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Recent Progress of the Cation Based Conductive Bridge Random Access Memory 阳离子导电桥随机存取存储器的研究进展
Pub Date : 2023-03-31 DOI: 10.31613/ceramist.2023.26.1.07
Hae Jin Kim
Demand for new computing systems equipped with ultra-high-density memory storage and new computer architecture is rapidly increasing with the tremendous increment of the amount of data produced and/or reproduced. In particular, the requirement for technology development is growing as conventional storage devices face the physical limitations for scaling down and the data bottleneck that the Von Neumann architecture increases. Among the recent emerging memory devices, the conductive bridge random access memory (CBRAM) has superior switching properties and excellent scalability to be adopted as the next-generation storage device and as the hardware implementation of the neuromorphic computing system. In this review, the previous papers on the resistive switching mechanism of CBRAM and the precedent CBRAM devices exploiting various materials proposed by many research groups are introduced. The principle of CBRAM is discussed including the operation mechanism, switching materials, and the challenges that need to be solved. A wide selection of materials including metal oxides, Chalcogenides, and other non-oxides have been examined as the electrolyte layer of the CBRAM. Various switching materials, device engineering, and material innovation approaches were introduced, and the research results for solving the problems of CBRAM were reviewed in depth.
随着产生和/或复制的数据量的巨大增加,对配备超高密度存储器和新型计算机体系结构的新型计算系统的需求正在迅速增加。特别是,随着传统存储设备面临缩小规模的物理限制和冯·诺依曼架构增加的数据瓶颈,对技术发展的需求正在增长。在新兴的存储器件中,导电桥随机存取存储器(CBRAM)具有优越的开关性能和优异的可扩展性,可作为下一代存储器件和神经形态计算系统的硬件实现。本文综述了近年来国内外关于CBRAM阻性开关机理的研究成果,以及许多研究小组提出的利用各种材料的CBRAM器件。讨论了CBRAM的原理,包括工作机制、开关材料和需要解决的挑战。广泛选择的材料包括金属氧化物、硫族化合物和其他非氧化物作为CBRAM的电解质层进行了研究。介绍了各种开关材料、器件工程和材料创新方法,并对解决CBRAM问题的研究成果进行了深入评述。
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引用次数: 0
A way to utilize SOFC systems: The energy solution for next-generation smart farm 利用SOFC系统的方法:下一代智能农场的能源解决方案
Pub Date : 2023-03-31 DOI: 10.31613/ceramist.2023.26.1.05
Gwangwoo Han, Jong-Eun Hong, Wang-Je Lee, Kyoung-Ho Lee, H. Joo, Young-Sub An, D. Joh, Hyegyoung Kim, Seung-Bok Lee, Tak-Hyoung Lim, S. Park, R. Song
In the field of food and agriculture, fuel cell-based energy supply technology is gaining much attention for sustainable food systems with carbon neutrality by 2050. Previous studies have focused on the electricity balance using polymer electrolyte fuel cells (PEMFCs) without considering the temperature quality to maintain the environmental conditions required in smart farms. However, this study proposes a system that can provide all four energy sources (electricity, cooling, heating, and CO2) required by smart farms by using solid oxide fuel cells (SOFC), which can utilize high-quality heat. To confirm the feasibility of the proposed idea, we demonstrate the world's first 10 kW-class SOFC-based integrated system for a smart farm in Jinju, South Korea. The system's core components consist of a SOFC system, a hot thermal storage system, a cold thermal storage system, and a CO2 supply system. In this study, the applicability of the proposed system is verified by the experimental results of the effective production of cold and hot heat required by smart farms. In addition, the technical problems encountered during the demonstration are presented. In doing so, we suggest the direction of more economical and sustainable SOFC technology development for smart farm applications.
在粮食和农业领域,基于燃料电池的能源供应技术正受到越来越多的关注,以实现到2050年实现碳中和的可持续粮食系统。以前的研究主要集中在使用聚合物电解质燃料电池(pemfc)的电力平衡上,而没有考虑温度质量来维持智能农场所需的环境条件。然而,这项研究提出了一种系统,可以通过使用固体氧化物燃料电池(SOFC)提供智能农场所需的所有四种能源(电力、冷却、加热和二氧化碳),这种电池可以利用高质量的热量。为了证实所提出想法的可行性,我们在韩国晋州的一个智能农场展示了世界上第一个10千瓦级的基于sofc的集成系统。该系统的核心部件包括SOFC系统、热储热系统、冷储热系统和二氧化碳供应系统。在本研究中,通过智能农场所需的冷热有效生产的实验结果验证了所提出系统的适用性。此外,还介绍了在演示过程中遇到的技术问题。在此基础上,我们提出了智能农场应用中更经济和可持续的SOFC技术发展方向。
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引用次数: 0
Recent progress in chalcogenide perovskites: toward low-temperature solution processing 硫系钙钛矿的研究进展:低温溶液处理
Pub Date : 2023-03-31 DOI: 10.31613/ceramist.2023.26.1.02
Jaewook Lee, Wooseok Yang
Chalcogenide perovskites, ABX3 crystal structure with X=S, Se or Te, are emerging light absorber as an alternative to toxic and unstable halide perovskites. Despite their promising properties, the absence of low-temperature solution processing poses a major obstacle for chalcogenide perovskite-based optoelectronic devices. In this review, we survey various synthetic techniques for chalcogenide perovskites, focusing on BaZrS3 composition. Research progress in non-solution processing methods, such as solid-state reaction and pulsed laser deposition, is briefly covered and recent reports about low-temperature solution processing for chalcogenide perovskite are highlighted. Future research perspective toward realizing chalcogenide-based optoelectronic device based on solution processing is provided. We believe this timely review will facilitate the discovery of novel solution processing for chalcogenide perovskites, the challenging materials with tantalizing prospects.
硫系钙钛矿具有X=S, Se或Te的ABX3晶体结构,是一种新兴的光吸收剂,可替代毒性和不稳定的卤化物钙钛矿。尽管它们具有很好的性能,但缺乏低温溶液处理对基于硫系钙钛矿的光电器件构成了主要障碍。本文综述了硫系钙钛矿的合成方法,重点介绍了BaZrS3的合成方法。简要介绍了固相反应和脉冲激光沉积等非固相处理方法的研究进展,重点介绍了硫系钙钛矿低温固相处理的最新报道。提出了基于溶液处理技术实现硫族化合物基光电器件的未来研究方向。我们相信这一及时的回顾将有助于发现新的硫系钙钛矿溶液处理方法,这是一种具有诱人前景的具有挑战性的材料。
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引用次数: 0
The Potential of ferroelectric HfO2 for Next-Generation Memory Device: Ferroelectric Properties and Applications 铁电HfO2在下一代存储器件中的潜力:铁电性质和应用
Pub Date : 2023-03-31 DOI: 10.31613/ceramist.2023.26.1.09
Myeong Seop Song, S. Chae
The discovery of the ferroelectricity of HfO2 in 2011 has opened up new avenues for the application of ferroelectric technology. With the stability of ferroelectricity in a few nm scales, HfO2 has become a valuable material for the development of next-generation electronic memory devices. The unique structure of HfO2 gives rise to various ferroelectric properties and behaviors that can be utilized in different types of devices such as ferroelectric field effect transistors (FeFETs), negative capacitance field effect transistors (NCFETs), ferroelectric tunnel junctions (FTJs), and ferroelectric capacitors (FeCAPs). In this review, we explore the potential of HfO2 for the high-density storage of data and low-energy consumption in next-generation devices. We demonstrate the operating principles and strengths of HfO2 in various device applications, shedding light on how this material can help address the electronics industry's current challenges.
2011年HfO2铁电性的发现为铁电技术的应用开辟了新的途径。HfO2在纳米尺度上具有稳定的铁电性,已成为开发下一代电子存储器件的重要材料。HfO2的独特结构产生了各种铁电性质和行为,可用于不同类型的器件,如铁电场效应晶体管(fefet)、负电容场效应晶体管(ncfet)、铁电隧道结(FTJs)和铁电电容器(fecap)。在这篇综述中,我们探讨了HfO2在下一代设备中高密度存储数据和低能耗的潜力。我们展示了HfO2在各种设备应用中的工作原理和优势,揭示了这种材料如何帮助解决电子行业当前的挑战。
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引用次数: 0
Nonvolatile Control of Metal-Insulator Transition in VO2 and Its Applications VO2中金属-绝缘子过渡的非易失性控制及其应用
Pub Date : 2023-03-31 DOI: 10.31613/ceramist.2023.26.1.01
Hyeongyu Gim, Kootak Hong
With the advent of the 4th industrial revolution era, there has been a high demand for high-performance electronic devices capable of collecting, storing, and calculating vast amounts of data. Vanadium dioxide (VO2) is considered an attractive candidate for next-generation electronic devices as a prototypical strongly correlated material exhibiting a metal-insulator transition (MIT) accompanied by huge electrical resistivity changes in a few nanoseconds. The nonvolatile control of the MIT in VO2 has recently been the subject of intensive research. In this report, we review recent advancements in the field of nonvolatile control of MIT in VO2, using electrochemical redox reactions, inverse piezoelectric effect, and ferroelectric polarization, and their potential to develop high-performance next-generation electronic devices.
随着第四次工业革命时代的到来,人们对能够收集、存储和计算大量数据的高性能电子设备的需求很高。作为一种典型的强相关材料,二氧化钒(VO2)被认为是下一代电子器件的一个有吸引力的候选者,它表现出金属-绝缘体转变(MIT),伴随着几纳秒内巨大的电阻率变化。VO2中MIT的非易失性控制是近年来研究的热点。在本报告中,我们回顾了近年来在电化学氧化还原反应、逆压电效应和铁电极化等方面的研究进展,以及它们在开发高性能下一代电子器件方面的潜力。
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引用次数: 0
Recent Advances and Trends in Metal Oxide-based Semiconductor Gas Sensors 金属氧化物基半导体气体传感器的最新进展和趋势
Pub Date : 2023-03-31 DOI: 10.31613/ceramist.2023.26.1.03
Sunho Lee, K. Kwon
With rapid industrial development, a large amount of waste gases has been produced, causing severe industrial disasters and human health problems. In order to avoid gas-related accidents and prevent potential health issues, the detection and monitoring of hazardous gases is essential. In order to effectively detect harmful gases, semiconductor gas sensors have gained increasing attention due to their high sensitivity, small size, cost-effectiveness and ease of manufacturing. This article reviews metal oxide-based semiconductor gas sensors. Firstly, features of metal oxide-based semiconductor gas sensors including major advantages and limitations are discussed. Then, the operating mechanism of semiconductor gas sensors are discussed with a list of widely studied metal oxides. Finally, the semiconductor gas sensors made of four different metal oxides – i) tin oxide (SnO2), ii) indium oxide (In2O3), iii) zinc oxide (ZnO), and iv) tungsten trioxide (WO3) – are discussed from the aspects of current challenges, recent research strategies and future perspectives.
随着工业的快速发展,产生了大量的废气,造成了严重的工业灾害和人体健康问题。为了避免与气体有关的事故和防止潜在的健康问题,检测和监测有害气体至关重要。为了有效地检测有害气体,半导体气体传感器因其灵敏度高、体积小、成本效益高、易于制造等优点而受到越来越多的关注。本文综述了基于金属氧化物的半导体气体传感器。首先,讨论了金属氧化物半导体气体传感器的特点,主要优点和局限性。然后,讨论了半导体气体传感器的工作机理,并列举了一系列广泛研究的金属氧化物。最后,从当前面临的挑战、近期的研究策略和未来的展望等方面讨论了由四种不同金属氧化物(i)氧化锡(SnO2)、ii)氧化铟(In2O3)、iii)氧化锌(ZnO)和iv)三氧化钨(WO3)制成的半导体气体传感器。
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引用次数: 0
Advances in developing protonic ceramic cells 质子陶瓷电池的研究进展
Pub Date : 2023-03-31 DOI: 10.31613/ceramist.2023.26.1.04
Donguk Kim, Tae-kyeong Lee, Seungwoo Han, Mingi Choi, Wonyoung Lee
Protonic ceramic cells (PCCs) are environmentally friendly energy conversion devices that operate in the intermediate temperatures due to their high ionic conductivity. This can resolve the drawbacks of solid oxide cells, such as thermochemical, physical, and thermal degradation caused by high operating temperatures. To effectively utilize PCCs as a next generation energy source, the development and optimization of PCC electrolyte materials and manufacturing process of electrochemical device are essential. This review summarizes the current progress, approaches, and challenges of PCCs and offers guidance on material design and manufacturing processes to overcome these difficulties.
质子陶瓷电池(PCCs)是一种环保的能量转换装置,由于其高离子电导率,可以在中等温度下工作。这可以解决固体氧化物电池的缺点,如高温引起的热化学、物理和热降解。为了有效地利用PCC作为下一代能源,PCC电解质材料的开发和优化以及电化学装置的制造工艺至关重要。本文总结了当前PCCs的进展、方法和挑战,并为克服这些困难的材料设计和制造工艺提供了指导。
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引用次数: 0
Recent progress of the p-type oxide thin films for transistor applications: Nickel oxide, Tin oxide, and Copper oxide 晶体管用p型氧化物薄膜的最新进展:氧化镍、氧化锡和氧化铜
Pub Date : 2023-03-31 DOI: 10.31613/ceramist.2023.26.1.06
Minki Choe, Dahui Jeon, Inhong Hwang, I. Baek
Over the past decade, many research groups have been striving to develop high-performance p-type switching oxide materials for implementing complementary metal–oxide–semiconductor (CMOS) thin film devices. However, realizing p-type oxide thin film transistors (TFTs) whose electrical properties are comparable to n-type oxide TFTs has been challenging. This is because of inherent characteristics of p-type oxide materials such as the high formation energy of native acceptors and high hole effective mass caused by localized hole transport path. Developing a p-type oxide with a delocalized hole transport pathway and low hole formation energy is crucial for the production of CMOS circuits utilizing oxide thin films. NiO, SnO, and CuOx are being actively studied as candidate materials that satisfy these requirements. This review discusses the latest advances in the synthesis method of p-type binary oxide thin films and the approach for electrical performance enhancement.
在过去的十年中,许多研究小组一直在努力开发高性能的p型开关氧化物材料,以实现互补金属氧化物半导体(CMOS)薄膜器件。然而,实现与n型氧化物薄膜晶体管电性能相当的p型氧化物薄膜晶体管(TFTs)一直是一个挑战。这是由于p型氧化物材料固有的特性,如原生受体的高形成能和局域化空穴输运路径导致的高空穴有效质量。开发具有离域空穴传输路径和低空穴形成能量的p型氧化物对于利用氧化物薄膜生产CMOS电路至关重要。NiO、SnO和CuOx作为满足这些要求的候选材料正在积极研究中。本文综述了p型二元氧化物薄膜的合成方法和电性能增强途径的最新进展。
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引用次数: 0
Synthesis and Applications of Single-Chain Atomic Crystal, LiMo3Se3 单链原子晶体LiMo3Se3的合成与应用
Pub Date : 2022-12-31 DOI: 10.31613/ceramist.2022.25.4.02
Sudong Chae
Among the currently available low-dimensional nanomaterials, single-chain atomic crystals (SCAC) exhibit unique physical and chemical properties because of their one-dimensional atomic structure. SCAC is the isolated molecular chain unit from bulk 1D chained materials, in which weak van der Waals or ionic interactions stack together SCACs with strong intra-chain bonding. They have one-dimensional fibrous morphology and sub-nanometer scale diameter similar to conventional organic polymers. Furthermore, unlike conventional organic polymers that consist only of organic elements such as C, H, N, O, and S, SCACs are composed of inorganic elements, such as transition metal, chalcogen, and halogen. Therefore, SCACs have novel additional properties, such as electrical, optical, mechanical, and electrochemical properties that conventional organic polymers do not.To investigate the properties of isolated SCAC, the preparation of bulk single crystal with high crystallinity, and strategy for exfoliation are required. In this review, the studies on synthesis, exfoliation and applications of the representative SCAC, LiMo3Se3 are described. These results demonstrate that solution processed SCACs are promising building block for future application.
在现有的低维纳米材料中,单链原子晶体(SCAC)由于其一维的原子结构而表现出独特的物理和化学性质。SCAC是从块状1D链材料中分离出来的分子链单元,其中弱范德华或离子相互作用将具有强链内键的SCAC堆叠在一起。它们具有一维纤维形态和与传统有机聚合物相似的亚纳米尺度直径。此外,与仅由C、H、N、O和S等有机元素组成的传统有机聚合物不同,SCACs由无机元素组成,如过渡金属、硫和卤素。因此,SCACs具有传统有机聚合物所不具备的新的附加性能,如电学、光学、机械和电化学性能。为了研究分离的SCAC的性能,需要制备高结晶度的大块单晶和剥离策略。本文综述了具有代表性的SCAC LiMo3Se3的合成、剥离及应用研究进展。这些结果表明,溶液处理的scac是未来应用的有希望的构建块。
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引用次数: 0
Recent Progress in Development of Artificial Neuromorphic Devices Based on Emerging Materials 基于新兴材料的人工神经形态装置研究进展
Pub Date : 2022-12-31 DOI: 10.31613/ceramist.2022.25.4.08
Y. Jo, Dae Kyu Lee, J. Y. Kwak
In the fourth industrial revolution, the efficient processing of huge amounts of data is important due to the development of artificial intelligence (AI), internet of things (IoT), and machine learning (ML). The conventional computing system, which is known as von Neumann architecture, has been facing bottleneck problems because of the physical separation of memory and central processing unit (CPU). Many researchers have interested to study on neuromorphic computing, inspired by the human brain, to solve the bottleneck problems. The development of artificial neuromorphic devices, such as neuron and synaptic devices, is important to successfully demonstrate a neuromorphic computing hardware. Various Si CMOS transistor-based circuits have been investigated to implement the behaviors of the biological neuron and synapse; however, they are not suitable for mimicking the large-scale biological neural networks because of Si CMOS transistor’s scalability and power consumption issues. In this report, we review the recent research progress in artificial neurons and synaptic devices based on emerging materials and discuss the future research direction of artificial neural networks.
在第四次工业革命中,由于人工智能(AI)、物联网(IoT)和机器学习(ML)的发展,对大量数据的有效处理变得非常重要。由于存储器和中央处理器(CPU)的物理分离,被称为冯·诺依曼架构的传统计算系统一直面临瓶颈问题。受人脑的启发,许多研究者对神经形态计算的研究感兴趣,以解决瓶颈问题。人工神经形态装置,如神经元和突触装置的发展,是成功展示神经形态计算硬件的重要手段。各种基于硅CMOS晶体管的电路已经被研究来实现生物神经元和突触的行为;然而,由于硅CMOS晶体管的可扩展性和功耗问题,它们不适合模拟大规模的生物神经网络。本文综述了近年来基于新兴材料的人工神经元和突触装置的研究进展,并讨论了人工神经网络未来的研究方向。
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引用次数: 0
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