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A Novel Promising Sensing Properties of Sprayed Ternary Co 2SnO 4 Towards Ethanol Vapours 喷涂三元co2sno4对乙醇蒸气的传感特性研究
Pub Date : 2020-01-01 DOI: 10.2139/ssrn.3708729
A. Labidi
For the first time Cubic spinel Cobalt Stannate Co2SnO4 (CTO) nanomaterial elaborated by spray pyrolysis root and used as sensitive layer for ethanol (C2H5OH) vapours detection. The response of layer towards low, medium and high ethanol concentrations exhibited a stable behaviour under dry and humid atmospheres at the optimal working temperature of 150 °C, which is relatively low temperature if we compared to those of the conventional semiconductor gas sensors. The morphology and structure of the elaborated layer were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Energy Dispersive X-ray Spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The characteristics results allow us to propose a detection mechanism involving CO2 as intermediate reactive molecules. According to its stable and acceptable sensing response, Co2SnO4 could be considered as a promising sensitive layer for ethanol sensors devices at low and high humidity rates.
采用喷雾热解法首次制备了立方尖晶石锡酸钴(CTO)纳米材料,并将其作为乙醇(C2H5OH)蒸汽检测的敏感层。该层对低、中、高浓度乙醇的响应在干燥和潮湿环境下表现出稳定的行为,最佳工作温度为150°C,与传统半导体气体传感器相比,这是相对较低的温度。利用扫描电镜(SEM)、x射线衍射(XRD)、x射线能谱(EDX)、x射线光电子能谱(XPS)和透射电镜(TEM)对制备层的形貌和结构进行了表征。这些特征结果使我们能够提出一种涉及二氧化碳作为中间反应分子的检测机制。根据其稳定且可接受的传感响应,Co2SnO4可以被认为是低湿度和高湿度下乙醇传感器器件的有前途的敏感层。
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引用次数: 0
Core Effect of Local Atomic Configuration and Design Principles of Al xCoCrFeNi High-Entropy Alloys alxcocrfeni高熵合金局部原子构型的核心效应及设计原则
Pub Date : 2019-09-03 DOI: 10.2139/ssrn.3446987
Yu-Chia Yang, Cuixia Liu, Chun-Yu Lin, Z. Xia
High-entropy alloys (HEAs) are known to have four core effects that lead to the superior mechanical properties over traditional alloys. In this paper, we investigated a new core effect that contribute to the unique characteristics of HEAs. The stacking fault and twin formation energies of AlxCoCrFeNi HEAs were calculated with the density functional theory (DFT) methods, which show large variations and even negative energies due to the new core effect. A design principle was proposed to predict the mechanical properties of the HEAs. The effect of temperature was also determined, which is consistent with the experimental results.
众所周知,高熵合金(HEAs)具有四种核心效应,这些效应导致其具有优于传统合金的机械性能。在本文中,我们研究了一种新的核心效应,它有助于高等教育机构的独特特征。用密度泛函理论(DFT)方法计算了AlxCoCrFeNi HEAs的层错和孪晶形成能,发现由于新核效应,层错和孪晶形成能变化较大,甚至出现负能量。提出了一种预测HEAs力学性能的设计原则。温度的影响与实验结果一致。
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引用次数: 0
Ductile-Brittle Transition of Open-Cell Nanoporous Cu in Tension: A Reliance of Specific Surface Area 开孔纳米孔铜在张力下的韧性-脆性转变:比表面积的依赖
Pub Date : 2019-07-03 DOI: 10.2139/ssrn.3414017
Liang Wang, W. Bi, L. Deng, S. Xiao, Li Bingqing, X. Deng, Xingming Zhang, Jian-feng Tang, Wangyu Hu
Abstract We report the ductile-brittle transitions and their reliances on specific surface area (γ), for the bi-continuous and open-cell nanoporous (NP) Cu in tension, using molecular dynamics simulations. With an increase of γ, NP Cu undergo the first ductile-to-brittle (γ≤ 2.13 nm−1) and subsequent brittle-to-ductile (γ > 2.13 nm−1) transitions. Two different plasticity modes are governing such two ductile-brittle transitions: dislocation activities inhibition for the former and dislocation networks formation contributes to the latter. Serving as the origin of dislocations/stacking faults, the surface characteristic plays a key role in such ductile-brittle transition and deformation modes.
摘要利用分子动力学模拟方法,研究了双连续开孔纳米孔(NP) Cu在张力下的韧性-脆性转变及其对比表面积(γ)的依赖关系。随着γ的增加,NP Cu经历了第一次从韧性到脆性(γ≤2.13 nm−1)和随后的脆性到韧性(γ > 2.13 nm−1)转变。两种不同的塑性模式控制着这两种韧脆转变:前者是位错活动的抑制,后者是位错网络的形成。表面特征作为位错/层错的根源,在这种韧脆转变和变形模式中起着关键作用。
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引用次数: 5
Decoration of Voids with Rhenium and Osmium Transmutation Products in Neutron Irradiated Single Crystal Tungsten 中子辐照单晶钨中铼锇嬗变产物对空洞的修饰
Pub Date : 2019-05-16 DOI: 10.2139/ssrn.3389518
M. J. Lloyd, R. Abernethy, I. Griffiths, P. Bagot, M. Moody, D. Armstrong, M. Gilbert
Abstract High temperature, neutron irradiated single crystal tungsten, with a post irradiation composition of W - 1.20 ± 0.11 at.%Re - 0.11 ± 0.05 at.%Os - 0.03 ± 0.01 at.%Ta was characterised using a combination of Atom Probe Tomography (APT) and Scanning Transmission Electron Microscopy (STEM). APT showed that within nanoscale clusters of Re/Os, the atomic density was above the theoretical limit. Complimentary High Angle Annular Dark Field (HAADF) imaging shows that some clusters contain voids at their centre which are leading to APT aberrations and enhancing the atomic density. High resolution Energy Dispersive X-ray (EDX) spectroscopy shows that voids are decorated with a shell of rhenium with a small osmium cluster to one side.
摘要高温、中子辐照单晶钨,辐照后成分为W - 1.20 ± 0.11 at。%Re - 0.11 ± 0.05 at。%Os - 0.03 ± 0.01 at。%Ta采用原子探针断层扫描(APT)和扫描透射电镜(STEM)相结合的方法进行表征。APT表明,在纳米级Re/Os簇内,原子密度高于理论极限。互补高角环形暗场(HAADF)成像显示,一些星团在其中心含有空洞,这导致APT像差和提高原子密度。高分辨率能量色散x射线(EDX)光谱显示,空腔被铼壳装饰,其中一侧有一个小的锇团簇。
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引用次数: 38
Fatigue Cohesive Zone-Magnetomechanical Coupling Model for Crack Initiation Detection at Coating/Substrate Interface 涂层/基体界面裂纹萌生检测的疲劳粘聚区-磁力耦合模型
Pub Date : 2019-05-16 DOI: 10.2139/ssrn.3389486
Zhengchun Qian, Haihong Huang
We develop a fatigue cohesive zone-magnetomechanical coupling model for predicting crack initiation at coating/substrate interface of ferromagnetic materials. The model is constructed based on the spontaneous magnetization phenomenon and the cohesive zone concept. The variation of measurable physical magnetic field intensity with fatigue cycles at the interfacial pre-crack tip is analyzed. The physical mechanism underlying generation and variation of interfacial spontaneous magnetization is also revealed from magnetic domain movement. The model can be used to calculate the magnetic field intensity threshold of interfacial crack initiation, which provides the evaluation guidance for magnetic nondestructive testing of coating/substrate interface.
建立了铁磁材料涂层/基体界面裂纹萌生的疲劳粘聚区-磁力耦合模型。该模型是基于自发磁化现象和内聚带概念建立的。分析了界面预裂尖端可测物理磁场强度随疲劳循环次数的变化规律。从磁畴运动的角度揭示了界面自发磁化产生和变化的物理机制。该模型可用于计算界面裂纹起裂的磁场强度阈值,为涂层/基体界面磁无损检测提供评价指导。
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引用次数: 0
Competing Failure Mechanisms in Metal Matrix Composites and Their Effects on Fracture Toughness 金属基复合材料的竞争失效机制及其对断裂韧性的影响
Pub Date : 2019-01-04 DOI: 10.2139/ssrn.3310383
Yan Li, Jun Cao, C. Williams
Abstract Development of high performance Metal Matrix Composites (MMCs) requires careful microstructure design which can improve material's fracture toughness while maintaining high strength. Microstructure and constituent properties combine to determine the overall fracture toughness of MMCs through the activation of different deformation and failure mechanisms. Although the effects of key microstructural attributes on the fracture toughness of MMCs have been discussed in previous studies, their effects on the interplay between plastic deformation and crack formation, as well as their effects on the competing failure mechanisms have not been systematically studied. In this paper, an integrated experimental and analytical framework is presented to evaluate the fracture toughness of MMCs through an assessment of energy contributions in terms of plastic deformation and crack surface formation in the matrix, reinforcement particles and interface. J-integral is calculated through displacement field measurement using Digital Image Correlation method. The competition of different failure mechanisms and their relations with material deformation are quantified through an analytical model by considering the effects of reinforcement volume fraction, interfacial property and yield stress of the matrix. Calculations carried out concern 6092Al/SiCp, but the overall approach applies to other MMCs as well. Results from this work indicate that interface debonding is a beneficial failure mechanism for fracture toughness enhancement of MMCs. It not only increases the surface energy dissipation by creating tortuous crack paths, but also promotes plastic deformation in the ductile matrix which largely contributes to the toughening of MMCs. The activation of interface debonding primarily depends on the volume fraction of SiCp, the yield stress of Al and the interface bonding energy.
高性能金属基复合材料的开发需要精心的微观结构设计,以提高材料的断裂韧性,同时保持高强度。显微组织和组分性能共同决定了复合材料在不同变形和破坏机制下的整体断裂韧性。虽然之前的研究已经讨论了关键组织属性对mmc断裂韧性的影响,但它们对塑性变形与裂纹形成相互作用的影响以及它们对竞争破坏机制的影响尚未得到系统的研究。本文提出了一个综合实验和分析框架,通过评估基体、增强颗粒和界面中塑性变形和裂纹表面形成的能量贡献来评估mmc的断裂韧性。采用数字图像相关法,通过位移场测量计算j积分。通过考虑增强体分数、界面特性和基体屈服应力影响的分析模型,量化了不同破坏机制的竞争及其与材料变形的关系。所进行的计算涉及6092Al/SiCp,但总体方法也适用于其他mmc。研究结果表明,界面脱粘是增强复合材料断裂韧性的有效破坏机制。它不仅通过形成弯曲裂纹路径增加表面能量耗散,而且还促进了韧性基体的塑性变形,这在很大程度上有助于mmc的增韧。界面脱键的激活主要取决于SiCp的体积分数、Al的屈服应力和界面键能。
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引用次数: 7
Preferential Slip Initiation in Interlayer β During Compression of a Widmannstätten-Structure Titanium Alloy Widmannstätten-Structure钛合金压缩过程中层间β的优先滑移萌生
Pub Date : 2019-01-01 DOI: 10.2139/ssrn.3414706
Ke Wang, Zhibing Yan, Yu Zhou, R. Xin, Qing Liu
Based on quasi in-situ observation on the slip trace during compression of a widmannstätten-structure titanium alloy, it was firstly found that the slip initiated in the interlayer β prior to lamellar α within one α colony. Interestingly, the preferential slip initiation in interlayer β did not occur at the highest Schmid factor (SF). The slip transfer from interlayer β to lamellar α did not only require a good collaboration between SF and geometric compatability parameter (m'), but also need a large accumulation of deformation in interlayer β.
通过对widmannstätten-structure钛合金压缩过程中滑移轨迹的准原位观察,首次发现在一个α集落内,滑移先发生在层间β层,后发生在片层α层。有趣的是,当施密德因子(SF)最高时,层间β的优先滑移起始并未发生。从层间β向片层α的滑移转移不仅需要SF与几何相容参数(m′)之间的良好协同作用,而且还需要在层间β中积累大量变形。
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引用次数: 1
Identification of a Ni 16Ti 11 Precipitate Phase within Nickel-Rich, Nickel-Titanium-Based Alloys 富镍镍钛基合金中Ni - 16Ti - 11相的鉴定
Pub Date : 2019-01-01 DOI: 10.2139/ssrn.3438560
Sean H. Mills, Yu Hong, B. Kappes, R. Noebe, M. A. Zaeem, A. Stebner, B. Amin-ahmadi
A "cubic Ni3Ti2" precipitate phase recently reported to exist within NiTi and NiTiNb alloys is documented to also form within a Ni56Ti36Hf8 alloy upon aging. Using transmission electron microscopy and ab intio density functional theory techniques, the phase is more precisely identified to be Ni16Ti11 with symmetry of the pm3m space group and a lattice parameter a = 8.816 Å. In this structure, nickel atoms preferentially segregate to the perimeter lattice sites of the 54-atom unit cell.
最近报道在NiTi和NiTiNb合金中存在的“立方Ni3Ti2”沉淀相也记录在Ni56Ti36Hf8合金中时效形成。利用透射电子显微镜和初始密度泛函理论技术,更精确地确定了相为Ni16Ti11,具有pm3m空间群的对称性,晶格参数a = 8.816 Å。在这种结构中,镍原子优先分离到54原子单元胞的周长晶格位置。
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引用次数: 0
Activation and Suppression of < c+a > Dislocations in a Textured Mg-3Al-1Zn Alloy 织构Mg-3Al-1Zn合金< c+a >位错的激活与抑制
Pub Date : 2019-01-01 DOI: 10.2139/ssrn.3490395
Dexin Zhao, Xiaolong Ma, S. Picak, I. Karaman, K. Xie
In this work, we statistically studied the activation and suppression of < c+a > dislocations in a textured Mg-3Al-1Zn alloy after compression. Our results revealed that the activation and suppression of < c+a > dislocations in polycrystals are primarily governed by the overall texture, regardless of the crystallographic orientation of each grain. This observation is explained by the requirement of five independent slip systems, reduced anisotropy, and twin-induced strain localization. These direct observations of < c+a > dislocation activities offer a key insight into understanding the deformation mechanism of polycrystalline Mg alloys.
在这项工作中,我们统计研究了<的激活和抑制;c +比;变形Mg-3Al-1Zn合金压缩后的位错。我们的结果显示<的激活和抑制;c +比;多晶中的位错主要是由整体织构决定的,而与每个晶粒的晶体取向无关。这一观察结果可以用五个独立滑移系统、降低各向异性和双致应变局部化的要求来解释。这些对<c +比;位错活动为理解多晶镁合金的变形机制提供了关键的见解。
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引用次数: 0
Small-Angle Neutron Scattering Reveals the Effect of Mo on Interphase Nano-Precipitation in Ti-Mo Micro-Alloyed Steels 小角中子散射揭示Mo对Ti-Mo微合金钢相间纳米析出的影响
Pub Date : 2019-01-01 DOI: 10.2139/ssrn.3441028
Yiqiang Wang, S. Clark, B. Cai, D. Venero, Md. Mohidul Hasan, M. Gorley, E. Surrey, G. McCartney, S. Seetharaman, P. Lee
Ti-containing micro-alloyed steels are often alloyed with molybdenum (Mo) to reduce nano-precipitate coarsening, although the mechanism is still disputed. Using small angle neutron scattering we characterised the precipitate composition and coarsening of Ti-alloyed and Ti-Mo-alloyed steels. The results demonstrate ~25 at.% of Ti is substituted by Mo in the (Ti, Mo)C precipitates, increasing both the precipitate volume percent and average size. Mo alloying did not retard precipitation coarsening, but improved lattice misfit between precipitate and matrix, contributing to better aging resistance of the Ti-Mo-alloyed steel. This new understanding opens opportunities for designing aging-resistant micro-alloyed steels with lean alloying elements.
含钛微合金钢常与钼(Mo)合金化以减少纳米析出的粗化,但其机制仍有争议。用小角中子散射法对钛合金和钛钼合金钢的析出相组成和粗化过程进行了表征。结果表明~25 at。(Ti, Mo)C析出相中%的Ti被Mo取代,增加了析出相的体积百分比和平均尺寸。Mo合金化没有延缓析出物粗化,但改善了析出物与基体之间的晶格失配,提高了ti -Mo合金钢的耐时效性能。这种新的认识为设计具有低合金元素的耐老化微合金钢提供了机会。
{"title":"Small-Angle Neutron Scattering Reveals the Effect of Mo on Interphase Nano-Precipitation in Ti-Mo Micro-Alloyed Steels","authors":"Yiqiang Wang, S. Clark, B. Cai, D. Venero, Md. Mohidul Hasan, M. Gorley, E. Surrey, G. McCartney, S. Seetharaman, P. Lee","doi":"10.2139/ssrn.3441028","DOIUrl":"https://doi.org/10.2139/ssrn.3441028","url":null,"abstract":"Ti-containing micro-alloyed steels are often alloyed with molybdenum (Mo) to reduce nano-precipitate coarsening, although the mechanism is still disputed. Using small angle neutron scattering we characterised the precipitate composition and coarsening of Ti-alloyed and Ti-Mo-alloyed steels. The results demonstrate ~25 at.% of Ti is substituted by Mo in the (Ti, Mo)C precipitates, increasing both the precipitate volume percent and average size. Mo alloying did not retard precipitation coarsening, but improved lattice misfit between precipitate and matrix, contributing to better aging resistance of the Ti-Mo-alloyed steel. This new understanding opens opportunities for designing aging-resistant micro-alloyed steels with lean alloying elements.","PeriodicalId":7765,"journal":{"name":"AMI: Scripta Materialia","volume":" 33","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91415495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
期刊
AMI: Scripta Materialia
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