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Synergetic Oxidation in Alkaline In-Situ Leaching Uranium: A Preliminary Case Study 碱地浸出铀的协同氧化:初步案例研究
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16200
Wensheng Liao, Weimin Que, Limin Wang, Zhiming Du
In alkaline in-situ leaching uranium, oxygen is the most common oxidizer with bicarbonate as a complexing agent. For those sandstone uranium deposits with strongly reductive capacity or complicated hydrogeological environment, the oxidation by oxygen is low efficiency. An efficient leaching method, therefore, is needed for these uranium deposits. In this study, a typical sandstone uranium deposit which characterizes with high TDS and high chloride content in groundwater and intractable uranium leach is selected to investigate the effects of synergetic oxidation by a strong oxidant with oxygen. Based on the research on batch leach, pressure leach and field trials, the oxidants such as hydrogen peroxide, potassium permanganate and sodium dichloroisocyanurate (NaDCC) are tested. The results of pressure batch leach indicate that synergetic oxidization is achieved by NaDCC in oxygen leaching process. Leaching tests indicate that a minor oxidizer of NaDCC shows good synergetic oxidization with oxygen and leaching effects on uranium minerals. The results also demonstrate that hydrogen peroxide shows no oxidation effects when it is used as a single oxidant. While potassium permanganate shows good oxidation on uranium when it is used as a single oxidant, however, it leads inhibiting effects on oxygen oxidation on uranium minerals. The further field tests are conducted to study the synergetic effects of oxygen with and without sodium dichloroisocyanurate. The preliminary results indicate that a fast leach is observed by the composite oxidants in early stage while no synergetic leach is found after 200 days. Further studies should be conducted in laboratory experiments and pilot scale tests for its potential applications.
在碱性地浸铀中,氧是最常见的氧化剂,碳酸氢盐作为络合剂。对于还原能力强或水文地质环境复杂的砂岩型铀矿床,氧氧化效率较低。因此,这些铀矿床需要一种有效的浸出方法。选取地下水TDS高、氯化物含量高、铀浸出难处理的典型砂岩铀矿床,研究强氧化剂与氧协同氧化的效果。在间歇浸出、压力浸出和现场试验的基础上,对过氧化氢、高锰酸钾和二氯异氰尿酸钠(NaDCC)等氧化剂进行了测试。压力间歇浸出结果表明,NaDCC在氧浸过程中实现了协同氧化。浸出试验表明,NaDCC是一种次要氧化剂,对铀矿物具有良好的氧协同氧化和浸出效果。结果还表明,当过氧化氢作为单一氧化剂使用时,它没有氧化作用。高锰酸钾作为单一氧化剂对铀有良好的氧化作用,但对铀矿物的氧氧化有抑制作用。进一步进行了现场试验,研究了氧与二氯异氰尿酸钠和不含二氯异氰尿酸钠的协同效应。初步结果表明,复合氧化剂在初期快速浸出,200 d后未出现协同浸出。应在实验室试验和中试规模试验中对其潜在应用进行进一步研究。
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引用次数: 0
Development of Design Support System for Piping Route and Differential Pressure Flowmeter by Three-Dimensional Fluid Analysis 基于三维流体分析的管路差压流量计设计支持系统的开发
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16745
Takatsugu Miura, K. Igarashi, Tomoyuki Hosaka, Takumi Kitagawa, Tatsurou Yashiki, Yuki Itabayashi, Hirotsugu Suzuki, T. Nakahara, J. Kitamura, T. Sano
In power plants that becoming more compact, it will expend much time and effort to satisfy the requirement for the differential pressure flow measurement according to ISO’s standards. Therefore, it is difficult for engineers in the design phase to completely remove the potential for large errors in flow measurement. This paper presents the 3D fluid analysis system that is a lower cost than the conventional method to confirm the soundness of such measurement in the phase of piping route design. This system has the function to automatically generate the analysis models from general 3D piping CAD data. The analysis program is written by the open source code to reduce a license fee. Also, this system has the function of calculating the swirl strength along the pipe axis as one of the means for efficiently supporting the design change. In order to verify and validate the analysis system, we analyzed several flow paths, confirmed the response of the swirl strength and flow rate indication value of the differential pressure flowmeter model. The analysis result well simulated the increase or decrease swirl strength in the complex flow path, and fluctuation of the flow rate indication value. Also, the system supports to set the flowmeter in the appropriate position by providing visualization of the swirl strength along the pipe axis. In the flow path analysis in this validation, it took about one month to visualization of the swirl strength along the pipe axis from the generation of the analysis models. The 3D fluid analysis system collaborative with 3D piping CAD design system has been developed. This system enable to confirm the effects of swirl strength on flow measurement and the soundness of the differential pressure flow measurement at a lower cost in comparison with conventional method.
在日趋紧凑的电厂中,要满足ISO标准对压差流量的测量要求,将花费大量的时间和精力。因此,工程师在设计阶段很难完全消除流量测量中存在较大误差的可能性。本文提出了一种比传统方法成本更低的三维流体分析系统,在管道路线设计阶段验证了这种测量方法的合理性。该系统具有将一般三维管道CAD数据自动生成分析模型的功能。分析程序是由开放源代码编写的,以减少许可费用。该系统还具有沿管道轴向的旋流强度计算功能,作为有效支持设计变更的手段之一。为了验证和验证分析系统,我们分析了几种流道,确认了差压流量计模型对旋流强度和流量指示值的响应。分析结果较好地模拟了复杂流道中旋流强度的增减和流量指示值的波动。此外,该系统支持将流量计设置在适当的位置,提供沿管道轴的旋流强度的可视化。在本次验证的流道分析中,从分析模型的生成开始,花了大约一个月的时间来可视化沿管道轴的旋流强度。开发了协同三维管道CAD设计的三维流体分析系统。与传统方法相比,该系统能够以较低的成本确认旋流强度对流量测量的影响和差压流量测量的正确性。
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引用次数: 0
Study on Heating Process of Dehumidifying Experiment in HTGR 高温高温堆除湿实验加热过程研究
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16358
Kaiyue Shen, Weizhen Zheng, Shengchao Ma, Huaqiang Yin, Xuedong He, T. Ma
A large number of carbon materials are used in high temperature gas-cooled reactor (HTGR). As a kind of porous material, the carbon material contains a certain amount of moisture and other impurities. In order to reduce the corrosion of internal material in reactor core of HTGR, the initial core or post-accident core must be strictly heated and dehumidified. The current primary circuit heating mainly relies on the rotation of the primary pump to convert the kinetic energy into thermal energy. Obviously, the current scheme was flawed: (1) Due to the insufficient heat generated by rotation of the primary pump, the temperature rising process of the primary circuit is sluggish; (2) The rotation of the primary pump converts the kinetic energy into thermal energy of the helium, at the meantime, the primary circuit dissipates heat outward. For the above reasons, it is difficult to achieve the desired dehumidification temperature in the heating process. While in this paper, an additional thermal source will be added to the steam generator to heat the primary circuit in a new scheme. A proper flow and heat-transfer model of heating the primary circuit in high-temperature reactor was established based on software COMSOL Multiphysics. The numerical analysis of the primary circuit heating process provides rewarding guidance for the selection of the dehumidification scheme in HTGR.
高温气冷堆(HTGR)中使用了大量的碳材料。碳材料作为一种多孔材料,含有一定量的水分和其他杂质。为了减少高温气堆堆芯内部材料的腐蚀,必须对堆芯进行严格的加热和除湿。目前一次回路加热主要依靠一次泵的旋转将动能转化为热能。显然,目前的方案存在缺陷:(1)由于一次泵旋转产生的热量不足,导致一次回路升温过程缓慢;(2)一次泵的旋转将氦的动能转化为热能,同时一次回路向外散热。由于上述原因,在加热过程中很难达到理想的除湿温度。而在本文中,在新的方案中,将在蒸汽发生器中增加一个额外的热源来加热一次回路。基于COMSOL Multiphysics软件,建立了高温反应器一次回路加热的合理流动和传热模型。对一次回路加热过程的数值分析为高温高温堆除湿方案的选择提供了有益的指导。
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引用次数: 0
Multiphysics Analysis of Thorium-Based Fuel Performance Under Reactor Steady-State and Transient Accident 反应堆稳态和瞬态事故下钍基燃料性能的多物理场分析
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16325
Chenjie Qiu, Rong Liu, Wenzhong Zhou
The ThO2 fuel has higher thermal conductivity and melting boiling point than the UO2 fuel, which is beneficial to the fast removal of heat and the improvement of fuel melt margin. In this paper, the material properties and thermodynamic behaviors of thorium-based fuel were firstly reviewed. And then the thermal physical properties and the fuel behavior models of Th0.923U0.077O2 fuel and Th0.923Pu0.077O2 fuel have been implemented in fuel performance analysis code FRAPCON and FRAPTRAN. Finally, the performances of Th0.923U0.077O2 fuel, Th0.923Pu0.077O2 fuel and UO2 fuel under both normal operating conditions and transient conditions (RIA and LOCA) are analyzed and compared. The Th0.923U0.077O2 fuel is found to have lower fuel center-line temperature and the thorium-based fuels are observed to have a delayed pellet-cladding mechanical interaction (PCMI) under steady state. Furthermore, the fission gas release, cladding strain and internal fuel energy under transient conditions are found to be lower too. Lastly, the cladding displacement and temperature under transient conditions are also compared. The thorium-based fuel was found to have a higher safety margin and accident resistance than conventional UO2 fuel under both normal operating conditions and accident conditions.
与UO2燃料相比,ThO2燃料具有更高的导热系数和熔点,有利于快速脱热和提高燃料熔体裕度。本文首先综述了钍基燃料的材料性质和热力学行为。然后在燃料性能分析程序FRAPCON和FRAPTRAN中实现了Th0.923U0.077O2燃料和Th0.923Pu0.077O2燃料的热物理性质和燃料行为模型。最后,对Th0.923U0.077O2燃料、Th0.923Pu0.077O2燃料和UO2燃料在正常工况和瞬态工况(RIA和LOCA)下的性能进行了分析和比较。发现Th0.923U0.077O2燃料具有较低的燃料中心线温度,并且观察到钍基燃料在稳态下具有延迟的球团包壳机械相互作用(PCMI)。此外,瞬态条件下的裂变气体释放量、包层应变和内部燃料能也较低。最后,对瞬态条件下的包层位移和温度进行了比较。在正常工况和事故工况下,钍基燃料都比常规UO2燃料具有更高的安全裕度和抗事故能力。
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引用次数: 0
Corrosion Property of Container Using Hybrid Material for Thermal Decomposition Process of Sulfuric Acid 混合材料硫酸热分解容器的腐蚀性能研究
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16783
I. Ioka, Y. Kuriki, J. Iwatsuki, Daisuke Kawai, Y. Inagaki, S. Kubo
A thermochemical water-splitting iodine-sulfur process (IS process) is one of candidates for the large-scale production of hydrogen using heat from nuclear energy. Severe corrosive environment which is thermal decomposition of sulfuric acid exists in the IS process. To achieve an industrialization of massive hydrogen production system, one of the key factors is the development of structural materials for the severe corrosive environment. A hybrid material with the corrosion-resistance and the ductility had been made by a silicon powder plasma spraying and laser treatment. To confirm the applicability of the hybrid material as the structural material, corrosion tests of the hybrid materials had been performed in 95 mass% and 47 mass% boiling sulfuric acid. The corrosion resistance of specimen in the condition of 95 mass% boiling sulfuric acid had been excellent. This was attributed to the formation of SiO2 on the surface. To confirm the production characteristics as a container using the hybrid material, the container which has a welded part, a chamfer, a curved surface had been experimentally made. A configuration of the container had been 150mm inside diameter, 120mm in height and 6mm in thickness. The substrate of the container made of Hastelloy C276® superalloy had included TIG weld part. To improve the corrosion resistance of the container, pre-oxidation was performed at 800°C for 100 hours in air. There was no detachment of the plasma spraying and laser treated layer on the base metal and the welded part. The pre-oxidized container using hybrid technique was prepared for the corrosion test in boiling sulfuric acid to evaluate the characteristics of the container.
热化学水裂解碘硫工艺(IS工艺)是利用核能热大规模生产氢的候选工艺之一。is工艺中存在硫酸热分解的严重腐蚀环境。为了实现大规模制氢系统的工业化,开发适应严重腐蚀环境的结构材料是关键因素之一。采用硅粉等离子喷涂和激光处理制备了一种既耐腐蚀又具有延展性的杂化材料。为证实该杂化材料作为结构材料的适用性,对该杂化材料在95%质量%和47%质量%沸腾硫酸中进行了腐蚀试验。试样在95%质量%沸腾硫酸条件下具有良好的耐蚀性。这是由于在表面形成了SiO2。为了确定混合材料作为容器的生产特性,实验制作了具有焊接部分、倒角、曲面的容器。集装箱的配置为内径150毫米,高120毫米,厚6毫米。哈氏C276®高温合金制成的容器基底包含TIG焊接部分。为了提高容器的耐腐蚀性,在空气中800℃预氧化100小时。等离子喷涂层和激光处理层在母材和焊接件上均无脱离现象。采用混合技术制备了预氧化容器,进行了沸腾硫酸腐蚀试验,以评价容器的性能。
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引用次数: 0
Sensitivity Analysis of External Exposure Dose for Future Burial Measures of Decontamination Soil Generated Outside Fukushima Prefecture 福岛县以外地区净化土壤未来掩埋措施的外照射剂量敏感性分析
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16826
A. Shimada, T. Sawaguchi, S. Takeda
A large area of east Japan was contaminated by radiocesium following a nuclear accident at the Fukushima Daiichi Nuclear Power Station. Following decontamination of the soil, external effective dose conversion factors were calculated by changing the volume of decontamination soil, depth of cover soil, and distance of the evaluation point from the decontamination soil. The decrement of the factors with an increase of the distance was larger for the smaller volume of decontamination soil. The factors decrease exponentially with an increase of the depth of cover soil in all cases. When there was no cover soil, annual external exposure doses for residents at 1 m from the repository site and public entry were over 10 μSv/y, even for the smallest size (2m × 2m × 1m) and 50 percentile value of radiation concentration (700 Bq/kg). When the surface was covered by 30 cm of non-contaminated soil, the annual external exposure doses were less than 10 μSv/y for the largest size (200m × 200m × 10m) and 95 percentile concentration (2500 Bq/kg).
福岛第一核电站发生核事故后,日本东部大片地区受到放射性元素污染。土壤去污后,通过改变去污土体积、覆盖土深度、评价点与去污土的距离,计算外有效剂量换算因子。消污土壤体积越小,各因子随距离的增加衰减越大。在所有情况下,这些因子随覆盖层深度的增加呈指数递减。在无覆盖土壤的情况下,即使是最小尺寸(2m × 2m × 1m)和辐射浓度的50%值(700 Bq/kg),距离库址和公众入口1m范围内的居民年外照射剂量也超过10 μSv/y。当表面覆盖30 cm的非污染土壤时,最大粒径(200m × 200m × 10m)和95%百分位浓度(2500 Bq/kg)的年外暴露剂量均小于10 μSv/y。
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引用次数: 0
Modelling of the H2020 INSPYRE Fuel Creep Experiment H2020 INSPYRE燃料蠕变试验的建模
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16231
A. Fedorov, Kevin Zwijsen, S. V. Til
To better understand irradiation creep of nuclear fuel, NRG has prepared, as part of the H2020 European project INSPYRE, a separate effect irradiation experiment in the High Flux Reactor (HFR) in Petten (the Netherlands) aiming to measure fuel creep in-pile as a function of temperature, flux, burn-up and axial pressure load. This continuous type of measurement will supply a large data set, leading to more detailed knowledge on fuel behaviour during irradiation. To support the experiment and make optimal use of the generated data, a model is created of the experiment to better predict the behaviour of the fuel samples during irradiation. The current paper describes the numerical model, which couples the 1.5D fuel performance code TRANSURANUS (TU) with a Finite Element Analysis (FEA). The thermal analysis of the experiment is carried out using the FEA. Such approach enables to model a rather complex geometry of the experiment, and to include axial heat transport, which is not implemented in TU. TU is modified in order to use the fuel pellet temperatures obtained using the FEA and to include the axial load present in the experiment. The model is validated against several test cases and used to predict the fuel behaviour during a selection of foreseen irradiation scenario’s. Results of the model will be used in the future for optimization of the irradiation parameters used in the experiment and for analysis of the data obtained during the irradiation.
为了更好地了解核燃料的辐照蠕变,作为H2020欧洲项目INSPYRE的一部分,NRG在荷兰Petten的高通量反应堆(HFR)中准备了一个单独的效应辐照实验,旨在测量堆内燃料蠕变作为温度、通量、燃烧和轴压载荷的函数。这种连续类型的测量将提供大量数据集,从而更详细地了解辐照期间的燃料行为。为了支持实验并最佳地利用所产生的数据,建立了实验模型,以更好地预测燃料样品在辐照期间的行为。本文描述了将1.5D燃油性能代码TRANSURANUS (TU)与有限元分析(FEA)耦合在一起的数值模型。利用有限元法对实验进行了热分析。这种方法能够模拟一个相当复杂的实验几何,并包括轴向热传输,这在TU中没有实现。TU被修改,以便使用通过有限元分析获得的燃料颗粒温度,并包括实验中存在的轴向负荷。该模型通过几个试验案例进行了验证,并用于预测在可预见的辐照情景中燃料的行为。该模型的结果将在将来用于优化实验中使用的辐照参数和分析辐照过程中获得的数据。
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引用次数: 0
Numerical Simulation of Multi-Physics Processes in Nuclear System Based on Galerkin Finite Element Method 基于伽辽金有限元法的核系统多物理场过程数值模拟
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16801
Bao-Xin Yuan, Wankui Yang, Songbao Zhang, Bin Zhong, Junxia Wei, Yangjun Ying
It is of practical significance to analyze the multi-physics process of nuclear system, which includes neutronics, heat transfer and thermoelasticity. Fission reaction is the heat source in system, the heat source will affect the distribution of temperature field, which will lead to the change of strain. Strain in turn will affect the distribution of neutron field. Therefore, it is necessary to analyze the distribution of neutron flux, temperature and strain in system. Three aspects of work have been carried out: 1) Based on Galerkin finite element theory, the governing equations of neutronics, heat transfer and thermoelasticity are established; 2) The multi-physics analysis code is developed; 3) The calculation results are analyzed and discussed.
分析核系统的多物理场过程,包括中子学、热传导和热弹性,具有重要的现实意义。裂变反应是系统中的热源,热源会影响温度场的分布,从而导致应变的变化。应变又会影响中子场的分布。因此,有必要对系统中中子通量、温度和应变的分布进行分析。本文从三个方面进行了工作:1)基于伽辽金有限元理论,建立了中子学、传热和热弹性的控制方程;2)开发了多物理场分析代码;3)对计算结果进行了分析和讨论。
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引用次数: 0
Local Damage to Reinforced Concrete Panels Subjected to Oblique Impact by Projectiles: Outline of Impact Test 受弹丸斜冲击的钢筋混凝土板的局部损伤:冲击试验大纲
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16843
A. Nishida, Zuoyi Kang, Y. Okuda, H. Tsubota, Yinsheng Li
Studies on the local damage to reinforced concrete (RC) panels subjected to projectile impact have mainly focused on collisions that occur at an angle normal to the structure; thus, research on oblique impact is scarce. Due to this, we conducted research focusing on oblique impact to enable more realistic impact assessment of projectile collisions. To date, the validity of the analytical method has been confirmed by comparing the results with those of previous tests, and the local damage to RC panels that have collided with projectiles has been analytically investigated focusing on the impact angle. Therefore, this study aims to confirm the validity of the analysis method by conducting specific impact tests under various conditions, including the impact angle, by obtaining the relevant data. This paper outlines the test for the local damage to RC panels subjected to both normal and oblique impacts.
钢筋混凝土板受弹丸冲击的局部损伤研究主要集中在与结构成法向角的碰撞上;因此,对斜冲击的研究较少。因此,我们开展了以倾斜冲击为重点的研究,以便对弹丸碰撞进行更真实的冲击评估。迄今为止,通过与以往试验结果的对比,验证了分析方法的有效性,并对RC板与弹丸碰撞后的局部损伤进行了以冲击角为重点的分析研究。因此,本研究旨在通过获取相关数据,进行包括冲击角度在内的各种条件下的具体冲击试验,来验证分析方法的有效性。本文概述了钢筋混凝土面板在正、斜冲击作用下的局部损伤试验。
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引用次数: 0
Impact Analysis of NPP H4 Connections Design Improvement on Emergency Operation 核电站H4连接设计改进对应急运行的影响分析
Pub Date : 2020-08-04 DOI: 10.1115/icone2020-16311
W. Yuqi, Yi Ke
After the loss of coolant accident (LOCA), the safety injection system injects water into the reactor coolant system (RCS), and the residual heat rejects from the break. The containment spray system is operating in recirculating cooling mode to ensure that the containment is cooldown. This state must be maintained for several months. After the accident, in order to respond the design extension conditions (DEC) of failure of two containment spray pumps or two low pressure safety injection pumps, the design of the original H4 connections was improved, and the H4 procedure (loss of containment spray pumps or low pressure safety injection pumps) was developed. H4 procedure demands to put into service 2 permanent (one for each train) interconnections of containment spray system and safety injection system, called “H4 connections”. Through the design improvement of the H4 connections, the mutual backup function of safety injection and containment spray can be realized implemented. The manual valves of the H4 connections in the original design were changed to electric valves, which ensured the accessibility of operator and avoided the radiation of high radioactivity level to operator after the accident. In addition, the improved H4 connections enable mutual backup of safety injection and containment spray in the early stage after the accident to be implemented, which fully improves the ability to respond to accidents and safety design level of the nuclear power plant (NPP). This also makes it possible to intervene early after the accident.
在冷却剂损失事故(LOCA)发生后,安全注入系统向反应堆冷却剂系统(RCS)注水,余热从断裂中排出。安全壳喷雾系统在循环冷却模式下运行,以确保安全壳冷却。这种状态必须维持几个月。事故发生后,为了应对两台安全壳喷雾泵或两台低压安全喷射泵失效的设计延伸条件(DEC),对原有H4连接设计进行了改进,形成了H4程序(安全壳喷雾泵或低压安全喷射泵失效)。H4程序要求将安全壳喷射系统和安全喷射系统的2个永久互连(每列列车一个)投入使用,称为“H4连接”。通过对H4接头的设计改进,实现了安全喷射与安全壳喷射的相互备份功能。原设计的H4接头手动阀改为电动阀,保证了操作人员的可及性,避免了事故发生后对操作人员的高放射性辐射。此外,改进后的H4连接使安全喷射和安全壳喷雾在事故发生后的早期阶段能够相互备份,充分提高了核电站的事故响应能力和安全设计水平。这也使得事故发生后的早期干预成为可能。
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引用次数: 0
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核工程研究与设计
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