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Study on microscale mechanical properties of minerals and organic matter in shale based on atomic force microscopy 基于原子力显微镜的页岩中矿物和有机物微观力学性能研究
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-03-01 DOI: 10.1306/11152322060
Zhuo Gong, Shangbin Chen, Hubert Ishimwe, Shaojie Zhang, Jamil Khan, Yang Wang, Xiong Sun
The micromechanical properties of shale are crucial for the modeling and prediction of its macromechanical properties. However, the elastic properties have not been comprehensively understood at nano- and microscales. In the present study, the mechanics-component mapping and logarithm filtering methods are proposed to overcome the defect of atomic force microscopy in identifying shale components to investigate the micromechanical properties of shale. Microscopically, the elasticity of shale is heterogeneous. Heterogeneous elastic characteristics of dolomite and quartz are caused by crystal structure anisotropy, isomorphism, and lattice defects. The anisotropy of crystal structure dominates the variation of Young’s modulus of dolomite and quartz. The Young’s modulus of framboidal pyrite depends greatly on its crystal evolution. The heterogeneous elasticity of organic matter is caused by the disordered molecular structure, the maturity variation, and the mixing of different organic macerals. Because of the difference in Young’s modulus among minerals, the metasomatism of feldspar by calcite, quartz, and clay minerals alters the micromechanical properties of shale. Our study reveals that mineral crystal structure characteristics, diagenesis, and organic petrological factors control the mechanical properties of shale microscopically.
页岩的微观机械特性对其宏观机械特性的建模和预测至关重要。然而,人们尚未全面了解页岩在纳米和微观尺度上的弹性特性。本研究提出了力学成分映射法和对数滤波法,以克服原子力显微镜在识别页岩成分方面的缺陷,从而研究页岩的微观力学性质。从显微镜下看,页岩的弹性是异质的。白云石和石英的异质弹性特征是由晶体结构的各向异性、同构性和晶格缺陷造成的。晶体结构的各向异性主导着白云石和石英杨氏模量的变化。框纹黄铁矿的杨氏模量在很大程度上取决于其晶体演化。有机物的异质弹性是由无序的分子结构、成熟度变化以及不同有机大分子的混合造成的。由于不同矿物的杨氏模量不同,方解石、石英和粘土矿物对长石的变质作用改变了页岩的微观力学性质。我们的研究揭示了矿物晶体结构特征、成岩作用和有机岩石学因素对页岩微观力学性质的控制。
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引用次数: 0
A novel method for digitizing sedimentological graphic logs and exporting into reservoir modeling software 将沉积学图形测井数字化并输出到储层建模软件的新方法
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-03-01 DOI: 10.1306/10182321114
Aly Abdelaziz, Greg M. Baniak, Thomas F. Moslow, Alessandro Terzuoli, Giovanni Grasselli
Sedimentology is a key technical discipline in the energy and resource industry. One of its greatest benefits is in the detailed description and interpretation of full-diameter core as well as wellbore cutting samples. Such information adds significant value to hydrocarbon exploration and development by providing the basis for determining reservoir characterization and constructing precise subsurface stratigraphic models. Typically, such information is gathered in a hand-drawn format and/or produced in a computer-aided graphic illustration software format. Although this information is invaluable, it is hard to come by due to associated costs, and when available, it is limited to the above formats. The work presented herein proposes a novel approach to digitize the information contained within graphic logs. The digitized data are captured in a manner that allows it to be mapped into various other software. Hence, adopting such an approach provides unprecedented value in terms of harvesting sedimentological and petrographic data and integrating them into various other fields.
沉积学是能源和资源行业的一门重要技术学科。它的最大优势之一在于详细描述和解释全直径岩芯以及井筒切割样本。这些信息为确定储层特征和构建精确的地下地层模型提供了依据,从而为油气勘探和开发带来了巨大价值。通常情况下,此类信息是以手绘格式和/或计算机辅助图形图像软件格式收集的。虽然这些信息非常宝贵,但由于相关成本,很难获得,即使获得,也仅限于上述格式。本文介绍的工作提出了一种将图形日志中包含的信息数字化的新方法。数字化数据的采集方式允许将其映射到其他各种软件中。因此,采用这种方法在获取沉积学和岩石学数据并将其整合到其他各种领域方面具有前所未有的价值。
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引用次数: 0
New insights on the retention and migration of shale oil within the hypersaline Qianjiang Formation in the Jianghan Basin, China 关于中国江汉盆地潜江超盐地层中页岩油滞留和迁移的新见解
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-03-01 DOI: 10.1306/11022323026
Zhiliang He, Yuanjia Han, Qinglai Luo, Fu Wang, Furong Wang, Shiqiang Wu
Super giants of oil are present in the hypersaline Qianjiang shale of the Jianghan Basin. Although the oil in place of intersalt shale is controlled potentially by the total organic carbon (TOC) content, the extremely high values of the oil saturation index (OSI), ranging from 100 to 600 mg/g TOC, are widely revealed to be a result of lateral charging of self-sourced petroleum from deep sags. However, a comprehensive review of the literature combined with a case study of producing wells leads to new insights into the retention and migration of oil within the hypersaline Qianjiang shale. Except for the lateral migration, vertical oil migration and oil retention within sulfur-rich kerogen in situ are important replenishments, if not key factors, accounting for the enrichment of high-quality petroleum fluids in the Qianjiang shale. Intraformational migration of oil vertically from source rock layers to juxtaposed shale reservoirs is evidenced by (1) anomalously high OSI values of >400 mg/g TOC, (2) negative expulsion efficiency values, and (3) preferential expulsion of saturate hydrocarbons > aromatic hydrocarbons > polar compounds. Notably, the widely used maturity parameters are unsuitable for assessing the sulfur-rich Qianjiang shale play. Therefore, previous findings on the updip oil migration within individual cyclothem units are questionable. We believe that the present concerns regarding oil retention and migration within the hypersaline Qianjiang shale deserve the focus of much debate and suggest their re-examination.
江汉盆地的高盐度潜江页岩中存在超巨型石油。虽然盐间页岩的含油量可能受总有机碳(TOC)含量的控制,但石油饱和度指数(OSI)的极高值(100 至 600 mg/g TOC)被广泛认为是深陷自采石油横向充注的结果。然而,通过对文献的全面梳理和对生产井的案例研究,我们对石油在高盐度黔江页岩中的滞留和迁移有了新的认识。除横向迁移外,石油的垂直迁移和原地富硫角质层内的石油滞留是黔江页岩富含优质石油流体的重要补充,甚至是关键因素。石油从源岩层垂直向并列页岩储层的构造内迁移表现为:(1)异常高的 OSI 值(大于 400 mg/g TOC);(2)负的排出效率值;(3)优先排出饱和烃 > 芳烃 > 极性化合物。值得注意的是,广泛使用的成熟度参数并不适合评估富含硫磺的黔江页岩区。因此,之前关于单个旋回单元内石油向下迁移的研究结果值得商榷。我们认为,目前有关黔江页岩中石油滞留和迁移的问题值得重点讨论,并建议重新研究。
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引用次数: 0
Guizhou modern karsts as analogues for paleokarst reservoirs in the Shunbei oil field, Tarim Basin, China 贵州现代岩溶作为中国塔里木盆地顺北油田古岩溶储层的模拟对象
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-03-01 DOI: 10.1306/11152321157
Jingbin Wang, Dongya Zhu, Zhiliang He, Haiming Song, Quanyou Liu, Cheng Zeng, Tianbo Yang, Qian Ding
The modern karst systems of Guizhou Province in southern China are examined as the key analogues for fault-controlled paleokarst reservoirs of the Shunbei oil field in the Tarim Basin in northwestern China. The size, distribution, and geometry of karst features are quantitatively described on millimeter-to-kilometer scales, and then we discuss their relationships to the faults, fractures, and bedding surfaces. A three-stage evolutionary model of the modern Guizhou karst is proposed, illustrating how faults and fractures control the flow pathways of drainage and the extent and processes of karstification. Middle Ordovician karstification in Shunbei was controlled by strike-slip faults and followed a similar pattern with Guizhou modern karst. Surface drainage flowed mostly along the gently sloping stratigraphic boundary between the Middle Ordovician and the Upper Ordovician (T74) stratigraphic surface and then downward along steep strike-slip faults. The consistency between the No. 1 fault strike and the southwest-oriented slope resulted in the formation of large-scale underground interconnected paleokarst cave systems at depths of 60 to 107 m. However, No. 5 and No. 7 faults formed fault-controlled paleokarst cavity along deep faults at depths of 0 to 450 m, displaying heterogeneous vertical distribution and poor connectivity in plane. These findings can aid in the design of well trajectories and thus improve exploration and development efficiency in Shunbei and similar fault-controlled paleokarst-dominated carbonate reservoirs.
我们将中国南方贵州省的现代岩溶系统作为中国西北部塔里木盆地顺北油田受断层控制的古岩溶储层的主要模拟对象进行了研究。我们以毫米到公里的尺度定量描述了岩溶特征的大小、分布和几何形状,然后讨论了它们与断层、裂缝和层理面的关系。我们提出了现代贵州岩溶的三阶段演化模型,说明了断层和断裂如何控制排水的流动路径以及岩溶化的范围和过程。顺北中奥陶统岩溶化受走向滑动断层控制,与贵州现代岩溶的模式相似。地表排水主要沿中奥陶统与上奥陶统(T74)地层面之间的缓坡地层边界流淌,然后沿陡峭的走向滑动断层向下流淌。1号断层走向与西南向斜坡的一致性,形成了深度为60至107米的大尺度地下互联古岩溶洞穴系统。然而,5号和7号断层则沿深度为0至450米的深层断层形成了断层控制的古岩溶洞穴,表现出垂直分布不均和平面连通性差的特点。这些发现有助于设计油井轨迹,从而提高顺北及类似以断层控制的古岩溶为主的碳酸盐岩储层的勘探和开发效率。
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引用次数: 0
Seismic sedimentology of a broad, low-relief carbonate platform: The Cambrian Longwangmiao Formation, Moxi–Gaoshiti area, Sichuan Basin, China 宽阔低隆起碳酸盐岩平台的地震沉积学:中国四川盆地磨西-高石梯地区寒武纪龙王庙地层
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-03-01 DOI: 10.1306/02242318016
Wenzhi Zhao, Hongliu Zeng, Zhaohui Xu, Suyun Hu, Qilong Fu
Broad, low-relief carbonate platforms are commonly relatively flat lying and show minimal topographic relief. These characteristics make the platforms difficult to interpret using seismic data. To systematically analyze these platforms for reservoirs, a seismic-sedimentological workflow was implemented to investigate the paleogeomorphology and reservoir quality of the Cambrian Longwangmiao Formation (LWM) in the Moxi–Gaoshiti area of the Sichuan Basin, China.Conventional core and wire-line log data indicate that carbonate lithofacies are composed of completely dolomitized grainstones, packstones, and wackestones to mudstones. Associated depositional environments were interpreted as shoal complex (shoal crest, shoal margin, and intershoal), lagoon, and deep shelf. The low (4%–8%) porosity reservoirs are largely related to the shoal complex facies. Two third-order sequences were correlated throughout the field area, each demonstrating an upward-shallowing trend. The reservoir-quality rocks were formed in the highstand systems tracts of the sequences.Lacking diagnostic shallow-water indicative seismic facies (e.g., the topset of clinoforms), seismic paleogeomorphology was assessed by restoring the paleostructure at the top of the LWM and then evaluating the gross thickness of the LWM to establish the accumulation rate of sediments across the area. This approach demonstrated a fair correlation to measured reservoir-thickness data from wire-line logs, indicating that the paleogeomorphology and depositional facies were largely controlled by a syndepositional, en echelon fault system that determined the distribution of shallow-water shoal complexes and deeper shelf areas across the field area. Seismic lithology determination by amplitude analysis of multiple frequency panels provided a quantitative assessment of reservoir distribution, supplementing the qualitative paleogeomorphologic maps for field development and reservoir modeling.
宽阔、低起伏的碳酸盐平台通常地势相对平坦,地形起伏极小。这些特点使得这些平台难以用地震数据进行解释。为了对这些平台进行系统的储层分析,我们采用了地震沉积学工作流程来研究中国四川盆地磨溪-高石梯地区寒武系龙王庙地层(LWM)的古地貌和储层质量。常规岩芯和测线数据表明,碳酸盐岩岩性由完全白云化的粒状石、包石和腊石至泥岩组成。相关沉积环境被解释为滩涂复合体(滩峰、滩缘和滩间)、泻湖和深海陆架。低(4%-8%)孔隙度储层主要与滩涂复合层有关。在整个油田区域内,有两个三阶序列相关联,每个序列都呈现出向上延伸的趋势。由于缺乏诊断性浅水指示地震面(如岩屑顶部),地震古地貌的评估方法是恢复低纬度岩层顶部的古结构,然后评估低纬度岩层的总厚度,以确定整个区域的沉积物堆积速度。这种方法与线性测井测得的储层厚度数据具有很好的相关性,表明古地貌和沉积面在很大程度上受一个联合沉积的梯状断层系统控制,该断层系统决定了浅水滩涂群和整个油田区较深陆架区域的分布。通过对多个频率面板的振幅分析确定地震岩性,可对储层分布进行定量评估,补充定性古地貌图,用于油田开发和储层建模。
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引用次数: 0
Paleocave architectures and controlling processes of the Ordovician carbonate paleokarst systems in western and central Tarim Basin, northwestern China 中国西北塔里木盆地中西部奥陶纪碳酸盐岩古岩溶系统的古岩洞结构及其控制过程
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-03-01 DOI: 10.1306/09212319006
Changsong Lin, Haijun Yang, Jianfa Han, Jingyan Liu, Zhenzhong Cai, Hao Li, Manli Zhang
The paleokarst systems of the Ordovician carbonate rocks in the Tarim Basin, northwestern China, comprise economically significant oil and gas reservoirs and display complex cave architectures. Based on comprehensive analysis of seismic, well log, core, and outcrop data, the cave architecture and controlling processes of the Ordovician paleokarst systems in the western margin and central uplift belt of the basin are documented. Cave fills of the paleokarst systems are composed mainly of collapse breccias, crackle or mosaic breccias, chaotic breccias, terrestrial sediment fills, and calcareous muddy deposits. Primary architectural elements of the paleokarst systems include surface collapse caves or pits, fractured roofs and walls, sinkholes and associated small-scale caves, cave-level or fault-cave complexes, fractured layers with fractured pores or cavities, and densely spaced small cavity layers. The paleokarst cave structures are characterized by the development of multiple phreatic cave-level or fault-cave complexes and were constrained mainly by the interplay of changing phreatic zones due to multiple stage uplifts or relative sea-level falls and existing high-angle fault belts. They were also transformed by karstification with composite unconformities and hypogenic process. The paleokarst system in the central uplift belt formed in a carbonate island environment during the late Middle Ordovician, whereas the system in the western basin margin developed in an attached carbonate platform setting at the end of the Late Ordovician. Partially filled cave-level or fault-cave complexes, fractured cave roofs, or fractured intervals with fractured pores or cavities comprise the most significant reservoirs in the paleokarst systems.
中国西北部塔里木盆地奥陶系碳酸盐岩的古岩溶系统是具有重要经济价值的油气藏,并显示出复杂的溶洞构造。基于对地震、测井、岩心和露头数据的综合分析,记录了盆地西缘和中部隆起带奥陶系古岩溶系统的洞穴结构和控制过程。古岩溶系统的洞穴填充物主要由崩塌角砾岩、裂隙或镶嵌角砾岩、混沌角砾岩、陆相沉积填充物和钙质泥质沉积物组成。古岩溶系统的主要建筑元素包括地表塌陷洞穴或坑洞、断裂的洞顶和洞壁、天坑和相关的小型洞穴、洞穴层或断层洞穴复合体、带有断裂孔隙或洞穴的断裂层以及密集分布的小型洞穴层。古岩溶洞穴结构的特点是发育多个岩溶洞穴层或断层洞穴复合体,主要受制于多级隆起或相对海平面下降导致的岩溶带变化以及现有高角度断层带的相互作用。此外,岩溶化、复合不整合以及低成岩过程也对其产生了影响。中部隆起带的古岩溶系统形成于中奥陶世晚期的碳酸盐岛环境中,而西部盆地边缘的古岩溶系统则形成于晚奥陶世末期的附着碳酸盐平台环境中。部分充填的洞穴层或断层洞穴复合体、断裂洞顶或带有断裂孔隙或空洞的断裂带是古岩溶系统中最重要的储层。
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引用次数: 0
Why does it take so long to publish a paper in the AAPG Bulletin? 为什么在《AAPG 简报》上发表一篇论文需要这么长时间?
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-02-01 DOI: 10.1306/11092323076
Wayne K. Camp
Many authors become frustrated with the amount of time it takes to review, accept, and publish their work in peer-reviewed scientific journals. An analysis of papers published in volume 107 of the AAPG Bulletin through November 2023 shows publication took an average of 25 months from manuscript submission to publication. Most of the time is consumed during the review period that averaged 15 months. The length of the review period includes the time taken to complete revisions, which averaged 12 months, and is a function of the manuscript quality and the number of revisions required prior to the final decision. Recommendations are provided to assist authors in preparing manuscripts for submission and guidelines for reviewers to help expedite the review process.
许多作者对同行评审的科学期刊从审稿、接受到发表其作品所花费的时间感到沮丧。对截至 2023 年 11 月《美国地质学家协会公报》第 107 卷发表的论文进行的分析表明,从投稿到发表平均需要 25 个月。大部分时间耗费在审稿期间,平均为 15 个月。审稿期包括完成修订所需的时间,平均为 12 个月,这与稿件质量和最终决定前所需的修订次数有关。本报告提供了帮助作者准备投稿的建议和帮助加快审稿过程的审稿指南。
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引用次数: 0
Strike-slip fault control on karst in ultra-deep carbonates, Tarim Basin, China 中国塔里木盆地超深碳酸盐岩岩溶的走向滑动断层控制
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-02-01 DOI: 10.1306/09212321161
Lianbo Zeng, Jinxiong Shi, Qingyou Ma, Wenya Lyu, Shaoqun Dong, Dongsheng Cao, Hehua Wei
Karst reservoirs in the Ordovician carbonates of Tarim Basin are currently major targets of deep and ultra-deep hydrocarbon exploration and development in China. New drilling and seismic data show that these deep-buried carbonate karst reservoirs are spatially dependent on strike-slip faulting. Based on the geological and geophysical data, this study developed an attempt to determine the impact and spatial distribution of strike-slip faulting on carbonate karst reservoirs in the Tahe oil field. Strike-slip faults in the Taha area can be classified as first order, second order, and third order. Fault damage zones are distributed along the strike-slip faults, and their widths have a positive correlation with fault order. Influenced by strike-slip faults, fault-related fractures, and rock mechanical properties, the development degree and spatial distribution of carbonate karst reservoirs display strong heterogeneity. The horizontal heterogeneity of karst reservoirs is controlled by strike-slip faults with different scales and strikes, and the vertical heterogeneity is combined results of the strike-slip faulting and mechanical properties of carbonates. In the Tahe area, ultra-deep carbonate karst reservoirs are generally concentrated within 550 m (∼1800 ft) of the damage zone of north-northeast– and north-northwest–striking first-order and second-order strike-slip faults. Fewer and smaller-scale karst reservoirs are developed further away from the fault core. Additionally, fracture intensity is greater in more brittle facies enhancing the karstification. The results from this research provide an analogue for understanding the distribution of fault-controlled karsting in deep carbonate reservoirs around the world.
塔里木盆地奥陶系碳酸盐岩岩溶储层是中国目前深层和超深层油气勘探开发的主要目标。新的钻探和地震资料表明,这些深埋碳酸盐岩岩溶储层在空间上依赖于走向滑动断层。本研究以地质和地球物理资料为基础,试图确定走向滑动断层对塔河油田碳酸盐岩喀斯特储层的影响和空间分布。塔河地区的走向滑动断层可分为一阶、二阶和三阶。断层破坏带沿走向滑动断层分布,其宽度与断层阶数呈正相关。受走向滑动断层、与断层有关的断裂和岩石力学性质的影响,碳酸盐岩岩溶储层的发育程度和空间分布具有很强的异质性。岩溶储层的水平异质性受不同规模和走向的走向滑动断层控制,垂直异质性是走向滑动断层和碳酸盐岩力学性质的综合结果。在塔河地区,超深碳酸盐岩岩溶储层一般集中在北北东向和北北西向一阶和二阶走向的走向滑动断层破坏带的 550 米(∼1800 英尺)范围内。远离断层核心区的岩溶储层数量较少,规模较小。此外,在脆性较大的岩层中,断裂强度较大,从而加剧了岩溶化。这项研究的结果为了解全球深层碳酸盐岩储层中受断层控制的岩溶分布提供了类比。
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引用次数: 0
Origin of bedding-parallel calcite “beef” layers in the Upper Jurassic Haynesville shale, northwestern Louisiana 路易斯安那州西北部上侏罗世海恩斯维尔页岩中与层理平行的方解石 "牛肉 "层的起源
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-02-01 DOI: 10.1306/01192321189
L. Taras Bryndzia, Calum I. Macaulay, Alexander P. Litvinchuk, Brian D. Monteleone
Bedding-parallel calcite layers (BPCLs) preserving a fibrous “beef” texture are common throughout the overmature Haynesville Formation shale. Their interfaces with the host shale contain radiating splays of anhydrite pseudomorphs after gypsum rosettes, suggesting either a primary evaporitic or an early burial origin. In places, the calcite layers contain remnant barite or anhydrite in crystallographic alignment with its host calcite, indicating that the calcite formed by replacing a fibrous sulfate precursor phase.During burial and heating, maturation of source rock organic matter resulted in the expulsion of hydrocarbons (oil and gas). Consequently, the redox state of the shale and hydrocarbon system became reducing, as indicated by the ubiquitous presence of H2S. Both anhydrite and barite are unstable in the presence of H2S and were consumed by thermochemical sulfate reduction. At peak burial, liquid hydrocarbons cracked to CH4 gas and remnant solid pyrobitumen, which typically occupies the median suture zone of the fibrous calcite layers. It was along this median suture that calcite replacement of anhydrite and barite was initiated, proceeding to replace sulfate minerals from the center of the layer out toward the shale contact.We estimated the in situ CH4 pressure attending thermochemical sulfate reduction in the Haynesville shale by using microlaser Raman spectroscopy to directly measure the density of CH4 gas inclusions in BPCLs. Average fluid pressure gradients preserved within the fibrous calcite are approximately 0.87 ± 0.03 psi/ft (±1σ; n = 4), considerably above hydrostatic but below both overburden and shale fracture gradients. We found no evidence to suggest that fluid pressures exceeded lithostatic or that fibrous calcite grew in dilated vein systems from their margins toward the center of the BPCLs.The replacement of primary bedded anhydrite and barite by calcite preserves the original orientation of the precursor sulfate minerals—in other words, their fibrous beef texture is an inherited feature. The replacement of sulfate by calcite results in a solid volume loss of approximately 20 to 30 vol. %. Collapse of the layers due to loss of volume and overburden stress results in the minimum horizontal stress being parallel to bedding. Pyrobitumen layers were compressed and disaggregated due to tensile failure. Both late-stage calcite and disaggregated pyrobitumen subsequently grew in the direction of minimum horizontal stress (i.e., parallel to bedding).
在整个海恩斯维尔地层过成熟页岩中,保持纤维状 "牛肉 "纹理的层状平行方解石层(BPCL)十分常见。方解石层与主页岩的交接处含有石膏花岗岩后的放射状无水石膏假象,这表明方解石层起源于原生蒸发或早期埋藏。在某些地方,方解石层含有残余的重晶石或无水石膏,与其主方解石在结晶学上保持一致,这表明方解石是通过取代纤维状硫酸盐前驱相而形成的。因此,页岩和碳氢化合物系统的氧化还原状态变成了还原状态,这一点可以从无处不在的 H2S 中看出来。无水石膏和重晶石在 H2S 的存在下不稳定,会被热化学硫酸盐还原所消耗。在埋藏高峰期,液态碳氢化合物裂解为 CH4 气体和残余的固态火沥青,通常占据纤维状方解石层的中间缝合带。我们利用微激光拉曼光谱直接测量了 BPCL 中 CH4 气体包裹体的密度,从而估算出了海恩斯维尔页岩中参加热化学硫酸盐还原的原位 CH4 压力。纤维状方解石中保留的平均流体压力梯度约为 0.87 ± 0.03 psi/ft(±1σ;n = 4),大大高于静水压力,但低于覆盖层和页岩裂缝梯度。我们没有发现任何证据表明流体压力超过了岩石压力,也没有发现纤维状方解石在扩张的脉系中从其边缘向BPCL的中心生长。方解石对原生层状无水石膏和重晶石的置换保留了前驱硫酸盐矿物的原始方向,换句话说,它们的纤维状牛肉纹理是一种继承特征。方解石取代硫酸盐导致固体体积损失约 20 至 30%。由于体积损失和覆土应力导致地层坍塌,最小水平应力与垫层平行。焦沥青层由于拉伸破坏而被压缩和分解。晚期方解石和解离的焦沥青随后都沿着最小水平应力的方向(即与垫层平行)生长。
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引用次数: 0
The impact of CO2-enhanced oil recovery on oil production and lifespan of old oil pools: A Canadian example 二氧化碳强化采油对石油产量和老油池寿命的影响:以加拿大为例
IF 3.5 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-02-01 DOI: 10.1306/09212322125
Mengwei Zhao
Analyses of oil production data from the Weyburn Midale oil pool reveal that CO2 injection substantially reduced the decline trend of annual oil outputs in an exponential way with an average decline rate of 2.5%, which is two times lower than that of the worldwide total giant oil fields (5.5% or 6.5%). Based on its production data, it is projected that without CO2 injection the pool would have ended its life by 2016 with an ultimate cumulative oil output of 448.1 million bbl (71.2 million m3) and a recovery factor of only 24.4%. However, with continuous CO2 injection, by 2055 when the pool will be celebrating its 100th birthday, it can still produce 4 million bbl (0.6 million m3) of oil annually with a cumulative output of 801.8 million bbl (127.5 million m3) of oil and a recovery factor of 43.7%, whereas an additional 9.2 TCF (259.9 billion m3) of CO2 will be poured into the pool. By 2100, after 100 yr of CO2 injection, the pool’s annual oil output could be near 1.5 million bbl (0.2 million m3) and its cumulative oil output would reach 914.0 million bbl (145.3 million m3) representing a recovery factor of 49.8%, whereas 21.3 TCF (604 billion m3) of more CO2 could be injected into and permanently stored in the pool. The CO2-enhanced oil recovery could extend the pool’s lifespan to 39 or even 84 more years.
对 Weyburn Midale 油藏石油生产数据的分析表明,二氧化碳注入大大减少了石油年产量的下降趋势,平均下降率为 2.5%,是全球巨型油田总下降率(5.5% 或 6.5%)的两倍。根据其生产数据,如果不注入二氧化碳,预计到 2016 年,该油池将结束其生命,最终累计石油产量为 4.481 亿桶(7120 万立方米),采收率仅为 24.4%。然而,如果持续注入二氧化碳,到 2055 年油池将迎来它的 100 岁生日时,它每年仍可生产 400 万桶(60 万立方米)石油,累计产量为 8.018 亿桶(1.275 亿立方米)石油,采收率为 43.7%,而注入油池的二氧化碳将增加 9.2 TCF(2,599 亿立方米)。到 2100 年,在注入二氧化碳 100 年后,油池的年石油产出量将接近 150 万桶(20 万立方米),累计石油产出量将达到 9.14 亿桶(1.453 亿立方米),采收率为 49.8%,而注入并永久储存在油池中的二氧化碳将增加 21.3 TCF(6,040 亿立方米)。二氧化碳提高石油采收率可将油池的寿命延长至 39 年甚至 84 年。
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