Pub Date : 2025-11-20DOI: 10.1134/S0021364025608358
P. A. Danilov, A. V. Gorevoy, I. D. Matyaev, I. V. Gritsenko, V. N. Kurlov, S. I. Kudryashov
The modification of the bulk of synthetic optical-grade sapphire by focused (NA = 0.55) 150-fs laser pulses with a wavelength of 525 nm results in the formation of 2 × 2 × 25-µm3 regions where luminescence in the 700–850 nm band, associated with the formation of multicomponent complexes involving F2 and ({text{F}}_{2}^{{2 + }}) vacancies and Cr3+ ions, is enhanced. For pulse energies of 5–22.5 nJ, the sapphire crystal lattice remains undamaged, which makes this process promising for writing three-dimensional microcodes for luminescent memory with capacities as high as 10 Gbit/cm3 suitable for error-free readout under single-photon laser excitation.
{"title":"Femtosecond-Laser Writing of Microbits for Luminescent Memory in Sapphire","authors":"P. A. Danilov, A. V. Gorevoy, I. D. Matyaev, I. V. Gritsenko, V. N. Kurlov, S. I. Kudryashov","doi":"10.1134/S0021364025608358","DOIUrl":"10.1134/S0021364025608358","url":null,"abstract":"<p>The modification of the bulk of synthetic optical-grade sapphire by focused (NA = 0.55) 150-fs laser pulses with a wavelength of 525 nm results in the formation of 2 × 2 × 25-µm<sup>3</sup> regions where luminescence in the 700–850 nm band, associated with the formation of multicomponent complexes involving F<sub>2</sub> and <span>({text{F}}_{2}^{{2 + }})</span> vacancies and Cr<sup>3+</sup> ions, is enhanced. For pulse energies of 5–22.5 nJ, the sapphire crystal lattice remains undamaged, which makes this process promising for writing three-dimensional microcodes for luminescent memory with capacities as high as 10 Gbit/cm<sup>3</sup> suitable for error-free readout under single-photon laser excitation.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"122 7","pages":"397 - 404"},"PeriodicalIF":1.3,"publicationDate":"2025-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S0021364025608358.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145555601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-20DOI: 10.1134/S0021364025607729
S. I. Dorozhkin, A. A. Kapustin, J. H. Smet
Fractional quantum Hall effect states have been studied on samples with an electron system formed by two layers of two-dimensional electrons of different densities in a wide (60 nm) GaAs quantum well. The experiment has been carried out at a temperature of 45 mK in an inclined magnetic field, where these states are more pronounced. It has been established that insignificant changes in the relation between electron densities by means of gate voltages can significantly change the picture of the observed states At various combinations of electron densities in the layers, pronounced quantized plateaus in the Hall resistance Rxy = q(h/e2) with quantum numbers q = 4/5, 3/4, 3/8, and 3/7 have been detected. Using the magnetocapacitive method, it has been established that the states with q = 4/5 and 3/4 or q = 3/8 and 3/7 arise when an incompressible state in a layer with a higher electron density exists due to a jump in the chemical potential of the layer between different spin Landau sublevels, which occurs when one or two sublevels are filled with the layer electrons, respectively. It has been established that the variation of the magnetic field makes it possible to implement two states of the fractional quantum Hall effect with q = 3/8 and 3/7 in the same incompressible state in the higher-density layer, which is broadened in the field due to the transition of electrons between layers, which occurs under the variation of the field.
{"title":"Combined States of the Fractional Quantum Hall Effect in Two-Layer Electron Systems","authors":"S. I. Dorozhkin, A. A. Kapustin, J. H. Smet","doi":"10.1134/S0021364025607729","DOIUrl":"10.1134/S0021364025607729","url":null,"abstract":"<p>Fractional quantum Hall effect states have been studied on samples with an electron system formed by two layers of two-dimensional electrons of different densities in a wide (60 nm) GaAs quantum well. The experiment has been carried out at a temperature of 45 mK in an inclined magnetic field, where these states are more pronounced. It has been established that insignificant changes in the relation between electron densities by means of gate voltages can significantly change the picture of the observed states At various combinations of electron densities in the layers, pronounced quantized plateaus in the Hall resistance <i>R</i><sub><i>xy</i></sub> = <i>q</i>(<i>h</i>/<i>e</i><sup>2</sup>) with quantum numbers <i>q</i> = 4/5, 3/4, 3/8, and 3/7 have been detected. Using the magnetocapacitive method, it has been established that the states with <i>q</i> = 4/5 and 3/4 or <i>q</i> = 3/8 and 3/7 arise when an incompressible state in a layer with a higher electron density exists due to a jump in the chemical potential of the layer between different spin Landau sublevels, which occurs when one or two sublevels are filled with the layer electrons, respectively. It has been established that the variation of the magnetic field makes it possible to implement two states of the fractional quantum Hall effect with <i>q</i> = 3/8 and 3/7 in the same incompressible state in the higher-density layer, which is broadened in the field due to the transition of electrons between layers, which occurs under the variation of the field.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"122 7","pages":"417 - 423"},"PeriodicalIF":1.3,"publicationDate":"2025-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145555608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-31DOI: 10.1134/S0021364025607961
V. A. Sautenkov, S. A. Saakyan, A. A. Bobrov, B. B. Zelener
A nonlinear selective reflection from the boundary between a transparent dielectric and dense Rb vapor has been investigated, where the dipole broadening of the 5S1/2–5P3/2 working transition is significantly larger than the contribution of the Doppler width. A tunable probe laser and a pump laser with a fixed frequency have been used in the experiment. At a high intensity of pump radiation, a dip has appeared in the reflection spectrum, which splits the spectrum into two symmetric resonances. The splitting value is twice the Rabi frequency. The observation of a narrow structure corresponding to the dressed atomic states opens up additional possibilities for the study of many-particle interactions.
{"title":"Splitting of the Selective Reflection Spectrum Due to the Resonance Optical Saturation of a Dipole-Broadened Atomic Transition","authors":"V. A. Sautenkov, S. A. Saakyan, A. A. Bobrov, B. B. Zelener","doi":"10.1134/S0021364025607961","DOIUrl":"10.1134/S0021364025607961","url":null,"abstract":"<p>A nonlinear selective reflection from the boundary between a transparent dielectric and dense Rb vapor has been investigated, where the dipole broadening of the 5<i>S</i><sub>1/2</sub>–5<i>P</i><sub>3/2</sub> working transition is significantly larger than the contribution of the Doppler width. A tunable probe laser and a pump laser with a fixed frequency have been used in the experiment. At a high intensity of pump radiation, a dip has appeared in the reflection spectrum, which splits the spectrum into two symmetric resonances. The splitting value is twice the Rabi frequency. The observation of a narrow structure corresponding to the dressed atomic states opens up additional possibilities for the study of many-particle interactions.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"122 6","pages":"342 - 346"},"PeriodicalIF":1.3,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S0021364025607961.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145406294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-31DOI: 10.1134/S0021364025608218
An. A. Gippius, A. V. Tkachev, S. V. Zhurenko, N. E. Gervits, Al. A. Gippius, I. V. Morozov
A series of new layered arsenides Ba(Cr1–xCox)2As2 with x = 0, 0.2, 0.3, 0.6, 0.8, and 1.0 has been studied by 59Co and 75As NMR spectroscopy. The hyperfine magnetic field on the 75As nuclei in the BaCr2As2 sample is absent due to the mutual compensation of hyperfine magnetic fields from neighboring magnetic Cr atoms. The mutual compensation of local magnetic fields on 75As nuclei in compounds with x = 0.2, 0.3, and 0.6 is disturbed, and a significant broadening of the line is observed, indicating the emergence of local magnetic fields of about 0.3–0.8 T on arsenic nuclei. With an increase in the Co content to 80%, the magnetic broadening of the 75As NMR line disappears completely, and the isotropic shift 75Kiso increases to 0.19%. This indicates the predominance of the Knight term due to conduction electrons in the total shift. The isotropic shift 75Kiso is maximal in the extreme BaCo2As2 compound, which indicates the maximum value of the density of states at the Fermi level. 59Co NMR in Ba(Cr0.7Co0.3)2As2 in zero external magnetic field measured for the first time has demonstrated a wide distribution of the intensity of the spin echo in the frequency range of 10‒55 MHz, corresponding to a local magnetic field of several Tesla on cobalt. This field is 5–7 times lower than the characteristic local fields detected in Co-based magnets, which indicates a significant reduction of the magnetic moment of cobalt in the Ba(Cr0.7Co0.3)2As2 compound. Starting from a cobalt content of 80%, the 59Co NMR line is sharply narrowed, which indicates the nonmagnetic state of Co in the Ba(C-r1‒xCox)2As2 compounds with x > 0.6.
{"title":"NMR Spectroscopy of Solid Solutions of New Layered Arsenides Ba(Cr1–xCox)2As2","authors":"An. A. Gippius, A. V. Tkachev, S. V. Zhurenko, N. E. Gervits, Al. A. Gippius, I. V. Morozov","doi":"10.1134/S0021364025608218","DOIUrl":"10.1134/S0021364025608218","url":null,"abstract":"<p>A series of new layered arsenides Ba(Cr<sub>1–<i>x</i></sub>Co<sub><i>x</i></sub>)<sub>2</sub>As<sub>2</sub> with <i>x</i> = 0, 0.2, 0.3, 0.6, 0.8, and 1.0 has been studied by <sup>59</sup>Co and <sup>75</sup>As NMR spectroscopy. The hyperfine magnetic field on the <sup>75</sup>As nuclei in the BaCr<sub>2</sub>As<sub>2</sub> sample is absent due to the mutual compensation of hyperfine magnetic fields from neighboring magnetic Cr atoms. The mutual compensation of local magnetic fields on <sup>75</sup>As nuclei in compounds with <i>x</i> = 0.2, 0.3, and 0.6 is disturbed, and a significant broadening of the line is observed, indicating the emergence of local magnetic fields of about 0.3–0.8 T on arsenic nuclei. With an increase in the Co content to 80%, the magnetic broadening of the <sup>75</sup>As NMR line disappears completely, and the isotropic shift <sup>75</sup><i>K</i><sub>iso</sub> increases to 0.19%. This indicates the predominance of the Knight term due to conduction electrons in the total shift. The isotropic shift <sup>75</sup><i>K</i><sub>iso</sub> is maximal in the extreme BaCo<sub>2</sub>As<sub>2</sub> compound, which indicates the maximum value of the density of states at the Fermi level. <sup>59</sup>Co NMR in Ba(Cr<sub>0.7</sub>Co<sub>0.3</sub>)<sub>2</sub>As<sub>2</sub> in zero external magnetic field measured for the first time has demonstrated a wide distribution of the intensity of the spin echo in the frequency range of 10‒55 MHz, corresponding to a local magnetic field of several Tesla on cobalt. This field is 5–7 times lower than the characteristic local fields detected in Co-based magnets, which indicates a significant reduction of the magnetic moment of cobalt in the Ba(Cr<sub>0.7</sub>Co<sub>0.3</sub>)<sub>2</sub>As<sub>2</sub> compound. Starting from a cobalt content of 80%, the <sup>59</sup>Co NMR line is sharply narrowed, which indicates the nonmagnetic state of Co in the Ba(C-r<sub>1‒<i>x</i></sub>Co<sub><i>x</i></sub>)<sub>2</sub>As<sub>2</sub> compounds with <i>x</i> > 0.6.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"122 6","pages":"385 - 389"},"PeriodicalIF":1.3,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145406295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-31DOI: 10.1134/S0021364025608450
V. N. Borodikhin, P. N. Malyarenko, V. V. Khitrintseva
A two-dimensional model of antiferromagnetic systems near the phase transitions of spin density waves has been considered taking into account the superconducting phase. Particular attention has been paid to the study of the influence of nonlinear effects, in particular, the interaction constant of the order parameter fluctuations, on the phase transitions arising in the system.
{"title":"Study of the Quantum Spin Model Taking into Account Phase Transitions of Spin Density Waves and the Superconducting Phase","authors":"V. N. Borodikhin, P. N. Malyarenko, V. V. Khitrintseva","doi":"10.1134/S0021364025608450","DOIUrl":"10.1134/S0021364025608450","url":null,"abstract":"<p>A two-dimensional model of antiferromagnetic systems near the phase transitions of spin density waves has been considered taking into account the superconducting phase. Particular attention has been paid to the study of the influence of nonlinear effects, in particular, the interaction constant of the order parameter fluctuations, on the phase transitions arising in the system.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"122 6","pages":"390 - 394"},"PeriodicalIF":1.3,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145406297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-31DOI: 10.1134/S0021364025608255
A. V. Demura, D. S. Leont’ev, V. S. Lisitsa
Resonant laser fluorescence on the Stark structure of levels of fast atoms in diagnostic beams in a nuclear fusion plasma has been theoretically studied. A nonstationary kinetic model of the population of Stark sublevels has been developed to describe resonant laser fluorescence depending on the parameters of the diagnostic beam, plasma, laser pulse, and time. The change in the fluorescence signal at the beam depending on the time and density of the plasma has been examined. The suppression of resonant laser fluorescence under both broadband and selective laser pumping of Stark sublevels with an increase in density and the tendency of nonstationary dynamic populations to statistical values, which follow from the Schrödinger theory of the Stark effect and do not depend on the density and nature of the equilibrium between the levels, has been revealed. The results are of general physical interest in the light of experimental confirmation of Schrödinger quantum theory of hydrogen-like systems, as well as in view of the relevance of the search for new possibilities for laser-beam plasma diagnostic.
{"title":"Statistical and Dynamic Populations of Atomic Beam Levels in a Plasma","authors":"A. V. Demura, D. S. Leont’ev, V. S. Lisitsa","doi":"10.1134/S0021364025608255","DOIUrl":"10.1134/S0021364025608255","url":null,"abstract":"<p>Resonant laser fluorescence on the Stark structure of levels of fast atoms in diagnostic beams in a nuclear fusion plasma has been theoretically studied. A nonstationary kinetic model of the population of Stark sublevels has been developed to describe resonant laser fluorescence depending on the parameters of the diagnostic beam, plasma, laser pulse, and time. The change in the fluorescence signal at the beam depending on the time and density of the plasma has been examined. The suppression of resonant laser fluorescence under both broadband and selective laser pumping of Stark sublevels with an increase in density and the tendency of nonstationary dynamic populations to statistical values, which follow from the Schrödinger theory of the Stark effect and do not depend on the density and nature of the equilibrium between the levels, has been revealed. The results are of general physical interest in the light of experimental confirmation of Schrödinger quantum theory of hydrogen-like systems, as well as in view of the relevance of the search for new possibilities for laser-beam plasma diagnostic.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"122 6","pages":"347 - 353"},"PeriodicalIF":1.3,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145406212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-31DOI: 10.1134/S002136402560805X
V. D. Zvorykin
The dynamics of strong plane shock waves (SW) was studied being generated in a hypersonic laser-driven shock tube (LDST) during the acceleration of thin polymer CH films by the ablation pressure of plasma produced by UV pulses of KrF laser (100 J and 100 ns). The LDST has a square cross-section of 7 × 7 mm and a length of 50 mm. At an incident radiation energy density of 70 J/cm2 and intensity of 0.7 GW/cm2, the SW velocity in air at atmospheric pressure of 2.6 km/s (Mach number M = 8.2) was constant while it propagated in the LDST, and it increased by an additional 30−50% when the laser plasma was confined by a transparent quartz plate. It was shown that the time of quasi-stationary propagation of the SW in the LDST is ~20 μs, being determined by the energy density of the laser pulse imparted to the plasma piston. For comparison, the SW velocity in free space quickly attenuated due to the lateral expansion of the gas, while the SW front acquired the hemispherical shape.
{"title":"Dynamics of Hypersonic Shock Waves Generated by Laser Acceleration of Thin-Film Targets in a Laser-Driven Shock Tube and Free Space","authors":"V. D. Zvorykin","doi":"10.1134/S002136402560805X","DOIUrl":"10.1134/S002136402560805X","url":null,"abstract":"<p>The dynamics of strong plane shock waves (SW) was studied being generated in a hypersonic laser-driven shock tube (LDST) during the acceleration of thin polymer CH films by the ablation pressure of plasma produced by UV pulses of KrF laser (100 J and 100 ns). The LDST has a square cross-section of 7 × 7 mm and a length of 50 mm. At an incident radiation energy density of 70 J/cm<sup>2</sup> and intensity of 0.7 GW/cm<sup>2</sup>, the SW velocity in air at atmospheric pressure of 2.6 km/s (Mach number M = 8.2) was constant while it propagated in the LDST, and it increased by an additional 30−50% when the laser plasma was confined by a transparent quartz plate. It was shown that the time of quasi-stationary propagation of the SW in the LDST is ~20 μs, being determined by the energy density of the laser pulse imparted to the plasma piston. For comparison, the SW velocity in free space quickly attenuated due to the lateral expansion of the gas, while the SW front acquired the hemispherical shape.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"122 6","pages":"354 - 360"},"PeriodicalIF":1.3,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S002136402560805X.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145406310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-31DOI: 10.1134/S0021364025607833
D. M. Rodkin, Yu. M. Tchuvil’sky
The energies and decay properties of the ground and lower excited levels of the 9C nucleus have been calculated with the no-core shell model using the cluster channel orthogonal function method we have developed. Using these data, the cross sections for the 8B(p, γ)9C radiative capture have been calculated and the astrophysical S factor has been analyzed in a wide range of collision energies. A strong dependence of the S factor at zero energy on positive parity levels in the spectrum of the 9C nucleus has been demonstrated.
{"title":"Ab Initio Analysis of the Astrophysical S Factor of the Radiative Capture of a Proton by a 8B Nucleus","authors":"D. M. Rodkin, Yu. M. Tchuvil’sky","doi":"10.1134/S0021364025607833","DOIUrl":"10.1134/S0021364025607833","url":null,"abstract":"<p>The energies and decay properties of the ground and lower excited levels of the <sup>9</sup>C nucleus have been calculated with the no-core shell model using the cluster channel orthogonal function method we have developed. Using these data, the cross sections for the <sup>8</sup>B(<i>p</i>, γ)<sup>9</sup>C radiative capture have been calculated and the astrophysical <i>S</i> factor has been analyzed in a wide range of collision energies. A strong dependence of the <i>S</i> factor at zero energy on positive parity levels in the spectrum of the <sup>9</sup>C nucleus has been demonstrated.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"122 6","pages":"335 - 341"},"PeriodicalIF":1.3,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S0021364025607833.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145406296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-27DOI: 10.1134/S0021364025608401
I. A. Kovalev, I. Yu. Eremchev, D. Roesel, M. Eremchev
Silica–aqueous interfaces are the foundation of electrokinetics, microfluidics, and countless physics and biophysics experiments. Yet despite their ubiquity, their molecular structure and electrostatics under flow conditions remain poorly understood. Here we use second-harmonic microscopy combined with Raman spectroscopy in glass microcapillaries, to directly track surface potential dynamics during pH cycling. Acidic and basic transitions from neutral pH conditions drive the interface along distinct kinetic pathways: forward pH jumps elicit instantaneous responses, whereas reverse relaxations are markedly slower, producing path-dependent hysteresis. Extended pH cycling experiments reveal that the silica interface can occupy multiple quasi-stable charge states with surface potential variation from –110 to –25 mV along distinct acid- and base-mediated pathways. Such history-dependent behavior has broad consequences wherever glass substrates are employed, from electrokinetic devices to single-molecule and condensed-matter studies.
{"title":"Hidden Metastable States, Hysteresis, and Slow Dynamics of Silica–Aqueous Interface Revealed with Second Harmonic Microscopy","authors":"I. A. Kovalev, I. Yu. Eremchev, D. Roesel, M. Eremchev","doi":"10.1134/S0021364025608401","DOIUrl":"10.1134/S0021364025608401","url":null,"abstract":"<p>Silica–aqueous interfaces are the foundation of electrokinetics, microfluidics, and countless physics and biophysics experiments. Yet despite their ubiquity, their molecular structure and electrostatics under flow conditions remain poorly understood. Here we use second-harmonic microscopy combined with Raman spectroscopy in glass microcapillaries, to directly track surface potential dynamics during pH cycling. Acidic and basic transitions from neutral pH conditions drive the interface along distinct kinetic pathways: forward pH jumps elicit instantaneous responses, whereas reverse relaxations are markedly slower, producing path-dependent hysteresis. Extended pH cycling experiments reveal that the silica interface can occupy multiple quasi-stable charge states with surface potential variation from –110 to –25 mV along distinct acid- and base-mediated pathways. Such history-dependent behavior has broad consequences wherever glass substrates are employed, from electrokinetic devices to single-molecule and condensed-matter studies.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"122 9","pages":"576 - 583"},"PeriodicalIF":1.3,"publicationDate":"2025-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145730226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}