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Unimolecular and bimolecular reactions of organic intermediates on metal oxide catalysts: an update 金属氧化物催化剂上有机中间体的单分子和双分子反应:最新进展
Pub Date : 2024-06-06 DOI: 10.1080/01614940.2024.2354699
Victor Fung, Michael Janik, S. Crossley, Ya-Huei Cathy Chin, A. Savara
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引用次数: 0
Advancements and Perspective of Environmentally Sustainable Technologies for Electrochemical Selective Conversion of CO 2 to Methanol 将 CO 2 电化学选择性转化为甲醇的环境可持续技术的进展与展望
Pub Date : 2024-05-22 DOI: 10.1080/01614940.2024.2340582
Allwin Sudhakaran, Chob Singh, Hemavathi M. Aaradhya, Ankush V. Biradar, A. Samal, Nitin K. Chaudhari, A. H. Jadhav
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引用次数: 0
Michael reaction in organocascade catalysis: A powerful tool for creating architectural complexity in the construction of medicinally privileged heterocyclic scaffolds 有机级联催化中的迈克尔反应:在构建具有药用价值的杂环支架时创造结构复杂性的有力工具
Pub Date : 2024-04-24 DOI: 10.1080/01614940.2024.2320802
R. N. Yadav, Md. Firoj Hossain, Devalina Ray, Ashok Kumar Srivastava, B. K. Banik
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引用次数: 0
State-of-the-art for the development of Cu-based heterogeneous catalysts for efficient utilization of furfural to value chemicals via liquid-phase and gas-phase reactions cu基多相催化剂的发展现状,用于通过液相和气相反应高效利用糠醛来评价化学品
Pub Date : 2023-10-24 DOI: 10.1080/01614940.2023.2267286
Rohit Rangnath Nikam, P. Manikanta, Komal N. Patil, None Mounesh, Itika Kainthla, Siddappa A. Patil, Bhari Mallanna Nagaraja
ABSTRACTIn the present review, we aim to provide important insights into copper-based heterogeneous catalytic systems and discuss the conversion of furfural (FF) through hydrogenation. Each discussed catalyst and the support used for the catalytic reactions play a vital role in the reaction mechanism along with different factors enhancing the catalytic activity. Also, the importance of Cu-based materials along with support, the importance of solvent in the liquid-phase reaction, and the importance of pre-reduction of catalysts are explained in detail. In addition, the superior activity of the catalyst and a few reports from the last decade for Cu-based catalytic systems have been summarized along with the tabulation of different synthesis procedures, mechanistic study, and detailed descriptions with tables and figures. Finally, the conclusions with future aspects for the development of the catalytic hydrogenation process via Cu-based catalytic systems are overviewed.KEYWORDS: Biomass-derived materialscopper catalystheterogeneous catalysishydrogenationliquid and gas phase Highlights A comprehensive study for the catalytic hydrogenation of furfural to value-added chemicals via liquid and gas phase reactions is discussed.Importance of solvent, the importance of reduction temperature and the role of copper for the furfural catalytic hydrogen transfer reactions are discussed in detail.The synthesis method and different analytical and spectroscopical factors along with a mechanism are discussed where required.Future aspects in the field of furfural catalytic hydrogen transfer reaction.List of Abbreviations Furfural=FFFurfuryl alcohol=FA2-methylfuran/Methylfuran=2-MF/MFCyclopentanone=CPCyclopentanol=CPOTetrahydrofuran=THFTetrahydrofurfural alcohol=THFAMethyl tetrahydrofurfural=MTHF5-hydroxymethylfurfural=HMF2,5-dimethyl furan=DMFMethanol=MeOHEthanol=EtOHIsopropyl alcohol=IPALevulinic acid=LAγ-valerolactone=GVL1,3,5-benzene tricarboxylate=BTC/CMetal-Organic Framework=MOFHypercrosslinked polystyrene=HPSTime on Stream=TOSCatalytic Transfer Hydrogenation=CTHLiquid Hourly Space Velocity=LHSVGas Hourly Space Velocity=GHSVTemperature Programmed Reduction=TPRTemperature Programmed Desorption=TPDX-ray Diffraction=XRDX-ray Photoelectron Spectroscopy=XPSField Emission Scanning Electron Microscopy=FE-SEMTransmission Electron Microscopy=TEMGreenhouse gases=GHGInternational Energy Agency=IEAUnited States=USAcknowledgmentsThe authors would like to acknowledge CNMS, JAIN (Deemed-to-be University) and Nano Mission, DST, Government of India, for financial support SR/NM/NS-20/2014, minor research project (No. JU/MRP/CNMS/11/2022)Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by the DST, Nanomission [SR/NM/NS-20/2014].
摘要本综述旨在对铜基非均相催化体系提供重要的见解,并讨论糠醛(FF)的加氢转化。讨论了催化反应所用的催化剂和载体在反应机理中起着至关重要的作用,不同的因素增强了催化活性。同时详细阐述了铜基材料及其载体的重要性、液相反应中溶剂的重要性以及催化剂预还原的重要性。此外,还对铜基催化体系的优异活性和近十年来的一些报道进行了总结,并对不同的合成方法、机理研究和详细的表格和图表进行了介绍。最后,对铜基催化体系催化加氢工艺的发展进行了展望。关键词:生物质衍生材料;scopper催化剂;异相催化;加氢;详细讨论了溶剂的重要性、还原温度的重要性以及铜在糠醛催化氢转移反应中的作用。在需要的地方讨论了合成方法和不同的分析和光谱因素以及作用机理。今后在糠醛催化氢转移反应领域的研究方向。缩写表糠醛= ff糠醇= fa2 -甲基呋喃/甲基呋喃=2-MF/ mf环戊酮= cp环戊醇= cpo四氢呋喃= thf四氢呋喃醇= thfam乙基四氢呋喃= mthf5 -羟甲基糠醛=HMF2,5-二甲基呋喃= dmf甲醇= mehe乙醇= etohiso丙醇= ipalevulic酸= la γ-戊内酯=GVL1,3,5-苯三羧酸酯=BTC/ c金属有机骨架= mof高交联聚苯乙烯= hps流上时间=催化转移加氢= cth液体小时空间速度=LHSVGas小时空间速度=GHSVTemperature Programmed Reduction=TPRTemperature Programmed解译= tpdx射线衍射= xrdx射线光电子能谱= xpsx场发射扫描电镜= fe - sem透射电镜= tem温室气体= ghg国际能源机构= iea美国=美国致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢未成年人研究项目(编号:;JU/MRP/CNMS/11/2022)披露声明作者未报告潜在利益冲突。本研究得到了DST, nan遗漏[SR/NM/NS-20/2014]的支持。
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引用次数: 0
Recent advancements in synthesis and multi-functional catalytic applications of graphitic carbon nitride 石墨氮化碳的合成及多功能催化应用研究进展
Pub Date : 2023-09-06 DOI: 10.1080/01614940.2023.2250652
M. Preeyanghaa, Ravikumar Dhanalakshmi, A. Aishwarya, Masakazu Anpo, Bernaudshaw Neppolian, Vajiravelu Sivamurugan
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引用次数: 0
Monolithic fiber/foam-structured catalysts: beyond honeycombs and micro-channels 单片纤维/泡沫结构催化剂:超越蜂窝和微通道
Pub Date : 2023-08-06 DOI: 10.1080/01614940.2023.2240661
Guofeng Zhao, J. Moulijn, F. Kapteijn, F. Dautzenberg, Bin Xu, Yong Lu
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引用次数: 1
Insights into selectivity modulation of electrochemical CO2 reduction reactions over Cu-based catalysts in terms of the key intermediates 在关键中间体方面对cu基催化剂上电化学CO2还原反应选择性调制的见解
Pub Date : 2023-07-26 DOI: 10.1080/01614940.2023.2240660
Yue Gong, Yanjie Wang, Tao He
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引用次数: 0
Mechanistic insights into the roles of graphene oxide and its derivatives in organic transformations – a review 氧化石墨烯及其衍生物在有机转化中的作用机理研究综述
Pub Date : 2023-07-14 DOI: 10.1080/01614940.2023.2232643
Hamed Barzinmehr, M. Mirza‐Aghayan, R. Boukherroub
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引用次数: 1
Key factors in improving the synthesis and properties of visible-light activated g-C3N4 for photocatalytic hydrogen production and organic pollutant decomposition 提高可见光活化g-C3N4光催化制氢和有机污染物分解性能的关键因素
Pub Date : 2023-07-03 DOI: 10.1080/01614940.2023.2228130
A. H. Navidpour, D. Hao, Xiaowei Li, Donghao Li, Zhenguo Huang, John L. Zhou
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引用次数: 2
Dear readers of catalysis reviews – science and engineering 亲爱的读者催化评论-科学与工程
Pub Date : 2023-06-30 DOI: 10.1080/01614940.2023.2228126
A. Bell
First, I want to announce that Prof. Kamil Klier (Lehigh University, retired) has asked to step down from the position of Co-Editor after serving for 33 years in this position. While I was sorry to hear this news, I could fully appreciate his decision, given the many years of devoted service to the journal. I want to say that I have greatly enjoyed working with Kamil and have found him to be to a wonderful editorial partner, who continuously helped the journal maintain its high intellectual standards.
首先,我要宣布,卡米尔·克利尔教授(里海伊大学,已退休)在担任联合编辑一职33年后,要求辞去该职位。虽然我很遗憾听到这个消息,但我完全理解他的决定,因为他多年来一直致力于为《华尔街日报》服务。我想说的是,我非常喜欢与卡米尔一起工作,并发现他是一位出色的编辑伙伴,他不断帮助杂志保持其高智力标准。
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引用次数: 0
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Catalysis Reviews
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