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Petrology, Geochemistry And Mineralogy Of Alaskan Type Ultramafic-Mafic Intrusive Complexes: A Case Study Around Mikbi-Zayatit District, South Eastern Desert, Egypt 阿拉斯加型超基性-基性侵入杂岩的岩石地球化学和矿物学研究——以埃及东南部沙漠Mikbi-Zayatit地区为例
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1638
Omar A. Soliman, Hatem M. El-Desoky, Mahmoud M. El-Rahmany, Hamada M. El-Awny
The present work deals with the field geology, petrography, geochemistry and mineralogy of Wadi Zayatit and Wadi Mikbi ultramafic-mafic intrusive complex, South Eastern Desert, Egypt. Based on the current geological maps, field observations, structural relationships, and previous works; the rocks that exposed in the study regions are dunites, peridotites, and gabbro. These rocks characterized by coarse-grained, dark greyish to whitish grey color, massive with lustric features and slightly deformed with low to moderate relief. The commonest of the accessory constituents is an oxide ore mineral of some kinds, the most frequent one is chromite, ilmenite, titano-magnetite and magnesio-ferrite. The petrographic descriptions of each rock unit of the studied layered ultramafic-mafic intrusion are recognized; dunites, serpentinized peridotites, and olivine gabbro. Petrographically, opaque minerals are found as coarse-grained, euhedral crystals dispersed throughout the mineral constituents and represented by titani-ferous magnetite and chromite. Titano-magnetite has high FeO and low TiO2. The Fe2O3 and TiO2 show increase with decrease in silica content (SiO2). These rock units have high contents of Ni (9767 ppm), Cr (7861ppm), and Co (1525 ppm). The clino-pyroxene and bulk-rock chemistry indicates strongly crystallization from orogenic hydrous tholeiitic to calc-alkaline magmatic affinity. These inferences suggest that their primary magma was derived from partial melting of a mantle wedge source that has suffered metasomatism in a subduction zone setting. Ore microscopy, XRD technique, and EDX microchemical analysis of representative mineralized samples of ultramafic-mafic intrusive complex identified chromite, ilmenite, titano-magnetite, magnesio-ferrite and clinochlore.
本文研究了埃及东南部沙漠Wadi Zayatit和Wadi Mikbi超基性-基性侵入杂岩的野外地质、岩石学、地球化学和矿物学。根据目前的地质图、野外观测、构造关系和以往的工作;研究区内出露的岩石主要有泥质、橄榄岩和辉长岩。这些岩石的特点是颗粒粗,颜色为深灰色至白灰色,块状,具有光泽特征,轻微变形,凹凸度低至中等。辅助成分中最常见的是某些种类的氧化矿矿物,最常见的是铬铁矿、钛铁矿、钛磁铁矿和镁铁氧体。识别了层状超基性—基性岩体各岩石单元的岩相特征;Dunites,蛇纹橄榄岩和橄榄辉长岩。岩石学上,不透明矿物以粗粒、自面体晶体分散在矿物成分中,以钛-亚铁磁铁矿和铬铁矿为代表。钛磁铁矿的FeO含量高,TiO2含量低。Fe2O3和TiO2随二氧化硅含量(SiO2)的降低而增加。这些岩石单元具有较高的Ni (9767 ppm)、Cr (7861ppm)和Co (1525 ppm)含量。斜辉石和块状岩石化学表明造山带含水拉斑岩到钙碱性岩浆亲和的强烈结晶作用。这些推断表明,它们的原始岩浆来自于俯冲带背景下地幔楔源的部分熔融。矿石显微、XRD技术和EDX微化学分析对超镁铁质侵入复合物代表性矿化样品进行了鉴定,鉴定出铬铁矿、钛铁矿、钛磁铁矿、镁铁氧体和斜锰矿石。
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引用次数: 0
Novel Technique In Production Of Pb (II)- Imprinted Polymers 生产铅(II)印迹聚合物的新技术
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1633
Ehab Mohammed, Mostafa M. Elsheikh, Adham A. El-Zomrawy, Farag A. Ahmed
Ion imprinting techniques were used to produce ion imprinted polymer (IIP) particles for the selective removal of Pb2+ from aqueous environments. As the Templating monomers, acrylic acid, acrylic amine ligand, and Methylene Bisacrylamide crosslinker were chosen. The imprinted polymer was prepared by free radical polymerization. By leaching with 0.1 M HCl, the (Pb2+) ion was removed from the template. The polymer particles were characterized by IR spectroscopy, Thermal analysis and potentiometric analysis. The produced polymer was mechanically crushed into fine particles, assembled into a sensor probe, and linked to a bare HB graphite pencil electrode (GPE). The sensor has a linear dynamic range for Lead (II) ion determination of 4.5-50 ppb and provides best results at pH 4.6 under conditions of continual stirring. In a setting with many analytes, the sensor has been applied to monitor Lead (II) ions. The prepared samples showed high thermal stability with high selectivity for electrochemical detection of lead metal ions.
离子印迹技术用于制备离子印迹聚合物(IIP)颗粒,用于选择性去除水中环境中的Pb2+。模板单体选用丙烯酸、丙烯酸胺配体和亚甲基双丙烯酰胺交联剂。采用自由基聚合法制备印迹聚合物。通过0.1 M HCl浸出,(Pb2+)离子从模板中去除。通过红外光谱、热分析和电位分析对聚合物颗粒进行了表征。生产的聚合物被机械粉碎成细颗粒,组装成传感器探针,并连接到裸露的HB石墨铅笔电极(GPE)上。该传感器对铅(II)离子的线性动态范围为4.5-50 ppb,在连续搅拌条件下,pH为4.6时可提供最佳结果。在有许多分析物的环境中,该传感器已被用于监测铅(II)离子。所制备的样品对铅金属离子的电化学检测具有较高的选择性和热稳定性。
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引用次数: 0
BAYESIAN AND NON-BAYESIAN ESTIMATION BASED ON STEP STRESS-PARTIALLY ACCELERATED LIFE TESTING FOR ODD GENERALIZED NADRAJAH HAGHIGHI EXPONENTIAL DISTRIBUTION 基于阶跃应力部分加速寿命试验的奇异广义nadrajah haghighi指数分布贝叶斯和非贝叶斯估计
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1652
Sarah Mohammad Behairy, Neama Taher Al-Sayed
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引用次数: 0
Detoxification of Hexavalent Chromium Using Biofilm Forming Paenochrobactrum pullorum Isolated from Tannery Wastewater Effluents 制革废水中白纹青杆菌生物膜脱毒研究
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1642
Mohamad Mohamad Elshabrawy, Ahmed Ibrahim Labena, Said Elsayed Desouky, Mohammed Gamal Barghoth, Mohamed Salah Azab
Bioremediation for wastewater using microbes that can detoxify the harmful effects of Cr-VI is concerned. Ninety-two isolates were collected from tannery effluents and screened based on their abilities to remediate hexavalent chromium using LB agar media supplemented by K2Cr2O7 as a source for Cr-VI. Out of the total isolates, 44 isolates can grow at 200 ppm of CR-VI, while 7, 6, 21, 11, and 3 isolates showed growth at concentrations of 400, 600, 800, 1000, and 1200 ppm of Cr-VI, respectively. Furthermore, determination of Cr-VI reduction efficiency for isolates was performed using 1,5-diphenylcarbazide (DPC) method, and the highest reduction efficiency (70.6%) was achieved by isolate 16R. This isolate was identified genetically based on the 16S rRNA gene with a higher similarity of 99.83% to Paenochrobactrum pullorum, and the genetic tree relationship was constructed. The optimization process was conducted to obtain the optimal reduction conditions, including contact time, pH, temperature, inoculum size, and Cr-VI concentration, using the One Factor at a Time (OFAT) method. The highest chromium reduction efficiency increased to 92.5% after optimization for the most potent isolate at pH 9, temperature 30-35°C, and inoculum size 3-4 ml after 5 days of incubation; biofilm formation was also represented. This study is the first to prove the chromium-reducing characteristic of this strain, along with its ability to form a biofilm, which strongly enhances the use of this strain in reduction and biological treatment processes in wastewater treatment contaminated with Cr-VI.
利用微生物解毒Cr-VI的有害影响对废水进行生物修复。从制革废水中收集了92株分离菌,并根据其修复六价铬的能力进行了筛选,以LB琼脂培养基补充K2Cr2O7作为Cr-VI的来源。在200 ppm CR-VI浓度下,44株菌株可以生长,而在400、600、800、1000和1200 ppm CR-VI浓度下,分别有7、6、21、11和3株菌株可以生长。采用1,5-二苯脲(DPC)法测定分离物对Cr-VI的还原效率,分离物16R的还原效率最高,为70.6%。基于16S rRNA基因对该分离株进行了遗传鉴定,与白斑Paenochrobactrum pullorum相似度高达99.83%,并构建了遗传树关系。采用OFAT (One Factor at a time)法进行优化,得到接触时间、pH、温度、接种量、Cr-VI浓度为最佳还原条件。在pH为9、温度为30 ~ 35℃、接种量为3 ~ 4 ml条件下,培养5 d后,效果最佳的菌株铬还原效率可达92.5%;生物膜的形成也有表现。本研究首次证明了该菌株的铬还原特性,以及其形成生物膜的能力,这有力地增强了该菌株在Cr-VI污染废水处理中的还原和生物处理工艺中的应用。
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引用次数: 0
Identification of Identical Bands and Energy Staggering Phenomena in Superdeformed Nuclei in A=190 Mass Region in the Framework of a Novel Proposed Simple Formula 在一个新提出的简单公式框架下,A=190质量区超变形核的同带和能量交错现象的识别
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1653
Farid.A. Elmanakely, Gamal.S.M. Ahmed, Shimaa Abdelfattah, Ali. M. Khalaf
A total of eleven superdeformed rotational bands (SDRB’s) in the A=190 mass zone were described in the framework of a novel proposed simple phenomenological rotational formula as outcome of collective model. The proposed model contains the original pure rotation limit AI (I+1) plus perturbation term proportionate to the cubic power of the spin I. The bandhead spins and the model parameters were selected by a best fit method, utilizing a computerized search program to obtain best match between experimental and calculated transition energies. The spin propositions are mostly consistent with the findings of earlier works. The calculated gamma-ray transition energies (Eγ) over spin (EGOS) in all SDRB’s agree well with experimental data. Detailed assessment of the dynamic moments of inertia with rotational frequency is surveyed in details which proves to be quite helpful for understanding the SDRB’s properties such as identical bands (IB’s). Four pairs namely: 191Hg (SD2, SD3), 193Hg(SD3, SD4),194Hg(SD2, SD3) and 193Pb(SD3, SD4) are investigated as signature partners which exhibit △I=1 staggering effects their transition energies. We looked at this staggering by taking into account parameters that describe the variance between average transitions I+2 → I → I-2 and the I+1 → I-1 energies in its signature partner and a staggering parameter depends on the dipole transition energies connecting the two signature partners with that quadrupole transition energies. Large amplitude staggering is found. The bandhead moments of inertia of each signature partner pairs are found to be identical. Our calculations predicts the occurrence of △I = 2 staggering effects in 194Hg (SD1, SD2, SD3). This predict △I = 2 energy staggering has been inspected by computing parameter indicate the finite difference approximation to the fourth order derivative of that indicating energies. The phenomenon of IB’s is investigated for the nuclei 191Hg and 192Hg and their neighbors.
作为集体模型的结果,提出了一种新的简单现象学旋转公式框架,描述了A=190质量区的11个超变形旋转带(SDRB)。该模型包含原始的纯旋转极限AI (I+1)加上与自旋I的三次幂成比例的扰动项。采用最佳拟合方法选择带头自旋和模型参数,利用计算机搜索程序获得实验和计算跃迁能的最佳匹配。自旋命题与早期工作的发现基本一致。所有SDRB的伽玛射线跃迁能(e - γ) /自旋(EGOS)的计算结果与实验数据吻合较好。详细地研究了随旋转频率变化的动惯量,这对理解SDRB的同频带(IB’s)等特性很有帮助。研究了191Hg (SD2, SD3)、193Hg(SD3, SD4)、194Hg(SD2, SD3)和193Pb(SD3, SD4)四对伴子,它们的跃迁能表现出△I=1的惊人效应。我们通过考虑描述平均跃迁I+2→I→I-2和I+1→I-1在它的特征伙伴中的能量之间的方差的参数来看待这个惊人的参数,一个惊人的参数取决于连接两个特征伙伴的偶极跃迁能量和四极跃迁能量。发现大振幅交错。发现每个签名对的带头转动惯量是相同的。我们的计算预测了194Hg中△I = 2的惊人效应(SD1, SD2, SD3)的发生。通过计算参数表示四阶导数的有限差分逼近,验证了△I = 2能量交错的预测。研究了191Hg和192Hg及其邻核的IB现象。
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引用次数: 0
Geoelectric Evaluation of Soil Foundation Utilizing Electrical Resistivity Tomography at West Gulf of Suez, Al-Ain Al Sokhna, Egypt 埃及Al- ain Al- Sokhna西苏伊士湾土壤地基电阻率层析成像地电评价
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1635
Mahmoud Zayed
To evaluate the subsurface layers and geological structures for construction in one of the tourist areas in Egypt, the geoelectrical survey was used, represented by the 2D Electrical Resistivity Tomography (ERT). The geoelectrical survey includes 16 ERT profiles that have been conducted by using the Winner electrode array with twenty electrodes connected to a multi-core cable. The electrode spacing (a) varies between 4 and 6 meters to investigate a depth of around twenty meters, and the length of the ERT profiles varies from 76 to 114 meters depending on the electrode spacing difference and the field's available space. Through the geoelectric results that are confirmed by drilling of six boreholes, five geoelectric layers were identified, in addition to six faults inferred from the geoelectrical results. These faults are concentrated in the north of the research area. Shale and shaly-sand layers were among the examined geoelectric layers that were found on a small scale in the research region. Because of the major impact that these layers have on buildings, it was advised that the required engineering solutions be developed for these layers.
为了对埃及某旅游区的地下地层和地质构造进行评价,采用了以二维电阻率层析成像(ERT)为代表的地电测量方法。地电测量包括16个ERT剖面,使用Winner电极阵列,将20个电极连接到多芯电缆上。电极间距(a)在4到6米之间变化,以研究大约20米的深度,ERT剖面的长度从76到114米不等,具体取决于电极间距差异和现场可用空间。通过钻探6口井确认的地电结果,确定了5个地电层,并根据地电结果推断出6条断层。这些断裂主要集中在研究区的北部。在研究区检测的地电层中,发现了规模较小的页岩和泥砂层。由于这些层对建筑物的重大影响,建议为这些层开发所需的工程解决方案。
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引用次数: 0
A NUMERICAL APPROACH TO SOLVE THE INITIAL-VALUE PROBLEM OF TWO-BODY WITH UNIVERSAL VARIABLE 具有通用变量的二体初值问题的数值求解方法
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1640
Ahmed B. Yassen, Waleed N. Ahmed, Ahmed H. Ibrahim, Abdelaziz A. Bakry, Hany R. Dwidar
The solution of the initial-value problem of two-body gives inaccurate final state predictions for the orbital motions of artificial satellites. This is due to the presence of singularities and the poor selection of variables. In the current study, we numerically investigated the initial-value problem using the universal anomaly approach. To clarify the problem under concern, we carried out several numerical examples using a homemade software package. We considered five space missions, around the two planets Earth and Venus, which represent circular, near circular and ellipse orbits. We showed that the universal anomaly approach facilitates the numerical and analytical treatments of the two-body dynamics and works equally well for different types of orbits. Moreover, we developed a computation algorithm to handle the perturbed problem in cylindrical coordinates for the initial value problem taking into consideration the geopotential of the two planets up to the third zonal harmonic and the tesseral coefficient .
二体初值问题的解对人造卫星的轨道运动给出了不准确的最终状态预测。这是由于奇点的存在和变量选择不当造成的。在本研究中,我们使用普遍异常方法对初值问题进行了数值研究。为了弄清所关注的问题,我们使用自制的软件包进行了几个数值算例。我们考虑了围绕地球和金星两颗行星的五次太空任务,这两颗行星代表圆形、近圆形和椭圆形轨道。我们表明,普遍异常方法有助于两体动力学的数值和解析处理,并同样适用于不同类型的轨道。此外,我们还开发了一种计算算法来处理柱面坐标系下的扰动问题,该算法考虑了两行星在三次纬向调和前的位势和特塞尔系数。
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引用次数: 0
Soft Topological Notions Via Molodtsov Model 基于Molodtsov模型的软拓扑概念
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1648
A.A. Nasef, A.I. Aggour, A. Fathy, S.M. Darwesh
In the present paper, we introduce a new concept of soft sets called soft $g(beta,omega)$-closed sets. Also, we study the basic properties of this new concept and we investigate the relation between soft $g(beta,omega)$-closed sets and some of the other soft sets. Finally, we introduce the concept of soft $g(beta,omega)$- continuous map and we study the relationship between the new concept and some of the other types of soft continuity.
本文引入了软集的一个新概念:软$g(beta,omega)$ -闭集。此外,我们还研究了这个新概念的基本性质,并研究了软$g(beta,omega)$ -闭集与其他一些软集之间的关系。最后,我们引入了软连续映射$g(beta,omega)$的概念,并研究了这一新概念与其他软连续映射之间的关系。
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引用次数: 0
Green Synthesis Of Zinc Oxide Nanoparticles: Characterization, Organic Dye Degradation And Evaluation Of Their Antibacterial Activity 绿色合成氧化锌纳米颗粒:表征、有机染料降解及其抗菌活性评价
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1650
Mona Khamis, Gamal A. Gouda, Adham M. Nagiub
The aim of this work is the green synthesis of zinc oxide nanoparticles (ZnO NPs) via red onion extract. The ZnO NPs wurtzite hexagonal structure was identified through X-ray diffraction (XRD) analysis, with an average crystallite size of 8.13 nm. The capping and stabilization of ZnO NPs biosynthesis were supported by an analysis of infrared spectra (FT-IR). The absorption peak at 374 nm with an energy bandgap of 3.32 eV was discovered via UV-Vis analysis. A morphological study was done by SEM and TEM techniques, and showed that spherical ZnO NPs with diameters ranging from 2.83 to 15.35 nm had formed. Using EDS, it was possible to identify the high purity, intensity, and crystalline width of zinc and oxygen. The removal rates of methylene blue (MB) by photocatalysis and adsorption were compared utilizing ZnO NPs. Under sunlight, the photodegradation of MB 10 mg/L has been examined. It was found that maximum decolorization efficiency happened after 120 minutes and a dose of 25 mg of ZnO NPs. The adsorption capacity (qm) was calculated by the Langmuir equation to be 10.8 mg/g. The kinetic analysis suggests the pseudo-second order model was followed during MB adsorption via the NPs. The findings showed that the photocatalytic and adsorption approaches removed the dye up to 95.2 % more efficiently than in earlier research. ZnO NPs exhibited better antibacterial action against E. coli than S. aureus bacteria when compared to a common antibiotic like Ciprofloxacin.
本研究的目的是利用红洋葱提取物绿色合成氧化锌纳米颗粒(ZnO NPs)。通过x射线衍射(XRD)分析,确定了ZnO NPs纤锌矿的六方结构,平均晶粒尺寸为8.13 nm。红外光谱(FT-IR)分析支持ZnO NPs生物合成的封顶和稳定性。通过紫外可见光谱分析,发现其吸收峰位于374nm处,能隙为3.32 eV。利用扫描电镜和透射电镜对ZnO纳米粒子的形貌进行了研究,结果表明ZnO纳米粒子的直径为2.83 ~ 15.35 nm。利用能谱分析,可以确定锌和氧的高纯度、高强度和高晶体宽度。比较了ZnO纳米粒子光催化和吸附对亚甲基蓝(MB)的去除率。在日光下,测定了10 mg/L的MB的光降解情况。结果表明,在氧化锌NPs用量为25 mg时,脱色时间为120 min,脱色效果最佳。根据Langmuir方程计算其吸附量qm为10.8 mg/g。动力学分析表明,吸附过程符合准二级模型。研究结果表明,光催化和吸附方法对染料的去除率比先前的研究提高了95.2%。与环丙沙星等常见抗生素相比,ZnO NPs对大肠杆菌的抑菌作用优于金黄色葡萄球菌。
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引用次数: 0
Bio-insecticidal potentiality of chitinase extracted from Amycolatopsis orientalis A13 sp. nova actinomycete against Galleria mellonella 从东方Amycolatopsis orientalis A13 sp. nova放线菌中提取几丁质酶对mellonella的生物杀虫潜力
Pub Date : 2023-01-01 DOI: 10.58675/2636-3305.1632
Hamada Hosney Elbadawy, Zeinab Khaled Abd El-Aziz, Azza Abdel-khalek Abdel-khalek, Abdel Naser Ahmed Kobisi, Mohamed El- Badry
Chitin is the outermost layer surrounding all arthropod’s bodies as the primary protective layer against any adverse conditions. Chitinase is a group of enzymes responsible for degrading the old chitin layer. The current study was conducted under laboratory conditions to evaluate the insecticidal potentiality of chitinase filtrate extracted from Amycolatopsis orientalis A13 sp. nova actinomycete against the 3rd and 5th larval instars of the greater wax moth, Galleria mellonella. A series of aqueous concentrations have been prepared (25, 50, 100, 150, and 200 µL/g) to carry out the current bio-assay experiment. The cumulative larval death percentages were concentration-dependent, i.e., the highest larval mortality (94.68%) got detected at the highest applied concentration (200 µL/g). LC50, LC90, and LC95 values of chitinase filtrate were recorded at 57.94, 187.82, and 262.14 after 37 days of exposure time, respectively. The obtained data also revealed that the higher the applied chitinase concentration, the longer the treated larvae and pupae duration. The calculated nutritional indices (Relative growth rate (RGR), Relative consumption rate (RCR), efficiency of conversion of ingested food to body substance (ECI), efficiency of digested food conversion (ECD%), and Approximate digestibility (A.D.) showed significant variation at the LC50 value. The results showed that such laboratory trials accredited the chitinase filtrate as a promising bio-agent. However, further studies should be conducted to prove its efficacy under semi-field and field conditions.
几丁质是所有节肢动物身体的最外层,是抵御任何不利条件的主要保护层。几丁质酶是一组负责降解旧几丁质层的酶。本研究在室内条件下,研究了从东方Amycolatopsis orientalis A13 sp. nova放线菌中提取的几丁质酶滤液对大蜡蛾(Galleria mellonella) 3龄和5龄幼虫的杀虫效果。制备了一系列的水溶液浓度(25、50、100、150和200µL/g)来进行当前的生物测定实验。累积幼虫死亡率呈浓度依赖性,在最高浓度(200µL/g)时,幼虫死亡率最高,为94.68%。暴露37 d后,几丁质酶滤液LC50、LC90和LC95分别为57.94、187.82和262.14。几丁质酶浓度越高,处理后的幼虫和蛹持续时间越长。在LC50值下,计算得到的营养指标(相对生长率(RGR)、相对消耗率(RCR)、摄入食物转化为体内物质效率(ECI)、消化食物转化效率(ECD%)和近似消化率(A.D.)均有显著差异。实验结果表明,几丁质酶滤液是一种很有前途的生物制剂。但是,还需要进一步的研究来证明其在半大田和大田条件下的有效性。
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引用次数: 0
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Al-Azhar Bulletin of Science
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