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Reflections in Chemical Safety and Research: Doing Science Against All Odds in the Philippines 化学品安全与研究的思考:在菲律宾不畏艰险开展科学研究
Pub Date : 2024-07-22 DOI: 10.1021/acs.chas.4c0004910.1021/acs.chas.4c00049
Imee Su Martinez*, 
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引用次数: 0
Potential Penetration of Engineered Nanoparticles under Practical Use of Protective Clothing Fabrics 工程纳米粒子在防护服织物实际使用中的潜在渗透性
Pub Date : 2024-07-17 DOI: 10.1021/acs.chas.4c0002110.1021/acs.chas.4c00021
Natalie Ireland, Yi-Hsuan Chen and Candace Su-Jung Tsai*, 

The commercial application of engineered nanoparticles (ENPs) has rapidly increased as their unique properties are useful to improve many products. ENPs, however, can pose a major health risk to workers through exposure routes such as inhalation and dermal contact. Research is lacking on the protective nature of lab coats when challenged with ENPs. This study investigated multiwalled carbon nanotubes (CNTs), carbon black (CB), and nano aluminum oxide (Al2O3) penetration through four types of lab coat fabrics (cotton, polypropylene, polyester cotton, and Tyvek). Penetration efficiency was determined with direct reading instruments. The front and back of contaminated fabric swatches were further assessed with microscopy analysis to determine fabric structure with contaminated and penetrated particle morphology and level of fabric contamination. Fabric thickness, porosity, structure, surface chemistry, and ENP characteristics such as shape, morphology, and hydrophobicity were assessed to determine the mechanisms behind particle capture on the four common fabrics. CNTs penetrated all fabrics significantly less than the other ENPs. CNT average penetration across all fabrics was 1.83% compared to 15.74 and 11.65% for CB and Al2O3, respectively. This can be attributed to their fiber shape and larger agglomerates than those of other ENPs. Tyvek fabric was found to be the most protective against CB and Al2O3 penetration, with an average penetration of 0.06 and 0.11%, respectively, while polypropylene was the least protective with an average penetration of 40.36 and 15.77%, respectively. Tyvek was the most nonporous fabric with a porosity of 0.50, as well as the most hydrophobic fabric, explaining the low penetration across all three ENPs. Polypropylene is the most porous fabric with a porosity of 0.77, making it the least protective against ENPs. We conclude that porosity, fabric structure, and thickness are more important fabric characteristics to consider when discussing particle penetration through protective clothing fabrics than surface chemistry.

由于工程纳米粒子(ENPs)的独特性能有助于改进许多产品,因此其商业应用迅速增加。然而,ENPs 可通过吸入和皮肤接触等途径对工人的健康造成重大威胁。目前还缺乏对实验服在受到 ENPs 挑战时的保护性质的研究。本研究调查了多壁碳纳米管 (CNT)、炭黑 (CB) 和纳米氧化铝 (Al2O3) 在四种白大褂织物(棉、聚丙烯、聚酯棉和特卫强)中的渗透情况。渗透效率用直读仪器测定。受污染织物色样的正面和背面通过显微镜分析进行进一步评估,以确定受污染和穿透颗粒形态的织物结构以及织物污染程度。对织物厚度、孔隙率、结构、表面化学以及 ENP 特性(如形状、形态和疏水性)进行了评估,以确定颗粒在四种常见织物上的捕获机制。与其他 ENP 相比,CNT 对所有织物的穿透力都明显较低。CNT 在所有织物上的平均渗透率为 1.83%,而 CB 和 Al2O3 的渗透率分别为 15.74% 和 11.65%。这可归因于它们的纤维形状和比其他 ENP 更大的团聚体。研究发现,特卫强织物对 CB 和 Al2O3 的渗透保护作用最强,平均渗透率分别为 0.06% 和 0.11%,而聚丙烯的保护作用最小,平均渗透率分别为 40.36% 和 15.77%。特卫强是最无孔隙的织物,孔隙率为 0.50,同时也是最疏水的织物,这也是所有三种 ENP 渗透率较低的原因。聚丙烯是最多孔的织物,孔隙率为 0.77,因此对 ENP 的防护能力最弱。我们的结论是,在讨论微粒穿透防护服织物时,孔隙率、织物结构和厚度是比表面化学性质更重要的织物特征。
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引用次数: 0
A Case Study in Assessing a Potential Severity Framework for Incidents from a Decadal Sample 从十年样本中评估事件潜在严重性框架的案例研究
Pub Date : 2024-07-11 DOI: 10.1021/acs.chas.4c0002610.1021/acs.chas.4c00026
Raul B. Lara*, Juliana H. Halbach, Steve Nakasaki and Sam Y. Paik, 

The primary objective of this case study is to determine the applicability and feasibility of a framework that leverages occupational incident details to prospectively identify “potential Serious Injury or Fatality” (pSIF) cases. This study comprehensively reviewed a random sample of 1,081 injury and illness cases across 21 generalized incident types spanning over a decade at Lawrence Livermore National Laboratory (LLNL), a U.S. Department of Energy research and development facility with more than 9,000 employees. The review applied a general framework that classified each case on information suitability, potential severity, and future incident mitigation. The findings from the study indicate that 86.6% of the cases had sufficient information to make a high-confidence determination on potential severity, underscoring the feasibility of applying this general framework. Additionally, cases with a higher pSIF score had, on average, a higher level of institutional response. Implementing a simplified methodology for incident classification that emphasizes incidents that pose high potential severity, regardless of incident type, can help LLNL prioritize resources and tailor responses to such incidents using a graded approach. LLNL has recognized the value of this capability and is integrating the framework into their injury and illness process in the 2024 calendar year.

本案例研究的主要目的是确定一个框架的适用性和可行性,该框架可利用职业事故细节来前瞻性地识别 "潜在的严重伤害或死亡"(pSIF)案例。这项研究全面审查了劳伦斯利弗莫尔国家实验室 (LLNL) 十多年来 21 种通用事件类型中的 1,081 个伤病案例的随机样本,劳伦斯利弗莫尔国家实验室是美国能源部的一个研发机构,拥有 9,000 多名员工。审查采用了一个通用框架,根据信息适用性、潜在严重性和未来事件缓解程度对每个案例进行分类。研究结果表明,86.6% 的案例有足够的信息来对潜在严重性做出高置信度的判断,这强调了应用此通用框架的可行性。此外,pSIF 分数较高的案例,其机构响应的平均水平也较高。实施简化的事件分类方法,强调潜在严重性高的事件(无论事件类型如何),可帮助 LLNL 确定资源的优先级,并采用分级方法对此类事件做出有针对性的响应。LLNL 已认识到这一能力的价值,并将在 2024 日历年度将该框架纳入其伤病流程。
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引用次数: 0
Reconstruction of Curriculum System for Chemical Safety Undergraduate Education under Emerging Engineering Education Requirements 新兴工程教育要求下化学安全本科教育课程体系的重构
Pub Date : 2024-07-09 DOI: 10.1021/acs.chas.4c0001710.1021/acs.chas.4c00017
Jianwen Zhang, Siyu Peng, Pengchao Wang, Feilong Zhang, Qianlin Wang and Zhan Dou*, 

Against the backdrop of the latest engineering and technical disciplines, cross-disciplinary fusion is a new strategy to cultivate high-level composite talents in the chemical safety field. Regulating China’s severe safety production situation is crucial. As an essential source of talent, universities should promptly reconstruct the discipline system according to the new framework under the guiding spirit of Emerging Engineering Education. The innovation and application of intelligent technology have led to a technological revolution in chemistry fields. Therefore, universities should reasonably adjust and optimize the knowledge structure to address the social situations and the development needs of the industry for ensuring the safety of the entire chemical production process. This paper investigates the chemical industry safety production to innovatively present the fresh concept of “5 flows, 3 tactics, and 3 controls,” with “5 flows” as the core, “3 tactics” as the focus, and “3 controls” as the goal. This concept serves as a significant reference for the reformation of the safety curriculum system.

在最新工程技术学科背景下,学科交叉融合是培养化工安全领域高层次复合型人才的新战略。规范我国严峻的安全生产形势至关重要。作为人才的重要来源,高校应在新兴工程教育精神的指导下,及时按照新的框架重构学科体系。智能技术的创新与应用引发了化学领域的技术革命。因此,高校应针对社会形势和行业发展需求,合理调整和优化知识结构,确保化工生产全过程的安全。本文通过对化工行业安全生产的研究,创新性地提出了以 "五流 "为核心、"三策 "为重点、"三控 "为目标的 "五流三策三控 "全新理念。这一理念对安全课程体系改革具有重要的借鉴意义。
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引用次数: 0
Community Connections Committee: How the Joint Safety Team of the University of Minnesota Innovates Promoting Vertical Safety Engagement 社区联系委员会:明尼苏达大学联合安全小组如何创新促进纵向安全参与
Pub Date : 2024-07-03 DOI: 10.1021/acs.chas.4c0002710.1021/acs.chas.4c00027
Vilma S. M. Brandao*, Gretchen S. Burke, Zoe A. Maxwell, Steven K. Butler, Xin I. N. Dong, Jeffrey Paz Buenaflor, Mckenna G. Hanson, Taysir K. Bader, Celina M. Harris, Harrison Frisk, Brian Andersson and Brady L. Bresnahan, 

The Joint Safety Team (JST) of the University of Minnesota Twin Cities is a well-established researcher-led safety team that recently developed a new Community Connections Committee (CCC) to build on its history of collaboration with other student-led Lab Safety Teams (LSTs) around the country. The CCC aims to engage with the larger scientific community by connecting with high school science instructors, early stage researchers at primarily undergraduate institutions (PUIs), and local chemical industries. As part of its early work, the CCC developed a safety workshop for high school chemistry teachers to help them identify and address common safety issues. Participants are introduced to fundamental safety concepts and new tools to understand and address safety concerns through classroom lectures and hands-on laboratories, all aimed at improving safety in their classrooms. Through an ongoing exchange of experiences and resources with PUIs, the CCC helped undergraduate students and faculty create an independent and resourceful student safety team that has engaged students in safety accountability, fostered leadership, and influenced safety practices at the PUI. Finally, this work discusses the collaboration between the CCC and industry partners that focuses on informing University of Minnesota graduate students of the safety standards of the industry so that they can best prepare themselves to be desirable hires and therefore benefit industries. Overall, the CCC is a powerful tool to expand the JST’s positive impacts to the broader chemistry community, helping pass on the JST’s safety practices to PUIs and high schools while also learning of industrial safety standards.

明尼苏达大学双城分校的联合安全团队 (JST) 是一个由研究人员领导的成熟安全团队,最近成立了一个新的社区联系委员会 (CCC),以巩固其与全国其他由学生领导的实验室安全团队 (LST) 的合作历史。社区联系委员会旨在通过与高中科学教师、以本科院校为主的早期研究人员以及当地化工行业建立联系,与更广泛的科学界进行接触。作为早期工作的一部分,CCC 为高中化学教师开发了一个安全讲习班,帮助他们识别和解决常见的安全问题。通过课堂讲座和动手实验室,向学员介绍基本的安全概念和新的工具,以了解和解决安全问题,所有这些都旨在提高他们课堂上的安全。通过与 PUI 不断交流经验和资源,CCC 帮助本科生和教师创建了一个独立、足智多谋的学生安全团队,让学生参与安全责任、培养领导力并影响 PUI 的安全实践。最后,本作品讨论了 CCC 与行业合作伙伴之间的合作,其重点是让明尼苏达大学的研究生了解行业的安全标准,以便他们为成为理想的员工做好最佳准备,从而造福行业。总之,CCC 是将 JST 的积极影响扩大到更广泛的化学界的有力工具,它有助于将 JST 的安全实践传授给 PUI 和高中,同时也让他们了解行业安全标准。
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引用次数: 0
The Gist of the List 清单要点
Pub Date : 2024-07-03 DOI: 10.1021/acs.chas.4c0005310.1021/acs.chas.4c00053
Lauren Goulding*, 
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引用次数: 0
Spotlights: Untargeted Forensic Drug Detection, Burn Pit Smoke Inhalation, and Problems in the Friction Sensitivity Literature 聚焦:非目标法医药物检测、烧伤坑烟雾吸入以及摩擦灵敏度文献中的问题
Pub Date : 2024-07-03 DOI: 10.1021/acs.chas.4c0005210.1021/acs.chas.4c00052
Lauren Goulding*, 
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引用次数: 0
The Chemical Exposure Multiverse: A Call for Papers that Provide Accurate Toxicity and Exposure Data in the Laboratory and Beyond 化学品暴露的多重宇宙:征集能在实验室内外提供准确毒性和暴露数据的论文
Pub Date : 2024-07-03 DOI: 10.1021/acs.chas.4c0005510.1021/acs.chas.4c00055
Pamela Pollet*,  and , Jeremy Breuzard, 
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引用次数: 0
Examining the Mediating Role of Psychological Capital between Perceived Management Commitment and Safety Compliance/Participation of Graduate Students in Research Laboratories 研究心理资本在研究生感知的管理承诺与实验室安全合规/参与之间的中介作用
Pub Date : 2024-06-13 DOI: 10.1021/acs.chas.4c0000210.1021/acs.chas.4c00002
Xue Han, Xiaoyan Wang*, Xinglong Jin* and Minghua Zhou, 

This study conducted a questionnaire survey to examine the influence mechanism of perceived management commitment on the safety compliance and participation of graduate students and to verify the mediating role of psychological capital. The questionnaire was distributed to graduate students through the MyCOS network platform. SPSS was used to conduct reliability and validity tests,test, correlation analysis, and bootstrapping mediation effect test. The results demonstrated that the perceived management commitment has a positive effect on both safety compliance and safety participation, with psychological capital as the mediating role. This study explains how graduate students’ perceived management commitment from their supervisors influences their safety behaviors.

本研究通过问卷调查的形式,探讨感知管理承诺对研究生安全遵从与参与的影响机制,并验证心理资本的中介作用。问卷通过 MyCOS 网络平台发放给研究生。采用 SPSS 进行信度和效度检验、相关分析和引导中介效应检验。结果表明,在心理资本的中介作用下,感知到的管理承诺对安全遵守和安全参与都有积极影响。本研究解释了研究生从其导师处感知到的管理承诺是如何影响其安全行为的。
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引用次数: 0
Reflections in Chemical Safety and Research: The Odyssey of a Female Chemical Engineer from Iraq 化学安全与研究的思考:来自伊拉克的女化学工程师的奥德赛之旅
Pub Date : 2024-05-27 DOI: 10.1021/acs.chas.4c00039
Saba A. Gheni*, 
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引用次数: 0
期刊
Journal of chemical health & safety
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