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An experimental study of the static magnetic properties of Co thin films 钴薄膜静磁特性的实验研究
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-25 DOI: 10.1140/epjb/s10051-024-00729-w
A. Kharmouche

Thermal heating process has been used, under a pressure of 10−7 mbar, to deposit thin films of cobalt onto monocrystalline silicon substrate. The incident beam strikes the substrates under normal incidence. The thickness ranges from 50 to 400 nm. To investigate the static magnetic properties, the hysteresis loops are performed by means of alternating gradient field magnetometer device. The zero-field magnetic structure has been investigated by magnetic force microscopy (MFM) technique, using a Veeco 3100 apparatus. MFM images reveal well-defined stripe patterns, mainly for the thickest films, which infer the dominance of the magnetocrystalline anisotropy. The easy magnetization axis lies within the plane of the film with a small component out-of-the plane for the thicker films. Coercivity evolution versus thickness follows a tn Néel law, characteristic of Bloch domain wall motion. In addition, it was found that coercivity depends plainly on the surface roughness of the films.

Graphical abstract

AFM (left) and MFM (right) images of Co thin films, with different thickness, (a) 100 nm, (b) 300 nm, (c) 400 nm. Scan area is 20 µm × 20 µm

在 10-7 毫巴的压力下,采用热加热工艺在单晶硅衬底上沉积钴薄膜。入射光束以正常入射方式照射基底。薄膜厚度从 50 纳米到 400 纳米不等。为了研究静磁特性,使用交变梯度磁场磁力计装置进行磁滞回线。使用 Veeco 3100 仪器,通过磁力显微镜(MFM)技术对零磁场磁性结构进行了研究。磁力显微镜图像显示了清晰的条纹图案,主要是最厚的薄膜,推断出磁晶各向异性的主导地位。易磁化轴位于薄膜平面内,较厚薄膜的易磁化轴在平面外有少量分量。矫顽力随厚度的变化遵循 t-n 奈尔定律,这是布洛赫畴壁运动的特征。此外,研究还发现矫顽力明显取决于薄膜的表面粗糙度。
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引用次数: 0
The impact of different unravelings in a monitored system of free fermions 自由费米子监控系统中不同解离的影响
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-25 DOI: 10.1140/epjb/s10051-024-00725-0
Giulia Piccitto, Davide Rossini, Angelo Russomanno

We consider a free-fermion chain undergoing dephasing, described by two different random-measurement protocols (unravelings): a quantum-state-diffusion and a quantum-jump one. Both protocols keep the state in a Slater-determinant form, allowing to address quite large system sizes. We find a bifurcation in the distribution of the measurement operators along the quantum trajectories, that’s to say, there is a point where the shape of this distribution changes from unimodal to bimodal. The value of the measurement strength where this phenomenon occurs is similar for the two unravelings, but the distributions and the transition have different properties reflecting the symmetries of the two measurement protocols. We also consider the scaling with the system size of the inverse participation ratio of the Slater-determinant components and find a power-law scaling that marks a multifractal behaviour, in both unravelings and for any nonvanishing measurement strength.

Position of the maxima of P n vs (gamma ) for the QSD protocol. The two maxima stem continuously and symmetrically at the bifurcation point (gamma ) QSD (sim 0.2), with a discontinuity of the derivative.

摘要 我们考虑了一个发生去相变的自由费米子链,它由两种不同的随机测量协议(解开)来描述:一种是量子态扩散协议,另一种是量子跳跃协议。这两种协议都将状态保持在斯莱特决定形式,从而可以处理相当大的系统规模。我们发现测量算子在量子轨迹上的分布存在分岔,也就是说,在某一点上,测量算子的分布形状从单峰变成了双峰。出现这种现象的测量强度值对于两种解旋来说是相似的,但分布和转变具有不同的性质,反映了两种测量协议的对称性。我们还考虑了斯莱特决定分量的反参与比随系统大小的缩放,并发现了一个幂律缩放,它标志着一种多分形行为,在两种解开和任何非消失的测量强度中都是如此。这两个最大值连续对称地指向分叉点 (gamma ) QSD (sim0.2),导数不连续。
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引用次数: 0
Entanglement detection in postquench nonequilibrium states: thermal Gibbs vs. generalized Gibbs ensemble 淬火后非平衡态中的纠缠探测:热吉布斯与广义吉布斯集合
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-25 DOI: 10.1140/epjb/s10051-024-00715-2
Ferenc Iglói, Csaba Zoltán Király

We use entanglement witnesses related to the entanglement negativity of the state to detect entanglement in the XY chain in the postquench states in the thermodynamic limit after a quench when the parameters of the Hamiltonian are changed suddenly. The entanglement negativity is related to correlations, which in the postquench stationary state are described by a generalized Gibbs ensemble, in the ideal case. If, however, integrability breaking perturbations are present, the system is expected to thermalize. Here, we compare the nearest-neighbor entanglement in the two circumstances.

Postquench states after a sudden quench protocol ((h_0, gamma ) rightarrow (h, gamma )) in the XY chain.

摘要 我们利用与状态的纠缠负性有关的纠缠见证来探测 XY 链在淬火后热力学极限状态下的纠缠,当时哈密顿参数突然改变。纠缠负性与相关性有关,在理想情况下,淬火后静止态的相关性由广义吉布斯集合描述。然而,如果存在打破可整性的扰动,系统就会热化。在这里,我们比较了这两种情况下的近邻纠缠。图解摘要XY链中突然淬火协议((h_0, gamma ) rightarrow (h, gamma ) )之后的淬火后状态。
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引用次数: 0
Non-Hermitian tearing by dissipation 非赫米撕裂耗散
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-24 DOI: 10.1140/epjb/s10051-024-00714-3
Qian Du, Xin-Ran Ma, Su-Peng Kou

In the paper, we study the non-Hermitian system under dissipation and give the effective (2times 2) Hamiltonian in the k-space by reducing the (Ntimes N) Hamiltonian in the real space for them. It is discovered that the energy band shows an imaginary line gap. To describe these phenomena, we propose the theory of “non-Hermitian tearing” , in which the tearability we define reveals a continuous phase transition at the exceptional point. The non-Hermitian tearing manifests in two forms — separation of bulk state and decoupling of boundary state. In addition, we also explore the one-dimensional Su–Schrieffer–Heeger model and the Qi–Wu–Zhang model under dissipation using the theory of non-Hermitian tearing. Our results provide a theoretical approach for exploring the controlling of non-Hermitian physics on topological quantum states.

摘要 在本文中,我们研究了耗散下的非赫米提系统,并通过还原它们在实空间中的(N次N次)哈密顿,给出了k空间中有效的(2次2次)哈密顿。我们发现,能带显示出虚线隙。为了描述这些现象,我们提出了 "非赫米提撕裂 "理论,其中我们定义的可撕裂性揭示了例外点的连续相变。非赫米撕裂表现为两种形式--体态分离和边界态解耦。此外,我们还利用非赫米撕裂理论探讨了一维 Su-Schrieffer-Heeger 模型和耗散条件下的齐-吴-张模型。我们的结果为探索非赫米提物理对拓扑量子态的控制提供了一种理论方法。
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引用次数: 0
Effects of ballistic transport on the thermal resistance and temperature profile in nanowires 弹道传输对纳米线热阻和温度曲线的影响。
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-24 DOI: 10.1140/epjb/s10051-024-00727-y
R. Meyer, Graham W. Gibson, Alexander N. Robillard

Effects of ballistic transport on the temperature profiles and thermal resistance in nanowires are studied. Computer simulations of nanowires between a heat source and a heat sink have shown that in the middle of such wires the temperature gradient is reduced compared to Fourier’s law with steep gradients close to the heat source and sink. In this work, results from molecular dynamics and phonon Monte Carlo simulations of the heat transport in nanowires are compared to a radiator model which predicts a reduced gradient with discrete jumps at the wire ends. The comparison shows that for wires longer than the typical mean free path of phonons the radiator model is able to account for ballistic transport effects. The steep gradients at the wire ends are then continuous manifestations of the discrete jumps in the model.

摘要:研究了弹道传输对纳米线的温度曲线和热阻的影响。对热源和散热器之间的纳米线进行的计算机模拟表明,与傅里叶定律相比,在这种纳米线的中间,靠近热源和散热器的陡峭梯度会减小。在这项研究中,我们将纳米线热传输的分子动力学和声子蒙特卡洛模拟结果与散热器模型进行了比较。比较结果表明,对于长于声子典型平均自由路径的导线,辐射器模型能够解释弹道传输效应。导线两端的陡峭梯度是模型中离散跃迁的连续表现:
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引用次数: 0
Differential equation for the Uehling potential 厄林电势微分方程
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-22 DOI: 10.1140/epjb/s10051-024-00728-x
Alexei M. Frolov

The second-order differential equation for the Uehling potential is derived explicitly. The right side of this differential equation is a linear combination of the two Macdonald’s functions (K_{0}(b r)) and (K_{1}(b r)). This central potential is of great interest in many QED problems, since it describes the lowest order correction for vacuum polarization in few- and many-electron atoms, ions, muonic and bi-muonic atoms/ions as well as in other similar systems.

摘要 明确推导出了上林势的二阶微分方程。这个微分方程的右边是两个麦克唐纳函数(K_{0}(b r))和(K_{1}(b r))的线性组合。这个中心势在许多 QED 问题中都具有重大意义,因为它描述了少电子和多电子原子、离子、μ介子和双μ介子原子/离子以及其他类似系统中真空极化的最低阶修正。
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引用次数: 0
Revisiting the Thomas–Fermi potential for three-dimensional condensed matter systems 重新审视三维凝聚态系统的托马斯-费米势
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-21 DOI: 10.1140/epjb/s10051-024-00711-6
Gionni Marchetti

We proposed a formally exact, probabilistic method to assess the validity of the Thomas–Fermi potential for three-dimensional condensed matter systems where electron dynamics is constrained to the Fermi surface. Our method, which relies on accurate solutions of the radial Schrödinger equation, yields the probability density function for momentum transfer. This allows for the computation of its expectation values, which can be compared with unity to confirm the validity of the Thomas–Fermi approximation. We applied this method to three n-type direct-gap III–V model semiconductors (GaAs, InAs, InSb) and found that the Thomas–Fermi approximation is certainly valid at high electron densities. In these cases, the probability density function exhibits the same profile, irrespective of the material under scrutiny. Furthermore, we show that this approximation can lead to serious errors in the computation of observables when applied to GaAs at zero temperature for most electron densities under scrutiny.

The Thomas-Fermi potential (V_textrm{ei}^textrm{TF}left( rright) ) and the the exponential cosine screened Coulomb potential (V_textrm{ei}^textrm{EC}left( rright) ) in coordinate space r, from the full interaction potential (V_textrm{ei}^textrm{RPA}left( qright) ) in the momentum space q at Random Phase approximation, through suitable Fourier transforms

摘要 我们提出了一种形式上精确的概率方法,用于评估电子动力学受限于费米面的三维凝聚态系统的托马斯-费米势的有效性。我们的方法依赖于径向薛定谔方程的精确解,可以得到动量传递的概率密度函数。这样就可以计算出其期望值,将其与统一值进行比较,从而确认托马斯-费米近似的有效性。我们将这种方法应用于三种 n 型直接隙 III-V 模型半导体(GaAs、InAs 和 InSb),发现托马斯-费米近似在高电子密度下肯定有效。在这些情况下,无论研究的是哪种材料,概率密度函数都呈现出相同的轮廓。此外,我们还表明,在零温条件下,对于大多数受研究的电子密度,将该近似应用于砷化镓时,会导致观测值的计算出现严重错误。图解摘要坐标空间r中的托马斯-费米势(V_textrm{ei}^textrm{TF}left( rright) )和指数余弦筛选库仑势(V_textrm{ei}^textrm{EC}left( rright) )、通过合适的傅里叶变换,从随机相近似时动量空间 q 中的全相互作用势 (V_textrm{ei}^textrm{RPA}left( qright))得到
{"title":"Revisiting the Thomas–Fermi potential for three-dimensional condensed matter systems","authors":"Gionni Marchetti","doi":"10.1140/epjb/s10051-024-00711-6","DOIUrl":"10.1140/epjb/s10051-024-00711-6","url":null,"abstract":"<p>We proposed a formally exact, probabilistic method to assess the validity of the Thomas–Fermi potential for three-dimensional condensed matter systems where electron dynamics is constrained to the Fermi surface. Our method, which relies on accurate solutions of the radial Schrödinger equation, yields the probability density function for momentum transfer. This allows for the computation of its expectation values, which can be compared with unity to confirm the validity of the Thomas–Fermi approximation. We applied this method to three <i>n</i>-type direct-gap III–V model semiconductors (GaAs, InAs, InSb) and found that the Thomas–Fermi approximation is certainly valid at high electron densities. In these cases, the probability density function exhibits the same profile, irrespective of the material under scrutiny. Furthermore, we show that this approximation can lead to serious errors in the computation of observables when applied to GaAs at zero temperature for most electron densities under scrutiny.</p><p>The Thomas-Fermi potential <span>(V_textrm{ei}^textrm{TF}left( rright) )</span> and the the exponential cosine screened Coulomb potential <span>(V_textrm{ei}^textrm{EC}left( rright) )</span> in coordinate space <i>r</i>, from the full interaction potential <span>(V_textrm{ei}^textrm{RPA}left( qright) )</span> in the momentum space <i>q</i> at Random Phase approximation, through suitable Fourier transforms</p>","PeriodicalId":787,"journal":{"name":"The European Physical Journal B","volume":"97 6","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141527919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kaniadakis entropy in extreme gravitational and cosmological environments: a review on the state-of-the-art and future prospects 极端引力和宇宙学环境中的卡尼达基斯熵:最新进展和未来展望综述
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-21 DOI: 10.1140/epjb/s10051-024-00730-3
Giuseppe Gaetano Luciano

Kaniadakis ((kappa )-deformed) statistics is being widely used for describing relativistic systems with non-extensive behavior and/or interactions. It is built upon a one-parameter generalization of the classical Boltzmann–Gibbs–Shannon entropy, possessing the latter as a particular sub-case. Recently, Kaniadakis model has been adapted to accommodate the complexities of systems under the influence of gravity. The ensuing framework exhibits a rich phenomenology that allows for a deeper understanding of the most extreme conditions of the Universe. Here we present the state-of-the-art of (kappa )-statistics, discussing its virtues and drawbacks at different energy scales. Special focus is dedicated to gravitational and cosmological implications, including effects on the expanding Universe in dark energy scenarios. This review highlights the versatility of Kaniadakis paradigm, demonstrating its broad application across various fields and setting the stage for further advancements in statistical modeling and theoretical physics.

摘要 卡尼亚达基斯(Kaniadakis)((kappa )-变形)统计被广泛用于描述具有非广延性行为和/或相互作用的相对论系统。它建立在经典玻尔兹曼-吉布斯-香农熵的单参数广义基础上,将后者作为一个特殊的子情况。最近,Kaniadakis 模型经过调整,以适应重力影响下系统的复杂性。随之而来的框架呈现出丰富的现象学,让我们能够更深入地了解宇宙中最极端的情况。在这里,我们介绍了(kappa )-统计的最新进展,讨论了它在不同能量尺度下的优点和缺点。特别关注引力和宇宙学的影响,包括在暗能量情况下对膨胀宇宙的影响。这篇综述突出了卡尼达基斯范式的多功能性,展示了它在各个领域的广泛应用,并为统计建模和理论物理的进一步发展奠定了基础。
{"title":"Kaniadakis entropy in extreme gravitational and cosmological environments: a review on the state-of-the-art and future prospects","authors":"Giuseppe Gaetano Luciano","doi":"10.1140/epjb/s10051-024-00730-3","DOIUrl":"10.1140/epjb/s10051-024-00730-3","url":null,"abstract":"<p>Kaniadakis (<span>(kappa )</span>-deformed) statistics is being widely used for describing relativistic systems with non-extensive behavior and/or interactions. It is built upon a one-parameter generalization of the classical Boltzmann–Gibbs–Shannon entropy, possessing the latter as a particular sub-case. Recently, Kaniadakis model has been adapted to accommodate the complexities of systems under the influence of gravity. The ensuing framework exhibits a rich phenomenology that allows for a deeper understanding of the most extreme conditions of the Universe. Here we present the state-of-the-art of <span>(kappa )</span>-statistics, discussing its virtues and drawbacks at different energy scales. Special focus is dedicated to gravitational and cosmological implications, including effects on the expanding Universe in dark energy scenarios. This review highlights the versatility of Kaniadakis paradigm, demonstrating its broad application across various fields and setting the stage for further advancements in statistical modeling and theoretical physics.</p>","PeriodicalId":787,"journal":{"name":"The European Physical Journal B","volume":"97 6","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141527918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of photoluminescence and colorimetric performance of Tb3+-induced calcium tungstate ceramic Tb3+ 引发的钨酸钙陶瓷的光致发光和比色性能评估
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-21 DOI: 10.1140/epjb/s10051-024-00726-z
R. Paikaray, T. Badapanda, S. Sahoo, H. Mohapatra

Photoluminescence and colorimetric investigations of Ca1−xTb2x/3WO4 with x vary from 0.01 to 0.05 samples made by employing the solid-state reaction routes are represented in this paper. Structural analyses of all the phosphors are done with the help of X-ray diffraction spectroscopy and denoted that they exhibit a tetragonal structure and I41/a space group without containing any secondary phase. Optical properties are described with the help of the UV–visible reflectance spectra. In addition, the energy bandgap values are evaluated from these spectra and the values are increased concerning the rise in the Tb contents in CaWO4. Photoluminescence studies are done by considering PL excitation spectra as well as PL emission spectra. The critical concentration of quenching is observed at the composition x = 0.03 along with the critical distance of energy transfer is computed to be ~ 20 Å. Moreover, this distance is created by the dipole–dipole exchanges and indicated by the calculated Q value. Colorimetric analyses of the samples are done from the CIE color coordinates. The green emission color is obtained for all the materials. All the colorimetric parameters are evaluated and quantum yield efficiency for x = 0.03 Tb incorporated CaWO4 material is obtained by exciting it with 485 nm wavelength. Average lifetime values are evaluated by analyzing the PL decay plots.

Graphical abstract

CIE chromaticity diagram of Tb-doped CaWO4 at 485 nm EX wavelength

本文介绍了采用固态反应路线制备的 Ca1-xTb2x/3WO4 样品(x 值从 0.01 到 0.05 不等)的光致发光和比色研究。本文利用 X 射线衍射光谱对所有荧光粉进行了结构分析,结果表明这些荧光粉具有四方结构和 I41/a 空间群,不含任何次生相。紫外-可见光反射光谱描述了这些荧光粉的光学特性。此外,还通过这些光谱评估了能带隙值,随着 CaWO4 中铽元素含量的增加,能带隙值也随之增加。光致发光研究是通过考虑 PL 激发光谱和 PL 发射光谱来完成的。在成分 x = 0.03 时观察到淬火的临界浓度,同时计算出能量转移的临界距离约为 20 Å。样品的色度分析是根据 CIE 色坐标进行的。所有材料的发射色均为绿色。对所有色度参数进行评估,并用 485 纳米波长激发 x = 0.03 Tb 的 CaWO4 材料,获得其量子产率效率。通过分析聚光衰减图,评估了平均寿命值。
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引用次数: 0
Rare earth element Pr enables high thermoelectric performance of Cu12Sb4S13 稀土元素 Pr 实现了 Cu12Sb4S13 的高热电性能
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-21 DOI: 10.1140/epjb/s10051-024-00716-1
Chen Zhu, Feng Hu, Lei Jiang, Shouxi Jiang, Kun Ding, Jian Shao, Manman Ding, Fali Chong

Cu12Sb4S13 has received great attention due to its remarkable thermoelectric properties among medium-temperature range. Herein, the effect of rare earth element Pr substitution at Cu site of Cu12Sb4S13 is comprehensively investigated. Heavy rare earth element Pr substitution can induce strong mass fluctuation and strain-field fluctuation, resulting in intense phonon scattering and decreased lattice thermal conductivity. Consequently, a low lattice thermal conductivity κL of 0.42 W m−1 K−1 is obtained at 748 K in Cu11.7Pr0.3Sb4S13 sample. Additionally, the substitution of Pr for Cu can function as donors, tuning the hole concentration and optimizing the thermopower over the entire temperature range, with a maximum thermopower of 165 μV K−1 at 748 K. Correspondingly, a peak ZT of~0.9 is obtained at 748 K in Cu11.7Pr0.3Sb4S13 sample, due to the significantly reduced thermal conductivity and slightly enhanced power factor.

Graphical abstract

Perspective of Cu12Sb4S13 crystal structure and the temperature-dependent ZT for Cu12-xPrxSb4S13 samples

Cu12Sb4S13 因其在中温范围内的显著热电性能而备受关注。本文全面研究了稀土元素 Pr 在 Cu12Sb4S13 的 Cu 位点上的取代效应。重稀土元素 Pr 取代会引起强烈的质量波动和应变场波动,导致强烈的声子散射和晶格热导率降低。因此,Cu11.7Pr0.3Sb4S13 样品在 748 K 时的晶格热导率κL 低至 0.42 W m-1 K-1。此外,用 Pr 替代 Cu 可作为供体,在整个温度范围内调节空穴浓度并优化热功率,在 748 K 时的最大热功率为 165 μV K-1。相应地,由于热导率显著降低和功率因数略有提高,Cu11.7Pr0.3Sb4S13 样品在 748 K 时的 ZT 峰值为~0.9。
{"title":"Rare earth element Pr enables high thermoelectric performance of Cu12Sb4S13","authors":"Chen Zhu,&nbsp;Feng Hu,&nbsp;Lei Jiang,&nbsp;Shouxi Jiang,&nbsp;Kun Ding,&nbsp;Jian Shao,&nbsp;Manman Ding,&nbsp;Fali Chong","doi":"10.1140/epjb/s10051-024-00716-1","DOIUrl":"10.1140/epjb/s10051-024-00716-1","url":null,"abstract":"<div><p>Cu<sub>12</sub>Sb<sub>4</sub>S<sub>13</sub> has received great attention due to its remarkable thermoelectric properties among medium-temperature range. Herein, the effect of rare earth element Pr substitution at Cu site of Cu<sub>12</sub>Sb<sub>4</sub>S<sub>13</sub> is comprehensively investigated. Heavy rare earth element Pr substitution can induce strong mass fluctuation and strain-field fluctuation, resulting in intense phonon scattering and decreased lattice thermal conductivity. Consequently, a low lattice thermal conductivity κ<sub>L</sub> of 0.42 W m<sup>−1</sup> K<sup>−1</sup> is obtained at 748 K in Cu<sub>11.7</sub>Pr<sub>0.3</sub>Sb<sub>4</sub>S<sub>13</sub> sample. Additionally, the substitution of Pr for Cu can function as donors, tuning the hole concentration and optimizing the thermopower over the entire temperature range, with a maximum thermopower of 165 μV K<sup>−1</sup> at 748 K. Correspondingly, a peak <i>ZT</i> of~0.9 is obtained at 748 K in Cu<sub>11.7</sub>Pr<sub>0.3</sub>Sb<sub>4</sub>S<sub>13</sub> sample, due to the significantly reduced thermal conductivity and slightly enhanced power factor.\u0000</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div><div><p>Perspective of Cu<sub>12</sub>Sb<sub>4</sub>S<sub>13</sub> crystal structure and the temperature-dependent ZT for Cu<sub>12-<i>x</i></sub>Pr<sub><i>x</i></sub>Sb<sub>4</sub>S<sub>13</sub> samples</p></div></div></figure></div></div>","PeriodicalId":787,"journal":{"name":"The European Physical Journal B","volume":"97 6","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141527916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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