Wei LI, Juxing TANG, Na GUO, Xinghai LANG, Shiwei SONG, Zhongru WU, Linlin PENG, Xiang FANG, Binfeng CHEN, Dunmei LIAN, Jie LU
The Tieshanlong ore field is an important part of the Nanling Range, which is famous worldwide for its W-Sn mineralization. Notably, the mineralization age of the Tieshanlong ore field is not well constrained, and our field investigation reveals that granitic emplacement occurred at different stages. However, previous studies have not distinguished these multiple stages of magmatism. The Tieshanlong granite complex is closely related to the Huangsha quartz vein-type W-Sn deposit and Tongling skarn-type Cu-W-Sn deposit in this field. Through field investigations and isotopic age analyses, this work studies the relationship between multistage magmatic activity and mineralization in the Tieshanlong ore field. LA-ICP-MS zircon U-Pb isotope analyses revealed that the first- and second-staged granites formed at 154.2 ± 0.6 Ma (MSDW = 1.4) and 151.2 ± 0.4 Ma (MSDW = 1.5), with zircon εHf(t) values ranging from -13.1 to -10.5 and from -14.7 to -11.1, respectively. These data suggest that the Tieshanlong granite complex was derived from the partial melting of ancient crustal material. LA-ICP-MS U-Pb dating of wolframite and cassiterite reveals that W-Sn mineralization occurred at 160–150 Ma, which agrees well with the U-Pb dating results of the second-staged granite within analytical errors. The magmatic activity in this ore field can be divided into three stages: 175–154 Ma, 154–150 Ma and 150–145 Ma. The quartz vein- and skarn-type W-Sn mineralization is closely related to second-staged fine-grained two-mica granite, and formed earlier than skarn-type Cu- mineralization. This study establishes a metallogenic model for the Tieshanlong ore field, and this model has important practical significance for identifying concealed W-Sn(-Cu) deposits around other granitic complexes in the Nanling Range.
{"title":"Robust Timing Constraints for Granitic Magmatism and Hydrothermal Mineralization in the Tieshanlong W-Sn Ore Field, Eastern Nanling Range, South China","authors":"Wei LI, Juxing TANG, Na GUO, Xinghai LANG, Shiwei SONG, Zhongru WU, Linlin PENG, Xiang FANG, Binfeng CHEN, Dunmei LIAN, Jie LU","doi":"10.1111/1755-6724.15212","DOIUrl":"https://doi.org/10.1111/1755-6724.15212","url":null,"abstract":"<p>The Tieshanlong ore field is an important part of the Nanling Range, which is famous worldwide for its W-Sn mineralization. Notably, the mineralization age of the Tieshanlong ore field is not well constrained, and our field investigation reveals that granitic emplacement occurred at different stages. However, previous studies have not distinguished these multiple stages of magmatism. The Tieshanlong granite complex is closely related to the Huangsha quartz vein-type W-Sn deposit and Tongling skarn-type Cu-W-Sn deposit in this field. Through field investigations and isotopic age analyses, this work studies the relationship between multistage magmatic activity and mineralization in the Tieshanlong ore field. LA-ICP-MS zircon U-Pb isotope analyses revealed that the first- and second-staged granites formed at 154.2 ± 0.6 Ma (MSDW = 1.4) and 151.2 ± 0.4 Ma (MSDW = 1.5), with zircon <i>ε</i><sub>Hf</sub>(<i>t</i>) values ranging from -13.1 to -10.5 and from -14.7 to -11.1, respectively. These data suggest that the Tieshanlong granite complex was derived from the partial melting of ancient crustal material. LA-ICP-MS U-Pb dating of wolframite and cassiterite reveals that W-Sn mineralization occurred at 160–150 Ma, which agrees well with the U-Pb dating results of the second-staged granite within analytical errors. The magmatic activity in this ore field can be divided into three stages: 175–154 Ma, 154–150 Ma and 150–145 Ma. The quartz vein- and skarn-type W-Sn mineralization is closely related to second-staged fine-grained two-mica granite, and formed earlier than skarn-type Cu- mineralization. This study establishes a metallogenic model for the Tieshanlong ore field, and this model has important practical significance for identifying concealed W-Sn(-Cu) deposits around other granitic complexes in the Nanling Range.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 5","pages":"1255-1269"},"PeriodicalIF":3.5,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142525467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
As important geological data, a geological report contains rich expert and geological knowledge, but the challenge facing current research into geological knowledge extraction and mining is how to render accurate understanding of geological reports guided by domain knowledge. While generic named entity recognition models/tools can be utilized for the processing of geoscience reports/documents, their effectiveness is hampered by a dearth of domain-specific knowledge, which in turn leads to a pronounced decline in recognition accuracy. This study summarizes six types of typical geological entities, with reference to the ontological system of geological domains and builds a high quality corpus for the task of geological named entity recognition (GNER). In addition, GeoWoBERT-advBGP (Geological Word-base BERT-adversarial training Bi-directional Long Short-Term Memory Global Pointer) is proposed to address the issues of ambiguity, diversity and nested entities for the geological entities. The model first uses the fine-tuned word granularity-based pre-training model GeoWoBERT (Geological Word-base BERT) and combines the text features that are extracted using the BiLSTM (Bi-directional Long Short-Term Memory), followed by an adversarial training algorithm to improve the robustness of the model and enhance its resistance to interference, the decoding finally being performed using a global association pointer algorithm. The experimental results show that the proposed model for the constructed dataset achieves high performance and is capable of mining the rich geological information.
地质报告作为重要的地质数据,蕴含着丰富的专家知识和地质知识,但如何在领域知识的指导下准确理解地质报告,是当前地质知识提取和挖掘研究面临的挑战。虽然通用命名实体识别模型/工具可用于地质科学报告/文档的处理,但由于缺乏特定领域的知识,其有效性受到影响,进而导致识别准确率明显下降。本研究参照地质领域的本体系统,总结了六类典型的地质实体,并为地质命名实体识别(GNER)任务建立了高质量的语料库。此外,针对地质实体的模糊性、多样性和嵌套实体等问题,提出了 GeoWoBERT-advBGP(Geological Word-base BERT-adversarial training Bi-directional Long Short-Term Memory Global Pointer)模型。该模型首先使用基于词粒度的微调预训练模型 GeoWoBERT(地质词库 BERT),并结合使用 BiLSTM(双向长短期记忆)提取的文本特征,然后使用对抗训练算法提高模型的鲁棒性并增强其抗干扰能力,最后使用全局关联指针算法进行解码。实验结果表明,针对所建数据集提出的模型性能很高,能够挖掘出丰富的地质信息。
{"title":"GeoNER: Geological Named Entity Recognition with Enriched Domain Pre-Training Model and Adversarial Training","authors":"Kai MA, Xinxin HU, Miao TIAN, Yongjian TAN, Shuai ZHENG, Liufeng TAO, Qinjun QIU","doi":"10.1111/1755-6724.15213","DOIUrl":"https://doi.org/10.1111/1755-6724.15213","url":null,"abstract":"<p>As important geological data, a geological report contains rich expert and geological knowledge, but the challenge facing current research into geological knowledge extraction and mining is how to render accurate understanding of geological reports guided by domain knowledge. While generic named entity recognition models/tools can be utilized for the processing of geoscience reports/documents, their effectiveness is hampered by a dearth of domain-specific knowledge, which in turn leads to a pronounced decline in recognition accuracy. This study summarizes six types of typical geological entities, with reference to the ontological system of geological domains and builds a high quality corpus for the task of geological named entity recognition (GNER). In addition, GeoWoBERT-advBGP (Geological Word-base BERT-adversarial training Bi-directional Long Short-Term Memory Global Pointer) is proposed to address the issues of ambiguity, diversity and nested entities for the geological entities. The model first uses the fine-tuned word granularity-based pre-training model GeoWoBERT (Geological Word-base BERT) and combines the text features that are extracted using the BiLSTM (Bi-directional Long Short-Term Memory), followed by an adversarial training algorithm to improve the robustness of the model and enhance its resistance to interference, the decoding finally being performed using a global association pointer algorithm. The experimental results show that the proposed model for the constructed dataset achieves high performance and is capable of mining the rich geological information.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 5","pages":"1404-1417"},"PeriodicalIF":3.5,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142525614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kai LIU, Huimin DAI, Yunhong SONG, Shuai LIANG, Zhongfang YANG
The understanding of the spatial distribution of soil organic carbon (SOC) and its influencing factors is crucial for comprehending the global carbon cycle. However, the impact of soil geochemical and climatic conditions on SOC remains limited, particularly in dryland farming areas. In this study, we aimed to enhance the understanding of the factors influencing the distribution of SOC in the drylands of the Songliao Plain, Northeast China. A dataset comprising 35,188 measured soil samples was used to map the SOC distribution in the region. Multiple linear regression (MLR) and random forest models (RFM) were employed to assess the importance of driving indicators for SOC. We also carried out partial correlation and path analyses to further investigate the relationship between climate and geochemistry. The SOC content in dryland soils of the Songliao Plain ranged from 0.05% to 11.63%, with a mean value of 1.47% ± 0.90%. There was a notable increasing trend in SOC content from the southwest to the northeast regions. The results of MLR and RFM revealed that temperature was the most critical factor, demonstrating a significant negative correlation with SOC content. Additionally, iron oxide was the most important soil geochemical indicator affecting SOC variability. Our research further suggested that climate may exert an indirect influence on SOC concentrations through its effect on geochemical properties of soil. These insights highlight the importance of considering both the direct and indirect impact of climate in predicting the SOC under future climate change.
{"title":"Climate and Soil Geochemistry Influence the Soil Organic Carbon Content in Drylands of the Songliao Plain, Northeast China","authors":"Kai LIU, Huimin DAI, Yunhong SONG, Shuai LIANG, Zhongfang YANG","doi":"10.1111/1755-6724.15211","DOIUrl":"https://doi.org/10.1111/1755-6724.15211","url":null,"abstract":"<p>The understanding of the spatial distribution of soil organic carbon (SOC) and its influencing factors is crucial for comprehending the global carbon cycle. However, the impact of soil geochemical and climatic conditions on SOC remains limited, particularly in dryland farming areas. In this study, we aimed to enhance the understanding of the factors influencing the distribution of SOC in the drylands of the Songliao Plain, Northeast China. A dataset comprising 35,188 measured soil samples was used to map the SOC distribution in the region. Multiple linear regression (MLR) and random forest models (RFM) were employed to assess the importance of driving indicators for SOC. We also carried out partial correlation and path analyses to further investigate the relationship between climate and geochemistry. The SOC content in dryland soils of the Songliao Plain ranged from 0.05% to 11.63%, with a mean value of 1.47% ± 0.90%. There was a notable increasing trend in SOC content from the southwest to the northeast regions. The results of MLR and RFM revealed that temperature was the most critical factor, demonstrating a significant negative correlation with SOC content. Additionally, iron oxide was the most important soil geochemical indicator affecting SOC variability. Our research further suggested that climate may exert an indirect influence on SOC concentrations through its effect on geochemical properties of soil. These insights highlight the importance of considering both the direct and indirect impact of climate in predicting the SOC under future climate change.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 5","pages":"1394-1403"},"PeriodicalIF":3.5,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/1755-6724.15211","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142525359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Indicating the tectonic features of the Hanshan–Wuwei basin can reconstruct the framework of the basins formed in Mesozoic and further understand the Mesozoic tectonic evolution of the South China Block. Studies on surface structure, regional stress field and deep geophysical characteristics of the Mesozoic Hanshan–Wuwei basin in Lower Yangtze region were carried out. NE–NNE trending folds and faults developed in the northern margin of the basins. The reconstruction of tectonic stress fields indicates four stress stages dominating the basins' evolution including NW–SE compression, N–S compression, NW–SE extension and NWW–SEE compression. 2D seismic profiles reveal coexistence of thrust, strike-slip and normal faults in the basin. Combined with regional geological studies, the geodynamic processes for the formation of the Hanshan–Wuwei basin can be divided into five stages: 1) During the Late Triassic, EW trending foreland basin was formed by N–S compression; 2) From Mid-Jurassic to Late Jurassic, continuous compression strengthened the foreland deformation and formed thrust nappes. In this stage, the integrated foreland basin was compartmentalized or fragmented, and transferred to the broken foreland basin; 3) NE-trending sinistral strike-slip movement at the beginning of the Early Cretaceous; 4) Regional extension resulted in normal faults and rift basins developing in the Late Cretaceous; 5) The NWW–SEE compression at the end of the Late Cretaceous caused NW sinistral strike-slip faults to form, which partly transformed the rift basin.
{"title":"Surface and Deep Structure of the Hanshan–Wuwei Basins in the Lower Yangtze Region: Implications for Mesozoic Tectonic Evolution of the South China Block","authors":"Tianxiang KAN, Longming LI, Hongjun ZHENG, Jiahao LI, Xilin ZHAO, Mo CHEN","doi":"10.1111/1755-6724.15210","DOIUrl":"https://doi.org/10.1111/1755-6724.15210","url":null,"abstract":"<p>Indicating the tectonic features of the Hanshan–Wuwei basin can reconstruct the framework of the basins formed in Mesozoic and further understand the Mesozoic tectonic evolution of the South China Block. Studies on surface structure, regional stress field and deep geophysical characteristics of the Mesozoic Hanshan–Wuwei basin in Lower Yangtze region were carried out. NE–NNE trending folds and faults developed in the northern margin of the basins. The reconstruction of tectonic stress fields indicates four stress stages dominating the basins' evolution including NW–SE compression, N–S compression, NW–SE extension and NWW–SEE compression. 2D seismic profiles reveal coexistence of thrust, strike-slip and normal faults in the basin. Combined with regional geological studies, the geodynamic processes for the formation of the Hanshan–Wuwei basin can be divided into five stages: 1) During the Late Triassic, EW trending foreland basin was formed by N–S compression; 2) From Mid-Jurassic to Late Jurassic, continuous compression strengthened the foreland deformation and formed thrust nappes. In this stage, the integrated foreland basin was compartmentalized or fragmented, and transferred to the broken foreland basin; 3) NE-trending sinistral strike-slip movement at the beginning of the Early Cretaceous; 4) Regional extension resulted in normal faults and rift basins developing in the Late Cretaceous; 5) The NWW–SEE compression at the end of the Late Cretaceous caused NW sinistral strike-slip faults to form, which partly transformed the rift basin.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 5","pages":"1154-1170"},"PeriodicalIF":3.5,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142541014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Identifying deformational mechanisms and associated structures at various scales, ranging from regional-scale structures to microscopic fabric, is crucial for the assessment of tectonic development. Thirty-three samples were taken from the Qazzaz metamorphic core complex to estimate the finite strain for felsic and mafic minerals. These samples included gneisses rocks, monzogranite, and metavolcano–sedimentary rocks for both the Thalbah and Bayda groups. Using the Rf/j and Fry methods, the axial ratios (XZ) range about 2.20 to 7.10 and 1.90 to 9.10, respectively. For various rock units, the strain measurements show moderate to highly deformation. Most of the observed samples show shallow WNW dipping along a N to WNW trend of finite strain (X). The short axes (Z) based to be subvertical foliation related with a subhorizontal foliation. The results demonstrate that contacts generated at semi-brittle to ductile deformation and that the strain of magnitude has the same value for different lithologic units. It concluded that nappe generation in orogens results from pure shear deformation.
{"title":"Structural Analysis for Qazzaz Metamorphic Core Complex, Northwestern Arabian Shield, Saudi Arabia","authors":"Mansour H. AL-HASHIM, Osama M.K. KASSEM","doi":"10.1111/1755-6724.15208","DOIUrl":"https://doi.org/10.1111/1755-6724.15208","url":null,"abstract":"<p>Identifying deformational mechanisms and associated structures at various scales, ranging from regional-scale structures to microscopic fabric, is crucial for the assessment of tectonic development. Thirty-three samples were taken from the Qazzaz metamorphic core complex to estimate the finite strain for felsic and mafic minerals. These samples included gneisses rocks, monzogranite, and metavolcano–sedimentary rocks for both the Thalbah and Bayda groups. Using the Rf/j and Fry methods, the axial ratios (XZ) range about 2.20 to 7.10 and 1.90 to 9.10, respectively. For various rock units, the strain measurements show moderate to highly deformation. Most of the observed samples show shallow WNW dipping along a N to WNW trend of finite strain (X). The short axes (Z) based to be subvertical foliation related with a subhorizontal foliation. The results demonstrate that contacts generated at semi-brittle to ductile deformation and that the strain of magnitude has the same value for different lithologic units. It concluded that nappe generation in orogens results from pure shear deformation.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 5","pages":"1187-1201"},"PeriodicalIF":3.5,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142541086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The Tarim Craton is an ancient Precambrian continental block, and detailed knowledge of its thermo-tectonic history is crucial for understanding the early history of continental evolution. Abundant layered mafic rocks, which have commonly been regarded as basalts, occur within the Ediacaran Sugetbrak Formation (Fm.) in the Aksu region of the northwestern Tarim Craton. Clear intrusive features have now been discovered, including mafic rocks truncating Ediacaran sedimentary layers, exhibiting an intrusion-baked margin where they interact with both the overlying and bottom wall rocks, and displaying a fine-grained transition zone from their interior to their margins. The new findings demonstrate that these mafic rocks within the Aksu Ediacaran strata were not erupted basalts but instead are intrusive diabase dykes. Therefore, these mafic rocks cannot be used to constrain the timing of the Sugetbrak Fm. in the Aksu area, nor as marker layers for regional stratigraphic correlation. Furthermore, the Ediacaran thermo-tectonic evolution in this region, deduced from the assumption that the mafic rocks are lavas, needs to be revised.
{"title":"Occurrence of Mafic Rocks within Ediacaran Strata in the Aksu Region, NW Tarim Craton, and its Geological Implications","authors":"Hongzhe XIE, Xiangkun ZHU, Xun WANG, Yuan HE, Weibing SHEN","doi":"10.1111/1755-6724.15214","DOIUrl":"https://doi.org/10.1111/1755-6724.15214","url":null,"abstract":"<p>The Tarim Craton is an ancient Precambrian continental block, and detailed knowledge of its thermo-tectonic history is crucial for understanding the early history of continental evolution. Abundant layered mafic rocks, which have commonly been regarded as basalts, occur within the Ediacaran Sugetbrak Formation (Fm.) in the Aksu region of the northwestern Tarim Craton. Clear intrusive features have now been discovered, including mafic rocks truncating Ediacaran sedimentary layers, exhibiting an intrusion-baked margin where they interact with both the overlying and bottom wall rocks, and displaying a fine-grained transition zone from their interior to their margins. The new findings demonstrate that these mafic rocks within the Aksu Ediacaran strata were not erupted basalts but instead are intrusive diabase dykes. Therefore, these mafic rocks cannot be used to constrain the timing of the Sugetbrak Fm. in the Aksu area, nor as marker layers for regional stratigraphic correlation. Furthermore, the Ediacaran thermo-tectonic evolution in this region, deduced from the assumption that the mafic rocks are lavas, needs to be revised.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 5","pages":"1244-1254"},"PeriodicalIF":3.5,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142525464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jing BAI, Xingyou XU, Weibin LIU, Wenzhi ZHAO, Hang JIANG
The Upper Cretaceous Qingshankou Formation black shales, deposited in the late Turonian (LTB shales), are the main source rocks of the Songliao Basin. The origins of organic matter enrichment of the shales is a contentious subject fuelling many ongoing debates. This study investigates the genesis of the organic matter-rich shale by using molecular geochemistry. The LTB shales can be divided into three sections. The Section I shales were deposited in saline, stratified and anoxic water conditions, which are related to seawater incursion events. At least three episodic and periodic seawater incursion events were recognized during Section I shale deposition. The Section II shales deposited in brackish to fresh and deep lake-level conditions with high primary productivity, which are related to lake-level transgression. The Section III shales were deposited under fresh and slightly oxidized water conditions, which are related to lake-level regression. Two organic matter enrichment models for the LTB shales are identified, that is, the seawater incursion model and the maximum lake-level transgression sedimentation model, which act on different shale sections, both playing significant roles in the enrichment of organic matter.
{"title":"Paleoenvironmental Evolution and Organic Matter Enrichment Genesis of the Late Turonian Black Shale in the Southern Songliao Basin, NE China","authors":"Jing BAI, Xingyou XU, Weibin LIU, Wenzhi ZHAO, Hang JIANG","doi":"10.1111/1755-6724.15209","DOIUrl":"https://doi.org/10.1111/1755-6724.15209","url":null,"abstract":"<p>The Upper Cretaceous Qingshankou Formation black shales, deposited in the late Turonian (LTB shales), are the main source rocks of the Songliao Basin. The origins of organic matter enrichment of the shales is a contentious subject fuelling many ongoing debates. This study investigates the genesis of the organic matter-rich shale by using molecular geochemistry. The LTB shales can be divided into three sections. The Section I shales were deposited in saline, stratified and anoxic water conditions, which are related to seawater incursion events. At least three episodic and periodic seawater incursion events were recognized during Section I shale deposition. The Section II shales deposited in brackish to fresh and deep lake-level conditions with high primary productivity, which are related to lake-level transgression. The Section III shales were deposited under fresh and slightly oxidized water conditions, which are related to lake-level regression. Two organic matter enrichment models for the LTB shales are identified, that is, the seawater incursion model and the maximum lake-level transgression sedimentation model, which act on different shale sections, both playing significant roles in the enrichment of organic matter.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 5","pages":"1338-1358"},"PeriodicalIF":3.5,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142525356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The Jenkyns Event, more widely known as the Toarcian Oceanic Anoxic Event (T-OAE), is marked by globally distributed negative carbon-isotope excursions, widespread oxygen depletion, and large-scale organic carbon burial, which indicate major climate/environmental perturbations in Earth's surface systems during the Early Jurassic. Although extensive research has been conducted in European continental settings, particularly in the western peri-Tethys regions, the impacts of this event beyond Europe remains largely unexplored. Here, a multiapproach study including investigations into the spore-pollen assemblages, pyrite framboids, clay minerals, total organic carbon (TOC) levels, and organic carbon isotope (δ13Corg) levels in a lacustrine borehole section (MED1) from the Yin'gen–Ejinaqi Basin, North China, provides evidence of the occurrence of the Jenkyns Event and its extensive sedimentary responses in the eastern Tethys terrestrial systems. Two distinct spore-pollen assemblages have been identified in MED1 (drilling depth: 982.4 m to 1267.5 m), with the Cycadopites–Protopinus–Osmundacidites assemblage in the lower part (1267.5 m to 1132.9 m) indicating a middle Early Jurassic age and the Classopollis assemblage in the upper part (1132.9 m to 985.7 m) suggesting a Toarcian age. Framboidal pyrite data suggest more anoxic conditions during the deposition of black mudstone and shale intercalations in the lower part of the Classopollis assemblage (1132.9 m to 1066.9 m), which combined with organic carbon enrichment and negative δ13Corg excursions, are considered the paleoenvironmental response to the Jenkyns Event in the study area. Furthermore, the evolution of vegetation groups changed from plant groups characterized by bisaccate and cycad pollen, as well as fern spores, to vegetation groups represented by Cheirolepidiaceae pollen across the Jenkyns Event, as evidenced by spore-pollen data, together with the clay mineral assemblage change characterized by a notable increase in illite at the expense of kaolinite, suggests that while a subtropical-temperate climate persisted, a change toward warmer and drier conditions most likely occurred in the early Toarcian in the study area. In contrast to the humidification evidenced in many coastal settings, this aridification trend in the Yin'gen–Ejinaqi Basin aligns with the conditions in many inland areas. It is hypothesized that the underlying cause of these divergent changes may be linked to certain patterns of spatially variable water availability on land, potentially driven by extremified hydrological conditions.
{"title":"Sedimentary Expressions of the Early Jurassic Jenkyns Event in an Inland Lacustrine System in the Yin'gen–Ejinaqi Basin, North China","authors":"Bing YANG, Guozhen XU, Guangji HUI, Yi WEI, Xinzhi ZHANG, Jinjun YI, Siyuan SUN, Sujiang ZHANG","doi":"10.1111/1755-6724.15186","DOIUrl":"https://doi.org/10.1111/1755-6724.15186","url":null,"abstract":"<p>The Jenkyns Event, more widely known as the Toarcian Oceanic Anoxic Event (T-OAE), is marked by globally distributed negative carbon-isotope excursions, widespread oxygen depletion, and large-scale organic carbon burial, which indicate major climate/environmental perturbations in Earth's surface systems during the Early Jurassic. Although extensive research has been conducted in European continental settings, particularly in the western peri-Tethys regions, the impacts of this event beyond Europe remains largely unexplored. Here, a multiapproach study including investigations into the spore-pollen assemblages, pyrite framboids, clay minerals, total organic carbon (TOC) levels, and organic carbon isotope (<i>δ</i><sup>13</sup>C<sub>org</sub>) levels in a lacustrine borehole section (MED1) from the Yin'gen–Ejinaqi Basin, North China, provides evidence of the occurrence of the Jenkyns Event and its extensive sedimentary responses in the eastern Tethys terrestrial systems. Two distinct spore-pollen assemblages have been identified in MED1 (drilling depth: 982.4 m to 1267.5 m), with the <i>Cycadopites</i>–<i>Protopinu</i>s–<i>Osmundacidites</i> assemblage in the lower part (1267.5 m to 1132.9 m) indicating a middle Early Jurassic age and the <i>Classopollis</i> assemblage in the upper part (1132.9 m to 985.7 m) suggesting a Toarcian age. Framboidal pyrite data suggest more anoxic conditions during the deposition of black mudstone and shale intercalations in the lower part of the <i>Classopollis</i> assemblage (1132.9 m to 1066.9 m), which combined with organic carbon enrichment and negative <i>δ</i><sup>13</sup>C<sub>org</sub> excursions, are considered the paleoenvironmental response to the Jenkyns Event in the study area. Furthermore, the evolution of vegetation groups changed from plant groups characterized by bisaccate and cycad pollen, as well as fern spores, to vegetation groups represented by Cheirolepidiaceae pollen across the Jenkyns Event, as evidenced by spore-pollen data, together with the clay mineral assemblage change characterized by a notable increase in illite at the expense of kaolinite, suggests that while a subtropical-temperate climate persisted, a change toward warmer and drier conditions most likely occurred in the early Toarcian in the study area. In contrast to the humidification evidenced in many coastal settings, this aridification trend in the Yin'gen–Ejinaqi Basin aligns with the conditions in many inland areas. It is hypothesized that the underlying cause of these divergent changes may be linked to certain patterns of spatially variable water availability on land, potentially driven by extremified hydrological conditions.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 5","pages":"1359-1375"},"PeriodicalIF":3.5,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142525358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The utilization of CO2-Enhanced Coal Bed Methane (CO2-ECBM) technology is pivotal in realizing the environmentally responsible and efficient exploitation of Coalbed Methane (CBM) energy resources. The optimization of carbon capture, utilization, and storage (CCUS) for carbon reduction mandates a nuanced understanding of the diverse geological attributes present in CBM reserves globally. Traditional estimations of CO2-ECBM's carbon sequestration potential have predominantly relied on rudimentary empirical models, notably those proposed by the United States Department of Energy (DOE), which overlook the intrinsic geological conditions and the physicochemical properties of subsurface fluids. Addressing these limitations, our study implements the advanced DR/Henry mixed adsorption model in tandem with the Peng-Robinson equation of state (PR-EOS). This approach meticulously identifies the critical parameters governing the mass exchange ratios between CO2 and CH4, pertinent to in-situ geological environments. Subsequently, we have formulated a comprehensive carbon sequestration potential assessment framework. This innovative model adheres to the mass conservation principles for individual CO2 and CH4 components, taking into account the specific surface and stratigraphic conditions prevalent. Employing this refined methodology, we evaluated the CO2-ECBM carbon sequestration potential of the 40 evaluation units of extensional, compressive, and cratonic continental coal bearing basins in China's three major temperature-pressure systems across different depth domains and coal ranks within 2000 m. Our findings reveal that the theoretical carbon sequestration capacity of China's continental coal-bearing basins is approximately 59.893 billion tons. Concurrently, the potential ECBM output stands at an estimated 4.92 trillion cubic meters, underscoring the substantial environmental and energy benefits inherent in harnessing CO2-ECBM technology effectively. The regional analysis revealed that North and Northwest China hold the highest sequestration and recovery potential, followed by the Northeast and Southern regions, respectively. Specific areas, including the eastern edge of the Ordos Basin and southern Junggar Basin, Qinshui, Huoxi, Xishan, and other areas in Shanxi, present promising future prospects for geological carbon storage in unrecoverable coal seams.
{"title":"Assessment of in-situ CO2 Sequestration Potential and Enhanced Coalbed Methane (ECBM) Production of Continental Coal-bearing Basins in China","authors":"Yaohua LI, Yang WANG, Caiqin BI, Qianyou WANG, Yu SHI, Yinbo XU, Yuan YUAN, Lihua TONG, Yue TANG, Yansheng SHAN, Weibin LIU","doi":"10.1111/1755-6724.15188","DOIUrl":"https://doi.org/10.1111/1755-6724.15188","url":null,"abstract":"<p>The utilization of CO<sub>2</sub>-Enhanced Coal Bed Methane (CO<sub>2</sub>-ECBM) technology is pivotal in realizing the environmentally responsible and efficient exploitation of Coalbed Methane (CBM) energy resources. The optimization of carbon capture, utilization, and storage (CCUS) for carbon reduction mandates a nuanced understanding of the diverse geological attributes present in CBM reserves globally. Traditional estimations of CO<sub>2</sub>-ECBM's carbon sequestration potential have predominantly relied on rudimentary empirical models, notably those proposed by the United States Department of Energy (DOE), which overlook the intrinsic geological conditions and the physicochemical properties of subsurface fluids. Addressing these limitations, our study implements the advanced DR/Henry mixed adsorption model in tandem with the Peng-Robinson equation of state (PR-EOS). This approach meticulously identifies the critical parameters governing the mass exchange ratios between CO<sub>2</sub> and CH<sub>4</sub>, pertinent to in-situ geological environments. Subsequently, we have formulated a comprehensive carbon sequestration potential assessment framework. This innovative model adheres to the mass conservation principles for individual CO<sub>2</sub> and CH<sub>4</sub> components, taking into account the specific surface and stratigraphic conditions prevalent. Employing this refined methodology, we evaluated the CO<sub>2</sub>-ECBM carbon sequestration potential of the 40 evaluation units of extensional, compressive, and cratonic continental coal bearing basins in China's three major temperature-pressure systems across different depth domains and coal ranks within 2000 m. Our findings reveal that the theoretical carbon sequestration capacity of China's continental coal-bearing basins is approximately 59.893 billion tons. Concurrently, the potential ECBM output stands at an estimated 4.92 trillion cubic meters, underscoring the substantial environmental and energy benefits inherent in harnessing CO<sub>2</sub>-ECBM technology effectively. The regional analysis revealed that North and Northwest China hold the highest sequestration and recovery potential, followed by the Northeast and Southern regions, respectively. Specific areas, including the eastern edge of the Ordos Basin and southern Junggar Basin, Qinshui, Huoxi, Xishan, and other areas in Shanxi, present promising future prospects for geological carbon storage in unrecoverable coal seams.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 6","pages":"1602-1614"},"PeriodicalIF":3.5,"publicationDate":"2024-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143248347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shaohua GAO, Yueping YIN, Bin LI, Yang GAO, Nan ZHANG, Tiantian ZHANG, Haoyuan GAO, Xiaojie LIU
Rock-ice avalanches have frequently occurred in the Eastern Himalayan Syntaxis region due to climate change and active tectonic movements. These events commonly trigger catastrophic geohazard chains, including debris flows, river blockages, and floods. This study focuses on the Zelongnong Basin, analyzing the geomorphic and dynamic characteristics of high-altitude disasters. The basin exhibits typical vertical zonation, with disaster sources initiating at elevations exceeding 4000 m and runout distances reaching up to 10 km. The disaster chain movement involves complex dynamic effects, including impact disintegration, soil-rock mixture arching, dynamic erosion, and debris deposition, enhancing understanding of the flow behavior and dynamic characteristics of rock-ice avalanches. The presence of ice significantly increases mobility due to lubrication and frictional melting. In the disaster event of September 10, 2020, the maximum flow velocity and thickness reached 40 m/s and 43 m, respectively. Furthermore, continuous deformation of the Zelongnong glacier moraine was observed, with maximum cumulative deformations of 44.68 m in the distance direction and 25.96 m in the azimuth direction from March 25, 2022, to August 25, 2022. In the future, the risk of rock-ice avalanches in the Eastern Himalayan Syntaxis region will remain extremely high, necessitating a focus on early warning and risk mitigation strategies for such basin disasters.
{"title":"Dynamic Characteristics of the Long Runout Rock-ice Avalanche at High Altitude—A Case from the Zelongnong Basin, Eastern Himalayan Syntaxis, China","authors":"Shaohua GAO, Yueping YIN, Bin LI, Yang GAO, Nan ZHANG, Tiantian ZHANG, Haoyuan GAO, Xiaojie LIU","doi":"10.1111/1755-6724.15207","DOIUrl":"https://doi.org/10.1111/1755-6724.15207","url":null,"abstract":"<p>Rock-ice avalanches have frequently occurred in the Eastern Himalayan Syntaxis region due to climate change and active tectonic movements. These events commonly trigger catastrophic geohazard chains, including debris flows, river blockages, and floods. This study focuses on the Zelongnong Basin, analyzing the geomorphic and dynamic characteristics of high-altitude disasters. The basin exhibits typical vertical zonation, with disaster sources initiating at elevations exceeding 4000 m and runout distances reaching up to 10 km. The disaster chain movement involves complex dynamic effects, including impact disintegration, soil-rock mixture arching, dynamic erosion, and debris deposition, enhancing understanding of the flow behavior and dynamic characteristics of rock-ice avalanches. The presence of ice significantly increases mobility due to lubrication and frictional melting. In the disaster event of September 10, 2020, the maximum flow velocity and thickness reached 40 m/s and 43 m, respectively. Furthermore, continuous deformation of the Zelongnong glacier moraine was observed, with maximum cumulative deformations of 44.68 m in the distance direction and 25.96 m in the azimuth direction from March 25, 2022, to August 25, 2022. In the future, the risk of rock-ice avalanches in the Eastern Himalayan Syntaxis region will remain extremely high, necessitating a focus on early warning and risk mitigation strategies for such basin disasters.</p>","PeriodicalId":7095,"journal":{"name":"Acta Geologica Sinica ‐ English Edition","volume":"98 5","pages":"1376-1393"},"PeriodicalIF":3.5,"publicationDate":"2024-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142525186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}