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“Generation III” Piezoelectric Single Crystals Developed by Solid-State Single Crystal Growth Method 采用固态单晶生长法研制“第三代”压电单晶
Pub Date : 2021-09-30 DOI: 10.31613/ceramist.2021.24.3.07
Ho-yong Lee
Crystallographically engineered Relaxor-PT single crystals, specifically PMN-PT (Generation I) and PIN-PMN-PT/PMN-PZT (Generation II), offer much higher piezoelectric and electromechanical coupling coefficients (d33>1,500 pC/N, k33>0.9), when compared to polycrystalline PZT-5H ceramics (d33>600 pC/N, k33>0.75). Recently Ceracomp Co., Ltd. (www.ceracomp.com) has developed the solid-state single crystal growth (SSCG) technique and successfully fabricated Gen III PMN-PZT single crystals modified with acceptors or donors. The piezoelectric constants (d33) of (001) Gen III PMN-PZT single crystals were measured to be higher than 4,000 pC/N and thus about two times higher than those of PMN-PT/PZN-PT (Gen I) and PIN-PMN-PT/PMN-PZT (Gen II) single crystals. The Gen III PMN-PZT single crystals have been firstly applied to single crystal-epoxy composites, ultrasonic transducers, piezoelectric sensors, and piezoelectric actuators. In this paper we introduce the development of Gen III PMN-PZT single crystals, piezoelectric composites and multilayer single crystal actuators.
晶体学工程的Relaxor-PT单晶,特别是PMN-PT(第一代)和PIN-PMN-PT/PMN-PZT(第二代),与PZT-5H多晶陶瓷(d33>600 pC/N, k33>0.75)相比,具有更高的压电和机电耦合系数(d33> 1500 pC/N, k33>0.9)。最近,Ceracomp有限公司(www.ceracomp.com)开发了固态单晶生长(SSCG)技术,并成功制备了用受体或供体修饰的第三代PMN-PZT单晶。(001) III代PMN-PZT单晶的压电常数(d33)高于4000 pC/N,比PMN-PT/PZN-PT (Gen I)和PIN-PMN-PT/PMN-PZT (Gen II)单晶的压电常数(d33)高出约2倍。第三代PMN-PZT单晶已首次应用于单晶环氧复合材料、超声波换能器、压电传感器和压电致动器。本文介绍了第三代PMN-PZT单晶、压电复合材料和多层单晶作动器的研究进展。
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引用次数: 2
Review of Single-Phase Magnetoelectric Multiferroic Thin Film and Process 单相磁电多铁薄膜及其工艺研究进展
Pub Date : 2021-09-30 DOI: 10.31613/ceramist.2021.24.3.01
H. Yeo
Advance in the growth and characterization of multiferroic thin film promises new device application such as next generation memory, nanoelectronics and energy harvesting. In this review, we provide a brief overview of recent progress in the growth, characterization and understanding of thin-film multiferroics. Driven by the development of thin film growth techniques, the ability to produce high quality multiferroic thin films offers researchers access to new phase and understanding of these materials. We discuss that epitaxial strain and atomic-level engineering of chemistry determine the muliferroic thin film properties. We then discuss the new structures and properties of non-equilibrium phases which is stabilized by strain engineering.
多铁性薄膜的生长和表征的进展为下一代存储器、纳米电子学和能量收集等新的器件应用提供了希望。在这篇综述中,我们简要概述了近年来在薄膜多铁性材料的生长、表征和理解方面的进展。在薄膜生长技术发展的推动下,生产高质量多铁薄膜的能力为研究人员提供了新的阶段和对这些材料的理解。讨论了外延应变和原子水平的化学工程决定了多态薄膜的性能。然后讨论了通过应变工程稳定的非平衡相的新结构和性质。
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引用次数: 0
Giant Grain Growth in (K,Na)NbO3 Ceramics (K,Na)NbO3陶瓷的巨型晶粒生长
Pub Date : 2021-09-30 DOI: 10.31613/ceramist.2021.24.3.08
S. Park, J. W. Lee, K. Cho, Y. Min, C. Ahn
In this manuscript, an interesting phenomenon is reported. It has been reported that the growth of single crystals is observed in donor-doped (K,Na)NbO3 (KNN)-based ceramics. It is very interesting that the growth happens without the addition of a seed. The growth of huge grains (single crystal, approximately 30 mm,) occurs due to the abnormal grain growth (AGG) in KNN-based ceramics. In the AGG compositions, moreover, the seed plates can be synthesized by not topochemical reaction but simple molten salt synthesis (SMSS) which is a simple-and-cheap process. They can be a good candidate for the seeds at reactive templated grain growth (RTGG) or templated grain growth (TGG) process.
在这份手稿中,报告了一个有趣的现象。有报道称,在给体掺杂(K,Na)NbO3 (KNN)基陶瓷中观察到单晶的生长。非常有趣的是,这种生长不需要添加种子。在knn基陶瓷中,由于晶粒生长异常(AGG),产生了巨大的晶粒(单晶,约30 mm)。此外,在AGG组合物中,种子板可以通过简单熔盐合成(SMSS)而不是拓扑化学反应来合成,这是一种简单而廉价的方法。它们可以作为活性模板粒生长(RTGG)或模板粒生长(TGG)过程中的种子候选材料。
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引用次数: 0
Ultrasound Mediated Wireless Power Transfer Technology 超声介导无线电力传输技术
Pub Date : 2021-09-30 DOI: 10.31613/ceramist.2021.24.3.05
Sunghoon Hur, Hyun Soo Kim, H. Song
Wireless energy transfer (WET) is the transmission of electric power without any physical connections such as wires. Currently, inductive coupling mediated by electromagnetic (EM) waves is the most common method of WET and is widely used to charge portable devices such as smartphones, Bluetooth earphones, electric shavers, and visual prostheses. However, its application is still limited due to a number of issues including low efficiency, short charging distance, heating problem, and limited choice of transmission medium. Due to these issues, EM-based WET cannot be applied to implantable medical devices, marine cable operation sensors, and electronic devices with electromagnetic interference shielding. Recently, as an alternative to EM-based WET, acoustic energy transfer mediated by sound waves becomes more attractive. Ultrasound offers advantages for transmission in dense media such as liquids or solids and is regardless of electromagnetic shielding. In this review, we investigate recent progress in acoustic power transfer technology in terms of acoustic energy conversion mechanism and provide the future research direction of acoustic power transfer technology.
无线能量传输(WET)是在没有任何物理连接(如电线)的情况下传输电能的技术。目前,以电磁波为媒介的感应耦合是最常见的湿法充电方式,被广泛用于智能手机、蓝牙耳机、电动剃须刀和视觉假体等便携式设备的充电。然而,由于效率低、充电距离短、发热问题、传输介质选择有限等问题,其应用仍然受到限制。由于这些问题,基于em的WET不能应用于植入式医疗设备、海洋电缆操作传感器和具有电磁干扰屏蔽的电子设备。近年来,以声波为媒介的声能传递作为一种替代电磁湿法的方法变得越来越有吸引力。超声波在液体或固体等致密介质中传输具有优势,并且不受电磁屏蔽的影响。本文从声能转换机理方面综述了声能传递技术的最新进展,并提出了声能传递技术未来的研究方向。
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引用次数: 0
Recent Reports of Magneto-Mechano-Electric Conversion Composites 磁-力-电转换复合材料研究进展
Pub Date : 2021-09-30 DOI: 10.31613/ceramist.2021.24.3.02
Geon‐Tae Hwang, J. Ryu, W. Yoon
Magneto-mechano-electric (MME) conversion composites composed of distinctive magnetostrictive and piezoelectric materials derive interfacial coupling of magnetoelectric conversion between magnetic and electric properties, thus enabling energy harvesting and magnetic sensing. To demonstrate high-performance MME composites and their applications, various research teams have studied tailoring device structures, enhancing material properties, and developing MME application system. This article reviews the recent research progress of MME composites for energy harvesting and magnetic sensing.
磁机电转换复合材料由独特的磁致伸缩和压电材料组成,在磁性和电性之间产生磁电转换的界面耦合,从而实现能量收集和磁传感。为了展示高性能MME复合材料及其应用,各个研究团队研究了定制器件结构,增强材料性能以及开发MME应用系统。本文综述了近年来用于能量收集和磁传感的MME复合材料的研究进展。
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引用次数: 0
Progress in the Development of Single-Phase Magnetoelectric Multiferroic Oxides 单相磁电多铁氧化物的研究进展
Pub Date : 2021-09-30 DOI: 10.31613/ceramist.2021.24.3.03
Jae-Hyeon Cho, W. Jo
Magnetoelectric (ME) multiferroics manifesting the coexistence and the coupling of ferromagnetic and ferroelectric order are appealing widespread interest owing to their fascinating physical behaviors and possible novel applications. In this review, we highlight the progress in single-phase ME multiferroic oxides research in terms of the classification depending on the physical origins of ferroic properties and the corresponding examples for each case, i.e., material by material, along with their ME multiferroic properties including saturation magnetization, spontaneous polarization, (anti)ferromagnetic/ferroelectric transition temperature, and ME coefficient. The magnetoelectrically-active applications of high expectancy are presented by citing the representative examples such as magnetoelectric random-access-memory and multiferroic photovoltaics. Furthermore, we discuss how the development of ME multiferroic oxides should proceed by considering the current research status in terms of developed materials and designed applications. We believe that this short review will provide a basic introduction for the researchers new to this field.
磁电多铁体表现出铁磁性和铁电序的共存和耦合,由于其令人着迷的物理行为和可能的新应用而引起了广泛的兴趣。在本文中,我们重点介绍了单相ME多铁氧化物的研究进展,根据铁性质的物理来源进行分类,并针对每种情况给出相应的例子,即按材料分类,以及它们的ME多铁性质,包括饱和磁化、自发极化、(反)铁磁/铁电转变温度和ME系数。以磁电随机存取存储器和多铁性光伏为例,介绍了具有较高期望的磁电主动应用。此外,我们从材料开发和应用设计两方面考虑了目前的研究现状,讨论了ME多铁氧化物的发展方向。我们相信这篇简短的综述将为新进入该领域的研究人员提供一个基本的介绍。
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引用次数: 1
A Brief Review of CoSb3-based Thermoelectric Materials and Modules for Mid-Temperature Power Generation 中温发电用cosb3基热电材料及模块研究进展
Pub Date : 2021-06-30 DOI: 10.31613/ceramist.2021.24.2.06
W. Nam, J. Cho
s To solve the global energy problems, investigating renewable and environmentally friendly energy resources has considerable significance. Thermoelectric materials and modules have gained considerable attention because they can directly convert waste heat into electric power while leaving no environmental pollution. The performance of the thermoelectric materials can be determined using the dimensionless figure of merit, ZT. However, trade-off relationships between the thermoelectric parameters (electrical conductivity, Seebeck coefficient, and thermal conductivity) have hindered significant improvement of ZT over the decades. Therefore, independent control of the charge and phonon transports is of great importance. In this respect, CoSb3–based skutterudites showing PGEC (phonon-glass electron-crystal) properties are considered to be promising thermoelectric materials for mid-temperature power generation. In this paper, we review the current status of research in the fields of CoSb3-based thermoelectric materials and modularization techniques.
研究可再生能源和环境友好型能源对解决全球能源问题具有重要意义。热电材料和热电模块由于能够将废热直接转化为电能而不造成环境污染而备受关注。热电材料的性能可以用无因次优值ZT来确定。然而,几十年来,热电参数(电导率、塞贝克系数和导热系数)之间的权衡关系阻碍了ZT的显著改善。因此,独立控制电荷和声子输运是非常重要的。在这方面,具有PGEC(声子-玻璃电子-晶体)特性的cosb3基滑石被认为是有前途的中温发电热电材料。本文综述了cosb3基热电材料及其模块化技术的研究现状。
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引用次数: 1
Recent Development of Transition Metal Oxide Based Aqueous Supercapacitor Electrode Materials 过渡金属氧化物基水性超级电容器电极材料的研究进展
Pub Date : 2021-06-30 DOI: 10.31613/ceramist.2021.24.2.03
J. Lim, Hye-jung Cho, Yonghan Jung, J. Roh, W. Shin
s With the development of electric devices such as smart phones or electric vehicles, energy storage systems with high energy/power density and stable operation need to be developed together. The supercapacitors using aqueous electrolyte have great potential for electrochemical energy storage system due to their high power densities and long cyclic performances. The state-of-the-art materials for supercapacitors are carbon based porous materials having high specific surface areas and electrical conductivities. However, they have relatively low energy density that still need to enhance specific capacitance by using the nanostructure of transition metal oxide (TMO) materials. The TMOs store charge through redox reactions like battery systems and their rates are comparable to those of conventional electrochemical double-layer capacitors. In this review, we describe the fundamental principle of TMO based supercapacitors and the recent progress for realizing high performance of TMO based supercapacitors. In addition, we categorize the TMO system as single cation and mixed cations and suggest the prospects for electrochemical energy storage fields.
随着智能手机、电动汽车等电动设备的发展,需要共同开发高能量/功率密度、运行稳定的储能系统。基于水电解质的超级电容器具有高功率密度和长循环性能,在电化学储能系统中具有很大的应用潜力。最先进的超级电容器材料是具有高比表面积和导电性的碳基多孔材料。然而,它们的能量密度相对较低,仍然需要利用过渡金属氧化物(TMO)材料的纳米结构来提高比电容。TMOs像电池系统一样通过氧化还原反应储存电荷,其速率与传统的电化学双层电容器相当。本文综述了基于TMO的超级电容器的基本原理以及实现高性能TMO超级电容器的最新进展。此外,我们将TMO体系分为单阳离子和混合阳离子两类,并展望了电化学储能领域的发展前景。
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引用次数: 2
Templated Grain Growth for High-Performance Lead-Free Piezoceramics 高性能无铅压电陶瓷的模板化晶粒生长
Pub Date : 2021-06-30 DOI: 10.31613/ceramist.2021.24.2.02
Seo-jeong Park, C. Ahn, J. W. Lee, Y. Min
s As a new class of novel technologies for fabrication of piezoceramics, the templated grain growth (TGG) has been gaining tremendous attention due to the ability to align ferroelectric domains and thus improve piezoelectric properties, which are similar with the ones of single crystal. Towards the realization of textured grains in a specific direction, two-dimensional template materials should be preferentially needed with some specific conditions such as small lattice mismatch, similar crystal structure and composition compared to those of matrix piezoelectric ceramic powders. This mini review presents recent progress on TGG to provide highperformance textured (K,Na)NbO3 ceramics as an ideal lead-free to lead-based piezoceramics with a focus on the fabrication fundamentals and underlying mechanism. Additionally, some parameters related to the fabrication of green body during a tape casting are surveyed. Finally, we provide an insight into challenges and future directions in the TGG-based piezoceramics.
作为一类新型的压电陶瓷制造技术,模板化晶粒生长(TGG)由于能够排列铁电畴,从而提高与单晶相似的压电性能而受到广泛关注。为了实现特定方向的织构颗粒,需要优先使用二维模板材料,并具有晶格错配小、晶体结构和成分与基体压电陶瓷粉末相似等特定条件。本文简要介绍了TGG的最新进展,以提供高性能织构(K,Na)NbO3陶瓷作为一种理想的无铅到铅基压电陶瓷,重点介绍了制备基础和潜在的机制。此外,还对带式铸造过程中坯体制造的有关参数进行了探讨。最后,我们提出了基于tg的压电陶瓷面临的挑战和未来的发展方向。
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引用次数: 0
A Mini-Review on Blue Light-Emitting Diodes Based on Metal-Halide Perovskite Nanocrystals 金属卤化物钙钛矿纳米晶体蓝色发光二极管研究进展
Pub Date : 2021-06-30 DOI: 10.31613/ceramist.2021.24.2.07
Sungchul Baek
s Metal-halide perovskite nanocrystals have attracted great scientific attention in the field of light-emitting diode (LED) due to their excellent optical and electrical properties such as narrow emission linewidth, photoluminescence quantum yield approaching unity, high charge carrier mobility, and halogen anion composition-dependent tunable bandgap. Over the last few years, considerable progress has been achieved on red and green perovskite LEDs (external quantum efficiencies exceeding 20%), however, the performance of blue LEDs still lags far behind that of red and green counterparts. In this review, overall background of perovskite nanocrystal and research progress of perovskite nanocrystal-based blue LEDs are summarized.
金属卤化物钙钛矿纳米晶体具有发射线宽窄、光致发光量子产率接近统一、载流子迁移率高、卤素阴离子组成可调带隙等优异的光学和电学性能,在发光二极管(LED)领域受到广泛关注。在过去的几年里,红色和绿色钙钛矿led取得了相当大的进展(外部量子效率超过20%),然而,蓝色led的性能仍然远远落后于红色和绿色led。本文综述了钙钛矿纳米晶的研究背景和钙钛矿纳米晶蓝光led的研究进展。
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引用次数: 1
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