{"title":"Seah’s Contribution to Calibration Binding Energies for XPS","authors":"Seiji Kawasaki","doi":"10.1384/jsa.28.205","DOIUrl":"https://doi.org/10.1384/jsa.28.205","url":null,"abstract":"","PeriodicalId":90628,"journal":{"name":"Journal of surface analysis (Online)","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66655672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Introduction of activities for standardization of electron spectroscopies in ISO/TC 201 -Activities related to ISO/TC 201/SC 4 and 7-","authors":"T. Nagatomi","doi":"10.1384/jsa.29.2","DOIUrl":"https://doi.org/10.1384/jsa.29.2","url":null,"abstract":"","PeriodicalId":90628,"journal":{"name":"Journal of surface analysis (Online)","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66656215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Recommendation of Active Surface Analysis","authors":"建一 堤","doi":"10.1384/jsa.29.1","DOIUrl":"https://doi.org/10.1384/jsa.29.1","url":null,"abstract":"","PeriodicalId":90628,"journal":{"name":"Journal of surface analysis (Online)","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66656114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"THE PROGRESS OF QUANTITATIVE ANALYSIS BY ELECTRON SPECTROSCOPY","authors":"M. Seah","doi":"10.1384/jsa.28.s15","DOIUrl":"https://doi.org/10.1384/jsa.28.s15","url":null,"abstract":"","PeriodicalId":90628,"journal":{"name":"Journal of surface analysis (Online)","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66655371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A brief review is given of the status of the tests of quantitative AES and XPS theory using three databases of true [1–5] spectra for AES [6-9], XPS [8-10] and REELS [10-12], respectively. For quantitative analysis by AES and XPS, it is important to test the theory and to use the correct sensitivity factors. We develop our previous analyses of peak area intensities for elemental spectra in digital Auger and X-ray photoelectron databases measured using a fully calibrated spectrometer. The intensities, instead of being analysed after removal of a Tougaard background are now analysed after removal of the extrinsic characteristic loss background by deconvolving the elemental angle-averaged reflected electron energy loss spectra (REELS). The photoelectron spectra now show clear intrinsic shake-up intensities, reduced to around 30% of the total peak intensities. A comparison of theory and experiment within a new matrix-less quantification formulation, using average matrix sensitivity factors, an example of which is shown in Fig 1, leads to correlations with rms scatters of 8% and 11% for AES and XPS, respectively, for a very wide range of transitions. This gives formulae and values of sensitivity factors, appropriate for use with spectrometers calibrated to give true spectra.
{"title":"Quantitative AES and XPS: Tests of Theory Using AES and XPS Databases with REELS Background Subtraction","authors":"M. Seah, I. Gilmore, S. Spencer","doi":"10.1384/jsa.28.s9","DOIUrl":"https://doi.org/10.1384/jsa.28.s9","url":null,"abstract":"A brief review is given of the status of the tests of quantitative AES and XPS theory using three databases of true [1–5] spectra for AES [6-9], XPS [8-10] and REELS [10-12], respectively. For quantitative analysis by AES and XPS, it is important to test the theory and to use the correct sensitivity factors. We develop our previous analyses of peak area intensities for elemental spectra in digital Auger and X-ray photoelectron databases measured using a fully calibrated spectrometer. The intensities, instead of being analysed after removal of a Tougaard background are now analysed after removal of the extrinsic characteristic loss background by deconvolving the elemental angle-averaged reflected electron energy loss spectra (REELS). The photoelectron spectra now show clear intrinsic shake-up intensities, reduced to around 30% of the total peak intensities. A comparison of theory and experiment within a new matrix-less quantification formulation, using average matrix sensitivity factors, an example of which is shown in Fig 1, leads to correlations with rms scatters of 8% and 11% for AES and XPS, respectively, for a very wide range of transitions. This gives formulae and values of sensitivity factors, appropriate for use with spectrometers calibrated to give true spectra.","PeriodicalId":90628,"journal":{"name":"Journal of surface analysis (Online)","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66655405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Evaluation of Electronic/Chemical State of Nano Carbon Materials Using Photoelectron Spectroscopy","authors":"S. Ogawa","doi":"10.1384/jsa.29.82","DOIUrl":"https://doi.org/10.1384/jsa.29.82","url":null,"abstract":"","PeriodicalId":90628,"journal":{"name":"Journal of surface analysis (Online)","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66656019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"XPS Analysis of SEI Coatings Formed on Graphite Negative Electrodes of LIB","authors":"S. Watanabe","doi":"10.1384/jsa.29.111","DOIUrl":"https://doi.org/10.1384/jsa.29.111","url":null,"abstract":"","PeriodicalId":90628,"journal":{"name":"Journal of surface analysis (Online)","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66656126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"CALIBRATION OF ELECTRON SPECTROMETER ENERGY SCALES FOR AES AND XPS","authors":"M. Seah","doi":"10.1384/jsa.28.s30","DOIUrl":"https://doi.org/10.1384/jsa.28.s30","url":null,"abstract":"","PeriodicalId":90628,"journal":{"name":"Journal of surface analysis (Online)","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66655320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"On the Republication of the Articles Contributed by Dr. Seah to JSA","authors":"S. Tanuma","doi":"10.1384/jsa.28.s1","DOIUrl":"https://doi.org/10.1384/jsa.28.s1","url":null,"abstract":"","PeriodicalId":90628,"journal":{"name":"Journal of surface analysis (Online)","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66655356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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