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Thermodynamic solid-liquid equilibrium model for mixed systems HF-NaF-H2O and HF-KF-H2O up to 2 m HF at T = 25oC T = 25℃时HF- naf - h2o和HF- kf - h2o混合体系高达2 m HF固液平衡模型
Pub Date : 2023-03-01 DOI: 10.2478/asn-2023-0002
Stanislav Donchev, Tsvetan Tsenov, C. Christov
Abstract In this study we developed thermodynamic models for solid-liquid equilibrium for mixed systems HF-NaF-H2O and HF-KF-H2O up to 2 m HF at T = 25oC. Models are developed on the basis of Pitzer ion interactions approach. The recommendations on mean activity coefficients (γ±) have been used to construct the model for HF-H2O system. The models for binary systems NaF-H2O and KF-H2O are taken from our previous study in the same journal [Donchev et al. ASN (2021) 8(2), 1-15]. To parameterize models for ternary systems we used the available solubility data, i.e. on the basis of solubility approach. The thermodynamic solubility products (as ln Kosp) of precipitating in mixed systems double salts [NaF.HF(cr), and KF.HF(cr)] have been determined on the basis of evaluated model ion interaction parameters and using experimental m(sat) solubility data. The model is in a good agreement with experimewnt solubility data in the systems HF–NaF–H2O and HF–NaF–H2O up to maximum HF molality of 2 mol·kg−1. At higher acid molality the model predicts much higher solubility of double salts (NaF.HF(cr) and KF.HF(cr) for both mixed systems. It was concluded that not a correct raw data for binary HF–H2O system used in parameterization are the main reason for concentration restriction of mixed HF models presented here.
摘要在本研究中,我们开发了HF-NaF-H2O和HF-KF-H2O混合系统在T=25℃下高达2 m HF的固液平衡热力学模型。模型是在Pitzer离子相互作用方法的基础上开发的。利用平均活度系数(γ±)的建议建立了HF-H2O系统的模型。NaF-H2O和KF-H2O二元系统的模型取自我们之前在同一期刊上的研究[Donchev等人ASN(2021)8(2),1-15]。为了参数化三元体系的模型,我们使用了可用的溶解度数据,即基于溶解度方法。基于评估的模型离子相互作用参数和使用实验m(sat)溶解度数据,确定了在混合体系中沉淀的热力学溶解度产物(如ln-Kosp)复盐[NaF.HF(cr)和KF.HF(cr)]。该模型与HF–NaF–H2O和HF–NaF–H2O体系中的经验溶解度数据非常一致,最大HF摩尔浓度为2 mol·kg−1。在较高的酸摩尔浓度下,该模型预测两种混合体系的复盐(NaF.HF(cr)和KF.HF(cr))的溶解度要高得多。得出的结论是,参数化中使用的二元HF–H2O系统的原始数据不正确是本文提出的混合HF模型的浓度限制的主要原因。
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引用次数: 0
Tourism as a prerequisite for changing the national identity 旅游业是改变民族身份的先决条件
Pub Date : 2023-03-01 DOI: 10.2478/asn-2023-0009
Tsvetelina Metodieva
Abstract The report reveals the impact of tourism on changing national identity. The interaction between tourism and cultural identity as social phenomena is noted. Globalization as a prerequisite for cultural disorientation is examined. The concept of anthropotok, as a mass self-sustaining process of identity change, is examined.
摘要该报告揭示了旅游业对改变民族认同的影响。人们注意到旅游业与文化特性作为一种社会现象之间的相互作用。全球化是文化迷失方向的先决条件。人类学的概念,作为一个大规模自我维持的过程,身份改变,被审查。
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引用次数: 1
Green infrastructure - the smart interpreting of natural capital 绿色基础设施——自然资本的智慧诠释
Pub Date : 2023-03-01 DOI: 10.2478/asn-2023-0006
Dora Kabakchieva, V. Vasileva
Abstract Humanity continues to degrade natural capital, threatening its long-term sustainability. This more and more categorically imposes the need to create a specific green infrastructure - a response to the natural solutions to the accumulating problems (environmental pollution, floods, natural disasters and cataclysms). The failure of decisions to pay sufficient attention to ecological consequences and to apply systematic measures of high quality are among the main reasons for the current situation in most ecosystems. The fast-paced and highly mechanized way of life of modern man creates the illusion of remoteness from the natural world. Yet all human activity depends entirely on ecosystems and their functions and at the same time has (threatening) impacts on them. Therefore, the achievement of greater efficiency in the use of natural resources and the creation of suitable ecological living conditions are critically important goals both for Europe and for the whole world. Green Infrastructure (GI) is a successfully tested tool for providing environmental, economic and social benefits through environmentally sound solutions. Such a tool helps to understand the values provided by nature to human society and mobilizes investments for their maintenance and growth.
人类不断破坏自然资本,威胁其长期可持续性。这就越来越明确地要求建立一个特定的绿色基础设施,这是对积累问题(环境污染、洪水、自然灾害和灾难)的自然解决方案的回应。没有作出足够重视生态后果的决定和没有采取高质量的系统措施是造成大多数生态系统目前状况的主要原因之一。现代人快节奏、高度机械化的生活方式,给人一种远离自然世界的错觉。然而,所有人类活动完全依赖于生态系统及其功能,同时也对它们产生(威胁性)影响。因此,提高自然资源的利用效率和创造适宜的生态生活条件是欧洲和全世界至关重要的目标。绿色基础设施(GI)是一种经过成功测试的工具,可以通过无害环境的解决方案提供环境、经济和社会效益。这种工具有助于理解自然为人类社会提供的价值,并动员投资以维持和增长这些价值。
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引用次数: 1
For optical flickering in symbiotic star MWC 560 用于共生恒星MWC 560的光学闪烁
Pub Date : 2022-11-01 DOI: 10.2478/asn-2022-0017
D. Marchev, K. Stoyanov, V. Marchev, R. Zamanov, B. Borisov, Doroteq Vasileva, T. Atanasova, Nataliya Pavlova
Abstract This study is based on observations of MWC560 during the last two observational seasons (2020/2021 and 2021/2022). Other than looking for flickering we were interested in following the variability of brightness in the same period. Looking for similarities in the spectra with other types of stars is also of great interest to us because it could help clarify the stellar configuration of such objects. Our observations during the last two observational seasons of MWC560 confirm the absence of flickering. From the similarities of the gathered spectra of XX Oph and MWC560 we assume that the components in XX Oph are a red giant and a white dwarf, which are also surrounded by a common shell.
摘要本研究基于过去两个观测季节(2020/2021和2021/2022)对MWC560的观测。除了寻找闪烁,我们感兴趣的是跟踪同一时期亮度的变化。寻找与其他类型恒星光谱的相似性也引起了我们的极大兴趣,因为这有助于澄清这些物体的恒星构型。我们在MWC560最后两个观测季节的观测结果证实了没有闪烁。根据收集到的XX Oph和MWC560光谱的相似性,我们假设XX Oph中的成分是红巨星和白矮星,它们也被一个共同的外壳包围。
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引用次数: 0
Survey on current status of folk medicine in Bulgaria reported by local knowledgeable persons 当地知情人士报告的保加利亚民间医学现状调查
Pub Date : 2022-11-01 DOI: 10.2478/asn-2022-0021
A. Dragoeva, Z. Stoyanova, M. Marinov, Vanya Koleva
Abstract Traditional knowledge is of real danger to be lost in modern society. This research is a part of an ethnobotanical survey aimed on documentation of current status of folk medicine in Central and Northeastern Bulgaria. Semi-structured interviews with local knowledgeable persons were provided. Quantitative ethnobotanical indices consisting of Fidelity level (FL) and Informant consensus factor (ICF) were calculated as indicatives of local importance of species and prevalent uses of species. The respondents reported 15 category uses: to treat 12 health disorders, for prophylaxis/immune stimulation, other health connected conditions and plants included in the diet as food/spices. The highest number of plants was used for the treatment of gastrointestinal diseases (65.9%), cardiovascular problems (53.4%) and urinary system problems (46.6%). It should be noted that many herbal medicines are related to disease prevention (52.3%). Maximum FL value (100%) of Hypericum perforatum for digestive and nervous system disorders and Thymus sp. for respiratory system diseases was calculated. Numerous species and specific applications were listed in the paper, contributing to the base ethnobotanical data. Specific use categories indicate most spread health disorders and proved treatments in the studied regions. Results also reflect the growing interest in disease prevention (immune stimulation) and a healthy diet.
摘要传统知识在现代社会中有失传的危险。这项研究是民族植物学调查的一部分,旨在记录保加利亚中部和东北部民间医学的现状。与当地知识渊博的人士进行了半结构化的访谈。以保真度(Fidelity level, FL)和知者共识因子(Informant consensus factor, ICF)为指标,计算了物种在当地的重要性和物种的普遍利用程度。答复者报告了15类用途:治疗12种健康失调、预防/免疫刺激、其他与健康有关的情况以及作为食物/香料的饮食中的植物。用于治疗胃肠道疾病(65.9%)、心血管疾病(53.4%)和泌尿系统疾病(46.6%)的植物最多。值得注意的是,许多草药与疾病预防有关(52.3%)。计算了贯叶连翘治疗消化系统和神经系统疾病和胸腺治疗呼吸系统疾病的最大FL值(100%)。文中列举了大量的种类和特定的应用,为民族植物学提供了基础资料。具体使用类别表明,在所研究的区域,最普遍的健康疾病和已证实的治疗方法。研究结果也反映了人们对疾病预防(免疫刺激)和健康饮食的兴趣日益浓厚。
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引用次数: 0
Interaction of the birch-bark terpenoids with human and bovine serum albumins 桦树皮萜类化合物和人、牛血清白蛋白的相互作用
Pub Date : 2022-11-01 DOI: 10.2478/asn-2022-0019
K. Kalchev, I. Hristova, Gergana Manova, Lyubomir Е Manov
Abstract Interactions between pentacyclic triterpenes isolated from white birch (Betula pendula Roth.) bark samples from Northeast Bulgaria and bovine serum albumin or human serum albumin were investigated using fluorescence techniques. The experimental results show the formation of complexes between the isolated triterpenes with serum albumins. Quenching of the intrinsic fluorescence of human serum albumins was monitored by emission spectra of varied quencher concentration solutions. By analysing the fluorescence spectra and fluorescence intensity, some parameters of the serum albumins - quencher interaction were determined to evaluate the type of quenching. An extract containing the isolated triterpenes formed complexes with both bovine serum albumin and human serum albumin, leading to quenching the fluorescence of both albumins by a combined quenching mechanism.
摘要利用荧光技术研究了从保加利亚东北部白桦树皮中分离的五环三萜与牛血清白蛋白或人血清白蛋白之间的相互作用。实验结果表明,分离的三萜与血清白蛋白形成复合物。通过不同猝灭剂浓度溶液的发射光谱监测人血清白蛋白固有荧光的猝灭。通过分析荧光光谱和荧光强度,确定了血清白蛋白-猝灭剂相互作用的一些参数,以评估猝灭的类型。含有分离的三萜的提取物与牛血清白蛋白和人血清白蛋白形成复合物,通过联合猝灭机制猝灭两种白蛋白的荧光。
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引用次数: 0
Editorial Note: The Botanical Garden in Balchik – harmonious coexistence between Man and Nature 编者按:巴尔奇克植物园——人与自然和谐共生
Pub Date : 2022-11-01 DOI: 10.2478/asn-2022-0016
D. Zahariev.
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引用次数: 0
Structural characterization of an exopolysaccharide produced by Lactobacillus plantarum Ts 植物乳杆菌Ts胞外多糖的结构表征
Pub Date : 2022-11-01 DOI: 10.2478/asn-2022-0022
Stephany Toschkova
Abstract An exopolysaccharide (EPS) was isolated from Lactobacillus plantarum Ts and purified by size exclusion chromatography train. L. plantarum showed the highest production (9.4 ± 0.8 g/l) of EPS. Furthermore, L. plantarum was cultured in medium with volume of 5 L and the EPS was extracted by ethanol precipitation. By HPLS analysis demonstrated, that the EPS has two fractions - polymer and olygomer. The molecular mass of the EPS from both fractions is respectively 8.3x104 Da for the greater pic and 5.0x102 Da. Fourier transform infrared spectroscopy analysis showed the presence of hydroxyl and carboxyl groups and glycosidic linkages. TLC analysis indicated that the EPS was a heteropolymer composed of fructose, and sucrose as monomeric constituent units. The strain L. plantarum and pathogenic E. coli 3398, St. aureus 745, B. subtilis 6633, S. typhimurium 3591, L. monocytogenes 863 and E. aerogenes 3691 were tested for their growth utilizing the EPS from L. plantarum as the sole carbon source for its possible use as a prebiotic. L. plantarum exhibited growth in the EPS supplied medium compared with sucrose as carbon source, whereas the pathogenic strains did not grow in the EPS-supplied medium. In vitro evaluations showed that, like other reported polysaccharides, this EPS displayed significant prebiotics properties.
摘要从植物乳杆菌Ts中分离得到一种胞外多糖(EPS),并用排阻色谱柱进行纯化。植物乳杆菌的EPS产量最高(9.4±0.8 g/L)。此外,植物乳杆菌在5L体积的培养基中培养,并通过乙醇沉淀提取EPS。通过HPLS分析表明,EPS具有两个组分——聚合物和多聚体。两个组分的EPS的分子量分别为8.3x104Da和5.0x102Da。傅里叶变换红外光谱分析显示存在羟基和羧基以及糖苷键。薄层色谱分析表明,EPS是一种以果糖和蔗糖为单体组成单元的杂聚物。植物乳杆菌菌株和致病性大肠杆菌3398、金黄色葡萄球菌745、枯草芽孢杆菌6633、鼠伤寒杆菌3591、单核细胞增多性乳杆菌863和产气大肠杆菌3691利用植物乳杆菌的EPS作为其可能用作益生元的唯一碳源进行生长测试。与蔗糖作为碳源相比,植物乳杆菌在EPS供应的培养基中表现出生长,而致病菌株在EPS供应培养基中不生长。体外评估表明,与其他报道的多糖一样,这种EPS显示出显著的益生元特性。
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引用次数: 0
Optimizing the processing of large amounts of spatial data related to the ecosystem water service provided by forest territories 优化处理与森林地区提供的生态系统水服务有关的大量空间数据
Pub Date : 2022-11-01 DOI: 10.2478/asn-2022-0018
R. Miltchev, N. Shuleva, Galin Milchev
Abstract Nowadays, an increased interest towards the integration of the concept of ecosystem services has been observed, both in regards to processes related to forest and water resources management, as well as in the context of sustainable development of the economy on a local, regional and national level. In the most common case, what is referred to as forest ecosystem services are possible benefits, which man can reap directly or indirectly from ecosystem functions of forest territories. Therefore, it is of great importance to analyse and assess the interactions between the human factor with the conditions and processes through which forest ecosystems create and sustain ecosystem services. The water ecosystem service provided by forest territory could cause the need to process large amounts of spatial data in the form of forest management and hydrological information, as well as information about sanitary protection zones around water sources, in the context of the administrative territorial division of the country at different levels, creates considerable challenges. The difficulties are due to both the various electronic formats in which the necessary information is maintained, and the need to perform different operations on the input data for the purpose of analysis and decision making. The present paper investigates the possibilities of automating the processing of large volumes of spatial data in the context of the ecosystem water service, provided by forest territories by developing a set of tools operating into the environment of open source GIS. The main purpose is to develop a unified approach based on the use of GIS and suitable for the creation and implementation of methods for analysis and management of processes related to the ecosystem water service provided by forest territories. The approach can be applied in different sectors of the economy, public relations and the environment.
如今,人们对生态系统服务概念的整合越来越感兴趣,无论是在与森林和水资源管理有关的过程中,还是在地方、区域和国家层面上经济可持续发展的背景下。在最常见的情况下,所谓森林生态系统服务是人类可以从森林领土的生态系统功能中直接或间接获得的可能利益。因此,分析和评估人类因素与森林生态系统创造和维持生态系统服务的条件和过程之间的相互作用是非常重要的。森林领土提供的水生态系统服务可能导致需要处理大量以森林管理和水文资料形式的空间数据,以及在国家不同级别的行政领土划分范围内有关水源周围卫生保护区的资料,这造成了相当大的挑战。困难是由于保存必要信息的各种电子格式,以及需要对输入数据进行不同的操作以进行分析和决策。本文通过开发一套在开源GIS环境中运行的工具,研究了在森林地区提供的生态系统水服务背景下自动化处理大量空间数据的可能性。主要目的是在使用地理信息系统的基础上发展一种统一的办法,适合于制定和执行分析和管理与森林领土提供的生态系统水服务有关的过程的方法。这种方法可以应用于经济、公共关系和环境的不同部门。
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引用次数: 0
Duration of fungicide activity against wheat powdery mildew 杀菌剂对小麦白粉病的活性持续时间
Pub Date : 2022-11-01 DOI: 10.2478/asn-2022-0023
M. Koleva, Y. Stanoeva, A. Ivanova, P. Chamurliyski
Abstract The most commonly used method to control wheat powdery mildew is by fungicides. The aim of the present study is to determine the duration of the fungicide activity of three fungicides: azoxystrobin; triadimenol; tebuconazole+spiroxamine+triadimenol. They were applied in three concentrations in phenophase 3-4 leaf of susceptible wheat variety. After treatment, each day one pot of the tested fungicide concentrations was inoculated with Blumeria graminis f. sp. tritici. When using azoxystrobin at concentrations of 0.2%, 0.4%, 0.8%, symptoms of powdery mildew appeared on plants inoculated with Blumeria graminis f.sp. tritici in the next day after treatment. When using triadimenol, first symptoms appeared in plants inoculated with the pathogen on the next day after applying a concentration 0.12%, on the second day after applying a concentration 0.25% and on the third day after treatment with a concentration 0.5%. With tebuconazole+spiroxamine+triadimenol, first postules appeared on plants inoculated with Blumeria graminis f. sp. tritici on the third day after treatment with a concentration 0.15%, on the 13th day after treatment with a concentration 0.3% and on the 14th day after treatment with a concentration 0.6%. This fungicide at a concentration of 0.6% (13 days) and 0.3% (12 days) has the longest duration of fungicide activity.
摘要控制小麦白粉菌最常用的方法是使用杀菌剂。本研究的目的是测定三种杀菌剂的杀菌活性持续时间:嘧菌酯;三唑醇;戊唑醇+螺沙明+三唑醇。在感病小麦品种的3~4叶期分别以三种浓度施用。处理后,每天在一盆测试浓度的杀菌剂中接种小麦布鲁菌。当使用浓度为0.2%、0.4%、0.8%的嘧菌酯时,接种小麦布鲁姆菌的植株在处理后的第二天出现了白粉病症状。当使用三唑醇时,接种病原体的植物在施用浓度0.12%后的第二天、施用浓度0.25%后的第2天和施用浓度0.5%后的第3天出现首次症状,用0.15%浓度的禾谷布鲁菌(Blumeria graminis f.sp.tritici)处理后第3天、0.3%浓度的禾沟布鲁菌处理后第13天和0.6%浓度的禾谷布鲁菌接种后第14天,植株上出现了第一个小芽,其中浓度为0.6%(13天)和0.3%(12天)的禾谷菌株具有最长的杀菌活性。
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