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In-Situ Manufacturing of SiC-Doped MgB2 Used for Superconducting Wire 超导线用sic掺杂MgB2的原位制备
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-04-30 DOI: 10.18280/ACSM.450210
Satrio Herbirowo, A. Imaduddin, Hendrik, A. Pramono, Sunardi, I. Saefuloh
Received: 1 June 2020 Accepted: 30 March 2021 Magnesium diboride (MgB2) is a highly potential superconducting material, in substitution of Nb3Sn, which has a critical temperature of ~ 39 K. This synthesis and manufacturing of MgB2 wire were conducted by in-situ powder in tube (PIT). The method doped with silicon carbide (SiC) was aimed to study the effect of phase formation on carbon substitution and morphological characteristics with the motivation to improve superconductivity properties. Magnesium, boron, and SiC powders were synthesized and functionally processed with stainless Steel 304 tube. Heat treatment was conducted at 750°C, 800°C, and 850°C for 2 hours followed by furnace cooling. Characterization was carried out by x-ray diffractometer (XRD), scanning electron microscopy (SEM), and cryogenic magnet testing. The results showed that 1% SiC optimally increased the zero critical temperature of MgB2 ~ 37.18 K along with the sintering at 750°C for 2 hours.
二硼化镁(MgB2)是一种极具潜力的取代Nb3Sn的超导材料,其临界温度为~ 39k。采用原位粉末管(PIT)法制备了MgB2线材。采用掺杂碳化硅(SiC)的方法,旨在研究相形成对碳取代和形态特征的影响,以提高超导性能。用不锈钢304管合成了镁、硼、碳化硅粉末,并对其进行了功能性加工。在750°C, 800°C和850°C下进行热处理2小时,然后进行炉冷却。通过x射线衍射仪(XRD)、扫描电镜(SEM)和低温磁体测试对其进行了表征。结果表明:在750℃下烧结2小时,添加1% SiC可使MgB2的零临界温度提高至37.18 K;
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引用次数: 2
Experimental Study on the Treatment of Rural Domestic Wastewater Using the Multi-Soil-Layering System Filled with Sludge-Based Biochar 污泥基生物炭多层土壤系统处理农村生活污水的试验研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-04-30 DOI: 10.18280/ACSM.450208
Jingrui Wang, Ze-Wen Zhang, Yinghe Guo, Liyong Zhang, Junliang Liu
Received: 28 November 2020 Accepted: 10 February 2021 This paper aims to improve the treatment effect of the multi-soil-layering system (MSL) on rural domestic wastewater. For this, sludge-based biochar materials were selected in the experiments to study its impacts on the treatment of rural domestic wastewater using the MSL. The comparative experiments were conducted for the three MSL systems filled with different materials: the sludge-based biochar (a), wood chips (b), and charcoal (c). The results showed that when the sludge-based biochar material was used as a filler, the removal effect of COD, NH4-N, TN, TP is better than that of wood chips and charcoal, and the removal rates were 80%, 90%, 65% and 92%, respectively, meeting the Grade A standard specified in the Hebei Province Rural Domestic wastewater Discharge Standard (DB13/2171-2015); hydraulic loading rates (HLRs) have a great impact on the removal of pollutants, and the pollutant indicators in the system (a)re affected by the HLRs in different degrees, i.e., NH4-N>TP>COD>TN from high to low; considering the treatment efficiency and pollutant removal effect, the HLRs should be selected between 800L/(m·d) and 1200L/(m·d). It’s concluded finally that the sludge-based biochar material can strengthen the removal effect of the MSL system. This study is of theoretical value for the further research on MSL system and resource utilization of the sludge.
本文旨在提高多层土壤系统(MSL)对农村生活污水的处理效果。为此,实验选择污泥基生物炭材料,研究其对MSL处理农村生活污水的影响。对填充不同材料的三种MSL体系进行了对比实验:结果表明:污泥基生物炭(a)、木屑(b)和木炭(c)作为填料时,对COD、NH4-N、TN、TP的去除效果优于木屑和木炭,去除率分别为80%、90%、65%和92%,达到《河北省农村生活污水排放标准》(DB13/2171-2015)规定的a级标准;水力加载率(HLRs)对污染物去除率影响较大,系统中的污染物指标(a)受水力加载率的影响程度不同,NH4-N>TP>COD>TN由高到低;综合考虑处理效率和污染物去除效果,hlr宜选择在800L/(m·d) ~ 1200L/(m·d)之间。最后得出结论,污泥基生物炭材料可以增强MSL系统的去除效果。本研究对MSL系统的进一步研究和污泥资源化利用具有一定的理论价值。
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引用次数: 0
Study of Thermal Behavior of a Horizontal Two Fins Annular Tube Heat Exchanger with Melting Phase Change Material: Fins Orientation Effects 熔化相变材料水平双翅片环形管换热器的热行为研究:翅片取向效应
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-04-30 DOI: 10.18280/ACSM.450206
Nesrine Boulaktout, E. Mezaache, Abdelghani Laouer
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引用次数: 3
The Elimination by Natural Algerian Clay of Chromium Ions from Salt Water 天然阿尔及利亚粘土去除海水中铬离子的研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-04-30 DOI: 10.18280/ACSM.450202
Rachid Chebbi, Amar Fadel, A. Aidi
Received: 23 November 2020 Accepted: 28 March 2021 This paper studies the removal of chromium ions from synthetic brackish water by an adsorption method using natural Algerian Bentonite (NAB), the mineral clay was characterized through FTIR, XRD and SEM/EDS analysis. The effect of the main physicochemical parameters; namely: clay dosage, initial metal ion concentration, pH, and contact time on the removal of Cr was investigated. The results showed that equilibrium was attained within 5 minutes of stirring time. The retention capacity of Cr increased with the increase of adsorbent dose and decreased with the increased initial metal ion concentration. The Langmuir and Freundlich isotherm models were applied to determine the efficiency of bentonite used as an adsorbent. According to the obtained results, the Langmuir model adjusts very well to the experimental data. Based on the kinetic studies for the raw bentonite, it was verified that the mechanism corresponds to predominant pseudo-secondorder adsorption.
本文研究了天然阿尔及利亚膨润土(NAB)吸附法去除合成咸淡水中的铬离子,通过FTIR、XRD和SEM/EDS分析对矿物粘土进行了表征。主要理化参数的影响;考察了粘土投加量、初始金属离子浓度、pH和接触时间对Cr去除率的影响。结果表明,搅拌5分钟即可达到平衡。Cr的截留量随吸附剂剂量的增加而增加,随初始金属离子浓度的增加而降低。采用Langmuir和Freundlich等温模型测定了膨润土作为吸附剂的效率。所得结果表明,Langmuir模型对实验数据有很好的适应性。通过对原料膨润土的动力学研究,验证了其吸附机理以准二级吸附为主。
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引用次数: 1
Physical Properties and Durability of Green Fiber-Reinforced Concrete for Road Bridges 道路桥梁用绿色纤维增强混凝土的物理性能和耐久性
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-04-30 DOI: 10.18280/ACSM.450211
Chenglong Ma
Received: 11 December 2020 Accepted: 23 March 2021 Dry shrinkage and brittleness are outstanding problems with the concrete in road bridges. However, the road bridge concrete has not been systematically studied. No research has fully considered the influence of age on the physical-mechanical properties of road bridge concrete. There are few reports on how the green fiber dosage affects road bridge concrete. This paper analyzes the physical properties and durability of green fiberreinforced concrete for road bridges (RBGFRC). Firstly, calculation methods were provided for physical-mechanical properties of RBGFRC, such as crack resistance, shear capacity of oblique section, and bending capacity of normal section. Next, the physicalmechanical properties of RBGFRC were investigated in terms of flexural strength, compressive strength, splitting tensile strength, and early cracking strength; the durability of the material was discussed from three aspects: carbonation resistance, resistance to freeze-thaw cycles, and porosity. Experimental results verify the good physical properties and durability of RBGFRC. The research provides a reference for applying RBGFRC in other scenarios.
干收缩和脆性是公路桥梁混凝土存在的突出问题。然而,公路桥梁混凝土还没有系统的研究。目前还没有研究充分考虑龄期对路桥混凝土物理力学性能的影响。关于绿色纤维掺量对路桥混凝土性能影响的报道很少。本文对道路桥梁用绿色纤维混凝土的物理性能和耐久性进行了分析。首先,给出了RBGFRC抗裂能力、斜截面抗剪能力、正截面抗弯能力等物理力学性能的计算方法;其次,研究了RBGFRC的抗弯强度、抗压强度、劈裂抗拉强度和早期开裂强度等物理力学性能;从抗碳化性、抗冻融循环性和孔隙率三个方面对材料的耐久性进行了探讨。实验结果验证了RBGFRC具有良好的物理性能和耐久性。该研究为RBGFRC在其他场景中的应用提供了参考。
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引用次数: 1
Application of Conductive Polymer-Based Hydrogel in Multi-robot Balance Control 导电聚合物基水凝胶在多机器人平衡控制中的应用
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-04-30 DOI: 10.18280/ACSM.450205
Tianbo Qiao
Received: 25 December 2020 Accepted: 12 February 2021 At present, the flexible electronic materials with both good flexibility and conductivity have become a major development trend of electronic materials in the future. Due to their flexibility in construction, controllable mechanical properties and electrical conductivity, the conductive polymer-based hydrogels (CPHs) are expected to become one of the candidate materials in flexible electronics and other fields, and have received extensive attention from researchers. However, the existing CPH systems generally have shortcomings such as low mechanical strength and single function. To this end, the authors attempt to construct a hydrogel using polyaniline (PANI) as the conductive component and polyacrylic acid (PAA) as the flexible component through in-situ polymerization and physical blending. The designed PAA/PANI conductive polymerbased hydrogel enjoys ultra-long stretchability and high strength. It can be used in the flexible strain sensors and pressure sensors to detect the step cycle of the multi-legged robot in real time, and adjust their rhythm during the walking gait, thereby achieving the physical balance. This paper provides a new idea for the application of the CPHs, and especially offers a wealth of theoretical foundation and practical experience for the research on its application to the flexible strain sensors.
目前,兼具良好柔韧性和导电性的柔性电子材料已成为未来电子材料的主要发展趋势。导电聚合物基水凝胶(CPHs)由于其结构灵活、力学性能可控和电导率可控,有望成为柔性电子等领域的候选材料之一,受到了研究者的广泛关注。但现有CPH系统普遍存在机械强度低、功能单一等缺点。为此,作者试图通过原位聚合和物理共混,以聚苯胺(PANI)为导电组分,聚丙烯酸(PAA)为柔性组分构建水凝胶。所设计的PAA/PANI导电聚合物基水凝胶具有超长拉伸性和高强度。它可以应用于柔性应变传感器和压力传感器中,实时检测多足机器人的步进周期,并在行走步态中调整其节奏,从而实现身体平衡。本文为CPHs的应用提供了新的思路,尤其为其在柔性应变传感器中的应用研究提供了丰富的理论基础和实践经验。
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引用次数: 1
The Study of Slag Cement’s Microstructural Properties 矿渣水泥微观结构性能研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-04-30 DOI: 10.18280/ACSM.450204
S. Boualleg
Received: 3 December 2020 Accepted: 17 March 2021 The objective of this work is the quantification of hydration in cement. To monitor this quantity of hydrated cement "hydration degrees" we adopted the method of thermogravimetric analysis (TGA) which allowed us to determine the degree of hydration α(t), bound water (WB) and non-evaporable water. This study is completed by the analysis of diffractometers (DRX). Cements containing different percentages of slag. The evolution of the kinetics was studied during 3, 7 and 28 days. According to the results obtained, the hydration rate is inversely proportional to the addition content in the cement. The degree of hydration is directly related to the formation of hydrates and portlandite, more non-evaporable water retained in the hydrates corresponds to a high degree of hydration. This technique is coupled with the carbonation and strength of ordinary mortar. The experimental data obtained have been correlated and interpreted with regard to the evolution of strength and carbonation as a function of the degree of hydration, bound water and non-evaporable water of the cement hydrates. The Bhatty method is verified for the calculation of the degree of hydration and can be successfully applied for composite cements.
接收日期:2020年12月3日接收日期:2021年3月17日本研究的目的是量化水泥中的水化。为了监测水化水泥的“水化度”,我们采用热重分析(TGA)的方法来测定水化程度α(t)、结合水(WB)和不可蒸发水。本研究是通过衍射仪(DRX)分析完成的。含不同比例矿渣的水泥。研究了3、7和28 d的动力学演变。结果表明,水化速率与水泥中掺量成反比。水化程度直接关系到水合物和硅酸盐的形成,水合物中保留的不可蒸发水越多,对应的水化程度越高。这种技术与普通砂浆的碳化和强度相结合。所获得的实验数据与水泥水合物的水化程度、结合水和不可蒸发水的函数强度和碳化的演变进行了关联和解释。验证了Bhatty法计算水化度的正确性,可以成功地应用于复合水泥。
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引用次数: 0
Effect of Martensite Morphologies on Corrosion in 5% H2SO4 Solution of Borided X70 Dual Phase Steel 马氏体形貌对含硼X70双相钢在5% H2SO4溶液中腐蚀的影响
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-02-28 DOI: 10.18280/ACSM.450109
Tassi Hocine, Zidelmel Sami, Al-Zuhairi Omar
Received: 12 November 2020 Accepted: 9 January 2021 In the present investigation, some electrochemical properties of dual phase X70 steels with different martensite morphologies which have undergone boriding were studied. To obtain a variety of martensite morphologies, Direct Quenching (DQ), Intermediate Quenching (IQ) and Step Quenching (SQ) heat treatments were applied at an intercritical annealing temperature (IAT) of 760°C. The treatment (DQ) allowed the formation of fine martensite evenly distributed in the ferrite matrix. (IQ) treatment showed the formation of martensite along the ferrite / ferrite grain boundaries. In contrast, treatment (SQ) induced the formation of a banded morphology of martensite and ferrite. The realization of borides on X70 (DP) steel was carried out in a powder mixture containing 5% of B4C as source of boron, 5% of NaBF4 as activator and 90% of SiC as diluent at 950°C for a period of time from 4 h. The corrosion behavior of X70 (DP) steel has been explored by the Tafel extrapolation method in a 5 wt. % H2SO4 solution. The corrosion resistance of steel which has undergone boriding (BDP) is higher than that of steel which has not undergone it (DP).
在本研究中,研究了不同马氏体形态的双相X70钢经渗硼处理后的一些电化学性能。为了获得多种马氏体形态,在760℃的临界间退火温度(IAT)下进行直接淬火(DQ)、中间淬火(IQ)和阶梯淬火(SQ)热处理。DQ处理使细小的马氏体均匀分布在铁素体基体中。(IQ)处理显示沿铁素体/铁素体晶界形成马氏体。相反,处理(SQ)诱导马氏体和铁素体形成带状形态。在含5% B4C为硼源,5% NaBF4为活化剂,90% SiC为稀释剂的粉末混合物中,在950℃下,从4小时开始,X70 (DP)钢上实现了硼化物。在5 wt. % H2SO4溶液中,用Tafel外推法研究了X70 (DP)钢的腐蚀行为。经渗硼处理的钢的耐蚀性高于未渗硼处理的钢。
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引用次数: 2
Effect of Friction Stir Process Parameters on Mechanical Properties of Al/Eggshell/SiC Composite Material 搅拌摩擦工艺参数对Al/蛋壳/SiC复合材料力学性能的影响
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-02-28 DOI: 10.18280/ACSM.450107
Anas Islam, V. Dwivedi, S. Dwivedi
Received: 26 November 2020 Accepted: 1 February 2021 The rise in pollution is a serious matter of concern for all nations. Industries are mainly responsible for damaging the balance of the cycle of pollution. In this paper, the mechanical properties of Aluminum have been enhanced by reinforcing it with eggshell wastes and SiC as reinforcement particles. Ball-milling technique has been applied for up to 75 hours for making the densities of Aluminum, Eggshell and SiC equal. The prime focus of this work is to improve the hardness value of Aluminium-based final composite material. Friction Stir Process (FSP) technique has been used to develop the composite and the driving parameters of FSP like rotational speed, transverse speed etc. are optimized with the help of the Box-Behnken Design approach. The optimized value of rotation speed was 966.14 rpm as well as transverse speed was 23.18 mm/min. Hardness and tensile strength of composite developed at an optimum combination of parameters were found to be 72.2 BHN and 194.48 MPa respectively. Results showed that tensile strength and hardness were enhanced by about 44.05% and 64.09% respectively.
污染加剧是各国共同关注的严重问题。工业对破坏污染循环的平衡负主要责任。本文以蛋壳渣和碳化硅为增强颗粒,增强铝的力学性能。球磨技术已经应用了长达75小时,使铝、蛋壳和SiC的密度相等。提高铝基最终复合材料的硬度值是本工作的主要重点。采用搅拌摩擦工艺(FSP)技术开发了复合材料,并利用Box-Behnken设计方法对FSP的驱动参数如转速、横向速度等进行了优化。最优转速为966.14 rpm,横向转速为23.18 mm/min。在最佳参数组合下,复合材料的硬度为72.2 BHN,抗拉强度为194.48 MPa。结果表明,复合材料的抗拉强度和硬度分别提高了44.05%和64.09%。
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引用次数: 6
Carbonization Law of Fly Ash Concrete under Freeze-Thaw Cycles Based on Image-Pro Plus 基于Image-Pro Plus的冻融循环下粉煤灰混凝土碳化规律研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-12-30 DOI: 10.18280/acsm.440604
Jingguo Yuan, Bo Zhao, Zhenqiang Wang, Yan Liu
To understand the influence of freeze-thaw on the carbonization performance of concrete in severe cold areas, this paper conducted experiments to explore the carbonization law of fly ash concrete under freeze-thaw cycles. First, carbonization tests were conducted under different freeze-thaw cycles and fly ash contents; then PS (Photoshop) and IPP (Image-Pro Plus) were adopted to measure the carbonized area and calculate the ratio of carbonized area (RCA). The experimental results showed that, when the fly ash content was between 10% and 30%, RCA increased slowly; when the fly ash content was 20%, the convergence point showed up; when the fly ash content was 0, the air-entrained fly ash concrete had the best resistance to carbonation. With the help of PS and IPP, this paper calculated the RCA more accurately and found that, the freeze-thaw cycles can aggravate carbonization, and there is a linear relationship between carbonization depth and RCA. The research findings in this paper can provide a reference for the durability evaluation and design of concrete structures in severe cold areas.
为了解冻融对严寒地区混凝土碳化性能的影响,本文开展了冻融循环下粉煤灰混凝土碳化规律的试验研究。首先,进行了不同冻融循环次数和粉煤灰掺量下的炭化试验;然后采用PS (Photoshop)和IPP (Image-Pro Plus)测量炭化面积,计算炭化面积比(RCA)。试验结果表明,当粉煤灰掺量在10% ~ 30%之间时,RCA增长缓慢;当粉煤灰掺量为20%时,出现了收敛点;粉煤灰掺量为0时,掺气粉煤灰混凝土抗碳化性能最好。利用PS和IPP对RCA进行了更精确的计算,发现冻融循环会加剧炭化,且炭化深度与RCA呈线性关系。本文的研究成果可为严寒地区混凝土结构的耐久性评价和设计提供参考。
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引用次数: 2
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Annales De Chimie-science Des Materiaux
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