor band inside the main band gap, which is determined by rhenium and manganese substituent atoms. Nuclear quadrupole resonance spectra, as well as nuclear spin–lattice relaxation and its temperature evolution, are significantly different for the compounds under study. This difference is due to different statistical distributions of substituent atoms (predominant formation of homo- and heterogeneous dumbbells in the rhenium- and manganese-substituted compounds, respectively) caused by their outer electron shells.

对有前途的热电材料FeGa3中的缺电子取代进行了核四极共振研究,从而导致研究较少的Fe0.92Re0.08Ga3和Fe0.92Mn0.08Ga3化合物。这种结构类型的化合物的掺杂促进了热电特性对电子结构依赖性的研究,最终使提高热电效率成为可能,这对应用具有重要意义。这两种化合物都表现出在主带隙内形成附加受体带的明显特征,这是由铼和锰取代原子决定的。核四极共振谱、核自旋-晶格弛豫及其温度演化在所研究的化合物中存在显著差异。这种差异是由于取代原子的不同统计分布(分别在铼和锰取代化合物中主要形成同质哑铃和异质哑铃)由它们的外层电子壳层引起的。
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引用次数: 0
Interparticle Magnetic Interactions and the Field Dependence of the Superparamagnetic Blocking Temperature in a Powder System of Ultrasmall Nickel Ferrite Particles 超小镍铁氧体颗粒粉末体系中粒子间磁相互作用及超顺磁阻塞温度的场依赖性
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-10 DOI: 10.1134/S0021364024603865
D. A. Balaev, A. A. Krasikov, Yu. V. Knyazev, S. V. Stolyar, A. O. Shokhrina, A. D. Balaev, R. S. Iskhakov

The dependence of the superparamagnetic blocking temperature on an external magnetic field TB(H) has been studied and analyzed for a nickel ferrite nanoparticle powder system in order to establish the influence of magnetic interparticle interactions on superparamagnetic blocking. The features of this system are: (i) a small particle size (~4–5 nm on average); (ii) a pronounced “core/shell” structure of particles, in which the magnetic moment of a particle is formed by a ferrimagnetically ordered core, while the spins of the surface layer, about 1 nm thick, do not contribute to this magnetic moment. The random anisotropy model, which describes the influence of magnetic interparticle interactions on the TB value in the external field, is used to reproduce the experimental dependence TB(H) obtained by static magnetometry. The analysis has demonstrated strong magnetic interactions in the studied system, which are manifested in a sharp decrease in the TB value in the weak-field region, and has made it possible to quantitatively estimate the intensity and energy of magnetic interparticle interactions, as well as to determine the magnetic anisotropy constant of individual particles (without the influence of magnetic interparticle interactions). The role of the subsystem of surface spins, which, according to the imaginary part of the magnetic susceptibility, exhibits signatures of collective behavior, is discussed as a possible source of magnetic interparticle interactions.

为了确定磁粒间相互作用对超顺磁阻塞的影响,研究并分析了镍铁氧体纳米颗粒粉末体系的超顺磁阻塞温度与外加磁场TB(H)的关系。该体系的特点是:(1)粒径小(平均约4 ~ 5 nm);(ii)明显的粒子“核/壳”结构,其中粒子的磁矩是由铁磁性有序的核形成的,而表面层(约1nm厚)的自旋对该磁矩没有贡献。随机各向异性模型描述了磁场粒子间相互作用对外场中TB值的影响,用于再现静态磁强计得到的实验依赖TB(H)。分析表明,所研究的体系中存在强磁相互作用,表现为弱场区TB值的急剧下降,从而可以定量估计磁粒子间相互作用的强度和能量,以及确定单个粒子的磁各向异性常数(不受磁粒子间相互作用的影响)。根据磁化率的虚部,表面自旋子系统表现出集体行为的特征,讨论了表面自旋子系统作为磁粒子间相互作用的可能来源的作用。
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引用次数: 0
Wind-Driven Sea Spectra Resilience as a Statistical Attractor
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-12-16 DOI: 10.1134/S0021364024603932
A. N. Pushkarev, V. V. Geogjaev, S. I. Badulin

We have observed numerically the resilience phenomenon for ocean wind-driven waves, where the wave spectra return to their original self-similar form after a strong perturbation. This self-similar behavior is seen as the manifestation of a statistical attractor associated with generalized spectra of Kolmogorov–Zakharov. We have confirmed this interpretation through numerical simulations of random water wave field within the kinetic (Hasselmann) equation. This equation with specific source functions similar to those of conventional wave forecasting models exhibits families of exact self-similar solutions. These source functions minimize the “non-self-similar” background, allowing us to evaluate the “clean rates” of wave spectra resilience. We use the indices of the exact self-similar solutions as parameters for the attractors of numerical solutions in a two-dimensional phase space.

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引用次数: 0
Soft Mode Behavior in Transition Metal Doped SrTiO3 Thin Films on MgO Substrates
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-12-16 DOI: 10.1134/S0021364024604561
A. V. Melentev, E. S. Zhukova, B. M. Nekrasov, V. S. Stolyarov, A. S. Frolov, M. Savinov, A. A. Bush, V. I. Kozlov, B. P. Gorshunov, M. V. Talanov

The ferroelectric soft mode in polycrystalline pristine SrTiO3 and weakly doped SrTiO3:M (M = 2 at % Fe, Ni, Mn, Co) thin films on (001) MgO substrates has been studied using time-domain terahertz spectroscopy. Spectra of real and imaginary parts of film permittivity were determined in the frequency range of 5–100 cm–1 at temperatures between 5 and 300 K. Central frequency and dielectric contribution of the ferroelectric soft mode show Barrett-like temperature dependencies similar to crystalline SrTiO3. Large negative values of Curie temperature and enhanced positive values of Barrett quantum temperatures are discovered indicating that doped SrTiO3 thin films are farther from ferroelectric phase transition than SrTiO3 crystals.

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引用次数: 0
Local Field and Dynamic Heterogeneities in the ±J Ising Spin Glasses
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-12-16 DOI: 10.1134/S0021364024604032
V. A. Abalmasov

The average domain size is calculated for zero and nonzero absolute values of the local field in the ( pm J) Ising spin glasses in 2D and 3D at different temperatures using Monte Carlo simulations. The absolute values of the local field determine the spin flip probability, and thus the obtained domain sizes shed light on dynamical heterogeneities in glasses, which are currently being actively studied. It turns out that the average domain size for nonzero absolute values of the local field, corresponding to slow spin dynamics at low temperature, increases and saturates with decreasing temperature, mainly due to an increase in the probability of finding nonzero local fields. However, a slight effect of spatial correlations of the local field is also revealed. These results can be useful for understanding the nature and specific features of glass transition and dynamical heterogeneities in glasses.

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引用次数: 0
Clustering of Defects and Crystallites in a Two-Dimensional Yukawa Fluid 二维汤川流体中的缺陷和晶粒团聚
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-12-13 DOI: 10.1134/S0021364024603403
B. A. Klumov

Various properties of crystal clusters (i.e., clusters consisting of particles with six nearest neighbors) in a two-dimensional Yukawa fluid have been considered for the first time in a wide temperature range beginning with the melting temperature. With increasing temperature, the concentration of crystal particles (which noticeably prevail in a melt) decreases slowly, while the defect concentration increases, which results in the formation of large clusters consisting of defects and in the degradation of large crystal clusters in the considered two-dimensional fluid. Their characteristic size and shape change sharply in a narrow temperature range. The comparative analysis of crystal clusters and clusters consisting of topological defects has been performed. Their size distributions and other structural characteristics have been obtained.

二维汤川流体中晶体团簇(即由六个近邻粒子组成的团簇)的各种性质首次在从熔化温度开始的宽温度范围内被考虑。随着温度的升高,晶体颗粒的浓度(在熔体中明显存在)缓慢下降,而缺陷浓度增加,这导致由缺陷组成的大团簇的形成以及所考虑的二维流体中大晶体团簇的降解。它们的特征尺寸和形状在较窄的温度范围内发生急剧变化。比较分析了晶体团簇和由拓扑缺陷组成的团簇。得到了它们的尺寸分布和其他结构特征。
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引用次数: 0
Reversible Transition between Topologically Equivalent States in a Chiral Liquid Crystal with Negative Dielectric Anisotropy 具有负介电各向异性的手性液晶中拓扑等效态之间的可逆转变
IF 1.4 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-12-13 DOI: 10.1134/S0021364024603452
I. V. Simdyankin, A. R. Geivandov, S. P. Palto

In a layer of a chiral liquid crystal with negative dielectric anisotropy and the thickness d corresponding to the second Grandjean zone ((3{{p}_{0}}{text{/}}4 < d < 5{{p}_{0}}{text{/}}4), where ({{p}_{0}}) is the natural helical pitch) under the action of a planar electric field, an orientational transition occurs from the ground state twisted by the angle (2pi ) to a topologically equivalent untwisted state (0 state). Although the 0 state is metastable and long-lived, it can rapidly be transformed back to the (2pi ) state by an electric field pulse of a comparatively small amplitude. The direct transition to the 0 state is induced by the interaction of the electric field with negative dielectric anisotropy, while the rapid reverse transition can be attributed to the flexoelectric interaction.

在具有负介电各向异性且厚度d对应于第二格朗让区((3{{p}_{0}}{text{/}}4 < d < 5{{p}_{0}}{text{/}}4),其中({{p}_{0}})为天然螺旋节距)的手性液晶层中,在平面电场的作用下,基态由角度(2pi )向拓扑等效的未扭曲态(0态)发生取向跃迁。虽然0态是亚稳态的,寿命长,但它可以通过一个振幅相对较小的电场脉冲迅速转变回(2pi )态。直接跃迁到0态是由电场与负介电各向异性的相互作用引起的,而快速的反向跃迁则是由挠曲电相互作用引起的。
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引用次数: 0
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JETP Letters
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