Laplacian matrix and its spectrum are commonly used for giving a measure in networks in order to analyse its topological properties. In this paper, Laplacian matrix of graphs and their spectrum are studied. Laplacian energy of a graph G of order n is defined as ( mathrm{{LE}}(G) = sum _{i=1}^n|lambda _i(L)-{bar{d}}|), where (lambda _i(L)) is the i-th eigenvalue of Laplacian matrix of G, and ({bar{d}}) is their average. If (mathrm{{LE}}(G) = mathrm{{LE}}(K_n)) for the complete graph (K_n) of order n, then G is known as L-borderenergetic graph. In the first part of this paper, we construct three infinite families of non-complete disconnected L-borderenergetic graphs: (Lambda _1 = { G_{b,j,k} = [(((j-2)k-2j+2)b+1)K_{(j-1)k-(j-2)}] cup b(K_j times K_k)| b,j,k in {{mathbb {Z}}}^+}), ( Lambda _2 = {G_{2,b} = [K_6 nabla b(K_2 times K_3)] cup (4b-2)K_9 | bin {{mathbb {Z}}}^+ }), ( Lambda _3 = {G_{3,b} = [bK_8 nabla b(K_2 times K_4)] cup (14b-4)K_{8b+6} | bin {{mathbb {Z}}}^+ }), where (nabla ) is join operator and (times ) is direct product operator on graphs. Then, in the second part of this work, we construct new infinite families of non-complete connected L-borderenergetic graphs (Omega _1= {K_2 nabla overline{aK_2^r} vert ain {{mathbb {Z}}}^+}), (Omega _2 = {overline{aK_3 cup 2(K_2times K_3)}vert ain {{mathbb {Z}}}^+ }) and (Omega _3 = {overline{aK_5 cup (K_3times K_3)}vert ain {{mathbb {Z}}}^+ }), where ({overline{G}}) is the complement operator on G.