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PREPARATION AND ELECTROCHEMICAL BEHAVIOR OF THE ACTIVATED CARBON FROM POMEGRANATE PEELS AS ENERGY-STORAGE MATERIALS 石榴皮储能材料活性炭的制备及电化学性能研究
Pub Date : 2020-06-01 DOI: 10.21608/absb.2020.111459
M. Morad, S. Attia, S. Mohamed, M. Moharam, R. Abou-shahba, M. Rashad
This study investigates the electrochemical evaluation of the activated carbon (AC) prepared from pomegranate peels which were collected, dried, carbonized and finally activated with KOH at different temperatures. The characterization of the as-prepared AC revealed an amorphous type of carbon and densely layer-stacking sheets with an interconnected micro porous network with a remarkable 3128.86m2g-1 surface area. The as-synthesized AC displayed a remarkable capacitance of 126 F g-1 at 0.5 A g-1with a storage retention of 137 % after 2000 cycles at a current density of 2 A g-1.  Meanwhile, the realistic symmetrical simulation has been installed, it shows an energy density of 4.58 W h kg-1 at a power density of 244 W kg-1 with a storage retention of 66 % of the initial capacity at a current density of 2 A g-1 after 2000 cycles. Overall, these results demonstrate that for supercapacitors evaluation, the AC electrode can be considered a successful electrode material.
研究了石榴皮在不同温度下经干燥、炭化、KOH活化制备的活性炭的电化学性能。表征结果表明,所制备的AC为非晶型碳,具有致密的层状堆叠层,具有相互连接的微孔网络,其表面积达到了惊人的3128.86m2g-1。合成的交流电在0.5 a g-1电流下的电容值为126 F -1,在2 a g-1电流密度下循环2000次后的存储保留率为137%。同时,进行了真实对称仿真,结果表明,当功率密度为244w kg-1时,电池的能量密度为4.58 W h kg-1,当电流密度为2a g-1时,经过2000次循环后,电池的储能容量为初始容量的66%。总的来说,这些结果表明,对于超级电容器的评估,交流电极可以被认为是一种成功的电极材料。
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引用次数: 0
PREPARATION OF ACTIVATED CARBON FROM ION EXCHANGE RESIN WASTE AND ITS APPLICATION FOR MANGANESE REMOVAL FROM GROUNDWATER 离子交换树脂废渣制备活性炭及其在地下水除锰中的应用
Pub Date : 2020-06-01 DOI: 10.21608/absb.2020.111469
A. Swelam, Y. Gedamy, A. El.shahed
The present study aims to synthesize an activated carbon adsorbent (S-AC, P-AC and OH-AC) from polystyrene divinyl benzene waste under different carbonization temperature (450oC and 900 oC and activation conditions (H2SO4, H3PO4 or NaOH). It being characterized and applied as an adsorbent for manganese removal from groundwater. FTIR results indicate that the changes in the peak intensities clear that the binding process was occurring on the surface of the adsorbent. Different factors such as solution pH, adsorbent dosage, contact time, temperature and Mn(II) initial concentration were investigated. The results showed that manganese adsorption capacity decreases with the increase of the carbonization temperature (900oC) and of activating agent H2SO4 > H3PO4 >NaOH. Kinetically, it was shown that the activation temperature of 450oC is the best temperature for activating the adsorbent carbons. The pseudo-first-order model is appropriate for predicting the adsorption process of Mn(II) onto the P-AC 450oC, P-AC 900oC and OH-AC 900oC, while the pseudo-second-order model is appropriate for predicting the adsorption process of Mn(II) onto the both S-AC 450oC, S-AC 900oC, OH-AC 450oCand OH-AC 900oC. Thermodynamic calculations affirmed that Mn(II) adsorption onto S-AC and P-AC was an endothermic process while onto OH-AC was exothermic process. Finally, the results suggested that the prepared S-AC has high adsorption capacities for Mn(II) compared with other adsorbents, such as P-AC and OH-AC. Therefore, S-AC 450oCcan be used in the groundwater treatment unit.
本研究以聚苯乙烯二乙烯苯废料为原料,在不同的炭化温度(450℃和900℃)和活化条件(H2SO4、H3PO4或NaOH)下合成活性炭吸附剂(S-AC、P-AC和OH-AC)。对其进行了表征,并将其作为一种吸附剂用于去除地下水中的锰。FTIR结果表明,峰强度的变化清楚地表明结合过程发生在吸附剂表面。考察了溶液pH、吸附剂投加量、接触时间、温度和Mn(II)初始浓度等因素的影响。结果表明:随着炭化温度(900℃)和活化剂H2SO4 > H3PO4 >NaOH的升高,锰的吸附量减小;动力学结果表明,450℃的活化温度是吸附炭活化的最佳温度。拟一阶模型适用于预测Mn(II)在P-AC 450oC、P-AC 900oC和OH-AC 900oC上的吸附过程,拟二阶模型适用于预测Mn(II)在S-AC 450oC、S-AC 900oC、OH-AC 450oC和OH-AC 900oC上的吸附过程。热力学计算证实了Mn(II)在S-AC和P-AC上的吸附是吸热过程,而在OH-AC上的吸附是放热过程。结果表明,与P-AC和OH-AC等吸附剂相比,制备的S-AC对Mn(II)具有较高的吸附能力。因此,S-AC 450oc可用于地下水处理机组。
{"title":"PREPARATION OF ACTIVATED CARBON FROM ION EXCHANGE RESIN WASTE AND ITS APPLICATION FOR MANGANESE REMOVAL FROM GROUNDWATER","authors":"A. Swelam, Y. Gedamy, A. El.shahed","doi":"10.21608/absb.2020.111469","DOIUrl":"https://doi.org/10.21608/absb.2020.111469","url":null,"abstract":"The present study aims to synthesize an activated carbon adsorbent (S-AC, P-AC and OH-AC) from polystyrene divinyl benzene waste under different carbonization temperature (450oC and 900 oC and activation conditions (H2SO4, H3PO4 or NaOH). It being characterized and applied as an adsorbent for manganese removal from groundwater. FTIR results indicate that the changes in the peak intensities clear that the binding process was occurring on the surface of the adsorbent. Different factors such as solution pH, adsorbent dosage, contact time, temperature and Mn(II) initial concentration were investigated. The results showed that manganese adsorption capacity decreases with the increase of the carbonization temperature (900oC) and of activating agent H2SO4 > H3PO4 >NaOH. Kinetically, it was shown that the activation temperature of 450oC is the best temperature for activating the adsorbent carbons. The pseudo-first-order model is appropriate for predicting the adsorption process of Mn(II) onto the P-AC 450oC, P-AC 900oC and OH-AC 900oC, while the pseudo-second-order model is appropriate for predicting the adsorption process of Mn(II) onto the both S-AC 450oC, S-AC 900oC, OH-AC 450oCand OH-AC 900oC. Thermodynamic calculations affirmed that Mn(II) adsorption onto S-AC and P-AC was an endothermic process while onto OH-AC was exothermic process. Finally, the results suggested that the prepared S-AC has high adsorption capacities for Mn(II) compared with other adsorbents, such as P-AC and OH-AC. Therefore, S-AC 450oCcan be used in the groundwater treatment unit.","PeriodicalId":7687,"journal":{"name":"Al-Azhar Bulletin of Science","volume":"56 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82469416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
RADIATION EFFECT ON MAGNETOHYDRODYNAMIC CARREAU NANOFLUID FLOW PAST NON-LINEAR PERMEABLE HEATED STRETCHING SHEET WITH PARTIAL SLIP 磁纳米流体通过部分滑移的非线性可渗透加热拉伸片的辐射效应
Pub Date : 2020-06-01 DOI: 10.21608/absb.2020.111480
H. Shawky, N. Eldabe, K. Kamel, Esmat A. Abd-Aziz
The motion of a Carreau nanofluid past an infinite vertical non-linear permeable stretching sheet embedded in a non-Darcy porous medium is investigated. It is stressed by a uniform external magnetic field. The thermal radiation and heat generation are taken in consideration as well as Brownian motion with thermophoresis, chemical reaction and partial slip velocity at the boundary layer. The nonlinear partial differential equations describing the motion with heat and mass transfer are transformed to non-linear ordinary differential equations and solved by using Runge-Kutta method with approbriate boundary conditions. The effects of the physical parameters of the problem on the obtained solutions are discussed numerically and graphically. Through the section of discussion the skin friction and the rate of heat and mass transfer are computed. It is found that these physical parameters play an important rules to control the obtained velocity, temperature and concentration of the fluid.
研究了卡罗纳米流体通过嵌入在非达西多孔介质中的无限垂直非线性渗透拉伸片的运动。它受到均匀的外磁场的压力。考虑了边界层的热辐射和热生成,以及带热泳动的布朗运动、化学反应和局部滑移速度。将描述传热传质运动的非线性偏微分方程转化为非线性常微分方程,并在适当的边界条件下采用龙格-库塔法求解。讨论了问题的物理参数对得到的解的影响。通过讨论部分,计算了表面摩擦和传热传质速率。发现这些物理参数对得到的流体速度、温度和浓度起着重要的控制作用。
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引用次数: 0
PLASMA POWER IMPACT ON ELECTROCHEMICAL PERFORMANCE OF LOW CARBON STEEL COATED BY PLASMA THIN TEOS FILMS 等离子体功率对等离子体teos薄膜涂层低碳钢电化学性能的影响
Pub Date : 2020-06-01 DOI: 10.21608/absb.2020.111474
Amr Gangan, M. ElSabbagh, M. Bedair, M. El-Sabbah, A. Fahmy
Electrochemical properties of thin silicon oxy carbide films were investigated as anticorrosive coatings. The film was deposited on low carbon steel substrate by radio frequency capacitive coupled plasma technique using tetraethyl ortho silicate (TEOS) as a precursor and Ar was used as a carrier gas in dependence on the applied power. The chemical composition and morphological of the deposited films were examined by energy-dispersive X-ray spectroscopy (EDX) coupled with scanning electron microscopy (SEM). The SEM results confirm a pinhole-free layer of oxy carbide was formed on the steel surface after plasma treatment. The corrosion resistance of the coatings was analyzed by potentiodynamic polarization and electrochemical spectroscopy (EIS) in 3.5% NaCl solution at room temperature. The electrochemical results show remarkable corrosion resistance enhancement after plasma treatments. The corrosion current (icorr) is significantly reduced from 12 µA/cm2 for the blank sample to 1 and 0.3 µA/cm2 for treated samples at 50, and 100 W, respectively. A marked increase of the protective properties was detected by 100 W sample with protective efficiency more than 98 % at room temperature.
研究了碳化氧硅薄膜作为防腐涂层的电化学性能。采用射频电容耦合等离子体技术,以正硅酸四乙酯(TEOS)为前驱体,氩气作为载气,根据施加功率在低碳钢衬底上沉积薄膜。利用能量色散x射线能谱仪(EDX)和扫描电子显微镜(SEM)对沉积膜的化学成分和形貌进行了检测。扫描电镜结果证实,等离子体处理后,钢表面形成了一层无针孔的碳化氧层。采用动电位极化和电化学光谱(EIS)分析了涂层在室温3.5% NaCl溶液中的耐蚀性。电化学结果表明,经等离子体处理后,其耐腐蚀性能显著增强。腐蚀电流(icorr)从空白样品的12µA/cm2显著降低到处理样品在50和100 W下的1和0.3µA/cm2。在室温下,100w样品的保护性能显著提高,保护效率达98%以上。
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引用次数: 9
CONTRIBUTION TO SOURCE ROCK EVALUATION OF THE BAHARIYA FORMATION IN SURFACE AND SUBSURFACE SECTIONS, NORTH WESTERN DESERT, EGYPT 埃及西北沙漠巴哈里亚组地表和地下剖面烃源岩评价贡献
Pub Date : 2019-06-20 DOI: 10.21608/absb.2019.80483
G. Attiaa, A. Abdou, S. Amir, D. Mousa
The present work deals with the identification of the generating capacity of oil generation and the hydrocarbon potentiality of the Bahariya Formation in Gebel El-Dist section and the Salam-1X well. This is depending on the organic geochemical analyses by using LECO SC632 and Rock Eval-6 pyrolysis techniques. The analysis shows that the studied samples of Gebel El-Dist are poor to fair organic richness, with poor hydrocarbon potentiality. The maturity evaluation using Tmax showed that the studied samples have immature thermal maturation not reaching the stage of oil and gas generation. Also, the analyses revealed that the studied kerogen is type III kerogen originated mainly from terrestrial plant debris and aquatic organic matter. The expected generated HC is mainly gas. The studied Salam-1X samples are poor to good organic richness, with poor to good source potiental. The studied samples are marginally mature to mature thermal maturation reaching the stage oil generation. The kerogen type is a mixture of type III/II kerogen derived mainly from mixed organic sources.
目前的工作涉及确定Gebel El-Dist剖面和Salam-1X井的Bahariya组的生油能力和碳氢化合物潜力。这取决于使用LECO SC632和Rock Eval-6热解技术进行的有机地球化学分析。分析表明,Gebel - El-Dist研究样品有机质丰度差至中等,烃源性差。Tmax成熟度评价表明,研究样品热成熟度不成熟,未达到油气生成阶段。分析表明,研究的干酪根为III型干酪根,主要来源于陆生植物碎屑和水生有机质。预计生成的HC主要是天然气。研究的Salam-1X样品有机丰富度差到好,源电位差到好。研究样品为微成熟至热成熟,达到生油阶段。干酪根类型为混合型/混合型干酪根,主要来源于混合有机质。
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引用次数: 0
MOLECULAR PHYLOGENETIC RELATIONS OF MAMMALS OF THE GENUS CANIS IN EGYPT 埃及犬属哺乳动物的分子系统发育关系
Pub Date : 2019-06-09 DOI: 10.21608/absb.2019.67883
Fouad Abdel Hamid, M. Sarhan, M. Younes, M. Saleh
The taxonomic identity of canids of the genus Canis in North Africa has been investigated using molecular phylogenetic analysis based on Cytochrome b mitochondrial DNA sequence analysis. Tissue samples from 18 Canis specimens collected from all known populations/taxa in Egypt were obtained and analyzed. The resulting Cyt b mt DNA sequences of current Canis taxa, described based morphological characters were compared to each other and to other Canis populations/taxa across North Africa and the Middle East. The results showed no detectable sequence differentiation among all populations, suggesting that the separation of the phenotypically differentiated populations of Egypt has been relatively recent. Estimate divergence time between different phylogroups of the genus and the phylogeographic history of the genus was discussed in a regional paleogeographic context.
采用基于细胞色素b线粒体DNA序列分析的分子系统发育分析方法,对北非犬科动物进行了分类鉴定。从埃及所有已知种群/分类群中收集的18只犬标本进行组织样本分析。基于形态特征描述的现有犬类分类群的Cyt b mt DNA序列相互比较,并与北非和中东的其他犬类种群/分类群进行比较。结果显示,在所有种群中没有可检测到的序列分化,这表明埃及表型分化种群的分离是相对较近的。在区域古地理背景下讨论了该属不同系群之间的分化时间估计和该属的系地理历史。
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引用次数: 0
NATURAL RADIOACTIVITY ASSESSMENT AND THE ASSOCIATED RADIOLOGICAL HAZARDS FOR BEACH SAND, BALTIM AREA, EGYPT. 埃及巴提姆地区沙滩的天然放射性评估及相关的放射性危害。
Pub Date : 2019-06-03 DOI: 10.21608/absb.2019.67879
H. Shousha, M. Atta, A. Bakhit, H. Diab, A. A. E. Hagg, Samah Dahy
Natural radioactivity of 238U, 232Th series and 40K of black sand samples collected along El-Fanar and El-Nargess Beaches in Baltim area, north of the Nile Delta in Kafr El-Sheikh Governorate, were measured using a gamma-ray spectrometer with a high purity germanium (HPGe) detector. Results showed that the average activity concentrations of 238U and 232Th in El-Fanar Beach was significantly higher (73.22±5.1 and 70.8 ± 4.9 Bq kg-1) than El-Nargess Beach (31.91±2.2 and 25.95 ±1.8 Bq kg-1) respectively. The average activity concentrations of 40K in El-Fanar Beach was lower (67.47±4.7 Bq kg-1) than that in El-Nargess Beach (80.75±5.6 Bq kg-1). The hazard indices due to these radionuclides have been calculated. The obtained results from this study indicate that the average activity concentrations of 238U, 232Th and40K at El-Nargess Beach are within world median ranges while average activities of 238U and232Th in El-Fanar Beach are higher than the world mean (33and45) Bq kg-1 respectively. This study aimed to establish a baseline map of radioactivity background levels in the aforementioned region to assess any change in the radiological background levels due to any artificial effects attributed to any radiation activities.
在Kafr El-Sheikh省尼罗河三角洲北部Baltim地区El-Fanar和El-Nargess海滩采集的黑沙样本中,238U、232Th系列和40K的天然放射性使用带有高纯度锗(HPGe)探测器的伽马射线光谱仪进行了测量。结果表明,El-Fanar海滩238U和232Th的平均活性浓度(73.22±5.1和70.8±4.9 Bq kg-1)显著高于El-Nargess海滩(31.91±2.2和25.95±1.8 Bq kg-1)。El-Fanar海滩40K的平均活性浓度(67.47±4.7 Bq kg-1)低于El-Nargess海滩(80.75±5.6 Bq kg-1)。这些放射性核素的危害指数已经计算出来了。本研究结果表明,El-Nargess海滩238U、232Th和40k的平均活性浓度处于世界中值范围内,El-Fanar海滩238U和232Th的平均活性浓度分别高于世界平均水平(33和45)Bq kg-1。这项研究的目的是在上述地区建立辐射本底水平的基线图,以评估任何辐射活动所造成的人为影响所造成的辐射本底水平的变化。
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引用次数: 2
CHARACTERIZATION OF 241AM-BE NEUTRON SOURCE USING THRESHOLD FOIL ACTIVATION TECHNIQUE 用阈值箔活化技术表征241am-be中子源
Pub Date : 2019-06-01 DOI: 10.21608/absb.2019.67880
N. Kotb, M. Tohamy, A. Solieman, T. E. Zakla, T. Z. Amer, S. Elmeniawi, M. Comsan
The aim of the study is to characterize 241Am-Be isotopic neutron source with 5 Ci activity and nominal neutron yield 1.1×107 n/s. The emitted neutrons were measured employing threshold multi-foil activation technique using the following reactions: 115In(n,n'), 58Ni(n,p), 64Zn(n,p), 27Al(n,p), 56Fe(n,p), 59Co(n,α), 24Mg(n,p), and27Al(n,α). The threshold reactions were selected based on their half-lives, adequate threshold energy and cross-section. The reaction rate of each sample foil is measured by detecting the gamma ray spectra produced as a result of reaction products decay. A hyper pure germanium detector (HPGe) is used for gamma-ray spectrum measurements. The obtained spectra were analyzed using Genie2000 software and the associated system absolute efficiency was calculated using Efftran software. Obtained reaction rates were compared with available published data.
该研究的目的是表征具有5 Ci活度和标称中子产率1.1×107 n/s的241Am-Be同位素中子源。采用阈值多箔活化技术,分别用115In(n,n’)、58Ni(n,p)、64Zn(n,p)、27Al(n,p)、56Fe(n,p)、59Co(n,α)、24Mg(n,p)和27Al(n,α)等反应测量了发射中子。根据反应的半衰期、足够的阈值能量和截面来选择阈值反应。每个样品箔的反应速率是通过检测反应产物衰变产生的伽马射线谱来测量的。超纯锗探测器(HPGe)用于伽马射线光谱测量。用Genie2000软件对所得光谱进行分析,用Efftran软件计算相关系统的绝对效率。得到的反应速率与现有的已发表的数据进行了比较。
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引用次数: 2
PERTURBED GROUND TRACK UNDER THE INFLUENCE OF J2 AND LUNISOLAR FORCES j2和日月力影响下的扰动地面轨迹
Pub Date : 2019-06-01 DOI: 10.21608/absb.2019.66072
M. E. Awad, I. A. Hassan, H. Dewdar, A. Saad
A several types of forces are acting on the satellite. These forces are classified into conservative and nonconservativeforce. The main concern in the present research work is to studding the effect of conservative forces on the satellite orbital motion and represent this effect on satellite ground track. Where the ground tracks are the locus of points formed by the points on the Earth directly below a satellite as it travels in orbit. A mathematical model and a program code is designed using Matlab package to calculate the perturbed ground track under J2 and luni-solar forces. Whereas the J2 and Luni-Solar are a conservative forces, the secular variation is presented only in RAAN and  . Otherwise the remaining orbital element is varies periodically. The perturbed ground track is calculated under the effect of J2 and luni-solar forces. The perturbed position vectors for a satellite are converted to its corresponding latitudes and longitudes. The satellite’s position in one revolution is displayed to represent where the satellite at the time desired.
几种力作用在卫星上。这些力分为保守力和非保守力。目前的研究工作主要是研究保守力对卫星轨道运动的影响,并在卫星地面轨道上表示这种影响。地面轨道是由卫星在轨道上运行时,地球上正下方的点形成的点轨迹。利用Matlab软件包设计了计算J2力和太阳-太阳力作用下的扰动地面轨迹的数学模型和程序代码。而J2和Luni-Solar是一个保守力,长期变化只出现在RAAN和。否则剩余的轨道元素是周期性变化的。计算了在J2力和日-日力作用下的扰动地面轨迹。将扰动后的卫星位置矢量转换为相应的经纬度。显示卫星在一次旋转中的位置,以表示卫星在所需时间的位置。
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引用次数: 0
IMPACT OF NANOSIZED SILICA ON THE PHYSICO-MECHANICAL PROPERTIES AND CORROSION PROTECTION OF CONCRETE 纳米二氧化硅对混凝土物理力学性能及防腐性能的影响
Pub Date : 2019-06-01 DOI: 10.21608/absb.2019.67893
E. M. Elnaggar, T. Elsokkary, Mostafa A. Shohide, Basil A. El Sabbagh
Nanomaterials have an important role for enhancingthe concrete properties and inhibition of rebar corrosion in reinforced concrete. Nanosilica (NS) is one of the most effective cementitious materials, which possess high pozzolanic nature. In this work, NS was added in mix design of concrete with different ratios as; 0, 0.5, 1, 1.5, 2and 2.5 % by weight of Portland cement. Physical, mechanical properties (workability, density) were determinedfor the fresh concrete samples. While, compressive strength andmicrostructural properties of the interfacial transition zone (ITZ) between cement pastes and aggregates of concrete were investigatedfor the hardened samples.As well as electrochemical measurements (open circuit potential and linear polarization) were done for the reinforced concrete samples. The results show that, concretes containing NS up to 2% have a higher compressive strength and a denser in interfacial transition zone (ITZ). Also, corrosion inhibition for reinforced concrete increased gradually by increasing NS addition up to 2%.
纳米材料在提高混凝土性能和抑制钢筋腐蚀方面具有重要作用。纳米二氧化硅(NS)具有高度的火山灰性质,是最有效的胶凝材料之一。在本工作中,在混凝土配合比设计中加入不同比例的NS;0、0.5、1、1.5、2和2.5%的硅酸盐水泥重量。测定了新鲜混凝土样品的物理、机械性能(和易性、密度)。同时,对硬化试样进行了水泥浆体与混凝土骨料界面过渡区(ITZ)的抗压强度和微观结构特性研究。并对钢筋混凝土试样进行了电化学测量(开路电位和线极化)。结果表明,NS含量为2%的混凝土具有较高的抗压强度和界面过渡区(ITZ)密度。当NS添加量增加至2%时,对钢筋混凝土的缓蚀作用逐渐增强。
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引用次数: 0
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Al-Azhar Bulletin of Science
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