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Trace Element Geochemistry and Sr-Nd Isotopic Characteristics of Scheelite from the Gejiu Sn-Cu-(W) Ore District: Constraints on Tungsten Sources and Evolution of W-bearing Hydrothermal Fluids 个旧Sn-Cu-(W)矿区白钨矿微量元素地球化学及Sr-Nd同位素特征:对钨源及含W热液演化的制约
IF 3.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-01 DOI: 10.1111/1755-6724.15328
Zhang HAN, Chao LI, Yaokun CHEN, Qinggao YAN, Fucheng YANG, Chao WEI, Xiaojun JIANG

The Gejiu tin-copper-(tungsten) (Sn-Cu-(W)) polymetallic district is located in the southwest of the W-Sn metallogenic belt in the western Youjiang Basin, Yunnan, Southwest China. Abundant W minerals have been identified in the region via exploration. However, metallogenic sources and evolution of W remain unclear, and the existing metallogenic model has to be updated to guide further ore prospecting. Elemental and Sr-Nd isotopic data for scheelites assist in the determination of sources and evolution of the W-mineralizing fluids and metals in the district. Based on field geological survey, the scheelites in the Gejiu district can be categorized into three types: altered granite (Type I), quartz vein (Type II) from the Laochang deposit, and skarn (Type III) from the Kafang deposit. Types I and II scheelites have low molybdenum (Mo) and strontium (Sr) contents, and Type II scheelite has lower Sr contents than Type I as well as higher Mo and Sr contents than Type III scheelites. Varying Mo contents across the scheelite types suggests that the oxygen fugacity varied during ore accumulation. Type I and Type II scheelites exhibit similar rare earth elements (REE) patterns; Type III scheelite contains lower REE content, particularly HREE, compared with the other scheelites. All scheelites exhibit negative Eu anomalies in the chondrite-normalized REE patterns. As the W-mineralization and two-mica granite share close spatial and temporal relationships, the negative Eu anomalies were likely inherited from the two-mica granite. Type I and Type II scheelites display varied (87Sr/86Sr)82 Ma (0.7090–0.7141) and εNd(82 Ma) (from –9.9 to –5.4) values, similar to those of granite. However, Type III scheelite exhibits lower (87Sr/86Sr)82 Ma (0.7083–0.7087) and lower εNd(82 Ma) (from –10.5 to –6.9) values than the two-mica granite. This indicates that the two-mica granite alone did not provide the ore-forming fluids and metals and that the Type III scheelite ore-forming fluids likely involved external fluids that were probably derived from carbonate rocks. The implication is that highly differentiated two-mica granites were the source of primary W-bearing metals and fluids, which is consistent with earlier research on the origin of Sn ore-forming materials.

个旧锡-铜-(钨)(锡-铜-(钨)(锡-铜-(钨))多金属带位于云南右江盆地西部锡-锡成矿带的西南部。经勘探,区内已发现丰富的钨矿。但钨的成矿来源和演化尚不清楚,需要更新现有的成矿模式,指导下一步找矿。白钨矿的元素和Sr-Nd同位素数据有助于确定该区钨矿化流体和金属的来源和演化。根据野外地质调查,个旧地区的白钨矿可分为蚀变花岗岩(ⅰ型)、老厂矿床的石英脉(ⅱ型)和卡方矿床的矽卡岩(ⅲ型)3种类型。ⅰ型和ⅱ型白钨矿的钼、锶含量较低,ⅱ型白钨矿的Sr含量低于ⅰ型白钨矿,Mo、Sr含量高于ⅲ型白钨矿。不同白钨矿类型的Mo含量不同,说明成矿过程中氧逸度发生了变化。ⅰ型白钨矿和ⅱ型白钨矿的稀土元素模式相似;与其他白钨矿相比,ⅲ型白钨矿的稀土元素含量较低,尤其是稀土元素。所有白钨矿均呈现负Eu异常。由于钨矿化与二云母花岗岩具有密切的时空关系,因此负Eu异常可能继承自二云母花岗岩。ⅰ型和ⅱ型白钨矿表现为87Sr/86Sr 82 Ma(0.7090 ~ 0.7141)和εNd(82 Ma)(-9.9 ~ -5.4)变化,与花岗岩相似。而III型白钨矿的87Sr/86Sr值低于2云母花岗岩(0.7083 ~ 0.7087),εNd(82 Ma)值低于2云母花岗岩(-10.5 ~ -6.9)。说明二云母花岗岩本身不能提供成矿流体和成矿金属,III型白钨矿成矿流体可能涉及来自碳酸盐岩的外部流体。说明高分异的二云母花岗岩是原生含w金属和流体的来源,这与前人对锡成矿物质来源的研究一致。
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引用次数: 0
Mineralization at Different Structural Levels in the Crust 地壳不同构造层次的成矿作用
IF 3.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-01 DOI: 10.1111/1755-6724.15319
Saisai LI, Hongrui ZHANG, Zengqian HOU

Metallogenic research on structural levels can reveal vertical patterns of mineralization and facilitate the deep exploration of economic minerals. However, research focusing on the correlation between structural levels and mineralization remains limited. In this study, we summarize the deformation patterns and associated mineral deposits observed at different crustal levels (i.e., surface, shallow, middle, and deep structural levels, corresponding to depths of <2, 2–8, 8–15, and >15 km, respectively). Furthermore, we examine the genetic association between structural levels and metallogenesis, demonstrating that distinct structural levels are linked to specific types of mineralization. Key factors that vary across crustal levels include temperature, pressure, and fluid circulation. Ore-forming processes involve interactions between structures and fluids under varying temperatures and pressures. Structural levels influence mineralization by controlling the temperatures, pressures, and deformation mechanisms that drive the activation, migration, and enrichment of ore-forming materials.

构造层面的成矿研究可以揭示成矿的纵向格局,为经济矿产的深部找矿提供有利条件。然而,对构造水平与矿化关系的研究仍然有限。本研究总结了不同地壳水平(即表层、浅层、中层和深层构造水平,分别对应深度为<;2、2 - 8、8-15和>;15 km)观测到的变形模式和伴生矿床。此外,我们研究了构造水平与成矿作用之间的遗传关联,表明不同的构造水平与特定类型的成矿作用有关。不同地壳水平的关键因素包括温度、压力和流体循环。成矿过程涉及构造与流体在不同温度和压力下的相互作用。构造水平通过控制温度、压力和变形机制来影响矿化,这些机制驱动成矿物质的活化、迁移和富集。
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引用次数: 0
Geochemistry and Reservoir Characteristics of Jurassic Lacustrine Shale in the Sichuan Basin: Insights from Paleoenvironmental Constraints on Pore Structure 四川盆地侏罗系湖相页岩地球化学及储层特征:古环境对孔隙结构的制约
IF 3.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-01 DOI: 10.1111/1755-6724.15318
Delu LI, Haibin LI, Wangpeng LI, Qianyang HE, Qiang SUN, Zilong WANG, Xingzhe WANG, Fei WANG, Cun LIU, Yi GAO

Pore structure directly affects the occurrence and migration of shale hydrocarbon, and the lack of research on the mechanism of the pore structure is an important reason for the hindrance of shale hydrocarbon exploration. By analysing the geochemistry and reservoir characteristics of Jurassic lacustrine shales in Sichuan Basin, this study recovers their paleoenvironments and further discusses paleoenvironmental constraints on pore structure. The results show that the Lower Jurassic lacustrine shales in the Sichuan Basin are in a warm and humid semi-anoxic to anoxic lake environment with high productivity, a strong stagnant environment, and a rapid sedimentation rate, with water depths ranging from about 11.54–55.22 m, and a mixture of type II/III kerogen is developed. In terms of reservoir characteristics, they are dominated by open-slit pores, and the pores are relatively complex. The percentage of mesopores is the highest, while the percentage of macropores is the lowest. Further analysis shows that paleoclimate controls the overall pore complexity and surface relaxation of shales by influencing the weathering rate of mother rocks. Paleoredox conditions control the proportion and complexity of shale pores by influencing TOC content. The research results will provide theoretical basis for improving the exploration efficiency of lacustrine shale resources and expanding exploration target areas.

孔隙结构直接影响页岩油气的赋存和运移,缺乏对孔隙结构机理的研究是阻碍页岩油气勘探的重要原因。通过对四川盆地侏罗系湖相页岩地球化学特征和储层特征的分析,恢复了其古环境,并进一步探讨了古环境对孔隙结构的制约。结果表明:四川盆地下侏罗统湖相页岩处于温暖湿润的半缺氧—缺氧湖泊环境,产能高,沉积速率快,水深约11.54 ~ 55.22 m,发育II/III型混合干酪根;储层特征以开缝孔隙为主,孔隙结构较为复杂。中孔的比例最高,大孔的比例最低。进一步分析表明,古气候通过影响母岩风化速率来控制页岩整体孔隙复杂性和表面松弛。古氧化还原条件通过影响TOC含量来控制页岩孔隙的比例和复杂性。研究成果将为提高湖相页岩资源勘探效率、扩大勘探目标区提供理论依据。
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引用次数: 0
A New Eusauropod Dinosaur from the Lower and Middle Jurassic Wangmen Formation of Ningming County, Guangxi, South China 广西宁明县中、下侏罗统王门组一种新的真蜥脚类恐龙
IF 3.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-01 DOI: 10.1111/1755-6724.15331
Jinyou MO, Xiuzhen ZHOU, Qiongyao FU, Duo XIONG, Minhang HU, Xing XU

We report a new eusauropod dinosaur, Huashanosaurus qini gen. et sp. nov., based on a partial skeleton recovered from a bed in the Lower to Middle Jurassic Wangmen Formation (Fm.) from Huqiu Quarry near Mingjiang River, Ningming County, Guangxi Zhuang Autonomous Region, southern China. The new taxon can be diagnosed by the following autapomorphies: posterior process of the ulna hook-shaped; the cross-section of the proximal part of the ulna crescent-shaped; groove structure present at the posterodistal surface of the fibula. Phylogenetic analysis reveals that H. qini is later-diverging than the Middle Jurassic Shunosaurus. Previous work showed that the Wangmen Fm. is early Early Jurassic in age whereas the new eusauropod discovery indicates that the Wangmen Fm. is probably somewhat younger Early–Middle Jurassic in age. The find increases the diversity of Jurassic eusauropods in China.

根据广西宁明县明江附近虎丘采石场下至中侏罗统王门组(Fm.)地层中发现的部分骨架,报道了一种新的真蜥脚类恐龙——华山龙(Huashanosaurus qini gen. et sp. nov.)。新分类群可通过以下自形态进行诊断:尺骨后突钩状;尺骨近端截面呈新月形;在腓骨的后远端表面有沟结构。系统发育分析表明,齐尼猿人的分化晚于中侏罗世的剑龙。先前的研究表明,王门Fm。属于早侏罗世早期,而新发现的真蜥脚类动物表明,王门组的化石属于早侏罗世早期。在年龄上可能更年轻,早中侏罗世。这一发现增加了中国侏罗纪真蜥脚类动物的多样性。
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引用次数: 0
Structural Deformation and Genetic Mechanism of Qinghe Gneiss Dome in the Altai Orogen, Western China 阿尔泰造山带清河片麻岩穹隆构造变形及成因机制
IF 3.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-01 DOI: 10.1111/1755-6724.15332
Zengchan DONG, Rengang XI, Bo CHEN, Kai WANG, Feng PAN, Botao HUANG

As a highly coupled aggregate of tectonism, magmatism, and metamorphism, a gneiss dome is usually taken as a vital window for understanding the crustal internal structure and the exchange of material and energy during orogenic exhumation. The Qinghe gneiss dome located in the eastern Chinese Altai orogen, lies in Qinghe County, Xinjiang, records important information of late accretionary orogeny associated with continental uplift and crustal growth. According to the field investigation, the dome shows core–mantle–margin domains, in which the core is composed of migmatized granite and gneiss, the mantle consists of banded gneiss, schist, and leptynite, and the margin has rock assemblages of phyllite, schist, and meta-sandstone. From the margin to the core, the dome can be divided into chlorite–sericite, andalusite–staurolite, sillimanite–biotite, and sillimanite–garnet metamorphic zones, recording progressive metamorphism. Detailed structural analyses in the Qinghe gneiss dome indicate progressive deformation from the margin to the core. Internal and external detachment faults are clarified, with the former characterized by inflow and outward migration of crustal material and the latter marked by brittle-ductile deformation with a lineation indicating lateral slip of the upper wall when the dome uplifted. Based on these faults, upper, middle, lower structural layers are observed from the outer to inner domains of the dome. Considering the general geological background and new data, the Qinghe gneiss dome probably predominantly underwent early ductile shear deformation and late heat-flow diapirism in the early Permian, closely related to upwelling of asthenosphere mantle that resulted from slab break-off in the extensional tectonic setting.

片麻岩穹丘是构造作用、岩浆作用和变质作用高度耦合的集合体,是研究地壳内部结构和造山掘出过程中物质和能量交换的重要窗口。清河片麻丘位于新疆清河县阿尔泰造山带东部,记录了与大陆隆升和地壳生长有关的晚期增生造山运动的重要信息。根据野外调查,圆顶呈核-幔-缘域,其中核由杂化花岗岩和片麻岩组成,幔由带状片麻岩、片岩和瘦斑岩组成,边缘有千层岩、片岩和变质砂岩组合。从边缘到岩心可划分为绿泥石-绢云母变质带、红柱石-橄榄石变质带、硅线石-黑云母变质带和硅线石-石榴石变质带,记录了渐进性变质作用。清河片麻岩穹隆的详细构造分析表明,其从边缘到岩心呈渐进性变形。明确了内拆离断层和外拆离断层,其中内拆离断层以地壳物质流入和向外运移为特征,外拆离断层以脆韧性变形为特征,并有一条线理表明穹隆隆起时上壁发生侧向滑移。在这些断层的基础上,从圆顶的外域到内域观察到上、中、下构造层。综合地质背景和新资料,清河片麻岩丘可能主要经历了早二叠世早期韧性剪切变形和晚期热流底辟作用,与伸展构造背景下板块断裂引起的软流圈地幔上涌密切相关。
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引用次数: 0
Early Paleozoic Bimodal Magmatism Documents the Transition from Collisional to Extensional Tectonics within the Central Himalaya 早古生代双峰岩浆作用记录了喜马拉雅中部由碰撞构造向伸展构造的转变
IF 3.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-30 DOI: 10.1111/1755-6724.15300
Zhiqiang YIN, Longqiang LIU, Xiaochun LÜ, Nan LI, Lidong ZHU, Qiang LIU, Erjia HA

The tectonic setting of the Himalaya during the Early Paleozoic has been a subject of enduring debate within the scientific community. Newly discovered bimodal intrusive rocks from comprehensive field geological investigation in the central mountain range were subjected to petrology, zircon U-Pb geochronology, zircon Hf isotopes and whole-rock geochemistry analyses. The Palie bimodal intrusive rocks, comprising amphibolite and granitic gneiss, were formed at ∼489 Ma. The amphibolite exhibits geochemical characteristics consistent with N-MORB, while the granitic gneiss is classified as high potassium calc-alkaline peraluminous S-type granite. Both igneous rocks exhibit negative zircon εHf(t) values and display ancient TDMC ages. In conjunction with regional geological survey findings, it can be inferred that the formation of the Palie bimodal intrusive rocks occurred within a post-collision extensional tectonic setting. The amphibolite genesis involved partial melting of an enriched lithospheric mantle with some crustal assimilation, whereas the origin of the granitic gneiss can be attributed to partial melting of pre-existing felsic crust. Our data indicate that during the Early Paleozoic, the Himalaya underwent a transition from a pan-African collisional setting to post-collisional extensional tectonics.

喜马拉雅早古生代的构造环境一直是科学界争论不休的话题。通过野外综合地质调查,对中部山脉新发现的双峰侵入岩进行了岩石学、锆石U-Pb年代学、锆石Hf同位素和全岩地球化学分析。Palie双峰侵入岩形成于~ 489 Ma,由角闪岩和花岗质片麻岩组成。角闪岩地球化学特征与N-MORB相一致,花岗质片麻岩属于高钾钙碱性过铝s型花岗岩。两种火成岩的锆石εHf(t)值均为负,表现为古TDMC时代。结合区域地质调查结果,可以推断出Palie双峰侵入岩的形成是在碰撞后伸展构造背景下形成的。角闪岩的成因是岩石圈地幔的部分熔融和地壳的同化作用,而花岗质片麻岩的成因则是先前长英质地壳的部分熔融作用。研究结果表明,喜马拉雅早古生代经历了从泛非碰撞环境到碰撞后伸展构造的转变。
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引用次数: 0
Lithostratigraphy and Microfacies Analysis of the Govanda Formation (Early–Middle Miocene) in the Sherwan Mazin Area, Kurdistan Region, NE Iraq 伊拉克东北部库尔德斯坦地区Sherwan Mazin地区古旺达组(早-中中新世)岩石地层及微相分析
IF 3.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-30 DOI: 10.1111/1755-6724.15314
Arkan O. SHARAZWRI, Bzhar A. DELIZY

The Govanda Formation was deposited during the Miocene in the intermontane areas between the Zagros suture and imbricate zones. The Govanda Formation was studied in the Sherwan Mazin area within Mergasor district, Erbil Governorate to identify the lithostratigraphy and microfacies analysis in order to determine the depositional environment of the formation. The formation in the studied section is 116 m thick and mainly consists of reddish-brown, hard, thick-bedded, chert-bearing conglomerate, pinkish shale and yellowish-grey, thick-bedded, detrital, fossiliferous limestone. The formation is unconformably underlain by the Upper Cretaceous Tanjero Formation and conformably overlain by the Merga Red Beds series. Four different lithostratigraphic units were identified, based on field observation and petrographic analysis, including a basal conglomerate unit (A), a shale unit (B), a well-bedded limestone unit (C) and a thick and massively-bedded limestone unit (D). The presence of a thick conglomerate bed at the base of the formation indicates a large unconformity that lasted nearly 40 million years. Based on detailed microfacies analysis of carbonate rocks, five main microfacies and 15 submicrofacies are recognized. The main microfacies types include mudstone, wackestone, packstone, grainstone and boundstone microfacies. Based on the microfacies types the depositional environment are defined as open lagoon, reef, fore-reef and back-reef environments of normal to saline, nutrient rich water.

戈万达组沉积于中新世,位于扎格罗斯缝合带与叠瓦带之间的山间地带。对埃尔比勒省Mergasor地区Sherwan Mazin地区的Govanda组进行了岩石地层识别和微相分析,以确定该组的沉积环境。研究剖面地层厚度为116 m,主要由红棕色、坚硬、厚层状、含燧石质砾岩、粉红色页岩和黄灰色、厚层状、碎屑、化石灰岩组成。该组为上白垩统Tanjero组不整合下覆,Merga红层系列整合上覆。根据野外观测和岩石学分析,确定了4个不同的岩石地层单元,包括基底砾岩单元(a)、页岩单元(B)、层状良好的灰岩单元(C)和厚层状块状灰岩单元(D)。地层底部厚砾岩层的存在表明一个持续了近4000万年的大不整合。在详细分析碳酸盐岩微相的基础上,识别出5个主要微相和15个亚微相。主要微相类型有泥岩微相、微相、砾岩微相、颗粒岩微相和边界岩微相。根据沉积微相类型,将沉积环境定义为正常至富盐水体的开放泻湖、礁、礁前和礁后环境。
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引用次数: 0
Sequence Stratigraphic Division of the Devonian Liujiang Formation Dominated by Silicalites in the Northeastern Part of the Dianqiangui Basin, South China 滇黔桂盆地东北部以硅质岩为主的泥盆系柳江组层序地层划分
IF 3.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-30 DOI: 10.1111/1755-6724.15309
Yingjie ZHANG, Wenpan CEN, Yinglun QIN, Chenglong MA, Jiyu CHEN, Wenfang HUANG, Long WANG

Silicalites are extensively developed in the Liujiang Formation (Fm.) of the Frasnian in the Dianqiangui Basin and are often associated with carbonaceous shales. This stratigraphic combination represents a special sequence stratigraphy formed in special deep-water environments, which not only gives the shales unusual spatio-temporal distribution features, but also induces the shales in the Liujiang Fm. to frequently be rich in organic matter (OM). This study summarises the special deep-water sedimentary succession of the Liujiang Fm., which is mainly distributed around synsedimentary faults, as well as establishing the sequence stratigraphic frameworks of the Liujiang Fm. in the west–east and southwest–northeast directions. Under the sequence stratigraphic frameworks, the spatio-temporal distribution features of the organic-rich shales of the Liujiang Fm. and the regional variations of the Liujiang Fm. were investigated. In addition, the rock components and OM occurrence states of the organic-rich shales were also observed and described in detail under the microscope. The results show that the organic-rich shales were formed temporally primarily during the third-order sea-level falling stage, developed spatially mainly on the east and west sides of the study area, as well as that the OM accumulation is closely related to tentaculitoids and seems to be influenced by a ‘biological pump’.

硅质岩广泛发育于滇前桂盆地弗拉斯系柳江组,常与碳质页岩伴生。这种地层组合代表了在特殊深水环境下形成的特殊层序地层,不仅赋予了页岩不同寻常的时空分布特征,而且还诱发了柳江组页岩的形成。通常富含有机物(OM)。总结了柳江组特殊的深水沉积演替。主要分布在同沉积断裂周围,建立了柳江组层序地层格架。在西-东和西南-东北方向。在层序地层格架下,研究了柳江组富有机质页岩的时空分布特征。柳江Fm的区域差异。被调查。此外,在显微镜下对富有机质页岩的岩石组分和有机质赋存状态进行了详细的观察和描述。结果表明,富有机质页岩在时间上主要形成于海平面下降三级阶段,空间上主要发育于研究区东西两侧,有机质富集与触手状体密切相关,可能受“生物泵”的影响。
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引用次数: 0
Seasonal Evolution of Eocene Saline Lakes in Eastern China: A Case Study of ‘Bamboo-like’ Rock Salt in the Shizhai Depression, Northern Jiangsu Province 中国东部始新世盐湖的季节演化——以苏北石寨凹陷“竹状”岩盐为例
IF 3.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-30 DOI: 10.1111/1755-6724.15298
Yang XU, Chenglin LIU, Sibo YANG, Yangtong CAO, Longtao WEN, Ruiqin LI

The phenomenon of ‘bamboo-like’ thin interlayers developed in rock salt is one of the most prominent features of Paleogene salt-bearing strata in eastern China, where centimeter-thick rock salts appear separately, forming rhythmic units. At present, detailed analyses of these rhythms of rock salt are still limited, which directly affects the achievement of comprehensive and in-depth understanding of the developmental laws pertaining to this kind of saline lake. Therefore, we selected the typical rhythmic ‘bamboo-like’ rock salts of the Shizhai Depression in Jiangsu Province as the research subject. Through careful observation of rock salts in hand samples and detailed petrographic and mineralogical analyses, we analyzed the hydrogen and oxygen isotopic compositions, homogenization temperatures and chemical compositions of individual fluid inclusions in halite crystals. Early-stage rhythmic deposition was a product of continental saline lake evolution in winter or spring, late-stage rhythmic deposition being the product of evolution in the summer. The seasonal evolution of the halite sequences was determined and two brine enrichment events were identified. In addition, the quiet saline lake environment with concentrated brine represented by rock salt was more likely to precipitate potassium. This study provides a new reference for the evolution of both Paleogene climate and saline lakes in eastern China.

岩盐中发育“竹状”薄夹层现象是中国东部古近系含盐地层最突出的特征之一,其中厘米厚的岩盐单独出现,形成韵律单元。目前对岩盐发育规律的详细分析还很有限,这直接影响了对该类盐湖发育规律的全面深入认识。因此,选取江苏石寨坳陷典型的节理“竹状”岩盐作为研究对象。通过对岩盐样品的仔细观察和详细的岩石学和矿物学分析,我们分析了岩盐晶体中单个流体包裹体的氢、氧同位素组成、均一温度和化学成分。早期节律性沉积是冬季或春季陆相盐湖演化的产物,晚期节律性沉积是夏季演化的产物。确定了岩盐层序的季节演化,确定了两次卤水富集事件。以岩盐为代表的浓盐水安静盐湖环境更容易析出钾。该研究为中国东部古近系气候和盐湖演化提供了新的参考。
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引用次数: 0
Miocene Pb-Zn Mineralization in the Eastern Gangdese Metallogenic Belt: Evidence from in situ Rb-Sr Dating of Mica and Trace Element Geochemistry of Sphalerite 冈底斯成矿带东部中新世铅锌成矿作用:云母原位Rb-Sr定年及闪锌矿微量元素地球化学证据
IF 3.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-30 DOI: 10.1111/1755-6724.15310
Xiaoyan ZHAO, Zhusen YANG, Chang LIU, Yanrui DONG, Haiyan SHI

Four Pb-Zn deposits, namely Bangpu (BP), Digei (DG), Nabuding (NB) and Cuoga (CG), are located within a 20 km distance of each other in the Gangdese porphyry copper belt (GPCB). The age and nature of the Pb-Zn mineralization, especially its relationship to magmatism, remain uncertain. In order to address this issue, mica from the four deposits was selected for in situ Rb-Sr dating, with sphalerite additionally being selected for in situ trace element analysis. Detailed geological research has revealed that the BP and NB deposits are primarily skarn-type Pb-Zn mineralization, while DG and CG are associated with magmatic hydrothermal breccia and are characterized by banded-type mineralization. The Rb-Sr isochron ages of syn-mineralization muscovite at the BP and CG deposits are 11 ± 6 Ma and 19.7 ± 0.7 Ma respectively. Fe, Cd, In, Mn and Sn occur as lattice substitutions in sphalerite from the four deposits. Cu exists as microinclusions in BP, but occurs isomorphically in the DG, NB and CG deposits. The formation temperatures of the four deposits, as calculated from sphalerite geothermometry, range from approximately 200°C to 300°C, indicating that they belong to medium temperature deposits. BP and NB are classified as skarn Pb-Zn deposits, while DG and CG are categorized as hydrothermal filled Pb-Zn deposits. These results suggest that, in addition to porphyry Cu mineralization, the GPCB also contains significant Miocene Pb-Zn mineralization.

在冈底斯斑岩铜带(GPCB)中,邦堡(BP)、迪盖(DG)、那定(NB)和果嘎(CG) 4个铅锌矿床彼此相距不到20公里。铅锌矿化的年龄和性质,特别是与岩浆作用的关系仍不确定。为了解决这一问题,从四个矿床中选择云母进行原位Rb-Sr测年,并选择闪锌矿进行原位微量元素分析。详细的地质研究表明,BP和NB矿床主要为矽卡岩型铅锌矿化,而DG和CG矿床与岩浆热液角砾岩伴生,具有带状矿化特征。BP和CG矿床同成矿白云母的Rb-Sr等时线年龄分别为11±6 Ma和19.7±0.7 Ma。Fe, Cd, In, Mn和Sn以晶格取代形式出现在四个矿床的闪锌矿中。铜在BP中以微包裹体形式存在,而在DG、NB和CG矿床中以同构形式存在。根据闪锌矿地热测量结果,4个矿床的形成温度在200 ~ 300℃之间,属于中温矿床。BP和NB为矽卡岩型铅锌矿床,DG和CG为热液充填型铅锌矿床。这些结果表明,GPCB除斑岩型铜矿化外,还存在明显的中新世铅锌成矿作用。
{"title":"Miocene Pb-Zn Mineralization in the Eastern Gangdese Metallogenic Belt: Evidence from in situ Rb-Sr Dating of Mica and Trace Element Geochemistry of Sphalerite","authors":"Xiaoyan ZHAO,&nbsp;Zhusen YANG,&nbsp;Chang LIU,&nbsp;Yanrui DONG,&nbsp;Haiyan SHI","doi":"10.1111/1755-6724.15310","DOIUrl":"https://doi.org/10.1111/1755-6724.15310","url":null,"abstract":"<p>Four Pb-Zn deposits, namely Bangpu (BP), Digei (DG), Nabuding (NB) and Cuoga (CG), are located within a 20 km distance of each other in the Gangdese porphyry copper belt (GPCB). The age and nature of the Pb-Zn mineralization, especially its relationship to magmatism, remain uncertain. In order to address this issue, mica from the four deposits was selected for in situ Rb-Sr dating, with sphalerite additionally being selected for in situ trace element analysis. Detailed geological research has revealed that the BP and NB deposits are primarily skarn-type Pb-Zn mineralization, while DG and CG are associated with magmatic hydrothermal breccia and are characterized by banded-type mineralization. The Rb-Sr isochron ages of syn-mineralization muscovite at the BP and CG deposits are 11 ± 6 Ma and 19.7 ± 0.7 Ma respectively. Fe, Cd, In, Mn and Sn occur as lattice substitutions in sphalerite from the four deposits. Cu exists as microinclusions in BP, but occurs isomorphically in the DG, NB and CG deposits. The formation temperatures of the four deposits, as calculated from sphalerite geothermometry, range from approximately 200°C to 300°C, indicating that they belong to medium temperature deposits. BP and NB are classified as skarn Pb-Zn deposits, while DG and CG are categorized as hydrothermal filled Pb-Zn deposits. These results suggest that, in addition to porphyry Cu mineralization, the GPCB also contains significant Miocene Pb-Zn mineralization.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"99 3","pages":"806-821"},"PeriodicalIF":3.5,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Acta Geologica Sinica ‐ English Edition
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