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The quality of x-ray microanalysis in the ultra-soft x-ray region 超软x射线区x射线显微分析质量
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/301
C. Andersen
The quality of a microanalysis by means of X-rays may be defined in terms of the degree of spatial resolution attained, the sensitivity of detection, the precision of the measurement and the accuracy of the measurement. These parameters are discussed in relation to the ultra-soft X-ray region. The ability to perform a quantitative analysis receives special attention, and is found to be greatly affected by the nature of the chemical bonding of the specimen, the correction theory used, and the availability of accurate mass-absorption coefficient data.
利用x射线进行微量分析的质量可以根据所获得的空间分辨率程度、检测的灵敏度、测量的精度和测量的准确性来定义。讨论了这些参数与超软x射线区的关系。进行定量分析的能力受到了特别的关注,并且被发现受到试样化学键的性质、所使用的校正理论和准确质量吸收系数数据的可用性的极大影响。
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引用次数: 25
Dissociation of N 2 in 2450 MHz discharges 2450 MHz放电中n2的解离
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/307
R. Jansson, L. A. Middleton
The degree of dissociation of molecular nitrogen in 2450 MHz discharges in dry N2 and N2-He mixtures at pressures between 09 and 60 torr have been measured by titration with nitric oxide. Using an X-band resonant-cavity technique, electron (ion) densities in the discharges have also been measured. It is concluded that atoms originate chiefly from thermal dissociation at a quasi-equilibrium gas temperature in the range 3000-3700°K, the neutral gas having been heated by random collisions with electrons at much higher temperatures. Between 05 and 2% of the power coupled to the discharge is used in heating the gas.
用一氧化氮滴定法测定了在压力为09 ~ 60托的干燥N2和N2- he混合物中,在2450 MHz放电条件下,分子氮的解离度。利用x波段谐振腔技术,也测量了放电中的电子(离子)密度。由此得出结论,原子主要是在3000-3700°K的准平衡气体温度下由热解离产生的,而中性气体则是在更高的温度下通过与电子的随机碰撞而加热的。耦合到放电的5%到2%的功率用于加热气体。
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引用次数: 4
Formation time and resonator loss in a Q-switched ruby laser 调q红宝石激光器的形成时间和谐振腔损耗
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/304
W. Gibbs
Measurements of the variation of formation time of a Q-switched ruby laser as a function of loop gain are presented. The loop gains were calculated from integrated pump intensities and the measured resonator loss at threshold. The relationship between formation time and loop gain predicted by fast Q-switching theory was confirmed. Although large optical distortions are to be expected in rubies pumped to Q-switching levels, no indication of increasing resonator loss was found under these conditions.
给出了调q红宝石激光器形成时间随环路增益变化的测量结果。回路增益由综合泵浦强度和测量的阈值谐振器损耗计算得到。证实了快速q开关理论预测的形成时间与环路增益之间的关系。虽然预计在泵浦到q开关水平的红宝石中会有很大的光学畸变,但在这些条件下没有发现增加谐振腔损失的迹象。
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引用次数: 2
Friction and dynamic mechanical characteristics of crystalline polymers during melting 结晶聚合物熔化过程中的摩擦和动态力学特性
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/315
G. Vinogradov, Y. Yanovsky, E. Frenkin
This paper describes a study of the temperature dependence of the dynamic characteristic and friction in the melting and crystallization region of linear polyethylene, isotactic polypropylene and their 9: 1, 5: 5 and 1: 9 mixtures. The measurements were made on a Ferry-Fitzgerald type transducer and on a tribometer. The temperature-dependence curves of shear storage and loss moduli, the loss tangent, the friction and the slider-to-polymer contact area of the above materials were plotted. It is suggested that correlation of the dynamic and tribometric characteristics of polymers may be expected when the nominal contact area of the friction body approximates its actual value. Comparison of these characteristics for linear polyethylene in its pre-melting range reveal only a qualitative similarity between the temperature dependence of its shear storage and loss moduli on the one hand, and the ratio of the loads and friction to the slider-to-polymer contact area on the other. Investigation of mixtures of crystalline polymers has made it possible to determine the sequence of melting of the components in the mixture or the formation of a single-phase system at a definite component concentration. After crystallization of both components, two-phase binary systems containing crystallizing polymers have the structure of two interlaced frameworks formed by the polymer crystallites.
本文研究了线性聚乙烯、等规聚丙烯及其9:1、5:5和1:9混合物的熔点和结晶区动态特性和摩擦的温度依赖性。测量是在费里-菲茨杰拉德式传感器和摩擦计上进行的。绘制了上述材料的剪切储存和损耗模量、损耗切线、摩擦力和滑块与聚合物接触面积的温度随曲线。建议当摩擦体的标称接触面积接近其实际值时,聚合物的动力特性和摩擦特性的相关性是可以预期的。对线性聚乙烯在预熔范围内的这些特性进行比较,一方面揭示了其剪切储存和损失模量的温度依赖性,另一方面揭示了载荷和摩擦与滑块与聚合物接触面积的比率之间的定性相似性。对结晶聚合物混合物的研究使确定混合物中组分的熔化顺序或在一定组分浓度下形成单相体系成为可能。两组分结晶后,含结晶聚合物的两相二元体系具有由聚合物结晶形成的两个交错框架的结构。
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引用次数: 8
The evaluation of thermally stimulated current curves 热激电流曲线的评价
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/302
T. Cowell, J. Woods
A method of evaluating experimentally determined thermally stimulated current curves by a process of successive approximation is described. The method is essentially one of curve fitting and an excellent fit is eventually obtained between the theoretical and experimental curves. The process of curve fitting serves to determine the electron-trapping parameters. The technique can be used for the two extreme cases of trap emptying: emptying with no retrapping and emptying with fast retrapping. The technique is illustrated by its application to some experimental results obtained from CdS crystals.
描述了一种用逐次逼近法评定实验确定的热激电流曲线的方法。该方法本质上是一种曲线拟合方法,理论曲线与实验曲线最终得到了很好的拟合。曲线拟合过程用于确定电子捕获参数。该技术可用于两种极端的疏水阀排空情况:不重新排空和快速重新排空。通过对CdS晶体实验结果的分析,说明了该方法的可行性。
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引用次数: 137
Air filtration by moving filaments 通过移动细丝过滤空气
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/318
H. Pyne, R. Wilson, B. Soole
It is shown that droplets may be removed from an air stream by impaction on a number of filaments mounted radially on a central disk which is rotated in a plane at right angles to the direction of flow. Published theoretical and experimental results indicate that particles will be impacted on the filaments when the rate of rotation of the disk is sufficient for the Stokes number of the smallest particle which is to be removed to be equal to at least 12. Experiments are described with a filter composed of 390 filaments, 10 cm long and 460 μm thick, mounted on a disk 56 cm in diameter. When the disk was rotated at 1900 rev min-1, just sufficient to ensure that the Stokes number for 4 μm particles of unit-density material was 12 and that the air flow of 2500 ft3 min-1 was fully swept, the measured filtration efficiency was equivalent to 90 ± 5% for 4 μm droplets of unit-density material and progressively more for the larger sizes. Filtration efficiencies were determined by the use of sodium-24 as a radioactive tracer in conjunction with cascade impactors. Filtration devices of the type described have the advantages that they are compact, self-cleaning and offer little resistance to large rates of air flow.
结果表明,液滴可以通过撞击若干沿径向安装在与气流方向成直角旋转的中心圆盘上的细丝而从气流中移除。已发表的理论和实验结果表明,当圆盘的旋转速度足以使要去除的最小颗粒的斯托克斯数至少等于12时,颗粒就会撞击到细丝上。实验描述了用390根长10 cm、厚460 μm的灯丝组成的滤光片,安装在直径56 cm的圆盘上。当圆盘转速为1900转/分钟-1时,刚好能够保证4 μm单位密度颗粒的斯托克斯数为12,并且充分扫过2500 ft3 min-1的气流时,测量到的过滤效率对于4 μm单位密度颗粒的过滤效率相当于90±5%,对于更大尺寸的过滤效率则逐渐提高。过滤效率是通过使用钠-24作为放射性示踪剂与级联撞击剂结合来确定的。所描述的类型的过滤装置的优点是,它们是紧凑的,自清洁,并提供小阻力大气流率。
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引用次数: 12
The calculation of the emissivity of cylindrical cavities giving near black-body radiation 近似黑体辐射下圆柱腔发射率的计算
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/310
T. Quinn
A new calculation has been made of the emissivities of cylinders closed at one end and having in the other end an opening of radius either equal to or smaller than the radius of the cylinder. The results are presented for cylinders having diffusely reflecting walls with dimensions such that the emissivity is very close to unity. The method of calculation is that devised by de Vos, but fewer approximations are made, and significantly higher values of emissivity obtained. Comparison with the results of other calculations leads to the conclusion that those of both Buckley and Gouffe are seriously in error for this type of cavity while those of Sparrow et al. are in very close agreement with the present results though obtained by quite different methods. Estimates are made of the effects on the emissivity of internal baffles and grooved surfaces.
对一端封闭,另一端开半径等于或小于圆柱体半径的圆柱体的发射率作了新的计算。结果提出了柱体漫反射壁的尺寸,使发射率非常接近统一。计算方法是由de Vos设计的,但近似较少,得到的发射率值明显较高。与其他计算结果比较,Buckley和Gouffe对这类空腔的计算结果都有严重的误差,而Sparrow等人的计算结果虽然采用了完全不同的方法,但与本文的结果非常吻合。估计了内部挡板和沟槽表面对发射率的影响。
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引用次数: 72
Lattice parameters of iron-aluminium alloys 铁铝合金的晶格参数
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/423
J. A. Fraunhofer
The linear expansion of the iron cubic lattice by aluminium additions has been determined by x-ray diffraction and the results compared with earlier work.
通过x射线衍射确定了铝的加入使铁立方晶格线性膨胀,并将结果与早期的工作进行了比较。
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引用次数: 1
The influence of pre-orientation on the optical and mechanical anisotropy of drawn polymers 预取向对拉伸聚合物光学和力学各向异性的影响
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/317
I. Ward
Expressions have been derived for the optical birefringence and elastic constants of an initially isotropic polymer or fibre subjected to a two-stage stretching process. The first stage is carried out at high temperatures, with the polymer or fibre in its rubbery state, and the second stage is cold drawing. The predicted birefringences and extensional moduli show good agreement with experimental data for polyethylene terephthalate.
推导了一种初始各向同性聚合物或纤维在两阶段拉伸过程中的光学双折射和弹性常数的表达式。第一阶段是在高温下进行,聚合物或纤维处于橡胶状态,第二阶段是冷拔。对聚对苯二甲酸乙二醇酯的双折射率和拉伸模量的预测结果与实验数据吻合较好。
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引用次数: 29
A new approach to the fracture of bonds in a random fibrous network such as paper 研究纸张等随机纤维网络中键断裂的新方法
Pub Date : 1967-08-01 DOI: 10.1088/0508-3443/18/8/320
C. Dodson
A new descriptive formalism is introduced to represent the state of a bonded random network of fibres, such as paper, when subjected to mechanical deformation. Energy is considered to be distributed among the lengths of free fibre between inter-fibre bonds and a criterion for the fracture of these bonds is postulated. The theory is used in the present paper to derive the cumulative fracture of bonds as a function of time in a network which suffers a uniform rate of elongation. Good agreement was obtained with experimental recordings of the failure of bonds in a thin sheet of paper. No systematic influence of the rate of straining on the mode of bond failure was detected.
引入了一种新的描述形式来表示纤维(如纸)在受到机械变形时的粘合随机网络的状态。认为能量分布在纤维间键之间的自由纤维长度之间,并假设了这些键断裂的判据。这一理论在本文中被用来推导出在一个具有均匀伸长率的网络中,键的累积断裂作为时间的函数。结果与薄纸上键破坏的实验记录吻合良好。没有发现应变速率对粘结破坏模式的系统影响。
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引用次数: 4
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British Journal of Applied Physics
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