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Color Phenomena Associated With Energy Transfer in Afterglows and Atomic Flames 余辉和原子火焰中与能量传递有关的颜色现象
A. Bass, H. Broida
Reactions involving reactive species produced in electric discharges are frequently characterized by the emission of visible light of many different colors. Some typical afterglows and atomic flames have been photographed, and the observed colors (or spectral distributions) are discussed with regard to the reactions from which they arise. Laboratory studies of this sort are helpful for the understanding of the energy transfer processes which occur in flames, in electrical discharges, and in the upper atmosphere.
在放电中产生的涉及活性物质的反应通常以发射许多不同颜色的可见光为特征。对一些典型的余辉和原子火焰进行了拍摄,并讨论了观察到的颜色(或光谱分布)与它们产生的反应。这类实验室研究有助于理解在火焰、放电和高层大气中发生的能量传递过程。
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引用次数: 4
Infrared Spectrum of the v2+ v6 Band of C13C12H6* C13C12H6*的v2+ v6波段红外光谱
W. J. Lafferty, E. K. Plyler
The infrared spectrum of the v2+v6 band of C13C12H6 has been analyzed and a value of B0= 0.64865 ±0.00005 cm−1 determined. When this value is combined with that found in recent work on isotopically normal ethane, a “rs” value of 1.527±0.004 A for the carboncarbon bond distance is obtained. (Uncertainties are probable errors.)
对C13C12H6的v2+v6波段的红外光谱进行了分析,确定了B0= 0.64865±0.00005 cm−1。当这个值与最近同位素正乙烷的研究结果相结合时,得到了碳-碳键距离的“rs”值1.527±0.004 a。(不确定性是可能的错误。)
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引用次数: 0
Self-Broadening of Carbon Monoxide in the 2 v and 3 v Bands * 一氧化碳在2v和3v波段的自展宽*
E. K. Plyler, R. J. Thibault
The self-broadening of carbon monoxide has been measured for the 2 v and 3 v bands with pressures up to 3.5 atmospheres. A grating spectrometer of high resolving power was used for the measurements and the correction for finite slits was small. The corrections varied from 3 to 20 percent for the different conditions of measurement. The half-widths per atmosphere, γ°, decreased from 0.089 cm−1 for |m| = 1 to 0.053 cm−1 for |m| = 21. The half-widths are compared with those obtained by other investigators and it is shown that the results reported in this work fall in between the self-broadening values previously obtained.
在2v和3v波段,在3.5个大气压下测量了一氧化碳的自展宽。采用高分辨率的光栅光谱仪进行测量,有限狭缝的校正很小。在不同的测量条件下,校正值从3%到20%不等。每大气半宽度γ°从|m| = 1时的0.089 cm−1下降到|m| = 21时的0.053 cm−1。将半宽度与其他研究者获得的结果进行了比较,结果表明,本工作报告的结果落在先前获得的自展宽值之间。
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引用次数: 16
An Absolute Calibration of the National Bureau of Standards Thermal Neutron Flux 国家标准局热中子通量的绝对校准
E. Axton
The NBS Thermal Neutron Flux has been calibrated in terms of the gold thermal neutron capture cross section. The effective thermal neutron (below cadmium cutoff energy) flux density is estimated to be 4307 ± 2 percent n/cm2 sec in September 1961. This figure is in agreement with a recent value quoted by the NBS.
根据金热中子捕获截面对NBS热中子通量进行了校准。1961年9月,热中子(低于镉的截止能量)的有效通量密度估计为4307±2% n/cm2秒。这一数字与国家统计局最近公布的数据一致。
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引用次数: 1
Thermodynamic Properties of Polyethylene Predicted from Paraffin Data. 根据石蜡数据预测的聚乙烯热力学性质。
Pub Date : 1963-05-01 Epub Date: 1963-06-01 DOI: 10.6028/jres.067A.023
Martin G Broadhurst

Thermodynamic data on the n-paraffins from n-C6H14 through n-C18H38 have been used to obtain values for the specific heat, entropy, enthalpy, and Gibbs free energy of a large, ideal CH2-chain crystal from 0 to 420 °K and of the liquid above 200 °K. Analytical expressions are given for the properties of the crystal and liquid above 200 °K. For the crystal, a modified Einstein function was used to adjust the melting temperature to 414.3 °K. Values between 975 and 1025 cal/mole for the heat of fusion were found to be the ones most consistent with the data. Comparison of the results with polyethylene data shows reasonable agreement.

通过 n-C6H14 至 n-C18H38 正石蜡的热力学数据,我们获得了 0 至 420 °K 的大型理想 CH2 链晶体和 200 °K 以上液体的比热、熵、焓和吉布斯自由能值。对于高于 200 °K 的晶体和液体的性质,给出了分析表达式。对于晶体,使用修正的爱因斯坦函数将熔化温度调整为 414.3 °K。研究发现,熔化热介于 975 和 1025 卡/摩尔之间的数值与数据最为吻合。将结果与聚乙烯数据进行比较,结果显示两者吻合。
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引用次数: 0
Synthesis of Isomers of Eugenol1 丁香酚1异构体的合成
G. Brauer, Richard W. Morris, Willard B. Howe
In connection with an investigation of the correlation between structure and reactivity of eugenol isomers, o-eugenol, 3-allyl-2-methoxyphenol and chavibetol were synthesized. A five-step synthesis was found to be most suitable for the preparation of 3-allyl-2-methoxyphenol. An improved separation of chavibetol from eugenol was achieved by gas chromatography.
通过研究丁香酚异构体的结构与反应性的关系,合成了邻丁香酚、3-烯丙基-2-甲氧基酚和沙维酚。结果表明,制备3-烯丙基-2-甲氧基苯酚的最佳方法为五步法。采用气相色谱法对丁香酚和沙维酚进行了分离。
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引用次数: 3
Purity Analysis of Highly Purified Materials by Time-Temperature Cryometry 时间-温度冷冻法分析高纯度材料的纯度
G. Ross, H. D. Dixon
Visual observation of the freezing and melting of compounds in cells used for the determination of purity has uncovered some heretofore unexpected behavior. This behavior has been correlated with certain difficulties experienced in the measurement of purity, particularly when the sample is very pure. Means for partially reducing these difficulties are proposed and procedures for increasing the accuracy of purity measurements are described.
肉眼观察用于纯度测定的细胞中化合物的冻结和融化,揭示了一些迄今为止意想不到的行为。这种行为与纯度测量中遇到的某些困难有关,特别是当样品非常纯净时。提出了部分减少这些困难的方法,并描述了提高纯度测量精度的方法。
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引用次数: 3
Absorption Bands of Carbon Dioxide* From 5.3 to 4.6 Microns 二氧化碳吸收波段*从5.3到4.6微米
A. Maki, E. K. Plyler, R. J. Thibault
Measurements have been made of the frequencies of the infrared absorption lines of CO2 in the region from 1850 cm−1 to 2150 cm−1. Observations were made at various pressures and pathlengths up to a maximum of 72 meter-atmospheres. Vibration-rotation constants were obtained characterizing the transitions 111c0–000, 111d0–000, 031c0–000, 031d0–000, 200–011c0, I22c0–011c0, 122d0–011d0 for C12O2. The 111c0–000 band due to the C13O2 molecule was also measured.
测量了1850 ~ 2150 cm - 1范围内CO2红外吸收谱线的频率。观测是在各种压力和路径下进行的,最高可达72米大气压。得到了表征C12O2的111c0-000、111d0-000、031c0-000、031d0-000、200-011c0、I22c0-011c0、122d0-011d0跃迁的振动旋转常数。同时测量了C13O2分子产生的111c0-000波段。
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引用次数: 7
A Controlled Atmosphere Chamber 可控气氛室
C. L. Gordon, R. Johannesen
An inert atmosphere chamber for the transfer of reactive materials is described. It has the advantages of being inexpensive, easily cleaned, and can be evacuated.
描述了一种用于转移反应物质的惰性气氛室。它的优点是价格便宜,容易清洗,可以抽真空。
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引用次数: 0
Analysis of Families of Curves 曲线族的分析
J. Mandel, F. McCrackin
A systematic approach is presented for fitting empirical expressions to data depending on two variables. The problem can also be described as the simultaneous fitting of a family of curves depending on a parameter. The proposed method reduces a surface fitting problem to that of fitting a few functions of one variable each. First, the surface is expressed in terms of these one-variable functions, and using an extension of two-way analysis of variance, the accuracy of this fit is assessed without having to determine, at this point, the nature of the one-variable functions. Then, the one-variable functions are fitted by customary curve-fitting procedures. For illustration, the method is applied to two sets of experimental data.
一个系统的方法提出拟合经验表达式的数据取决于两个变量。这个问题也可以被描述为依赖于一个参数的一系列曲线的同时拟合。提出的方法将曲面拟合问题简化为拟合一个变量的几个函数的问题。首先,用这些单变量函数来表示曲面,并使用双向方差分析的扩展,评估这种拟合的准确性,而不必在此时确定单变量函数的性质。然后,用常规的曲线拟合程序对单变量函数进行拟合。为了说明,将该方法应用于两组实验数据。
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引用次数: 10
期刊
Journal of research of the National Bureau of Standards. Section A, Physics and chemistry
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