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Characterization and Modeling Using Non-Destructive Test (NDT) and Experimental Design Methods of a Self Compacting Concrete (SCC) Based on Mineral Additions 基于矿物添加剂的自密实混凝土(SCC)的无损检测(NDT)和试验设计方法表征和建模
Pub Date : 2022-04-30 DOI: 10.18280/acsm.460204
Ibtissem Allali, L. Belagraa, M. Beddar, O. Kessal
The formulation of an innovative concrete that meets the requirements of a self-compacting concrete (SCC), with acceptable performance in terms of rheology in the fresh state; good fluidity, ease of placing, without segregation as well as good mechanical strength and durability at hardened state has become of great research interest for the last decades. Numerous studies have shown the favorable effects of limestone fillers on the SCC properties. This study aims at investigating the effect of inert mineral addition of limestone fillers with dosages of 10% and 20% grinded to different fine nesses 2000, 3000 and 4000 cm2/g on the physico-mechanical properties of a fresh self-placing concrete using slump, the L-box and the sieve stability tests. Also, the means of destructive and non-destructive tests (NDT) methods to the assessment of the mechanical performances of SCC at hardened state were used. The use of experiment factorial design method allows us to have behavior laws to predict the mechanical strength response when combined with (NDT) according to a numerical model in such study. Hence, a numerical modeling of mechanical response could be derived by such statistical analysis in regards to the effects of factors and their interaction. The results obtained showed that the incorporation of limestone filler in the composition of the SCC improves the fluidity with limited segregation, as well as the good mechanical performances (resistance to compression and flexion). The numerical modeling of the predicted compressive strength response, in particular at the age of 28 days, is judged to be with an acceptable determined coefficient R2 equal to 0.994.
符合自密实混凝土(SCC)要求的创新混凝土配方,在新状态下具有可接受的流变性能;流动性好、易于放置、不偏析以及在硬化状态下具有良好的机械强度和耐久性已成为近几十年来的研究热点。大量研究表明石灰石填料对SCC性能有良好的影响。通过坍落度试验、L-box试验和筛稳定性试验,研究了石灰石粉料中添加10%和20%的惰性矿物,磨成2000、3000和4000 cm2/g不同细度,对新拌自浇筑混凝土物理力学性能的影响。同时,采用了破坏性和非破坏性试验(NDT)的方法,对SCC在硬化状态下的力学性能进行了评价。实验析因设计方法的使用使我们能够根据数值模型来预测与无损检测相结合时的机械强度响应的行为规律。因此,可以通过统计分析得出力学响应的数值模型,考虑各种因素的影响及其相互作用。结果表明,石灰石填料的掺入提高了混凝土的流动性和隔离程度,并具有良好的力学性能(抗压缩和抗弯曲)。预测抗压强度响应的数值模拟,特别是在28天龄时,判断具有可接受的确定系数R2 = 0.994。
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引用次数: 0
Nitride Materials: Synthesis, Crystal Structures, and Optical Properties 氮化材料:合成、晶体结构和光学性质
Pub Date : 2022-04-30 DOI: 10.18280/acsm.460206
D. Kerdoud, Faouzia Benkafada, N. Boussouf, C. Benhamideche
Our research involves the preparation of transition metal nitrides of the composition Mn4N, NbN, Mo2N, TaN and ZrN. The synthesis of Li3N binary alkali metal nitride was also part of this work. Simple and cost-effective methods with relatively low impact on the environment have been privileged in the selection. The experimental work has focused on determining the optimum conditions of synthesis and the convenient high yield route to the desired nitrides, and ultimately improvement of the properties of the final materials. All samples were characterised by X-ray powder diffraction. Their structures will be discussed in more detail here. Optical band gap has been calculated from diffuse reflectance measurements. The air sensitivity of the nitrides was also probed.
我们的研究涉及到Mn4N, NbN, Mo2N, TaN和ZrN组成的过渡金属氮化物的制备。Li3N二元碱金属氮化物的合成也是本工作的一部分。对环境影响相对较小的简单、经济有效的方法在选择中被优先考虑。实验工作的重点是确定最佳合成条件和制备所需氮化物的便捷高产路线,并最终改善最终材料的性能。所有样品均采用x射线粉末衍射进行表征。它们的结构将在这里更详细地讨论。从漫反射测量中计算了光学带隙。并对氮化物的空气敏感性进行了研究。
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引用次数: 2
Perforation Analysis by Punching of Metal Sheets 金属板冲压穿孔分析
Pub Date : 2022-02-28 DOI: 10.18280/acsm.460101
Ayoub Laoucine, M. Bachene, S. Rechak, G. Lorenzini, N. Kaid, Y. Menni
In this work, a numerical study of the perforation of 6061-T6 aluminum, Titanium Ti6Al4V and stainless steel (Nitronic33) plates by a rigid flat nose punch is carried out. The Johnson-Cook model was used to define the behavior of the material constituting the plate. This homogeneous behavior was coupled with the Johnson-Cook rupture criterion to completely predict the perforation process. Initially, the present results are validated by comparing them with the results reported in the literature, including those obtained from experimental work. Thereafter, several numerical parametric analyses are performed to investigate the behavior of these metal plates depending on the maximum breaking force, the temperature in the perforated plates, the kinetic energy, the clearance on the shape of the sheared edge, and the dimensional accuracy of the plates.
本文对6061-T6铝板、Ti6Al4V钛板和Nitronic33不锈钢板进行了刚性扁头冲孔穿孔的数值研究。Johnson-Cook模型用于定义构成板的材料的行为。这种均匀性与Johnson-Cook破裂准则相结合,可以完全预测射孔过程。首先,通过与文献中报告的结果(包括实验结果)进行比较,验证了本文的结果。然后,进行了一些数值参数分析,以研究这些金属板的行为取决于最大断裂力,穿孔板中的温度,动能,剪切边缘形状的间隙以及板的尺寸精度。
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引用次数: 0
Effectiveness of Shannon Entropy Weight Method on Wear Behaviour of Polyester/Carbon Fibre Composites Using GRA 基于GRA的Shannon熵权法对聚酯/碳纤维复合材料磨损性能的影响
Pub Date : 2022-02-28 DOI: 10.18280/acsm.460102
Naga Venkata Sai Ram Yellapragada, S. Devarakonda, Kondala Rao Dasari, Naga Sai Rama Krishna Thati, Jaya Sai Abhaya Veeranjaneya Vara Prasad Alapati
In recent past conventional monolithic materials are replaced with fiber reinforced polymer composite materials due to their high specific strength. The current study focused on dry-sliding wear behaviour of carbon fiber reinforced polyester (CFRP) composites using a pin-on-disc tribometer. The two output responses selected were rate of wear and frictional force with respect to controlled variables using the Taguchi L16 OA (Orthogonal Array). In order to assess the best optimal conditions GRA technique has been used in the study. The effectiveness of entropy weights on the optimal result has been carried out in support with ANOVA studies. In GRA analysis, the combined effect of wear and frictional force is considered and the optimal conditional identified in two ways namely equal weightage method (EWM) and entropy based weightage method (EBWM). While considering EWM method the optimal condition obtained is S1 L4 D3 R4 whereas in EBWM the optimal solution obtained is S1 L4 D1 R4. This shows because of the uneven weights generated by EBWM method there is a change in optimal solution in comparison with EWM method.
近年来,由于纤维增强聚合物复合材料具有较高的比强度,传统的单片材料被取代。目前的研究重点是使用针盘式摩擦计研究碳纤维增强聚酯(CFRP)复合材料的干滑动磨损行为。选择的两个输出响应是使用田口L16 OA(正交阵列)的控制变量的磨损率和摩擦力。为了确定最佳条件,采用GRA技术进行了研究。为了支持方差分析研究,熵权对最优结果的有效性进行了研究。在GRA分析中,考虑了磨损和摩擦力的综合影响,并采用等权重法和基于熵的权重法确定了最优条件。采用EWM方法得到的最优解为S1 L4 D3 R4,而采用EBWM方法得到的最优解为S1 L4 D1 R4。这表明,由于EBWM方法产生的权重不均匀,与EWM方法相比,最优解发生了变化。
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引用次数: 2
Impact of Rolled and Crushed Aggregate with Natural Pozzolan on the Behavior of HPC 天然火山灰碾碎骨料对高性能混凝土性能的影响
Pub Date : 2022-02-28 DOI: 10.18280/acsm.460106
S. Zitouni, M. Maza, N. Tebbal, Z. Rahmouni
High performance concrete (HPC) has several advantages in building construction that cannot be achieved using conventional concrete in terms of strength durability, resistance to chemical attack, and workability of high performance concrete are high. The introduction of fillers and additives contributed to the improvement of high-performance concrete (HPC), other parameters also influence the performance of these HPCs, coarse aggregate fraction is known to strongly influence both fresh and hardened concrete’s properties. Consequently, selection of both content and particle size distribution for (HPC) mixture is an important issue regarding the predicted performance of concrete. For to make concrete more improvement , the porosity of the granular skeleton as well as the rheology of our HPC, 3/8 fraction of rolled gravel with smooth and rounded surfaces was introduced, in substitution for the crushed gravel of the same fraction , by testing various combinations of fractions 3/8 of rolled gravel and fraction 8/15 of crushed gravel in the present study, and based on previous results obtained the combinations 35,40 and 45% fraction 3/8 of rolled gravel and 65 , 60 and 55% fraction 8/15 of crushed gravel (binary granular system) respectively, gives a minimal porosity . Super plasticizer and four percentages of pozzolan were experimented. Compressive strength function of coarse aggregate was determined at 7, 14 and 28 days. Results have revealed that the mixtures with modified granule size distribution system ,1.5% of superplasticizer and 5% by weight of pozzolan allow an improvement in the compressive strength of 35.1% relative to the control concrete.
高性能混凝土(HPC)在建筑施工中具有传统混凝土在强度、耐久性、抗化学侵蚀、和易性等方面无法达到的优点。填料和添加剂的引入有助于高性能混凝土(HPC)的改善,其他参数也影响这些高性能混凝土的性能,已知粗骨料分数对新混凝土和硬化混凝土的性能都有强烈的影响。因此,选择(HPC)混合料的含量和粒径分布是预测混凝土性能的一个重要问题。为使混凝土更加改善,颗粒骨架的孔隙度以及HPC的流变学,3/8的砾石和光滑圆滚表面被引入,在替换的碎砾石相同分数,通过测试的各种组合分数3/8的轧制碎石和分数8/15的碎砾石在目前的研究中,基于之前的结果组合35岁,40 - 45%分数3/8的砾石和65年,滚60%和55%的破碎砾石(二元颗粒体系)的8/15分别给出最小孔隙度。试验了强力增塑剂和四百分火山灰。测定粗骨料在7、14、28 d时的抗压强度函数。结果表明,改性粒径分配体系、掺量为1.5%的高效减水剂和掺量为5%的火山灰混合料的抗压强度比对照混凝土提高了35.1%。
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引用次数: 2
Study of the Effect of ACL Anode Catalytic Layer Porosity on the Efficiency of a Direct Methanol Fuel Cell ACL阳极催化层孔隙率对直接甲醇燃料电池效率影响的研究
Pub Date : 2022-02-28 DOI: 10.18280/acsm.460107
Mihoub Medkour, N. Kaid, H. Ameur, Chutarat Tearnbucha, W. Sudsutad, G. Lorenzini, Hijaz Ahmad, Y. Menni
The current work investigates the efficiency of a Direct Methanol Fuel Cell (DMFC) by using COMSOL. The set-up model takes into consideration the electrochemical kinetics and chemical reactions. The anode catalyst layers are a main element in the PEM fuel cell; their porosity significantly affects the fuel cell efficiency. We focus on the impact of catalytic layers porosity on the battery efficiency. As claimed by the results, the porosity of catalytic layer greatly affects the performance of the battery. In addition, better output performance of µDMFC may be obtained when the catalytic layer porosity is chosen as εACL=0.009-0.1. The distributions of methanol, carbon dioxide, water, oxygen, polarization, and the current density are plotted to highlight the impact of porosity on the global performances.
目前的工作是利用COMSOL研究直接甲醇燃料电池(DMFC)的效率。建立的模型考虑了电化学动力学和化学反应。阳极催化剂层是PEM燃料电池的主要组成部分;它们的孔隙度显著影响燃料电池的效率。重点研究了催化层孔隙率对电池效率的影响。结果表明,催化层的孔隙率对电池的性能影响很大。此外,选择催化层孔隙率εACL=0.009-0.1时,µDMFC的输出性能较好。绘制了甲醇、二氧化碳、水、氧、极化和电流密度的分布,以突出孔隙度对整体性能的影响。
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引用次数: 0
Nanoencapsulation of Anthocyanin Extract from Fermented Black Garlic (FBG) Based on Biocompatible Polymeric Materials 基于生物相容性高分子材料的发酵黑蒜花青素提取物纳米胶囊化研究
Pub Date : 2022-02-28 DOI: 10.18280/acsm.460105
Jocelyn P. Doronio, J. R. Salazar, J. Monserate, Benyl John A. Arevalo, P. Eugenio, M. M. Sarong
Garlic contains various polyphenolic compounds such as anthocyanin, a bioactive, water-soluble compound generally known for its remarkable health-enhancing properties. However, it is chemically unstable and easily degrades due to various environmental conditions (temperature, pH, presence of oxygen and light, etc.) in addition to its low bioavailability due to fast metabolization and low absorption in the body. Therefore, a nanoencapsulation strategy is essential to address these limitations. In this work, anthocyanin extraction from FBG (Ilocos variety) with 85% acidified ethanol and its encapsulation using the chitosan-alginate nanoparticle system via pre-gelation and polyelectrolyte complex formation were demonstrated. Anthocyanin-loaded chitosan-alginate nanocapsules were characterized in terms of structural features, particle size, morphology, encapsulation efficiency, total phenolic content (TPC), and radical scavenging activity of 2,2-diphenyl-1-picrylhydrazyl (DPPH). The obtained anthocyanin-loaded nanocapsules have small particle sizes ranging from 50.7 nm to 92.0 nm with high encapsulation efficiency (T3: 78.82%, T2: 68.18%, T1: 65.77%). Results showed that a higher initial concentration of anthocyanin extract promotes higher encapsulation efficiency. Antioxidant activity of the nanocapsules showed low phenolic content (0.11 mg GAE/g) but high DPPH scavenging activity (14.02 mg AAE/g). The chitosan-alginate complex has successfully encapsulated the anthocyanin from fermented black garlic.
大蒜含有多种多酚类化合物,如花青素,这是一种生物活性的水溶性化合物,通常以其显著的促进健康的特性而闻名。然而,它的化学性质不稳定,而且由于各种环境条件(温度、pH值、氧气和光等)的存在,它的生物利用度很低,因为它在体内代谢快,吸收低。因此,纳米封装策略对于解决这些限制至关重要。本文研究了用85%酸化乙醇从FBG (Ilocos品种)中提取花青素,并利用壳聚糖-海藻酸盐纳米颗粒体系通过预凝胶和聚电解质复合物的形成对花青素进行包封。从结构特征、粒径、形态、包封效率、总酚含量(TPC)和2,2-二苯基-1-苦味酰肼(DPPH)自由基清除活性等方面对负载花青素的壳聚糖海藻酸盐纳米胶囊进行了表征。所制得的花青素纳米胶囊粒径在50.7 ~ 92.0 nm之间,具有较高的包封率(T3: 78.82%, T2: 68.18%, T1: 65.77%)。结果表明,花青素提取物初始浓度越高,包封率越高。纳米胶囊的抗氧化活性表现为低酚含量(0.11 mg AAE/g),高DPPH清除活性(14.02 mg AAE/g)。壳聚糖-海藻酸盐复合物成功地包封了发酵黑蒜中的花青素。
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引用次数: 1
Effect of Gravel Content on Mechanical Performance and Porous Structure of Concrete 碎石掺量对混凝土力学性能及多孔结构的影响
Pub Date : 2022-02-28 DOI: 10.18280/acsm.460103
Abderrachid Amriou, H. Ziani, Sadek Deboucha, M. Bencheikh
Concrete is the most widely used material in the field of civil engineering. In order to obtain a strong and durable concrete, it is necessary to study the various parameters entering into its formulation. Mainly the elements forming the concrete skeleton, in particular the gravel content. The transfer of water into concrete directly affects its durability. This transfer is linked to the porous structure and to the continuity of the pores in the concrete. This research studies the effect of gravel content on compressive strength, porosity accessible to water, depth of water penetration and ultrasonic velocity of concrete samples. The study includes 15 types of concrete made by varying the gravel-sand ratio (G/S), 0, 1, 1.5, 2 and 2.5. The cement dosage is taken equal to 150, 250 and 350 Kg/m3. The tests are carried out on cubic samples 10x10x10 cm3 and 15x15x15 cm3 after storage in water for 28 days. The experimental results obtained show that the gravel-sand ratio (G/S) affects the mechanical strength and the porous structure of concrete. Increasing the gravel content in concrete leads to an increase in mechanical strength and ultrasonic speed. However, a high gravel content results in a reduction in the porosity accessible to water and the depth of water penetration.
混凝土是土木工程领域中应用最广泛的材料。为了获得坚固耐用的混凝土,有必要对其配方中的各种参数进行研究。主要是构成混凝土骨架的元素,特别是砾石含量。水在混凝土中的转移直接影响混凝土的耐久性。这种转移与混凝土的多孔结构和孔隙的连续性有关。本文研究了含砾量对混凝土试样抗压强度、可水孔隙率、水渗透深度和超声速度的影响。该研究包括15种不同类型的混凝土,通过改变砾砂比(G/S), 0,1,1.5, 2和2.5。水泥用量分别为150、250、350 Kg/m3。试验采用10x10x10cm3和15x15x15cm3的立方试样,在水中保存28天。试验结果表明,砂砾比(G/S)影响混凝土的力学强度和多孔结构。混凝土中碎石含量的增加导致混凝土的机械强度和超声速度的增加。然而,高砾石含量会降低水的孔隙度和水的渗透深度。
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引用次数: 1
Limit Analyses of the Active Earth Pressure on Rigid Retaining Walls under Strip Loading on Backfills 填土条形荷载作用下刚性挡土墙主动土压力极限分析
Pub Date : 2022-02-28 DOI: 10.18280/acsm.460104
N. Tallah, A. Mabrouki, A. Boulaouad, M. Khemissa, A. Bouaicha
Recent studies of retaining walls include experimental studies, numerical analysis and analytical models. Although active earth pressure against retaining structures has received much attention, the evaluation of active earth pressure of backfill when loaded by a strip foundation, has been slightly studied. This paper studies the effect of a strip load on the active pressure force and the distribution of the horizontal stresses on a rigid wall, using a finite element limit analysis. The strip loading is located at different distances from the vertical face of the wall. The OptumG2 code is used to analyze the effect of width of strip surcharge (soil-wall), interface friction angle and soil internal friction angle. New interesting results are demonstrated and presented here: the dependency of the active earth pressure coefficient on both position and width of the strip load, in one hand, and the effect of the internal friction angle of the soil, the soil-wall interface, and the position of the strip loading on the failure mechanism, in the other hand.
最近对挡土墙的研究包括实验研究、数值分析和分析模型。虽然挡土结构的主动土压力受到了广泛的关注,但对条形基础荷载作用下充填体主动土压力的评价研究较少。本文采用有限元极限分析方法,研究了条形荷载对刚性壁面主动压力和水平应力分布的影响。条形荷载位于离壁垂直面不同距离处。采用OptumG2程序分析了条状堆填物宽度(土-墙)、界面摩擦角和土内摩擦角对土体结构的影响。本文展示并展示了一些有趣的新结果:一方面,主动土压力系数与条形荷载的位置和宽度有关;另一方面,土的内摩擦角、土-墙界面和条形荷载的位置对破坏机制的影响。
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引用次数: 0
Conduction Band Offset Effect on the Cu2ZnSnS4 Solar Cells Performance 传导带偏移对Cu2ZnSnS4太阳能电池性能的影响
Pub Date : 2021-12-31 DOI: 10.18280/acsm.450601
A. Latrous, R. Mahamdi, N. Touafek, M. Pasquinelli
Among the causes of the degradation of the performance of kesterite-based solar cells is the wrong choice of the n-type buffer layer which has direct repercussions on the unfavorable band alignment, the conduction band offset (CBO) at the interface of the absorber/buffer junction which is one of the major causes of lower VOC. In this work, the effect of CBO at the interface of the junction (CZTS/Cd(1-x)ZnxS) as a function of the x composition of Zn with respect to (Zn+Cd) is studied using the SCAPS-1D simulator package. The obtained results show that the performance of the solar cells reaches a maximum values (Jsc = 13.9 mA/cm2, Voc = 0.757 V, FF = 65.6%, ɳ = 6.9%) for an optimal value of CBO = -0.2 eV and Zn proportion of the buffer x = 0.4 (Cd0.6Zn0.4S). The CZTS solar cells parameters are affected by the thickness and the concentration of acceptor carriers. The best performances are obtained for CZTS absorber layer, thichness (d = 2.5 µm) and (ND = 1016 cm-3). The obtained results of optimizing the electron work function of the back metal contact exhibited an optimum value at 5.7 eV with power conversion efficiency of 13.1%, Voc of 0.961 mV, FF of 67.3% and Jsc of 20.2 mA/cm2.
氮型缓冲层的选择不当直接影响了吸收层/缓冲层界面处的导带偏移(CBO),这是导致VOC降低的主要原因之一。在这项工作中,使用SCAPS-1D模拟器包研究了连接界面(CZTS/Cd(1-x)ZnxS)的CBO作为Zn相对于(Zn+Cd)的x组成的函数的影响。结果表明,当CBO = -0.2 eV,缓冲液Zn比例x = 0.4 (Cd0.6Zn0.4S)时,电池的性能达到最大值(Jsc = 13.9 mA/cm2, Voc = 0.757 V, FF = 65.6%, bex = 6.9%)。受体载流子的厚度和浓度对CZTS太阳能电池的参数有影响。吸收层厚度(d = 2.5µm)和ND = 1016 cm-3时,吸收层的性能最好。优化后金属触点的电子功函数在5.7 eV时达到最优值,功率转换效率为13.1%,Voc为0.961 mV, FF为67.3%,Jsc为20.2 mA/cm2。
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引用次数: 1
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Annales de Chimie - Science des Matériaux
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