Pub Date : 2023-10-17DOI: 10.1080/17436753.2023.2268436
Eugene Medvedovski
{"title":"Special Issue: ‘Advanced Ceramics and Coatings for Wear and Corrosion Applications’","authors":"Eugene Medvedovski","doi":"10.1080/17436753.2023.2268436","DOIUrl":"https://doi.org/10.1080/17436753.2023.2268436","url":null,"abstract":"","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"122 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136033281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ABSTRACTIn this study, we will apply the hot-press moulding method for the first time to the preparation of alkali-activated slag composites (AASC) and incorporate 1vol.-%, 3vol.-%, 5vol.-%, and 7vol.-% steel, copper, and carbon fibres into the matrix in order to investigate the characteristics of the HP-AASC and fibre reinforced (HP-FRAASC) in terms of compressive strength, flexural strength, impact toughness, and bulk density of HP-AASC and HP-FRAASC. Results show that the composites have good flexural strength, compressive strength, and impact toughness when the content of steel fibres is 5 vol.-%, copper fibres are 7 vol.-%, and carbon fibres are 1–3 vol.-%. It was observed from each sample of HP-FRAASC and HP-AASC that the HP-AASC samples had lower porosity, better density, and an easy preparation process, which can be used as a suitable preparation method for this material.KEYWORDS: Alkali-activated slagfibre reinforcementhot-press mouldingmechanical propertiesporositybulk density Disclosure statementNo potential conflict of interest was reported by the author(s).
{"title":"Influences on the mechanical and physical properties of hot-press moulding alkali-activated slag (HP-FRAASC) composite with various fibers","authors":"Haonian Wang, Lixin Xu, Sirui Zang, Dajian Huang, Song Wang, Qing Guo, Jiale Yang, Changjun Jiang","doi":"10.1080/17436753.2023.2265194","DOIUrl":"https://doi.org/10.1080/17436753.2023.2265194","url":null,"abstract":"ABSTRACTIn this study, we will apply the hot-press moulding method for the first time to the preparation of alkali-activated slag composites (AASC) and incorporate 1vol.-%, 3vol.-%, 5vol.-%, and 7vol.-% steel, copper, and carbon fibres into the matrix in order to investigate the characteristics of the HP-AASC and fibre reinforced (HP-FRAASC) in terms of compressive strength, flexural strength, impact toughness, and bulk density of HP-AASC and HP-FRAASC. Results show that the composites have good flexural strength, compressive strength, and impact toughness when the content of steel fibres is 5 vol.-%, copper fibres are 7 vol.-%, and carbon fibres are 1–3 vol.-%. It was observed from each sample of HP-FRAASC and HP-AASC that the HP-AASC samples had lower porosity, better density, and an easy preparation process, which can be used as a suitable preparation method for this material.KEYWORDS: Alkali-activated slagfibre reinforcementhot-press mouldingmechanical propertiesporositybulk density Disclosure statementNo potential conflict of interest was reported by the author(s).","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136112763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ABSTRACTA viable material to address oil pollution in water is the super wetting surface, which is accessible to realise the separation of oil and water. According to Young’s equation, hydrophobic/oleophilic materials are theoretically simple to realise and have a wide range of applications. The hydrophobic/oleophilic membrane, however, has a poor separating effect on the mixture in which the oil has a lower density than water. Hence, to optimise the oil/water separation performance, hydrophilic modified titanium dioxide particles were introduced to a novel porous superhydrophilic/oleophobic substrate fabricated by 3D printing technology in this work. The contact angle of n-hexadecane on the membrane surface was about 130°, which was an oleophobic surface. The oil/water separation efficiency of the 0.7 mm thick oleophobic membrane was over 98% and the penetration flux was up to 11,191 L m−2 h−1, indicating that the membranes prepared in this work might be used in high-flux oil/water separation applications. This study provides an efficient, simple, and reliable method for preparing oil/water separation materials with 3D printing technology, and may have broader significance among the academic and industry communities.KEYWORDS: 3D printingsuperhydrophilic/oleophobic membraneoil/water separationhydrophilic modificationporous structure AcknowledgementsWe would like to thank the Analytical & Testing Center of Northwestern Polytechnical University for SEM and TEM.Disclosure statementNo potential conflict of interest was reported by the author(s).Declaration of competing interestThe authors declare that they have no known competing financial interests or personal relations that could have appeared to influence the work reported in this paper.Additional informationFundingThis work was financially supported by the Fundamental Research Funds for the Central Universities [grant number 3102019PJ008 and 3102018JCC002]; National Key Research and Development Program of China [grant number 2021YFB3701500]; National Natural Science Foundation of China [grant number 52072306].
解决水中油类污染的可行材料是可实现油水分离的超润湿表面。根据杨氏方程,疏水/亲油材料理论上易于实现,具有广泛的应用范围。然而,疏水/亲油膜对油密度低于水的混合物分离效果较差。因此,为了优化油水分离性能,本研究将亲水改性二氧化钛颗粒引入到3D打印技术制备的新型多孔超亲水/疏油基板中。正十六烷与膜表面的接触角约为130°,为疏油表面。0.7 mm厚的疏油膜的油水分离效率可达98%以上,渗透通量可达11191 L m−2 h−1,表明所制备的膜可用于高通量油水分离。本研究为利用3D打印技术制备油水分离材料提供了一种高效、简单、可靠的方法,在学术界和工业界可能具有更广泛的意义。关键词:3D打印;超亲水/疏油膜;油水分离;亲水改性;披露声明作者未报告潜在的利益冲突。竞争利益声明作者声明,他们没有已知的竞争经济利益或个人关系,可能会影响本文所报道的工作。经费资助:中央高校基本科研业务费专项资金[批准号:3102019PJ008和3102018JCC002];国家重点研发计划项目[批准号2021YFB3701500];国家自然科学基金项目[批准号52072306]。
{"title":"3D-printed porous Al <sub>2</sub> O <sub>3</sub> membrane coated with hydrophilic modified titanium dioxide particles for large-flux oil/water separation","authors":"Hao Li, Hui Mei, Zhipeng Jin, Longkai Pan, Laifei Cheng, Litong Zhang","doi":"10.1080/17436753.2023.2265203","DOIUrl":"https://doi.org/10.1080/17436753.2023.2265203","url":null,"abstract":"ABSTRACTA viable material to address oil pollution in water is the super wetting surface, which is accessible to realise the separation of oil and water. According to Young’s equation, hydrophobic/oleophilic materials are theoretically simple to realise and have a wide range of applications. The hydrophobic/oleophilic membrane, however, has a poor separating effect on the mixture in which the oil has a lower density than water. Hence, to optimise the oil/water separation performance, hydrophilic modified titanium dioxide particles were introduced to a novel porous superhydrophilic/oleophobic substrate fabricated by 3D printing technology in this work. The contact angle of n-hexadecane on the membrane surface was about 130°, which was an oleophobic surface. The oil/water separation efficiency of the 0.7 mm thick oleophobic membrane was over 98% and the penetration flux was up to 11,191 L m−2 h−1, indicating that the membranes prepared in this work might be used in high-flux oil/water separation applications. This study provides an efficient, simple, and reliable method for preparing oil/water separation materials with 3D printing technology, and may have broader significance among the academic and industry communities.KEYWORDS: 3D printingsuperhydrophilic/oleophobic membraneoil/water separationhydrophilic modificationporous structure AcknowledgementsWe would like to thank the Analytical & Testing Center of Northwestern Polytechnical University for SEM and TEM.Disclosure statementNo potential conflict of interest was reported by the author(s).Declaration of competing interestThe authors declare that they have no known competing financial interests or personal relations that could have appeared to influence the work reported in this paper.Additional informationFundingThis work was financially supported by the Fundamental Research Funds for the Central Universities [grant number 3102019PJ008 and 3102018JCC002]; National Key Research and Development Program of China [grant number 2021YFB3701500]; National Natural Science Foundation of China [grant number 52072306].","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"11 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136013534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ABSTRACTIn this paper, the municipal sludge was used as the main raw material to prepare a kind of porous ceramsite. The porous ceramsite composition of 50 wt-% of municipal sludge, 10 wt-% of municipal solid waste incineration bottom ash, 45 wt-% of waste glass powders, sintering temperature of 900°C and holding duration of 30 min. The best of the ceramsite synthesised had 1-h water absorption capacity of 51.53%, apparent porosity of 64.14% and pore volume 0.671 mL g−1. During the sintering process, the waste glass powders generated a large amount of liquid phase, wrapt the gas produced by organic matter, and formed a porous structure inside the ceramic particles. At the same time, the silica and aluminium were combined to form Kyanite, which constitutes the basic skeleton of the ceramic particles showing a certain strength. Besides, silicon oxide and calcium silicate generated Wollastonite improving the corrosion resistance of ceramic particles as well. The adsorption capacity of the prepared porous ceramsite modified by acid combined with sodium citrate was 3.1 mg g−1 using the prepared porous ceramsite as substrate. The adsorption kinetics of ammonia nitrogen by porous ceramics conforms to the quasi-second-order kinetic model, and the adsorption isotherm model conforms to the Langmuir model. The findings lay a theoretical foundation for the integration of resource utilisation of solid waste and later application.KEYWORDS: Municipal sludgeapparent porosityporous ceramsitepore structureresource recovery Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis study was funded by the National Key Research and Development Program of China [grant number 2019YFC1904605].
摘要本文以城市污泥为主要原料,制备了一种多孔陶粒。以50 wt-%的城市污泥、10 wt-%的城市生活垃圾焚烧底灰、45 wt-%的废玻璃粉为原料,烧结温度为900℃,保温时间为30 min,合成的最佳陶粒1 h吸水率为51.53%,表观孔隙率为64.14%,孔隙体积为0.671 mL g - 1。在烧结过程中,废玻璃粉产生大量液相,包裹有机物产生的气体,在陶瓷颗粒内部形成多孔结构。同时,二氧化硅与铝结合形成蓝晶石,蓝晶石构成了具有一定强度的陶瓷颗粒的基本骨架。此外,氧化硅和硅酸钙生成硅灰石也提高了陶瓷颗粒的耐腐蚀性。以制备的多孔陶粒为底物,酸与柠檬酸钠复合改性的多孔陶粒的吸附量为3.1 mg g−1。多孔陶瓷对氨氮的吸附动力学符合准二级动力学模型,吸附等温线模型符合Langmuir模型。研究结果为固体废物资源化利用与后期应用的整合提供了理论基础。关键词:城市污泥;表观孔隙率;多孔陶粒;本研究由国家重点研发计划资助[批准号:2019YFC1904605]。
{"title":"Preparation of porous ceramsite from municipal sludge and its structure characteristics","authors":"Junping Meng, Zhenxiao Cui, Chandrasekar Srinivasakannan, Xinhui Duan, Jinsheng Liang, Guangyan Tian, Zhiling Yang, Xiangying Wei","doi":"10.1080/17436753.2023.2265192","DOIUrl":"https://doi.org/10.1080/17436753.2023.2265192","url":null,"abstract":"ABSTRACTIn this paper, the municipal sludge was used as the main raw material to prepare a kind of porous ceramsite. The porous ceramsite composition of 50 wt-% of municipal sludge, 10 wt-% of municipal solid waste incineration bottom ash, 45 wt-% of waste glass powders, sintering temperature of 900°C and holding duration of 30 min. The best of the ceramsite synthesised had 1-h water absorption capacity of 51.53%, apparent porosity of 64.14% and pore volume 0.671 mL g−1. During the sintering process, the waste glass powders generated a large amount of liquid phase, wrapt the gas produced by organic matter, and formed a porous structure inside the ceramic particles. At the same time, the silica and aluminium were combined to form Kyanite, which constitutes the basic skeleton of the ceramic particles showing a certain strength. Besides, silicon oxide and calcium silicate generated Wollastonite improving the corrosion resistance of ceramic particles as well. The adsorption capacity of the prepared porous ceramsite modified by acid combined with sodium citrate was 3.1 mg g−1 using the prepared porous ceramsite as substrate. The adsorption kinetics of ammonia nitrogen by porous ceramics conforms to the quasi-second-order kinetic model, and the adsorption isotherm model conforms to the Langmuir model. The findings lay a theoretical foundation for the integration of resource utilisation of solid waste and later application.KEYWORDS: Municipal sludgeapparent porosityporous ceramsitepore structureresource recovery Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis study was funded by the National Key Research and Development Program of China [grant number 2019YFC1904605].","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"814 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136098138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-10DOI: 10.1080/17436753.2023.2265204
Y. Belrhiti, P. Kerth, M. McGilvray, L. Vandeperre
{"title":"Gel-casting for manufacturing porous alumina ceramics with complex shapes for transpiration cooling","authors":"Y. Belrhiti, P. Kerth, M. McGilvray, L. Vandeperre","doi":"10.1080/17436753.2023.2265204","DOIUrl":"https://doi.org/10.1080/17436753.2023.2265204","url":null,"abstract":"","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"358 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136293464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-05DOI: 10.1080/17436753.2023.2265193
Amirreza Sazvar, Hossein Sarpoolaky, Mohammad Golmohammad
ABSTRACTFlash sintering arouses the interest since high-density ceramics can be obtained at shorter dwell times and lower temperatures than conventional sintering. In this study, the cubic garnet Li6.25Al0.25La3Zr2O12 (Al-LLZO) was successfully synthesised by the solid-state method. The powders were uniaxially pressed and were subjected to flash sintering at 850°C in a tube furnace under a DC bias using various current densities. It is evidenced that control of the flash electric current is a crucial factor for densification of Al-LLZO. The sample sintered in 50 V cm−1 and 200 mA mm−2 showed a cubic LLZO, 94 ± 0.4% relative density, 0.37 mS cm−1 total ionic conductivity and 0.32 eV activation energy. In addition, it was demonstrated that increasing the current density had a considerable impact on the relative density. This outstanding ionic conductivity might be due to the lower lithium loss and higher density as a result of flash sintering method applied.KEYWORDS: GarnetLLZOlithium lossflash sinteringsolid-state batteries Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work is based upon research funded by Iran National Science Foundation (INSF) under project No. 4000823.
与传统烧结相比,闪速烧结可以在更短的停留时间和更低的温度下获得高密度陶瓷,因此引起了人们的关注。本研究采用固相法成功合成了立方石榴石Li6.25Al0.25La3Zr2O12 (Al-LLZO)。粉末被单轴压制,并在850°C的管状炉中在直流偏置下使用不同的电流密度进行闪烧。结果表明,对闪蒸电流的控制是Al-LLZO致密化的关键因素。在50 V cm−1和200 mA mm−2条件下烧结的样品具有立方LLZO,相对密度为94±0.4%,总离子电导率为0.37 mS cm−1,活化能为0.32 eV。此外,研究还表明,增加电流密度对相对密度有相当大的影响。这种优异的离子导电性可能是由于采用了闪速烧结方法,锂损失更低,密度更高。关键词:garnetllzlithium lossflash sintering固态电池披露声明作者未报告潜在的利益冲突。本工作基于伊朗国家科学基金会(INSF)项目资助的研究,项目编号4000823。
{"title":"Enhanced densification and ionic conductivity of LLZO by flash sintering","authors":"Amirreza Sazvar, Hossein Sarpoolaky, Mohammad Golmohammad","doi":"10.1080/17436753.2023.2265193","DOIUrl":"https://doi.org/10.1080/17436753.2023.2265193","url":null,"abstract":"ABSTRACTFlash sintering arouses the interest since high-density ceramics can be obtained at shorter dwell times and lower temperatures than conventional sintering. In this study, the cubic garnet Li6.25Al0.25La3Zr2O12 (Al-LLZO) was successfully synthesised by the solid-state method. The powders were uniaxially pressed and were subjected to flash sintering at 850°C in a tube furnace under a DC bias using various current densities. It is evidenced that control of the flash electric current is a crucial factor for densification of Al-LLZO. The sample sintered in 50 V cm−1 and 200 mA mm−2 showed a cubic LLZO, 94 ± 0.4% relative density, 0.37 mS cm−1 total ionic conductivity and 0.32 eV activation energy. In addition, it was demonstrated that increasing the current density had a considerable impact on the relative density. This outstanding ionic conductivity might be due to the lower lithium loss and higher density as a result of flash sintering method applied.KEYWORDS: GarnetLLZOlithium lossflash sinteringsolid-state batteries Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work is based upon research funded by Iran National Science Foundation (INSF) under project No. 4000823.","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"68 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135480732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-03DOI: 10.1080/17436753.2023.2265191
Biswajit Baruah, Rahul Anand, Shantanu K. Behera
ABSTRACTIn the present work, the effect of Zr-doping on the sintering, microstructure development, and mechanical properties of polycrystalline Al2O3 was studied. Dopant concentrations of 830 and 2070ppm cationic ratio of Zr in Al2O3 corresponding to 2000 and 5000 wt. ppm of ZrO2 in Al2O3, respectively, were used. The sintering schedule of undoped as well as Zr-doped Al2O3 samples was optimised following a series of precoarsening experiments. The Zr-doped Al2O3 ceramics exhibited controlled grain size and improved density. Upon increasing the Zr-dopant concentration from 830 cat. ppm to 2070 cat. ppm. Zr-doped Al2O3 ceramics having a refined microstructure with a homogeneous distribution of controllably grown ZrO2 in Al2O3 matrix was obtained. Microhardness of the Zr-doped samples showed negligible dependence with Zr-doping, whereas mechanical strength was found to improve with it. The improvement in strength was attributed to the combined effect of improved sinter density, microstructural refinement, and grain-boundary strengthening.KEYWORDS: Al2O3ZrO2sinteringmicrostructurehardnessstrength AcknowledgementThe authors gratefully acknowledge the support of Mr Sarbapi Mukherjee, Almatis India, for the supply of alumina powders for this work.Disclosure statementNo potential conflict of interest was reported by the author(s).Data availability statementThe authors declare that the data supporting the findings of this study and supporting documents will be made available on reasonable request.
{"title":"Sintering, microstructure, and mechanical properties of ZrO <sub>2</sub> -doped Al <sub>2</sub> O <sub>3</sub>","authors":"Biswajit Baruah, Rahul Anand, Shantanu K. Behera","doi":"10.1080/17436753.2023.2265191","DOIUrl":"https://doi.org/10.1080/17436753.2023.2265191","url":null,"abstract":"ABSTRACTIn the present work, the effect of Zr-doping on the sintering, microstructure development, and mechanical properties of polycrystalline Al2O3 was studied. Dopant concentrations of 830 and 2070ppm cationic ratio of Zr in Al2O3 corresponding to 2000 and 5000 wt. ppm of ZrO2 in Al2O3, respectively, were used. The sintering schedule of undoped as well as Zr-doped Al2O3 samples was optimised following a series of precoarsening experiments. The Zr-doped Al2O3 ceramics exhibited controlled grain size and improved density. Upon increasing the Zr-dopant concentration from 830 cat. ppm to 2070 cat. ppm. Zr-doped Al2O3 ceramics having a refined microstructure with a homogeneous distribution of controllably grown ZrO2 in Al2O3 matrix was obtained. Microhardness of the Zr-doped samples showed negligible dependence with Zr-doping, whereas mechanical strength was found to improve with it. The improvement in strength was attributed to the combined effect of improved sinter density, microstructural refinement, and grain-boundary strengthening.KEYWORDS: Al2O3ZrO2sinteringmicrostructurehardnessstrength AcknowledgementThe authors gratefully acknowledge the support of Mr Sarbapi Mukherjee, Almatis India, for the supply of alumina powders for this work.Disclosure statementNo potential conflict of interest was reported by the author(s).Data availability statementThe authors declare that the data supporting the findings of this study and supporting documents will be made available on reasonable request.","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"64 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135744615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-28DOI: 10.1080/17436753.2023.2262277
M. Lugovy, M. Bondar, N. Orlovskaya, M.J. Reece, T. Graule, G. Blugan
ABSTRACTAnalysis of the creep behaviour of ferroelastic LaCoO3 and La0.8Ca0.2CoO3 perovskites at room and elevated temperatures is presented. It was found that the creep behaviour of the two LaCoO3-based compositions was determined by ferroelastic and non-ferroelastic creep strain components. Both the ferroelastic and non-ferroelastic creep strain components showed a strong dependence on bending stress. The ferroelastic creep depends on the coercive stress in LaCoO3 based perovskites, which in turn is a function of temperature. In addition, the ferroelastic creep strain has the same sign as the total strain of cobaltites upon loading, however, it has the opposite sign relative to the total strain upon unloading. Non-ferroelastic creep was negligibly small in both perovskites at low temperatures, however, its contribution toward the total creep increased significantly at elevated temperature. Non-ferroelastic creep strain has the same sign as the total strain both upon loading and upon unloading.KEYWORDS: Perovskiteferroelastic creepnon-ferroelastic creepcoercive stressbending AcknowledgementsDr. Lugovy’s work at Empa was supported by Swiss National Science Foundation via the Scientific Exchanges grants (proposal MENDEL). It is also important to highlight the circumstances in which the paper was prepared. The authors jointly worked to prepare results during 2021 and 2022, when NO visited Ukraine as a Visiting Professor. She has to run away from Kyiv early morning February 24th, 2022, when Russian terrorists started bombing Ukraine. NO journey to the western Ukrainian border with Poland took 4 days with sleepless nights by bus, but by February 28th, 2022 NO was able to safely arrive in Poland and shortly depart back home to the US. However, two of her colleagues, ML and MB remained in Ukraine and decided to continue working on the paper using Zoom calls and email exchanges. In March 2022, loud air ride siren could be heard during Zoom calls in Kyiv along with sounds of the explosions and nearby artillery. Nevertheless the paper was almost finished by the end of March 2022 and now it is ready to be presented to the attention of the scientific community.Disclosure statementNo potential conflict of interest was reported by the author(s).
{"title":"Time dependent deformation of LaCoO <sub>3</sub> based perovskites at different temperatures: ferroelastic and non-ferroelastic creep behaviour","authors":"M. Lugovy, M. Bondar, N. Orlovskaya, M.J. Reece, T. Graule, G. Blugan","doi":"10.1080/17436753.2023.2262277","DOIUrl":"https://doi.org/10.1080/17436753.2023.2262277","url":null,"abstract":"ABSTRACTAnalysis of the creep behaviour of ferroelastic LaCoO3 and La0.8Ca0.2CoO3 perovskites at room and elevated temperatures is presented. It was found that the creep behaviour of the two LaCoO3-based compositions was determined by ferroelastic and non-ferroelastic creep strain components. Both the ferroelastic and non-ferroelastic creep strain components showed a strong dependence on bending stress. The ferroelastic creep depends on the coercive stress in LaCoO3 based perovskites, which in turn is a function of temperature. In addition, the ferroelastic creep strain has the same sign as the total strain of cobaltites upon loading, however, it has the opposite sign relative to the total strain upon unloading. Non-ferroelastic creep was negligibly small in both perovskites at low temperatures, however, its contribution toward the total creep increased significantly at elevated temperature. Non-ferroelastic creep strain has the same sign as the total strain both upon loading and upon unloading.KEYWORDS: Perovskiteferroelastic creepnon-ferroelastic creepcoercive stressbending AcknowledgementsDr. Lugovy’s work at Empa was supported by Swiss National Science Foundation via the Scientific Exchanges grants (proposal MENDEL). It is also important to highlight the circumstances in which the paper was prepared. The authors jointly worked to prepare results during 2021 and 2022, when NO visited Ukraine as a Visiting Professor. She has to run away from Kyiv early morning February 24th, 2022, when Russian terrorists started bombing Ukraine. NO journey to the western Ukrainian border with Poland took 4 days with sleepless nights by bus, but by February 28th, 2022 NO was able to safely arrive in Poland and shortly depart back home to the US. However, two of her colleagues, ML and MB remained in Ukraine and decided to continue working on the paper using Zoom calls and email exchanges. In March 2022, loud air ride siren could be heard during Zoom calls in Kyiv along with sounds of the explosions and nearby artillery. Nevertheless the paper was almost finished by the end of March 2022 and now it is ready to be presented to the attention of the scientific community.Disclosure statementNo potential conflict of interest was reported by the author(s).","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"21 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135387015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-22DOI: 10.1080/17436753.2023.2246270
Marek Grabowy, Agnieszka Wojteczko, Piotr Osada, Grzegorz Wiązania, Zbigniew Pędzich
ABSTRACTAn alumina-toughened zirconia (ATZ) material, fabricated using a procedure consisting of the common sintering of two different zirconia powders, was tested using the ball-on-disc method in a temperature range between room temperature and 400°C. Tetragonal zirconia balls were used as a counterpart. Two different types of microstructure were designed, one consisting of separated alumina inclusions in a zirconia matrix and another one which was a combination of two continuous phases, penetrating the whole volume of the composite. It was detected that at elevated temperatures both materials showed a distinct decrease in the wear rate. Composite with a low alumina content showed minimal wear rate at 300°C and composite with higher amount of alumina showed it at 400°C. There are some observations that this minimal wear rate result is connected with a pseudoplastic behaviour of a layer formed between co-operating elements of tribological pair. This layer is composed of the debris of both, sample and counterpart, and its behaviour during sliding is connected with the mean grain size of this debris which is correlated with the mean grain size of sintered material.KEYWORDS: Alumina toughened zirconiaTribologySliding wearBall-on-disc test Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThis work was supported by subvention of the Polish State Ministry of Education and Science for AGH University of Science and Technology under projects 16.16.160.557 and 16.16.130.942. Tribological investigations were performed in Laboratory of Tribology and Surface Engineering of Department of Machine Design and Technology of AGH University. Microstructural investigations were performed in Laboratory of Scanning Electron Microscopy and Microanalysis of Faculty of Materials Science and Ceramics of AGH University.
{"title":"Wear behaviour of alumina-toughened-zirconia composites with different phase arrangement under ball-on-flat tribological tests","authors":"Marek Grabowy, Agnieszka Wojteczko, Piotr Osada, Grzegorz Wiązania, Zbigniew Pędzich","doi":"10.1080/17436753.2023.2246270","DOIUrl":"https://doi.org/10.1080/17436753.2023.2246270","url":null,"abstract":"ABSTRACTAn alumina-toughened zirconia (ATZ) material, fabricated using a procedure consisting of the common sintering of two different zirconia powders, was tested using the ball-on-disc method in a temperature range between room temperature and 400°C. Tetragonal zirconia balls were used as a counterpart. Two different types of microstructure were designed, one consisting of separated alumina inclusions in a zirconia matrix and another one which was a combination of two continuous phases, penetrating the whole volume of the composite. It was detected that at elevated temperatures both materials showed a distinct decrease in the wear rate. Composite with a low alumina content showed minimal wear rate at 300°C and composite with higher amount of alumina showed it at 400°C. There are some observations that this minimal wear rate result is connected with a pseudoplastic behaviour of a layer formed between co-operating elements of tribological pair. This layer is composed of the debris of both, sample and counterpart, and its behaviour during sliding is connected with the mean grain size of this debris which is correlated with the mean grain size of sintered material.KEYWORDS: Alumina toughened zirconiaTribologySliding wearBall-on-disc test Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThis work was supported by subvention of the Polish State Ministry of Education and Science for AGH University of Science and Technology under projects 16.16.160.557 and 16.16.130.942. Tribological investigations were performed in Laboratory of Tribology and Surface Engineering of Department of Machine Design and Technology of AGH University. Microstructural investigations were performed in Laboratory of Scanning Electron Microscopy and Microanalysis of Faculty of Materials Science and Ceramics of AGH University.","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"57 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136060105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-14DOI: 10.1080/17436753.2023.2238987
Tomas Grejtak, Jun Qu
ABSTRACTSteels are commonly used in high-performance demanding applications due to their favourable mechanical properties. Various surface engineering techniques have been developed for steels, among which chromizing is an affordable high-throughput case-hardenig process for improved surface hardness and wear resistance while retaining the substrate ductility and toughness. In this work, tribological testing along with nano- and micro-indentation and morphological and composional characterisation were used to understand the effects of the chromizing process on the AISI 1095 carbon steel, 52100 bearing steel and A2, D2 and M2 tool steels. The results of this study demonstrate that the chromizing treatment of low-cost 1095 and 52100 steels significantly improves their wear and hardness properties to a level comparable to the more costly tool steels. While chromizing also increased the hardness of the tool steels, it had little improvement on the wear resistance for the D2 and M2 tool steels.KEYWORDS: Case chromizingsteelabrasive wearnanoindentation AcknowledgementsThe authors would like to thank Jim Keiser from Oak Ridge National Laboratory (ORNL), Oyelayo O. Ajayi and George Fenske from Argonne National Laboratory for their thoughtful comments and insight, Briar Faulkner from Applied Thermal Coatings for conducting chromizing of the steel samples, and Brain Long and Caitlin Duggan from ORNL for sectioning and polishing the samples for morphological and nanoindentation studies. This research was sponsored by the Feedstock Conversion Interface Consortium (FCIC) of the Bioenergy Technologies Office, Office of Energy Efficiency and Renewable Energy, United States Department of Energy (DOE).Disclosure statementNo potential conflict of interest was reported by the authors.Author NoteThis manuscript has been authored by UT-Battelle, LLC under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid up, irrevocable, world-wide license to publish, or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan (http://energy.gov/downloads/doe-public-access-plan).Additional informationFundingThis work was supported by Office of Energy Efficiency and Renewable Energy: [Grant Number].
摘要钢因其良好的力学性能而被广泛用于高性能苛刻的应用中。各种表面工程技术已经被开发出来,其中铬化是一种经济实惠的高通量表面硬化工艺,可以在保持基体延展性和韧性的同时提高表面硬度和耐磨性。在这项工作中,摩擦学测试以及纳米和微压痕、形态和成分表征被用来了解铬化工艺对AISI 1095碳钢、52100轴承钢和A2、D2和M2工具钢的影响。本研究结果表明,低成本的1095和52100钢的铬化处理显著提高了它们的耐磨性能和硬度,达到了与更昂贵的工具钢相当的水平。铬化处理提高了工具钢的硬度,但对D2和M2工具钢的耐磨性没有明显改善。作者要感谢橡树岭国家实验室(ORNL)的Jim Keiser,阿贡国家实验室的Oyelayo O. Ajayi和George Fenske,感谢他们深思的评论和见解,感谢应用热涂层公司的Briar Faulkner对钢样品进行铬化处理,感谢ORNL的Brain Long和Caitlin Duggan对样品进行切片和抛光,用于形态学和纳米压痕研究。这项研究由美国能源部能源效率和可再生能源办公室生物能源技术办公室的原料转换接口联盟(FCIC)赞助。披露声明作者未报告潜在的利益冲突。作者说明:本手稿由UT-Battelle, LLC根据合同编号:DE-AC05-00OR22725与美国能源部。美国政府保留和出版商,通过接受文章的出版,承认美国政府保留非排他性的,付费的,不可撤销的,世界范围的许可,为美国政府的目的出版,或复制该手稿的出版形式,或允许其他人这样做。能源部将根据能源部公共访问计划(http://energy.gov/downloads/doe-public-access-plan).Additional)向公众提供这些由联邦政府资助的研究成果。这项工作由能源效率和可再生能源办公室支持:[授权号]。
{"title":"Improving mechanical properties of carbon and tool steels via chromizing","authors":"Tomas Grejtak, Jun Qu","doi":"10.1080/17436753.2023.2238987","DOIUrl":"https://doi.org/10.1080/17436753.2023.2238987","url":null,"abstract":"ABSTRACTSteels are commonly used in high-performance demanding applications due to their favourable mechanical properties. Various surface engineering techniques have been developed for steels, among which chromizing is an affordable high-throughput case-hardenig process for improved surface hardness and wear resistance while retaining the substrate ductility and toughness. In this work, tribological testing along with nano- and micro-indentation and morphological and composional characterisation were used to understand the effects of the chromizing process on the AISI 1095 carbon steel, 52100 bearing steel and A2, D2 and M2 tool steels. The results of this study demonstrate that the chromizing treatment of low-cost 1095 and 52100 steels significantly improves their wear and hardness properties to a level comparable to the more costly tool steels. While chromizing also increased the hardness of the tool steels, it had little improvement on the wear resistance for the D2 and M2 tool steels.KEYWORDS: Case chromizingsteelabrasive wearnanoindentation AcknowledgementsThe authors would like to thank Jim Keiser from Oak Ridge National Laboratory (ORNL), Oyelayo O. Ajayi and George Fenske from Argonne National Laboratory for their thoughtful comments and insight, Briar Faulkner from Applied Thermal Coatings for conducting chromizing of the steel samples, and Brain Long and Caitlin Duggan from ORNL for sectioning and polishing the samples for morphological and nanoindentation studies. This research was sponsored by the Feedstock Conversion Interface Consortium (FCIC) of the Bioenergy Technologies Office, Office of Energy Efficiency and Renewable Energy, United States Department of Energy (DOE).Disclosure statementNo potential conflict of interest was reported by the authors.Author NoteThis manuscript has been authored by UT-Battelle, LLC under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid up, irrevocable, world-wide license to publish, or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan (http://energy.gov/downloads/doe-public-access-plan).Additional informationFundingThis work was supported by Office of Energy Efficiency and Renewable Energy: [Grant Number].","PeriodicalId":7224,"journal":{"name":"Advances in Applied Ceramics","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134911403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}