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In-situ zircon and cassiterite LA-ICP-MS geochronology and implications for granite hosted Sn deposit models and exploration: insights from the Cameroon Line 原位锆石和锡石 LA-ICP-MS 地球年代学及其对花岗岩包裹锡矿床模型和勘探的影响:喀麦隆线的启示
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-04-01 DOI: 10.2138/am-2023-9174
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引用次数: 0
Raman Spectroscopy of the Ilmentite — Geikielite Solid Solution Ilmentite - Geikielite 固溶体的拉曼光谱分析
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-03-28 DOI: 10.2138/am-2023-9262
L. Breitenfeld, M. Dyar, Leif Tokle, Kevin Robertson
Ilmenite (Fe2+TiO3) and geikielite (MgTiO3) are important terrestrial minerals relevant to the geology of the Earth, the Moon, Mars, and meteorite samples. Raman spectroscopy is a powerful technique that allows for mineral cation determination for the ilmenite — geikielite solid solution. We report on a sample suite of nine samples within the ilmenite — geikielite solid solution and provide context for their quantitative interpretation. We compare a univariate Raman peak position model for predicting ilmenite composition with a multivariate machine learning model. The univariate model is currently recommended, though the multivariate model may become superior if the data set size is increased. This study lays the groundwork for quantifying Fe (ilmenite) and Mg (geikielite) within oxides minerals using a cheap, portable, and efficient technology like Raman spectroscopy.
钛铁矿(Fe2+TiO3)和镁钛铁矿(MgTiO3)是与地球、月球、火星和陨石样本地质有关的重要陆地矿物。拉曼光谱是一种功能强大的技术,可用于确定钛铁矿-黝帘石固溶体的矿物阳离子。我们报告了钛铁矿-黝帘石固溶体中的九个样品套件,并提供了定量解释的背景。我们比较了预测钛铁矿成分的单变量拉曼峰位模型和多变量机器学习模型。目前推荐使用单变量模型,但如果数据集的规模扩大,多变量模型可能会更优越。这项研究为利用拉曼光谱这种廉价、便携、高效的技术量化氧化物矿物中的铁(钛铁矿)和镁(geikielite)奠定了基础。
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引用次数: 0
Three new iron-phosphate minerals from the El Ali iron meteorite, Somalia: Elaliite, Fe2+8Fe3+ (PO4)O8; elkinstantonite, Fe4(PO4)2O; and olsenite, KFe4(PO4)3 索马里埃尔阿里铁陨石中的三种新的铁磷酸盐矿物:埃尔阿里铁陨石,Fe2+8Fe3+ (PO4)O8;埃尔金斯坦顿铁陨石,Fe4(PO4)2O;以及奥尔森铁陨石,KFe4(PO4)3
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-03-28 DOI: 10.2138/am-2023-9225
C. D. Herd, Chi Ma, A. Locock, Radhika Saini, E. Walton
Petrologic investigation of the El Ali IAB iron meteorite (Somalia) revealed three new minerals: elaliite (Fe2+8Fe3+ (PO4)O8, IMA 2022-087), elkinstantonite(Fe4(PO4)2O, IMA 2022-088), and olsenite (KFe4(PO4)3, IMA 2022-100). The name elaliite recognizes the occurrence of this mineral within the El Ali meteorite, originally located at 4° 17′ 17″N, 44° 53′ 54″E. Elkinstantonite is named after Linda (Lindy) Elkins-Tanton (b. 1965), a planetary scientist and professor in the School of Earth and Space Exploration at Arizona State University. The name olsenite is in honor of Edward J. Olsen (1927-2020), the former Curator of Mineralogy and Meteorites at the Field Museum of Natural History in Chicago (1960-1991). The new minerals and their names have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association. The holotype specimens of elaliite, elkinstantonite and olsenite consist of the polished block mount with accession number MET11814/2-1/EP1 deposited in the University of Alberta Meteorite Collection. Elaliite, elkinstantonite and olsenite occur along with wustite, troilite, sarcopside and Ca-bearing graftonite within inclusions in the iron-nickel metal (kamacite, 9.4 wt% Ni) that makes up the bulk of the El Ali sample. The empirical formulas determined by electron probe microanalysis for elaliite, elkinstantonite, and olsenite are: (Fe2+7.943Fe3+1.020Cr0.010Ni0.006Ca0.004Mn0.004)Σ8.987(P0.932Si0.077S0.005)Σ1.014O12, (Fe2+3.947Mn0.016Ni0.003Ca0.001Cr0.001)Σ3.968(P1.986Si0.014S0.013)Σ2.013O9, and (K0.820Na0.135Ca0.004)Σ0.959(Fe3.829Mn0.050)Σ3.879(P2.972S0.058Si0.017)Σ3.047O12. Electron backscatter diffraction was used to confirm the crystal structures of the three new minerals. Raman spectra for all three minerals are also presented.
对埃尔阿里 IAB 铁陨石(索马里)进行的岩石学调查发现了三种新矿物:埃拉利石(Fe2+8Fe3+ (PO4)O8,IMA 2022-087)、埃尔金斯坦顿石(Fe4(PO4)2O,IMA 2022-088)和奥尔森石(KFe4(PO4)3,IMA 2022-100)。埃尔阿里陨石原位于北纬 4° 17′ 17″,东经 44° 53′ 54″,埃尔阿里陨石的名称是对埃尔阿里陨石中出现的这种矿物的认可。埃尔金斯坦顿石以行星科学家、亚利桑那州立大学地球与太空探索学院教授琳达-埃尔金斯坦顿(Linda (Lindy) Elkins-Tanton,生于 1965 年)的名字命名。奥尔森石是为了纪念芝加哥菲尔德自然历史博物馆矿物学和陨石馆前馆长爱德华-J-奥尔森(Edward J. Olsen,1927-2020 年)(1960-1991 年)。这些新矿物及其名称已获得国际矿物学协会新矿物、命名和分类委员会(Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association)的批准。elaliite、elkinstantonite 和 olsenite 的主模式标本由存放在阿尔伯塔大学陨石收藏馆的编号为 MET11814/2-1/EP1 的抛光块状底座组成。埃拉利石、埃尔金斯坦顿石和奥尔森特石与乌斯托石、特罗利石、弧闪石和含钙质的石榴石一起出现在构成埃尔阿里样本主体的铁镍金属(卡马奇石,镍含量为 9.4 wt%)的包裹体中。通过电子探针显微分析法确定的埃利石、埃金石和奥尔森石的经验公式为(Fe2+7.943Fe3+1.020Cr0.010Ni0.006Ca0.004Mn0.004)Σ8.987(P0.932Si0.077S0.005)Σ1.014O12, (Fe2+3.947Mn0.016Ni0.003Ca0.001Cr0.001)Σ3.968(P1.986Si0.014S0.013)Σ2.013O9, and (K0.820Na0.135Ca0.004)Σ0.959(Fe3.829Mn0.050)Σ3.879(P2.972S0.058Si0.017)Σ3.047O12.电子反向散射衍射被用来确认这三种新矿物的晶体结构。此外,还展示了这三种矿物的拉曼光谱。
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引用次数: 0
Interpreting Mineral Deposit Genesis Classification with Decision Maps: A Case Study Using Pyrite Trace Elements 利用决策图解读矿床成因分类:使用黄铁矿微量元素的案例研究
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-03-28 DOI: 10.2138/am-2023-9254
Yu Wang, Kun-Feng Qiu, A. C. Telea, Zhao-Liang Hou, Tong Zhou, Yi-Wei Cai, Zheng-Jiang Ding, Hao-Cheng Yu, Jun Deng
Machine learning improves geochemistry discriminant diagrams in classifying mineral deposit genetic types. However, the increasingly recognized ‘black box’ property of machine learning has been hampering the transparency of complex data analysis, leading to the challenge in deep geochemical interpretation. To address the issue, we revisited pyrite trace elements and propose to use ‘Decision Map’, a cutting-edge visualization technique for machine learning. This technique reveals mineral deposit classifications by visualizing the ‘decision boundaries’ of high-dimensional data, a concept crucial for model interpretation, active learning, and domain adaptation. In the context of geochemical data classification, it enables geologists to understand the relationship between geo-data and decision boundaries, assess prediction certainty, and observe the data distribution trends. This bridges the gap between the insightful properties of traditional discriminant diagrams and the high-dimensional efficiency of modern machine learning. Using pyrite trace element data, we construct a decision map for mineral deposit type classification, which maintains the accuracy of machine learning while adding valuable visualization insight. Additionally, we demonstrate two applications of decision maps. First, we show how decision maps can help resolve the genetic type dispute of a deposit whose data was not used in training the models. Second, we demonstrate how the decision maps can help understand the model, which further helps find indicator elements of pyrite. The recommended indicator elements by decision maps are consistent with geologists’ knowledge. This study confirms the decision map’s effectiveness in interpreting mineral genetic type classification problems. In geochemistry classification, it marks a shift from conventional machine learning to a visually insightful approach, thereby enhancing the geological understanding derived from the model. Furthermore, our work implies that decision maps could be applicable to diverse classification challenges in geosciences.
机器学习改进了地球化学判别图在矿床成因类型分类中的作用。然而,机器学习的 "黑箱 "特性日益得到认可,这阻碍了复杂数据分析的透明度,从而给深度地球化学解释带来了挑战。为了解决这个问题,我们重新研究了黄铁矿痕量元素,并建议使用 "决策图"--一种用于机器学习的前沿可视化技术。该技术通过可视化高维数据的 "决策边界 "来揭示矿床分类,这一概念对于模型解释、主动学习和领域适应至关重要。在地球化学数据分类方面,它使地质学家能够理解地质数据与决策边界之间的关系,评估预测的确定性,并观察数据分布趋势。这在传统判别图的洞察力特性与现代机器学习的高维效率之间架起了一座桥梁。利用黄铁矿痕量元素数据,我们构建了用于矿床类型分类的判别图,在保持机器学习准确性的同时,增加了宝贵的可视化洞察力。此外,我们还展示了决策图谱的两种应用。首先,我们展示了决策图如何帮助解决矿床的遗传类型争议,而这些矿床的数据并未用于模型训练。其次,我们展示了决策图如何帮助理解模型,从而进一步帮助找到黄铁矿的指示元素。决策图推荐的指示元素与地质学家的知识是一致的。这项研究证实了决策图在解释矿物成因类型分类问题上的有效性。在地球化学分类中,它标志着从传统的机器学习到视觉洞察方法的转变,从而增强了从模型中得出的地质认识。此外,我们的工作还意味着决策图可以适用于地球科学领域的各种分类挑战。
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引用次数: 0
Geochemical characteristics of mineral inclusions in the Luobusa chromitite (Southern Tibet): Implications for an intricate geological setting 罗布莎铬铁矿(西藏南部)矿物包裹体的地球化学特征:对复杂地质环境的影响
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-03-28 DOI: 10.2138/am-2023-9273
F. Xiong, B. Zoheir, Xiangzhen Xu, G. Guo, M. Frische, Jingsui Yang
The Luobusa chromitite and ophiolite present a captivating geological feature marked by peculiar mineralogical and geochemical characteristics. Abundant platinum-group minerals (PGM), base-metal sulfides (BMS), and PGE-sulfides and alloys in the chromitite unveil a multi-stage genesis, encompassing partial mantle melting, melt-rock interactions, and dynamic shifts in oxygen and sulfur fugacity (fO2, fS2). This study explores the geochemical signatures and PGE patterns of these mineral inclusions to elucidate the evolutionary process of the Luobusa ophiolite, tracing its transition from a sub-ridge environment to a sub-arc setting. The variable ΣPGE values (40 - 334 ppb) in chromitite, coupled with notably lower ΣPGE values (10 - 63 ppb) in dunite imply extensive melt fractionation and melt-rock interactions. Coexisting well-crystalline Os-Ir alloys alongside interstitial BMS likely reflect low fS2 and high temperatures during the early formational stages, whereas abundant anhedral sulfarsenide and pyrite inclusions in chromite point to lower temperatures and higher fS2 during the late stages. The trace element composition of pyrite inclusions resonates with the characteristics of mid-ocean ridge (MOR) and oceanic island rocks, manifesting interplay of diverse magmatic sources during the evolution of the Luobusa ophiolite.
罗布莎铬铁矿和蛇绿混杂岩呈现出一种迷人的地质特征,具有奇特的矿物学和地球化学特征。铬铁矿中丰富的铂族矿物(PGM)、贱金属硫化物(BMS)以及 PGE 硫化物和合金揭示了多阶段成因,包括部分地幔熔化、熔岩相互作用以及氧和硫富集度(fO2、fS2)的动态变化。本研究探讨了这些矿物包裹体的地球化学特征和 PGE 模式,以阐明罗布莎蛇绿岩的演化过程,追溯其从亚脊环境向亚弧环境的过渡。铬铁矿的ΣPGE值(40 - 334 ppb)变化不定,而云英岩的ΣPGE值(10 - 63 ppb)明显较低,这意味着存在广泛的熔体分馏和熔岩相互作用。与间隙BMS共存的结晶良好的Os-Ir合金可能反映了早期形成阶段的低fS2和高温,而铬铁矿中丰富的正方体硫砷化物和黄铁矿包裹体则表明晚期阶段的低温和较高的fS2。黄铁矿包裹体的微量元素组成与洋中脊(MOR)和大洋岛屿岩石的特征相吻合,表明在罗布莎蛇绿岩的演化过程中多种岩浆源相互作用。
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引用次数: 0
Mechanisms of fluid degassing in shallow magma chambers control the formation of porphyry deposits 浅岩浆室流体脱气机制控制斑岩矿床的形成
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-03-28 DOI: 10.2138/am-2023-9091
Zixuan Wang, Yuanchuan Zheng, Bo Xu, Zengqian Hou, Ya-hui Shen, Aiping Zhang, Lu Wang, Chang-da Wu, Qingfeng Guo
Magmatic fluid degassing within shallow magma chambers underneath the ore bodies is critical to the formation of porphyry Cu-Au deposits (PCDs). Yet, it remains unclear that how the ways of fluid degassing influence on the development of PCDs. Here, geochemical data of apatite, amphibole and plagioclase from ore-forming and coeval barren porphyries have been analyzed in Sanjiang metallogenic belt, China. The ore-forming porphyries normally exhibit high and wide XF/XCl (31.76-548.12) and XF/XOH (0.779-7.370) ratios of apatites, which are evidently higher than those of the barren porphyries (XF/XCl of 1.03-26.58; XF/XOH of 0.686-3.602). Combined with the continuous variation features of Cl/OH ratios and H2O contents of melts calculated by amphiboles, as well as fluid migration models, we constrained the mechanisms of fluid degassing within shallow magma chambers underneath PCDs. There are three different ways of fluid degassing, while only fluid degassing via fluid channel stage can migrate and focus the metal-rich fluids effectively, conducive to the development of PCDs. The mechanisms of magmatic fluid degassing processes are further controlled by the storage depths of magma chambers and initial H2O contents of the magmas revealed by the compositions of amphibole, plagioclase and thermodynamic modelling. Magmas, with shallower storage depth and higher initial H2O content, are more likely to experience extensive and focused fluid degassing, leading to the generation of PCDs. This study demonstrates the potential utility of integrated mineral analyses, the thermodynamic modelling for investigating the mechanisms of magmatic fluid degassing in porphyry systems, as well as identifying prospective buried PCDs.
矿体下方浅岩浆腔内的岩浆流体脱气对斑岩型铜金矿床(PCD)的形成至关重要。然而,流体脱气的方式如何影响斑岩型铜金矿床的形成仍不清楚。本文分析了中国三江成矿带成矿斑岩和共生贫瘠斑岩中磷灰石、闪石和斜长石的地球化学数据。成矿斑岩中磷灰石的XF/XCl(31.76-548.12)和XF/XOH(0.779-7.370)比值高且宽,明显高于贫瘠斑岩(XF/XCl为1.03-26.58;XF/XOH为0.686-3.602)。结合闪长岩计算的熔体中Cl/OH比值和H2O含量的连续变化特征,以及流体迁移模型,我们对PCD地下浅岩浆腔内流体脱气机制进行了约束。流体脱气有三种不同的方式,而只有通过流体通道阶段的流体脱气才能有效地迁移和集中富含金属的流体,有利于PCD的发育。岩浆流体脱气过程的机制还受岩浆室的储存深度和岩浆中闪石、斜长石成分及热力学模型所揭示的初始 H2O 含量的控制。储存深度较浅、初始 H2O 含量较高的岩浆更有可能经历广泛而集中的流体脱气,从而产生 PCD。这项研究证明了综合矿物分析和热力学建模在研究斑岩系统岩浆流体脱气机制以及确定潜在埋藏的多孔质结核方面的潜在用途。
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引用次数: 0
Fluids in the Shallow Mantle of Southeastern Australia: Insights from Phase Equilibria 澳大利亚东南部浅地幔中的流体:相平衡的启示
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-03-28 DOI: 10.2138/am-2022-8735
William M. Lamb, Lindsey E. Hunt, Robert K. Popp
Small amounts of water (10s to 100s of ppm) can have a profound effect on the properties of mantle peridotites, including viscosities, conductivities, and melting temperatures. Measuring the water content of nominally anhydrous minerals (NAMs) has provided insight into the amounts of water contained within mantle rocks. However, converting from NAM water contents to the activity of H2O is non-trivial. Equilibria involving amphibole can be used to determine values of the activity of H2O (aH2O) at the time of mineral equilibration. This approach yields low values of the activity of H2O (< 0.3) for four peridotite xenoliths from Southeastern Australia. These four xenoliths also record values of oxygen fugacity (fO2) that range from -0.2 to -1.2 (Log units relative to FMQ). All these values of fO2 are inconsistent with the presence of a CH4-rich fluid (too oxidizing), and the lowest value of oxygen fugacity, as recorded by one sample, is inconsistent with the presence of a CO2-rich fluid.
少量的水(10 至 100 ppm)会对地幔橄榄岩的性质产生深远的影响,包括粘度、电导率和熔化温度。测量名义无水矿物(NAMs)的含水量有助于了解地幔岩石中的含水量。然而,将名义无水矿物的含水量转换为 H2O 的活度并非易事。涉及闪石的平衡可以用来确定矿物平衡时的 H2O 活度(aH2O)值。这种方法可以得出澳大利亚东南部四块橄榄岩奇石的 H2O 活度值较低(< 0.3)。这四块奇石还记录了从-0.2到-1.2的氧富集度(fO2)值(相对于 FMQ 的对数单位)。所有这些 fO2 值都与富含 CH4 的流体(氧化性太强)不符,其中一个样本记录的最低氧富集度值与富含 CO2 的流体不符。
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引用次数: 0
Evidence for Oceans pre-4300 Ma Confirmed by Preserved Igneous Compositions in Hadean Zircon 哈代锆石中保留的火成岩成分证实了 4300 Ma 以前的海洋证据
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-03-28 DOI: 10.2138/am-2023-9180
Emilia M. Cameron, Tyler Blum, A. Cavosie, K. Kitajima, Lutz Nasdala, I. Orland, C. Bonamici, J. Valley
Detrital zircons from the Jack Hills are the dominant source of Hadean (pre-4000 Ma) terrestrial material available for study today. Values of δ18O in many of these zircons (6.0 to 7.5‰ are above the mantle-equilibrated value. For two decades, these mildly elevated values have been the primary evidence that protoliths of the zircon-forming magmas interacted at low temperature with liquid water before burial and melting, implying that the surface of Earth cooled quickly after core and moon formation, and that habitable conditions for life existed within 250 Myr of the formation of Earth, over 800 Myr before the oldest generally accepted microfossils. These conclusions are based on oxygen isotope analyses of zircon domains with well-defined growth zoning and nearly concordant U-Pb ages within zircon grains with low magnetic susceptibility, which are further inferred to be unaltered by various tests. However, no studies of Jack Hills zircons have directly correlated oxygen isotope ratios and radiation damage, which facilitates alteration in zircon. Several previous studies have selected zircons that show radiation damaged, discordant and/or hydrous domains, and have shown that such altered material is not reliable as a record of igneous composition. In contrast, this study targeted zircons that are interpreted to pristine and not altered, and demonstrates the importance of testing zircons for radiation damage and alteration as part of any geochemical study, regardless of age. This study expands on existing data, and presents the first comprehensive evaluation of δ18O, OH/O, CL imaging, U-Pb concordance and radiation-damage state within Jack Hills zircons. A total of 115 Hadean zircon grains in this study have water contents similar to nominally anhydrous standard reference zircons and are interpreted as pristine. In situ Raman data for band broadening correlated with δ18O analyses document low levels of radiation damage, indicating significant annealing. The present-day effective doses (Deff) are uniformly less than the first percolation point (dose where damage domains, that are isolated at lower damage state, overlap to form a continuous pathway through the crystal, ~2×1015 α-decays/mg, Ewing et al., 2003) and most zircons have Deff<1×1015 α-decays/mg. Modeling of representative alpha-recoil damage and annealing histories indicates that most zircons in this study have remained below the Deff of the first percolation point throughout their history. The δ18O values for these primary zircons include many that are higher than would be equilibrated with the mantle at magmatic temperatures and average 6.32 ± 1.3‰ in the Hadean and 6.26 ± 1.6‰ in the Archean. There is no correlation in our suite of pristine Hadean zircons between δ18O and OH/O, Deff, age, or U-Pb age-concordance. These carefully documented Hadean-age zircons possess low amounts of radiation damage in domains sampled by δ18O analysis, are water-poor. The mildly elevated δ18O values are
杰克山的碎屑锆石是目前可研究的哈代(4000Ma以前)陆地物质的主要来源。其中许多锆石的δ18O值(6.0-7.5‰)都高于地幔平衡值。二十年来,这些轻度升高的数值一直是锆石形成岩浆的原岩在埋藏和熔化前与液态水发生低温作用的主要证据,这意味着地球表面在地核和月球形成后迅速冷却,在地球形成后 250 Myr 内就存在适合生命居住的条件,这比公认的最古老的微化石要早 800 多 Myr。这些结论的依据是对具有明确生长分带的锆石域进行的氧同位素分析,以及对具有低磁感应强度的锆石晶粒进行的几乎一致的 U-Pb 年龄分析。然而,对杰克山锆石的研究还没有将氧同位素比率与辐射损伤直接联系起来,而辐射损伤会促进锆石的蚀变。之前的几项研究选择了出现辐射损伤、不和谐和/或水合畴的锆石,结果表明,这类改变的材料作为火成岩成分的记录并不可靠。与此相反,本研究选取的锆石被解释为原始的、未被改变的锆石,并证明了作为地球化学研究的一部分,无论年代如何,对锆石进行辐射损伤和改变测试的重要性。该研究扩展了现有数据,首次对杰克山锆石的δ18O、OH/O、CL成像、U-Pb一致性和辐射损伤状态进行了全面评估。在这项研究中,共有 115 个哈代锆石晶粒的含水量与名义上的无水标准参考锆石相似,并被解释为原始锆石。与 δ18O 分析相关的带宽原位拉曼数据记录了低水平的辐射损伤,表明存在明显的退火现象。目前的有效剂量(Deff)普遍低于第一渗滤点(在此剂量下,在较低损伤状态下孤立的损伤域重叠形成一条连续的途径穿过晶体,~2×1015 α-decays/mg,Ewing 等人,2003 年),大多数锆石的 Deff<1×1015 α-decays/mg。对具有代表性的α-反弹性损伤和退火历史的建模表明,本研究中的大多数锆石在其整个历史中都保持在第一个渗滤点的 Deff 值以下。这些原生锆石的δ18O值有许多高于在岩浆温度下与地幔平衡时的值,在黑云纪平均为6.32 ± 1.3‰,在阿寒纪平均为6.26 ± 1.6‰。在我们这套原始的哈代锆石中,δ18O与OH/O、Deff、年龄或U-Pb年龄一致性之间没有相关性。这些经过仔细记录的哈代锆石在通过δ18O分析采样的区域内具有较低的辐射损伤,并且贫水。轻度升高的δ18O值是一种原生物质地球化学特征。这些结果加强了哈代时期存在轻度升高δ18O岩浆的结论,支持了4300Ma之前存在海洋和宜居地球的假说。
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引用次数: 0
The OH stretching region in infrared spectra of the apatite OH-Cl binary system 磷灰石 OH-Cl 二元系统红外光谱中的 OH 伸缩区域
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-03-28 DOI: 10.2138/am-2023-9059
R. Tacker, John Rakovan, Daniel Harlov, John M. Hughes, Sarah B. Cichy
Polarized Fourier Transform Infrared (FTIR) microspectroscopy of the OH stretching region of hydroxylapatite-chlorapatite solid solutions presents novel problems for the assignment of peaks to specific OH-Cl pairs. Crystal structure refinements of Hughes et al. (2016) identified new positions for column anions in synthetic mixed Cl-OH apatites, with three different column anion arrangements depending on composition. These structural refinements, combined with bond valence calculations, allow for interpretation of the OH stretching region. A peak at 3574 cm-1 is identified as that from end member hydroxylapatite. A second major peak at 3548 cm-1 is only found in mixed chlorapatite-hydroxylapatite solid solutions, as is a third peak at 3592 cm-1. Both represent perturbations of the OH stretching vibration as compared to hydroxylapatite, to lower and higher frequency, respectively. Both of the new peaks are the result of a Clb-OH sequence, with adjacent anions in crystallographically similar positions, both above or both below adjacent mirror planes. One configuration has the hydrogen atom pointed towards the chlorine atom. The second has the hydrogen of the OH group pointed away from the chlorine atom. Both configurations present novel problems. The shift to lower wavenumber at 3548 cm-1 is characteristic of hydrogen bonding in fluorapatite-hydroxylapatite mixtures, yet the distance between O(H) and Clb is too great to allow it. The shift of OH stretching vibrations to lower wavenumber is produced through changes in polarization of intervening Cl-Ca2’ (or Ca2) and Ca2(’)-O3 bonds, which are affected by the presence of the large chlorine atom. Lowering the OH stretching vibration mimics the expected effect of a chlorine on a neighboring OH group in the apatite c-axis column, though without hydrogen bonding. The shift to higher wavenumbers, i.e. higher frequency at 3592 cm-1, is the opposite of that expected for hydrogen bonding between column anions in the apatite mineral group. It is ascribed to interaction between an adjacent Clb and the oxygen end of an adjacent OH dipole. This pairing places an oxygen and a chlorine atom in close proximity. Possible means of accommodation are discussed. A ubiquitous peak at 3498 cm-1 represents hydrogen bonding between an OH and the OHa site, with an interoxygen distance of about 2.9 Å. Published modeling supports the hypothesis that the OHa site is occupied by an O rather than an OH. However, no clear counterpart to this pairing is observed in crystal structure refinements for specimens lacking OHa, although the infrared absorbance is present. The existence of oxyapatite is inferred from studies of plasma-sprayed biomaterials, but the crystallographic details of the substitution have remained elusive. A minor shoulder at 3517 cm-1 does not have a clear counterpart in the structural refinements. Sequences of three columnar anions (e.g. OH-Cl-OH or Cl-OH-OH) can be ruled out, but unequivocal assignment awai
对羟基磷灰石-氯磷灰石固溶体的羟基伸展区进行偏振傅立叶变换红外(FTIR)微光谱分析,为将峰值分配到特定的羟基-氯对提出了新的问题。Hughes 等人(2016 年)的晶体结构细化确定了合成混合 Cl-OH 磷灰石中柱阴离子的新位置,根据成分的不同,柱阴离子有三种不同的排列方式。这些结构细化与键价计算相结合,可以解释羟基伸展区域。3574 cm-1 处的峰值被确定为来自羟基磷灰石末端成员的峰值。3548 cm-1 处的第二个主要峰值只出现在绿磷灰石-羟基磷灰石混合固溶体中,第三个峰值出现在 3592 cm-1 处。与羟基磷灰石相比,这两个峰都代表了羟基拉伸振动的扰动,分别频率较低和较高。这两个新峰值都是 Clb-OH 序列的结果,相邻的阴离子处于晶体学上相似的位置,都在相邻镜面的上方或下方。一种构型的氢原子指向氯原子。第二种构型是羟基的氢原子远离氯原子。这两种构型都带来了新的问题。3548 cm-1 处向较低波长的移动是氟磷灰石-羟基磷灰石混合物中氢键的特征,但 O(H)和 Clb 之间的距离太大,无法实现这种移动。羟基伸缩振动向低波数移动是由于中间的 Cl-Ca2'(或 Ca2)键和 Ca2(')-O3 键的极化发生了变化,而这些变化会受到大的氯原子存在的影响。降低 OH 伸缩振动模拟了磷灰石 c 轴柱中一个氯原子对邻近 OH 基团的预期影响,尽管没有氢键。向更高文数的移动,即 3592 cm-1 处频率的升高,与磷灰石矿物组中柱阴离子之间氢键作用的预期相反。这是由于相邻的 Clb 与相邻 OH 偶极的氧端之间的相互作用造成的。这种配对将一个氧原子和一个氯原子紧密地结合在一起。讨论了可能的适应方式。3498 cm-1 处无处不在的峰值代表 OH 与 OHa 位点之间的氢键作用,氧间距离约为 2.9 Å。然而,在缺乏 OHa 的标本的晶体结构细化中,虽然存在红外线吸收,但没有观察到与这种配对明显对应的现象。对等离子喷射生物材料的研究推断出了氧磷灰石的存在,但替代物的晶体学细节仍然难以捉摸。3517 cm-1 处的一个小肩在结构细化中没有明确的对应物。可以排除三个柱状阴离子(如 OH-Cl-OH 或 Cl-OH-OH)的序列,但明确的分配有待进一步研究。
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引用次数: 0
The application of “transfer learning” in optical microscopy: the petrographic classification of metallic minerals 光学显微镜中 "迁移学习 "的应用:金属矿物的岩石学分类
IF 3.1 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-03-22 DOI: 10.2138/am-2023-9092
Yi-Wei Cai, Kun-Feng Qiu, Maurizio Petrelli, Zhao-Liang Hou, M. Santosh, Hao-Cheng Yu, Ryan T. Armstrong, Jun Deng
Analysis of optical microscopic image data is crucial for the identification and characterization of mineral phases, and thus directly relevant to the subsequent methodology selections of further detailed petrological exploration. Here we present a novel application of Swin Transformer, a deep learning algorithm to classify metal mineral phases such as arsenopyrite, chalcopyrite, gold, pyrite, and stibnite, in images captured by optical microscopy. To speed up the training process and improve the generalization capabilities of the investigated model, we adopt the “transfer learning” paradigm by pretraining the algorithm using a large, general-purpose, image dataset named ImageNet-1k. Further, we compare the performances of the Swin Transformer with those of two well-established Convolutional Neural Networks (CNNs) named MobileNetv2 and ResNet50, respectively. Our results highlight a maximum accuracy of 0.92 for the Swin Transformer, outperforming the CNNs. To provide an interpretation of the trained models, we apply the so-called Class Activation Map (CAM), which points to a strong global feature extraction ability of the Swin Transformer metal mineral classifier that focuses on distinctive (e.g., colors) and microstructural (e.g., edge shapes) features. The results demonstrate that the deep learning approach can accurately extract all available attributes, which reveals the potential to assist in data exploration and provides an opportunity to carry out spatial quantization at a large scale (cm-mm). Simultaneously, boosting the learning processes with pre-trained weights can accurately capture relevant attributes in mineral classification, revealing the potential for application in mineralogy and petrology, as well as enabling its use in resource explorations.
光学显微图像数据分析对于矿物相的识别和特征描述至关重要,因此直接关系到后续详细岩石学勘探的方法选择。在此,我们提出了一种新颖的 Swin Transformer 应用,这是一种深度学习算法,用于在光学显微镜捕获的图像中对砷黄铁矿、黄铜矿、金矿、黄铁矿和锡黄铁矿等金属矿相进行分类。为了加快训练过程并提高所研究模型的泛化能力,我们采用了 "迁移学习 "范式,使用名为 ImageNet-1k 的大型通用图像数据集对算法进行预训练。此外,我们还比较了 Swin Transformer 与两个成熟的卷积神经网络(CNN)(分别名为 MobileNetv2 和 ResNet50)的性能。我们的结果表明,Swin Transformer 的最高准确率为 0.92,优于 CNN。为了对训练好的模型进行解释,我们应用了所谓的类激活图(CAM),该图表明 Swin Transformer 金属矿物分类器具有很强的全局特征提取能力,它侧重于独特特征(如颜色)和微观结构特征(如边缘形状)。结果表明,深度学习方法可以准确提取所有可用属性,这揭示了其协助数据探索的潜力,并为在大尺度(厘米-毫米)上进行空间量化提供了机会。同时,利用预先训练的权重增强学习过程可以准确捕捉矿物分类中的相关属性,揭示了在矿物学和岩石学中的应用潜力,并使其能够用于资源勘探。
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American Mineralogist
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