L. Prabhu, R. Saravanan, A. Anderson, A. Senthilkumar, V. Aneesh, Avinash Malladi, A. Krishnan, Manaye Majora
The growth of polymer-based materials is becoming requisite in various industrial applications like energy storage, automobile, membrane, and orthopaedics, due to advantages over conventional metallic metal, such as less weight, superior corrosion resistance, ease of the process, and good chemical stability. The current research work is to synthesize the polysulfone (PSU) nanocomposite consisting of 2 wt%, 4 wt%, and 6 wt% of graphene nanoplatelets (GNP) and 3 wt%, 5 wt%, and 7 wt% of carbon nanotube (CNT) nanofillers via cast solution technique. The synthesized composite microstructural, heat storage, and thermal adsorption characteristics are studied. The scanning electron microscopic examination for both PSU/GNP and PSU/CNT composites illustrates good interfacial bonded PSU structure with the uniform distribution of GNP and CNT nanofillers. Due to the effect of percolation, the thermal adsorption characteristics and heat storage of PSU nanocomposite were increased progressively with the additions of GNP/CNT. The PSU composite contained 6 wt% GNP and 7 wt% CNT nanofillers, which showed effective thermal conductivity of 1.23 W/m.K and 1.52 W/m.K, which is 1.7 times larger than the unreinforced polysulfone. Interestingly, the increased temperature of the glass transition decreased the thermal expansion of the nanocomposite.
{"title":"Synthesis, Thermal Adsorption, and Energy Storage Calibration of Polysulfone Nanocomposite Developed with GNP/CNT Nanofillers","authors":"L. Prabhu, R. Saravanan, A. Anderson, A. Senthilkumar, V. Aneesh, Avinash Malladi, A. Krishnan, Manaye Majora","doi":"10.1155/2023/7376542","DOIUrl":"https://doi.org/10.1155/2023/7376542","url":null,"abstract":"The growth of polymer-based materials is becoming requisite in various industrial applications like energy storage, automobile, membrane, and orthopaedics, due to advantages over conventional metallic metal, such as less weight, superior corrosion resistance, ease of the process, and good chemical stability. The current research work is to synthesize the polysulfone (PSU) nanocomposite consisting of 2 wt%, 4 wt%, and 6 wt% of graphene nanoplatelets (GNP) and 3 wt%, 5 wt%, and 7 wt% of carbon nanotube (CNT) nanofillers via cast solution technique. The synthesized composite microstructural, heat storage, and thermal adsorption characteristics are studied. The scanning electron microscopic examination for both PSU/GNP and PSU/CNT composites illustrates good interfacial bonded PSU structure with the uniform distribution of GNP and CNT nanofillers. Due to the effect of percolation, the thermal adsorption characteristics and heat storage of PSU nanocomposite were increased progressively with the additions of GNP/CNT. The PSU composite contained 6 wt% GNP and 7 wt% CNT nanofillers, which showed effective thermal conductivity of 1.23 W/m.K and 1.52 W/m.K, which is 1.7 times larger than the unreinforced polysulfone. Interestingly, the increased temperature of the glass transition decreased the thermal expansion of the nanocomposite.","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79230717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wengang Wang, Lei Wang, Ming Zhang, Bo Yu, Xiaoning Li, Han Yan
Disagreements over various unanswered questions about contribution of the adsorption process and functional groups on dye adsorption still exist. The main aim of this research was to evaluate the contributions of physical hole structure, hydrogen bond, and electrostatic attraction on dye adsorption. Three ideal representatives, namely, a sponge with porous structure, P(AM) containing -CONH2 groups, and P(AANa/AM) containing -COONa groups, were chosen to evaluate the above contributions. The methylene blue (MB) removal rates of these three products were compared through individual experiments. The results revealed that physical hole structure did not play a role in decreasing dye concentration. Hydrogen bond existed in dye adsorption but did not remarkably reduce dye concentration. The excellent removal results of P(AANa/AM) demonstrated that electrostatic attraction was critical in enriching dye contaminants from the solution into solid adsorbent. The results could provide insights into the dye adsorption mechanisms for further research.
{"title":"Contribution Evaluation of Physical Hole Structure, Hydrogen Bond, and Electrostatic Attraction on Dye Adsorption through Individual Experiments","authors":"Wengang Wang, Lei Wang, Ming Zhang, Bo Yu, Xiaoning Li, Han Yan","doi":"10.1155/2023/4596086","DOIUrl":"https://doi.org/10.1155/2023/4596086","url":null,"abstract":"Disagreements over various unanswered questions about contribution of the adsorption process and functional groups on dye adsorption still exist. The main aim of this research was to evaluate the contributions of physical hole structure, hydrogen bond, and electrostatic attraction on dye adsorption. Three ideal representatives, namely, a sponge with porous structure, P(AM) containing -CONH2 groups, and P(AANa/AM) containing -COONa groups, were chosen to evaluate the above contributions. The methylene blue (MB) removal rates of these three products were compared through individual experiments. The results revealed that physical hole structure did not play a role in decreasing dye concentration. Hydrogen bond existed in dye adsorption but did not remarkably reduce dye concentration. The excellent removal results of P(AANa/AM) demonstrated that electrostatic attraction was critical in enriching dye contaminants from the solution into solid adsorbent. The results could provide insights into the dye adsorption mechanisms for further research.","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73556265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
F. M. Anjalin, A. Krishnan, G. Arunkumar, K. Raju, M. Vivekanandan, S. Somasundaram, T. Thirugnanasambandham, Elangomathavan Ramaraj
Inorganic-based ceramic reinforcements are promising superior thermal behaviour and are lightweight and developed with aluminium alloy matrix for automobile applications. The AA6061 alloy nanocomposite containing 0 wt%, 4 wt%, 8 wt%, and 12 wt% of silicon nitride nanoparticles(50 nm) was synthesized by stir cast. The influences of thermal adsorption on silicon nitride (nano) additions, density, thermal response, hardness, and wear characteristics of AA6061 matrix nanocomposites are studied. Based on the rule of mixture, the density of nanocomposites is evaluated. The differential thermal and thermogravimetric analysis techniques are used to find the thermal response nanocomposite. The differential scanning calorimeter is used to find the heat flow between 400°C and 700°C. The micro Vickers hardness and wear characteristics of AA6061 nanocomposite were experimentally investigated by ASTM E384 and ASTM G99-05 standards. The adsorption of inorganic nanosilicon nitride particles (12 wt%) in AA6061 alloy showed a decreased mass loss with increased temperatures 0° to 700°C. The differential thermal analysis of nanocomposite reveals the transformation of solid-to-liquid phase under high temperature (528°C).
{"title":"Inorganic Adsorption on Thermal Response and Wear Properties of Nanosilicon Nitride-Developed AA6061 Alloy Nanocomposite","authors":"F. M. Anjalin, A. Krishnan, G. Arunkumar, K. Raju, M. Vivekanandan, S. Somasundaram, T. Thirugnanasambandham, Elangomathavan Ramaraj","doi":"10.1155/2023/8468644","DOIUrl":"https://doi.org/10.1155/2023/8468644","url":null,"abstract":"Inorganic-based ceramic reinforcements are promising superior thermal behaviour and are lightweight and developed with aluminium alloy matrix for automobile applications. The AA6061 alloy nanocomposite containing 0 wt%, 4 wt%, 8 wt%, and 12 wt% of silicon nitride nanoparticles(50 nm) was synthesized by stir cast. The influences of thermal adsorption on silicon nitride (nano) additions, density, thermal response, hardness, and wear characteristics of AA6061 matrix nanocomposites are studied. Based on the rule of mixture, the density of nanocomposites is evaluated. The differential thermal and thermogravimetric analysis techniques are used to find the thermal response nanocomposite. The differential scanning calorimeter is used to find the heat flow between 400°C and 700°C. The micro Vickers hardness and wear characteristics of AA6061 nanocomposite were experimentally investigated by ASTM E384 and ASTM G99-05 standards. The adsorption of inorganic nanosilicon nitride particles (12 wt%) in AA6061 alloy showed a decreased mass loss with increased temperatures 0° to 700°C. The differential thermal analysis of nanocomposite reveals the transformation of solid-to-liquid phase under high temperature (528°C).","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84989289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. A. Pinedo-Torres, A. Bonilla-Petriciolet, M. E. García-Arreola, Yenetzi Villagrana-Pacheco, Ana G. Castañeda-Miranda, M. S. Berber-Mendoza
The adsorption of As(V), Pb(II), Cd(II), and Cr(III) ions from aqueous solutions on natural and modified chabazite was studied. The functionalization of chabazite was performed via a protonation and calcination with the aim of generating Lewis acid sites to improve its anion exchange properties. The surface and physicochemical properties of both adsorbents were studied and compared. The adsorption isotherms of tested heavy metal ions were quantified and modeled to identify the best isotherm equation. Steric parameters for the adsorption of these ions were also calculated with a monolayer statistical physics model. Natural chabazite showed the maximum adsorption capacity for Pb(II), while the modified zeolite improved its As(V) properties in 79%. These results showed that the modified zeolite was able to remove both cations and anions from aqueous solution. The application of this functionalized chabazite can be extended for the removal of other anionic pollutants from water, thus opening the possibility of preparing new adsorbents with tailored properties for water treatment.
{"title":"Adsorption of Arsenic, Lead, Cadmium, and Chromium Ions from Aqueous Solution Using a Protonated Chabazite: Preparation, Characterization, and Removal Mechanism","authors":"L. A. Pinedo-Torres, A. Bonilla-Petriciolet, M. E. García-Arreola, Yenetzi Villagrana-Pacheco, Ana G. Castañeda-Miranda, M. S. Berber-Mendoza","doi":"10.1155/2023/2018121","DOIUrl":"https://doi.org/10.1155/2023/2018121","url":null,"abstract":"The adsorption of As(V), Pb(II), Cd(II), and Cr(III) ions from aqueous solutions on natural and modified chabazite was studied. The functionalization of chabazite was performed via a protonation and calcination with the aim of generating Lewis acid sites to improve its anion exchange properties. The surface and physicochemical properties of both adsorbents were studied and compared. The adsorption isotherms of tested heavy metal ions were quantified and modeled to identify the best isotherm equation. Steric parameters for the adsorption of these ions were also calculated with a monolayer statistical physics model. Natural chabazite showed the maximum adsorption capacity for Pb(II), while the modified zeolite improved its As(V) properties in 79%. These results showed that the modified zeolite was able to remove both cations and anions from aqueous solution. The application of this functionalized chabazite can be extended for the removal of other anionic pollutants from water, thus opening the possibility of preparing new adsorbents with tailored properties for water treatment.","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75850501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Amari, V. Yadav, S. K. Pathan, Bijendra Singh, H. Osman, N. Choudhary, K. M. Khedher, Anup Basnet
The disposal of biological waste into water bodies is a major global concern as it leads to water pollution resulting in the loss of plenty of revenue in the cleaning of water bodies. Here, in the present research work, sacred flowers were collected, segregated, sun-dried, and powdered. The dried floral powders (marigold and rose) were characterized by field emission scanning electron microscopy (FESEM), electron diffraction spectroscopy (EDS), Fourier transforms infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The microscopy revealed the irregular spherical shape of the sheet-like structure whose size varies in microns. The EDS revealed the elemental composition which was dominated by mainly carbon and oxygen. The XRD shows the presence of carbon (10-25ɵ) in the amorphous form and the absence of any crystalline phase in the biosorbents. The FT-IR showed peaks that conformed to the presence of functional groups like -OH and a carbonyl group. The dried powders were used as an economical and eco-friendly biosorbent for the removal of methyl red (MR) dye from the aqueous solutions by batch adsorption study. After 60 minutes of contact time, the marigold powder (MGP) and rose petal powder (RPP) showed decolorization of 61.16% and 56.08% for 2 ppm of MR dye. The kinetic revealed that the dye removal reaction does not follow the pseudo-first-order as well as the pseudo-second-order. The utilization of such waste-based biosorbents will minimize solid waste and also will provide an economical biosorbent for the removal of environmental pollutants.
{"title":"Remediation of Methyl Red Dye from Aqueous Solutions by Using Biosorbents Developed from Floral Waste","authors":"A. Amari, V. Yadav, S. K. Pathan, Bijendra Singh, H. Osman, N. Choudhary, K. M. Khedher, Anup Basnet","doi":"10.1155/2023/1532660","DOIUrl":"https://doi.org/10.1155/2023/1532660","url":null,"abstract":"The disposal of biological waste into water bodies is a major global concern as it leads to water pollution resulting in the loss of plenty of revenue in the cleaning of water bodies. Here, in the present research work, sacred flowers were collected, segregated, sun-dried, and powdered. The dried floral powders (marigold and rose) were characterized by field emission scanning electron microscopy (FESEM), electron diffraction spectroscopy (EDS), Fourier transforms infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The microscopy revealed the irregular spherical shape of the sheet-like structure whose size varies in microns. The EDS revealed the elemental composition which was dominated by mainly carbon and oxygen. The XRD shows the presence of carbon (10-25ɵ) in the amorphous form and the absence of any crystalline phase in the biosorbents. The FT-IR showed peaks that conformed to the presence of functional groups like -OH and a carbonyl group. The dried powders were used as an economical and eco-friendly biosorbent for the removal of methyl red (MR) dye from the aqueous solutions by batch adsorption study. After 60 minutes of contact time, the marigold powder (MGP) and rose petal powder (RPP) showed decolorization of 61.16% and 56.08% for 2 ppm of MR dye. The kinetic revealed that the dye removal reaction does not follow the pseudo-first-order as well as the pseudo-second-order. The utilization of such waste-based biosorbents will minimize solid waste and also will provide an economical biosorbent for the removal of environmental pollutants.","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79952106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. H. Sosa Lissarrague, S. Alshehri, Abdullah Alsalhi, V. Lassalle, Ignacio López Corral
The presence of heavy metals in wastewater, such as Ni, Pb, Cd, V, Cr, and Cu, is a serious environmental problem. This kind of inorganic pollutant is not biodegradable for several years, and its harmful effect is cumulative. Recently, semiconductor nanomaterials based on metal oxides have gained interest due to their efficiency in the removal of heavy metals from contaminated water, by inducing photocatalytic ion reduction when they absorb light of the appropriate wavelength. The most commonly applied semiconductor oxides for these purposes are titanium oxide (TiO2), zinc oxide (ZnO), and binary nanomaterials composed of both types of oxides. The main purpose of this work is to critically analyse the existent literature concerning this topic focusing specially in the most important factors affecting the adsorption or photocatalytic capacities of this type of nanomaterials. In particular, photocatalytic activity is altered by various factors, such as proportion of polymorphs, synthesis method, surface area, concentration of defects and particle size, among others. After a survey of the actual literature, it was found that, although these metal oxides have low absorption capacity for visible light, it is possible to obtain an acceptable heavy metal reduction performance by sensitization with dyes, doping with metallic or nonmetallic atoms, introduction of defects, or the coupling of two or more semiconductors.
{"title":"Heavy Metal Removal from Aqueous Effluents by TiO2 and ZnO Nanomaterials","authors":"M. H. Sosa Lissarrague, S. Alshehri, Abdullah Alsalhi, V. Lassalle, Ignacio López Corral","doi":"10.1155/2023/2728305","DOIUrl":"https://doi.org/10.1155/2023/2728305","url":null,"abstract":"The presence of heavy metals in wastewater, such as Ni, Pb, Cd, V, Cr, and Cu, is a serious environmental problem. This kind of inorganic pollutant is not biodegradable for several years, and its harmful effect is cumulative. Recently, semiconductor nanomaterials based on metal oxides have gained interest due to their efficiency in the removal of heavy metals from contaminated water, by inducing photocatalytic ion reduction when they absorb light of the appropriate wavelength. The most commonly applied semiconductor oxides for these purposes are titanium oxide (TiO2), zinc oxide (ZnO), and binary nanomaterials composed of both types of oxides. The main purpose of this work is to critically analyse the existent literature concerning this topic focusing specially in the most important factors affecting the adsorption or photocatalytic capacities of this type of nanomaterials. In particular, photocatalytic activity is altered by various factors, such as proportion of polymorphs, synthesis method, surface area, concentration of defects and particle size, among others. After a survey of the actual literature, it was found that, although these metal oxides have low absorption capacity for visible light, it is possible to obtain an acceptable heavy metal reduction performance by sensitization with dyes, doping with metallic or nonmetallic atoms, introduction of defects, or the coupling of two or more semiconductors.","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81411229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
P. Karthikeyan, L. Prabhu, B. Bhuvaneswari, K. Yokesvaran, A. Jerin, R. Saravanan, S. Raghuvaran, Kassu Negash, Shubham Sharma
Exposure to advanced materials with unique thermomechanical characteristics has fulfilled the requirements of automotive, marine, and structural industries. The current research investigates the thermal adsorption and mechanical properties of epoxy composite enriched by basalt fiber via resin moulding technique with an applied pressure of 2 bar. Hydrophobic and dynamic analyzer tests developed composite’s adsorption storage and loss modulus with 10, 30, 50, 70, 90, and 110 thermal cycles under 18°C to 150°C. ASTM test standards evaluated the effect of the thermal cyclic process on mechanical properties. The composite contained 45 vol% basalt fiber with 90 thermal cycles and found higher adsorption storage modulus, elasticity, tensile strength, and flexural strength of 9200 GPa, 80 GPa, 229 MPa, and 398 MPa, respectively. The thermal adsorption loss modulus was limited by 12% on 90 thermal cycles at 150°C compared to 10 thermal cycles.
{"title":"Influences of Various Thermal Cyclic Behaviours on Thermo Adsorption/Mechanical Characteristics of Epoxy Composite Enriched with Basalt Fiber","authors":"P. Karthikeyan, L. Prabhu, B. Bhuvaneswari, K. Yokesvaran, A. Jerin, R. Saravanan, S. Raghuvaran, Kassu Negash, Shubham Sharma","doi":"10.1155/2023/9716173","DOIUrl":"https://doi.org/10.1155/2023/9716173","url":null,"abstract":"Exposure to advanced materials with unique thermomechanical characteristics has fulfilled the requirements of automotive, marine, and structural industries. The current research investigates the thermal adsorption and mechanical properties of epoxy composite enriched by basalt fiber via resin moulding technique with an applied pressure of 2 bar. Hydrophobic and dynamic analyzer tests developed composite’s adsorption storage and loss modulus with 10, 30, 50, 70, 90, and 110 thermal cycles under 18°C to 150°C. ASTM test standards evaluated the effect of the thermal cyclic process on mechanical properties. The composite contained 45 vol% basalt fiber with 90 thermal cycles and found higher adsorption storage modulus, elasticity, tensile strength, and flexural strength of 9200 GPa, 80 GPa, 229 MPa, and 398 MPa, respectively. The thermal adsorption loss modulus was limited by 12% on 90 thermal cycles at 150°C compared to 10 thermal cycles.","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73547742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. T. Tu, Tran Si Thanh, P. Quy, Tran Thi Minh Ha, Phan Thi Kim Thu, Nguyen Thi Hong Bich, L. Son, Vo Thang Nguyen, D. N. Nhiem, P. K. Lieu, Dinh Quang Khieu
Porous TiO2/activated carbon (AC) material was synthesized by grafting peroxo-hydro titanium complexes to rice husk-derived activated carbon. It was found that the morphology of TiO2/AC consists of TiO2 fine particles highly dispersed on the AC matrix. The obtained TiO2/AC composites with high surface area and a red shift exhibit an excellent adsorption performance in both single and trinary system toward methylene blue (MB), methyl orange (MO), and methyl red (MR). The isotherm models including extended Langmuir, P-factor, ideal adsorbed solution theory (IAST) for Langmuir, Freundlich, and Sips models were applied to study the adsorption equilibrium data of trinary solutions. It was found that IAST for Freundlich and Langmuir models were the most suitable one to describe the adsorption of the three dyes on TiO2/AC material. The high maximum adsorption capacities (mmol g-1) in single/trinary mixture were found as 0.452/0.340 for MB; 0.329/0.321 for MO; and 0.806/2.04 for MR. Moreover, the recyclability experiments showed that the adsorbent could be reused through photocatalytic self-cleaning for at least three cycles with stable capacity. Thus, the TiO2/AC can be effectively employed for the removal of dyes from industrial textile wastewater.
{"title":"Trinary Component Adsorption of Methylene Blue, Methyl Orange, and Methyl Red from Aqueous Solution Using TiO2/Activated Carbon","authors":"N. T. Tu, Tran Si Thanh, P. Quy, Tran Thi Minh Ha, Phan Thi Kim Thu, Nguyen Thi Hong Bich, L. Son, Vo Thang Nguyen, D. N. Nhiem, P. K. Lieu, Dinh Quang Khieu","doi":"10.1155/2023/8943198","DOIUrl":"https://doi.org/10.1155/2023/8943198","url":null,"abstract":"Porous TiO2/activated carbon (AC) material was synthesized by grafting peroxo-hydro titanium complexes to rice husk-derived activated carbon. It was found that the morphology of TiO2/AC consists of TiO2 fine particles highly dispersed on the AC matrix. The obtained TiO2/AC composites with high surface area and a red shift exhibit an excellent adsorption performance in both single and trinary system toward methylene blue (MB), methyl orange (MO), and methyl red (MR). The isotherm models including extended Langmuir, P-factor, ideal adsorbed solution theory (IAST) for Langmuir, Freundlich, and Sips models were applied to study the adsorption equilibrium data of trinary solutions. It was found that IAST for Freundlich and Langmuir models were the most suitable one to describe the adsorption of the three dyes on TiO2/AC material. The high maximum adsorption capacities (mmol g-1) in single/trinary mixture were found as 0.452/0.340 for MB; 0.329/0.321 for MO; and 0.806/2.04 for MR. Moreover, the recyclability experiments showed that the adsorbent could be reused through photocatalytic self-cleaning for at least three cycles with stable capacity. Thus, the TiO2/AC can be effectively employed for the removal of dyes from industrial textile wastewater.","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74933842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. Ahmed, Kareem Salihi, S. Kaufhold, Bakhtyar K. Aziz, Musa Hama Radha, Lava Karim, Hevi Nooralddin
The Ziehl-Neelsen stain is a mixture of Basic Fuchsin (BF), phenol (Ph), and methylene blue. It is used to stain the cell walls of Mycobacterium species. In this study, Basic Fuchsin was efficiently removed from synthetic wastewater using natural clay of Gankawa (GC) from Sulaimanyah city, and the effect of the presence of high concentrations of phenol in the adsorption mixture is demonstrated. In addition, X-ray diffraction (XRD), X-ray fluorescence (XRF), N2 gas adsorption analyzer, and field-emission scanning electron microscopy (FESEM) were used to characterize the natural clay. The clay was found to be mostly calcite, with a minor percentage of smectite, and contaminated with low percentages of illite. The adsorption kinetics show a relatively fast equilibration time (60-70 minutes). A second-order pseudokinetic model better fits the experimental kinetic data. The effect of the initial pH of the solution mixture was negligible at the experimental concentration range of the study. Freundlich and Langmuir’s adsorption isotherm models were applied to the equilibrium experimental data using nonlinear regression curve fitting. Both kinetics and isotherm studies point to a chemical adsorption mechanism for the process. For adsorption in the mixture, phenol molecules were found to compete with BF molecules for the active adsorption sites, while a synergetic effect of BF exists on phenol adsorption. As a naturally abundant cheap material, GC shows a superior adsorption capacity toward BF (287.0 mg g-1) over all natural materials and most of the synthetic or modified materials found in the literature.
{"title":"Efficient Removal of Basic Fuchsin from Synthetic Medical Wastewater and Competitive Adsorption in the Mixture","authors":"H. Ahmed, Kareem Salihi, S. Kaufhold, Bakhtyar K. Aziz, Musa Hama Radha, Lava Karim, Hevi Nooralddin","doi":"10.1155/2023/4672622","DOIUrl":"https://doi.org/10.1155/2023/4672622","url":null,"abstract":"The Ziehl-Neelsen stain is a mixture of Basic Fuchsin (BF), phenol (Ph), and methylene blue. It is used to stain the cell walls of Mycobacterium species. In this study, Basic Fuchsin was efficiently removed from synthetic wastewater using natural clay of Gankawa (GC) from Sulaimanyah city, and the effect of the presence of high concentrations of phenol in the adsorption mixture is demonstrated. In addition, X-ray diffraction (XRD), X-ray fluorescence (XRF), N2 gas adsorption analyzer, and field-emission scanning electron microscopy (FESEM) were used to characterize the natural clay. The clay was found to be mostly calcite, with a minor percentage of smectite, and contaminated with low percentages of illite. The adsorption kinetics show a relatively fast equilibration time (60-70 minutes). A second-order pseudokinetic model better fits the experimental kinetic data. The effect of the initial pH of the solution mixture was negligible at the experimental concentration range of the study. Freundlich and Langmuir’s adsorption isotherm models were applied to the equilibrium experimental data using nonlinear regression curve fitting. Both kinetics and isotherm studies point to a chemical adsorption mechanism for the process. For adsorption in the mixture, phenol molecules were found to compete with BF molecules for the active adsorption sites, while a synergetic effect of BF exists on phenol adsorption. As a naturally abundant cheap material, GC shows a superior adsorption capacity toward BF (287.0 mg g-1) over all natural materials and most of the synthetic or modified materials found in the literature.","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90401668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Coal samples from the Shanxi Shaping coal mine were selected to investigate the occurrence of H2S in low sulfur coal seams. The adsorption mechanism of coal to H2S was explored, and an occurrence equation for H2S in coal seams was fitted through adsorption experiment results. The results showed that under ambient temperature and pressure conditions, the H2S adsorbed by coal reached equilibrium within 24 h. The increase in H2S concentrations and the moisture content of coal samples resulted in an increase in the adsorption capacity of H2S. Chemical adsorption of H2S by the coal also occurred. The total sulfur content in the coal increased, and water promoted the conversion from H2S to sulfur in coal. After adsorption, most of the H2S remains in the coal structure in the form of inorganic sulfur, such as sulfur hydride, iron sulfide sulfur, and monomeric sulfur, and a small proportion of H2S is bonded in the structure of the coal in the form of organic sulfur such as thiophene, C-S-C, and C-SH. Therefore, the higher the total sulfur content in coal, the greater the occurrence of H2S. The total amount of H2S increased exponentially with the concentration of free H2S and the moisture content of coal at equilibrium. This meant that the total amount of H2S in the coal seam could be estimated by fitting an equation according to the concentration of free H2S and the moisture content of coal seams. The concentration of free H2S decreased linearly with the increase in moisture content of the coal, therefore, the concentration of H2S in space could be reduced by injecting water into coal seams.
{"title":"Study on H2S Occurrence in Low Sulfur Coal Seams","authors":"Fei Gao, Zhe Jia, J. Xia, Dapeng Wang, Yulong Yang, Yafei Shan, Jinlong Shen","doi":"10.1155/2022/5455101","DOIUrl":"https://doi.org/10.1155/2022/5455101","url":null,"abstract":"Coal samples from the Shanxi Shaping coal mine were selected to investigate the occurrence of H2S in low sulfur coal seams. The adsorption mechanism of coal to H2S was explored, and an occurrence equation for H2S in coal seams was fitted through adsorption experiment results. The results showed that under ambient temperature and pressure conditions, the H2S adsorbed by coal reached equilibrium within 24 h. The increase in H2S concentrations and the moisture content of coal samples resulted in an increase in the adsorption capacity of H2S. Chemical adsorption of H2S by the coal also occurred. The total sulfur content in the coal increased, and water promoted the conversion from H2S to sulfur in coal. After adsorption, most of the H2S remains in the coal structure in the form of inorganic sulfur, such as sulfur hydride, iron sulfide sulfur, and monomeric sulfur, and a small proportion of H2S is bonded in the structure of the coal in the form of organic sulfur such as thiophene, C-S-C, and C-SH. Therefore, the higher the total sulfur content in coal, the greater the occurrence of H2S. The total amount of H2S increased exponentially with the concentration of free H2S and the moisture content of coal at equilibrium. This meant that the total amount of H2S in the coal seam could be estimated by fitting an equation according to the concentration of free H2S and the moisture content of coal seams. The concentration of free H2S decreased linearly with the increase in moisture content of the coal, therefore, the concentration of H2S in space could be reduced by injecting water into coal seams.","PeriodicalId":7279,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86543383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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