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Assessment of Mechanical Properties of Aluminium Metal Matrix Composite Reinforced with Carbonized Eggshell Ash (CESA) 碳化蛋壳灰增强铝基复合材料力学性能评价
Pub Date : 2022-08-31 DOI: 10.18280/acsm.460408
T. Azeez, L. Mudashiru, Teslem B. Asafa, S. Akande, O. Ikumapayi, A. Yusuff, J. Kayode
A useful alloying agent for aluminium-based composites is eggshell powder, which has a well-deserved reputation for hardness. Aluminium cans and eggshells are regarded as waste and a pollutant because they are no longer needed. Conversion of wastes into useful products will be of economic boost for a nation and make the environment clean. Eggshell particles were studied for their reinforcing properties in a waste aluminium alloy in this study. An eggshell particle of 150 µm in size and a weight fraction of 2%, 4.4%; 6.6%; 8.8%; and 10% was incorporated into aluminium produced from recycled aluminium wastes during casting. A Light Emission Polyvac Spectrometer was used to determine the alloy's constituent makeup. The required experimental procedures and tools were used to measure the tensile strength, hardness, and impact strength. Using a weight fraction of reinforcement of 2, 4, 6, 8, and 10%, tensile strength was found to be 78.07098MPa; 81.09587MPa; 83.04546MPa; 86.12769MPa; and 89.12769MPa respectively. Hardness values of 75.25Hv, 77.03Hv, 78.27Hv, 80.15Hv, and 85.72Hv were obtained at the same specified% weight fraction. Impact strength values of 12.64J, 10.08J, 7.39J, 7.12J, and 7.39J were obtained at the same composition. It may be inferred that the mechanical characteristics of the aluminium alloy reinforced with eggshell particles improved considerably with the number of eggshell particles used and the study, therefore, converted waste to worth.
蛋壳粉是制备铝基复合材料的一种有用的合金剂,蛋壳粉具有很高的硬度。铝罐和蛋壳被视为废物和污染物,因为它们不再被需要。将废物转化为有用的产品将促进一个国家的经济发展,并使环境清洁。研究了蛋壳颗粒在废铝合金中的增强性能。蛋壳颗粒大小为150µm,重量分数为2%,4.4%;6.6%;8.8%;在铸造过程中,将10%的铝添加到回收铝废料生产的铝中。采用分光光度计测定合金的成分组成。采用所需的实验程序和工具测量拉伸强度、硬度和冲击强度。当配筋质量分数为2、4、6、8和10%时,拉伸强度为78.07098MPa;81.09587 mpa;83.04546 mpa;86.12769 mpa;和89.12769MPa。硬度值分别为75.25Hv、77.03Hv、78.27Hv、80.15Hv和85.72Hv。相同成分下的冲击强度分别为12.64J、10.08J、7.39J、7.12J和7.39J。由此可以推断,随着蛋壳颗粒用量的增加,蛋壳颗粒增强铝合金的力学性能得到了较大的改善,从而实现了研究的“废转值”。
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引用次数: 1
Investigation of Hydrothermal Aging on Polyvinyl Chloride (PVC) Used in Medium Voltage Cables 中压电缆用聚氯乙烯(PVC)水热老化研究
Pub Date : 2022-08-31 DOI: 10.18280/acsm.460407
Hassene Ait Ouazzou, M. Nedjar, S. Hocine, Rachid Belhocine, Ferhat Belabbas
This investigation deals with the effect of hydrothermal aging on the electrical insulating properties of polyvinyl chloride used in medium voltage cables. The evolution of dielectric properties (dielectric loss factor, dielectric constant, dielectric strength and volume resistivity) as a function of aging time and temperature has been studied. After that, the mechanical characteristics (elongation at break and tensile strength) were also determined. Physico-chemical analysis was performed to highlight the structural changes induced by hydrothermal aging. Infrared spectroscopy using the Fourier transform (ATR-FTIR) and thermogravimetric analysis (TGA-DTA) have been performed. The results obtained show that the loss factor and dielectric constant increase gradually with the increase of temperature, while the volume resistivity decreases. At 100℃, the general shape of the curves giving the evolution of dielectric properties as a function of aging time shows that both loss factor and dielectric constant increase while those of volume resistivity and dielectric strength decrease. In the case of 80℃, the loss factor decreases slightly and the dielectric constant remains almost constant with aging time, whereas the volume resistivity and dielectric strength increase. The activation energy varies with aging time. The impact of hydrothermal aging on the properties of the material has been established in this study. At the beginning of aging, the degradation is mainly due to the elimination of molecular HCl. At more advanced stages of aging, the degradation is attributed to the elimination of HCl and double bonds formation followed by a change in color. Other consequences of the degradation like crosslinking and swelling of the samples are also noticed.
研究了水热老化对中压电缆用聚氯乙烯电绝缘性能的影响。研究了介质性能(介电损耗因子、介电常数、介电强度和体积电阻率)随老化时间和温度的变化规律。之后,还测定了其力学特性(断裂伸长率和抗拉强度)。理化分析表明热液老化引起的结构变化。利用傅里叶变换(ATR-FTIR)和热重分析(TGA-DTA)进行了红外光谱分析。结果表明:随着温度的升高,材料的损耗因子和介电常数逐渐增大,而体积电阻率减小;在100℃时,介质性能随时效时间的变化曲线的一般形状表明损耗因子和介电常数增大,而体积电阻率和介电强度减小。在80℃时,随着时效时间的延长,材料的损耗因子略有下降,介电常数基本保持不变,而体积电阻率和介电强度则有所增加。活化能随时效时间的变化而变化。本研究确定了水热老化对材料性能的影响。在老化初期,降解主要是由于HCl分子的消除。在更高级的老化阶段,降解是由于HCl的消除和双键的形成,然后是颜色的变化。降解的其他后果,如交联和膨胀的样品也被注意到。
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引用次数: 1
Impact of Calcium Chloride on the Microstructure of a Collapsible ‎Soil 氯化钙对湿陷性土壤微观结构的影响
Pub Date : 2022-08-31 DOI: 10.18280/acsm.460405
Ouassila Bahloul, H. Ziani, S. Benmoussa
The study of the collapse of soils under the effect of flooding is a major problem in soil ‎mechanics. Most of the work done on the treatment of these soils has been devoted to ‎the use of binders of hydraulic or organic types. However, little work has been devoted to the use of salt calcium chloride in ‎collapsible soil treatments.‎ The purpose of this study is to evaluate the effect salt calcium chloride on a reconstituted collapsible soil in the laboratory, at ‎different levels of water content, compaction energy and concentration of the saline solution. The ‎results obtained showed a significant reduction in the potential for soil deformation ‎and an illustration and a noticeable interaction between the soil particles ‎and the saline solution resulting in a denser material.
研究洪水作用下土体的崩塌是土力学中的一个重要问题。在处理这些土壤方面所做的大部分工作都致力于使用水力或有机类型的粘合剂。然而,盐化氯化钙在湿陷性土壤处理中的应用研究较少。本研究的目的是在实验室中评估在不同含水量、压实能和盐溶液浓度下氯化钙对可湿性土的影响。获得的结果表明,土壤变形的可能性显著降低,土壤颗粒和盐溶液之间的明显相互作用导致了更致密的材料。
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引用次数: 0
Pyrogasification to Produce Biogas and Biomethane from Wood Wastes 利用木材废料进行火气化生产沼气和生物甲烷
Pub Date : 2022-08-31 DOI: 10.18280/acsm.460401
M. Livi, F. Trifiró
This communication contains information on some existing plants in Italy of pyrogasification of woody biomass, there is the treatment at a temperature between 800-1200℃ before in absence of oxygen(pyrolysis) and subsequent in lack of oxygen (gasification) to obtain a gas which it then sent to an internal combustion engine which produce electricity and heat. Subsequently we shall report information of two demonstration plants realized in Europe of production of biogas from woody biomass by gasification and consecutive hydrogenation to biomethane. It is also reported a pilot plant realized in Italy of production of biogas by gasification and consecutive hydrogenation to biomethane by hydrogenation with hydrogen produced by electrolysis of water.
本通讯包含了意大利现有的木质生物质热解工厂的信息,在800-1200℃的温度下进行处理,然后在缺氧的情况下进行(热解),随后在缺氧的情况下进行(气化),以获得气体,然后将其发送给内燃机,从而产生电力和热量。随后,我们将报告两个在欧洲实现的从木质生物质通过气化和连续加氢生产生物甲烷的示范工厂的信息。据报道,在意大利实现了一个中试工厂,通过气化生产沼气,并通过电解水产生的氢加氢连续加氢生产生物甲烷。
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引用次数: 1
Corroded RC Beam Behavior Subjected to Random Loading in Various Pore Saturation Levels: Coupled Numerical Analysis 不同孔隙饱和度下随机荷载作用下腐蚀RC梁的耦合数值分析
Pub Date : 2022-08-31 DOI: 10.18280/acsm.460402
Yasmine Meterfi, H. Trouzine, Youcef Houmadi
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引用次数: 0
Assessment of Polyethylene Geomembrane Properties after Accelerated Thermal Ageing 加速热老化后聚乙烯土工膜的性能评价
Pub Date : 2022-08-31 DOI: 10.18280/acsm.460404
A. Hamma, Addessalam Bezza, S. Bouhelal
Application temperatures and exposure environments are among the causes of premature antioxidant loss in polymer geomembranes. Therefore, over the long term, polymer degradation takes place which is reflected in geomembrane properties. In this work, accelerated thermal ageing of polyethylene geomembrane was carried out in a climatic chamber at 70℃ with 21% oxygen. The evolution of tensile properties, puncture resistance, and shore D hardness with exposure time was assessed. Changes in chemical and crystalline structure and melt flow index were made. According to the findings, geomembrane surface oxidation takes place in the polyethylene matrix after 9 months of exposure. This fact is confirmed by evaluating carbonyl, vinyl, and hydroxyl indexes. Uniaxial tensile properties, puncture resistance, and shore D hardness indicated slight changes after one year of exposure. While the crystallinity index, determined by XRD measurement, has shown an increase with exposure. Further, melt flow index measurements confirmed the absence of chain scission during the early exposure periods. However, for longer periods, chain scission reactions occurred and MI values increased moderately after five months of accelerated aging. All results indicated no significant bulk degradation while maintaining a certain mechanical resistance with applications under a temperature of 70℃. This temperature value is relevant in a waste storage center, but the studied geomembrane is not recommended for this case.
应用温度和暴露环境是聚合物土工膜过早抗氧化损失的原因之一。因此,从长期来看,聚合物降解发生,这反映在土工膜的性能上。在此工作中,在70℃和21%氧气的气候室中对聚乙烯土工膜进行了加速热老化。评估了拉伸性能、抗穿刺性能和邵氏硬度随暴露时间的变化。化学、晶体结构和熔体流动指数发生了变化。根据研究结果,土工膜表面氧化发生在聚乙烯基质暴露9个月后。这一事实通过评价羰基、乙烯基和羟基指数得到证实。单轴拉伸性能、抗穿刺性能和邵氏硬度在暴露一年后略有变化。而结晶度指数,通过x射线衍射测定,显示出随着曝光的增加。此外,熔体流动指数测量证实了在早期暴露期间没有链断裂。然而,在较长的时间内,加速老化5个月后,发生了链断裂反应,MI值适度增加。所有结果表明,在70℃的温度下,材料没有明显的体积退化,同时保持一定的机械阻力。该温度值与废物储存中心有关,但所研究的土工膜不适合这种情况。
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引用次数: 0
Experimental Investigations of Al-Cr3C2 Composite Preform Densification and Deformation Al-Cr3C2复合预制件致密化变形实验研究
Pub Date : 2022-08-31 DOI: 10.18280/acsm.460403
Naga Venkata Srinivas Borra, Veera Venkata Krishna Prasad Davuluri
This investigation on strain hardening, densification and workability of the Sintered aluminium- Chromium Carbide composition of (Al-Cr3C2 of 2, 4 and 6%) preforms subjected to upsetting were investigated in this research. Industrial practitioners needed the workability data and densification mechanisms to plan and envisage the failure strains. In the current study, under triaxial stress state conditions Al-Cr3C2 preform with primary preform densities and various aspect ratios were compressed. Strain hardening, densification behaviors of aluminium- Chromium Carbide be investigated by gradually increasing the load till the fracture occurs. The outcome of adding Cr3C2 to Al and the impact of aspect ratio on formability was also extensively investigated. We looked at the parameters of stress ratio, instant varying strain rate, work hardening exponent, instantaneous density coefficient and densification attained.
本文研究了烧结铝铬碳化物成分(Al-Cr3C2含量分别为2,4和6%)预坯在镦粗条件下的应变硬化、致密化和可加工性。工业从业者需要可加工性数据和致密化机制来计划和设想失效应变。在本研究中,在三轴应力状态下,压缩了具有初级预制体密度和不同长径比的Al-Cr3C2预制体。通过逐渐增大载荷直至断裂,研究了碳化铝铬合金的应变硬化、致密化行为。研究了Cr3C2在Al中添加的效果以及长径比对成形性能的影响。考察了应力比、瞬时变应变率、加工硬化指数、瞬时密度系数和获得的致密化参数。
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引用次数: 1
Enhancing of Concrete Properties by Using Aluminium and Iron Residues as a Partial Replacement of Fine Aggregate 铝、铁渣部分替代细骨料提高混凝土性能的研究
Pub Date : 2022-08-31 DOI: 10.18280/acsm.460406
Ammar A. Hammadi, A. Mohammed, Majeed Mattar Ramal
According to the growing of the world's population, the necessitate for using different building materials such as cement, steel, admixtures, wood and aluminium increased. The main problem faces the world with the increasing need for building materials is the construction wastes, which are a type of environmental pollution that must be reduced. This study focused on aluminium and iron wastes resulted from factories and the possibility to reuse these wastes again like partial replacement from sand with proportions (0.25, 0.5, 0.75 and 1%) in concrete mixtures for both types of residues at ages (7, 14, and 28) days. It had studied the effect of the using of aluminium residues (AR) and iron residues (IR) especially on the mechanical characteristics of concrete. These mechanical characteristics were the compression strength (CS) and tensile strength (TS). The achieved results were compared between the residues concrete specimens and those of reference concrete. Also, the effect of age and replacement percentage for samples which they contain AR and IR had been discussed. The results had shown that the (CS) of iron residues concrete samples (IRC) was increasing with increasing of the iron residues percentage till (0.5%) (IR) in opposite of the observed values of aluminium residues concrete (ARC), as well as for the results of the (TS) of concrete samples which containing the mineral residues at all ages. Where it was observed that the using of aluminium residues (AR) showed a decreasing in the values of (TS) and (CS) compare with reference concrete, but with the use of iron residues (IR) both of (TS) and (CS) results were more than their counterparts of reference concrete at all ages for the first two percentages of replacement.
随着世界人口的增长,对水泥、钢铁、外加剂、木材和铝等不同建筑材料的需求也在增加。随着对建筑材料需求的不断增加,世界面临的主要问题是建筑垃圾,这是一种必须减少的环境污染。本研究的重点是工厂产生的铝和铁废物,以及再次再利用这些废物的可能性,例如在混凝土混合物中部分替换比例为(0.25,0.5,0.75和1%)的两种残留物(7,14和28)天。研究了铝渣(AR)和铁渣(IR)的使用对混凝土力学性能的影响。这些力学特性是压缩强度(CS)和拉伸强度(TS)。将所得结果与残馀混凝土试件与参考混凝土试件进行了比较。此外,还讨论了年龄和替换率对含有AR和IR的样品的影响。结果表明:铁渣混凝土试样(IRC)的CS值随铁渣掺量的增加而增大,直至(0.5%)(IR),与铝渣混凝土试样(ARC)的观测值相反;含矿物渣混凝土试样在各龄期的CS值也与TS值相反。我们观察到,与参考混凝土相比,使用铝渣(AR)显示(TS)和(CS)的值有所下降,但使用铁渣(IR), (TS)和(CS)的结果在所有年龄的前两个替换百分比都高于参考混凝土的对应值。
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引用次数: 0
Breakdown Behaviour of Polyesterimide Enamelled Wire Subjected to Thermal Aging 热老化下聚酯亚胺漆包线的击穿行为
Pub Date : 2022-06-30 DOI: 10.18280/acsm.460308
Nedjar Mohammed
This work concerns the effect of thermal aging on breakdown voltage of polyesterimide enamelled copper wire. Samples are aged in ovens at different temperatures. After aging, a large population of samples were taken and submitted to dielectric breakdown under AC and DC voltages. The material was characterized by TGA and DSC. The values of failure were treated statistically using Weibull model. The study shows a decrease in breakdown voltage with respect to aging time. DC breakdown voltage is greater than AC breakdown voltage. Under DC stress, breakdown voltage is related to the polarity. TGA thermograms exhibit one decomposition stage. The beginning temperature of the mass loss and the residue are greater in the case of pure samples. The glass transition temperature decreases as a function of aging time resulting to a plasticization in the material. In long-term, the decomposition occurs by a scission reaction of imide - bond and ester – bond at interface of polyesterimide-copper. A through discuss of the obtained results is given as well.
研究了热老化对聚亚胺漆包线击穿电压的影响。样品在不同温度的烤箱中陈化。老化后,大量样品在交流和直流电压下被击穿。通过热重分析和差热分析对材料进行了表征。失效值采用威布尔模型进行统计处理。研究表明,击穿电压随老化时间的延长而降低。直流击穿电压大于交流击穿电压。在直流应力下,击穿电压与极性有关。热重热图显示为一个分解阶段。在纯样品中,质量损失和残留物的起始温度较大。玻璃化转变温度作为老化时间的函数而降低,从而导致材料的塑化。从长期来看,分解是通过聚亚胺-铜界面上的亚胺键和酯键的断裂反应发生的。并对所得结果进行了详细的讨论。
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引用次数: 0
Investigation of Dynamic Mechanical Behavior of Nanosilica Filled Carbon-Kevlar-Epoxy Polymer Hybrid Nanocomposite 纳米二氧化硅填充碳-芳纶-环氧聚合物杂化纳米复合材料动态力学行为研究
Pub Date : 2022-06-30 DOI: 10.18280/acsm.460305
Pranesh K Gopalakrishnamurthy, Channabasavaraj Sandur
Reinforcement of epoxy-carbon-Kevlar fabric composite with the addition of nanosilica has resulted in the evolution of new hybrid polymer nanocomposite, which results in the improved mechanical properties of polymer hybrid nanocomposite. The current investigation concentrated on the dynamic mechanical behavior of unfilled and nanosilica filled carbon-Kevlar-epoxy polymer composite with five and four layers of carbon and Kevlar woven fibers respectively with epoxy matrix (5C4K). Nanosilica was mixed into the epoxy at different weight percentages (wt.%) of 0, 0.5, 1.0, and 1.5. The laminates were fabricated using the vacuum-assisted resin infusion moulding (VARIM) technique. The dynamic mechanical properties, storage modulus, loss modulus, damping factor (tan delta), and glass transition temperature was investigated using a dynamic-mechanical analyzer at temperature ranging from 25 to 165 degrees Celsius. The test specimens were prepared in accordance with the ASTM D4065 standard to investigate dynamic mechanical analysis (DMA) of the hybrid polymer nanocomposite. The results of the tested specimens for dynamic mechanical behaviors of carbon-Kevlar-epoxy hybrid nanocomposites are very much influenced by the presence of nanosilica. The storage modulus, loss modulus for nanosilica added hybrid polymer composites were more than the unfilled ones and the damping factor (tan delta) was observed more in an unfilled composite.
纳米二氧化硅对环氧-碳-凯夫拉纤维复合材料的增强作用导致了新型杂化聚合物纳米复合材料的发展,从而提高了聚合物杂化纳米复合材料的力学性能。目前的研究主要集中在未填充和纳米二氧化硅填充的碳-凯夫拉-环氧聚合物复合材料的动态力学行为上,该复合材料分别为5层和4层碳和凯夫拉编织纤维,以环氧基(5C4K)为基体。将纳米二氧化硅以0、0.5、1.0和1.5的重量百分比(wt.%)混合到环氧树脂中。采用真空辅助树脂注射成型(VARIM)技术制备层压板。在25 ~ 165℃的温度范围内,使用动态力学分析仪研究了材料的动态力学性能、储存模量、损耗模量、阻尼系数(tan delta)和玻璃化转变温度。按照ASTM D4065标准制备了混合聚合物纳米复合材料的动态力学分析(DMA)。纳米二氧化硅的存在对碳-芳纶-环氧杂化纳米复合材料的动态力学性能有很大的影响。添加纳米二氧化硅的杂化聚合物复合材料的存储模量、损耗模量大于未填充的复合材料,未填充的复合材料的阻尼系数(tan delta)更大。
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引用次数: 1
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Annales de Chimie - Science des Matériaux
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