Pub Date : 2023-06-09DOI: 10.3390/chemengineering7030054
A. Koizhanova, B. Kenzhaliyev, D. Magomedov, E. Kamalov, Mariya Yerdenova, A. Bakrayeva, N. Abdyldayev
This paper provides an overview of hydrometallurgical copper extraction studies in which liquid extraction technology has been used with four copper deposits of different compositions. The sulfuric acid consumption rate and copper extraction efficiency, which are dependent on the initial content and forms of calcium compounds and other impurities in ore samples, were calculated, and the results are presented herein. It was established that during the leaching process, silicate compounds of alkaline earth metals, in addition to calcium and magnesium carbonate compounds, would affect the levels of sulfuric acid consumption, thereby actively lowering the acidity of the environment. Moreover, these compounds could partially sorb copper ions from sulfuric acid leaching solutions. Thus, the analysis of waste ore samples showed that residual copper is mainly contained in the form of complex silicate complexes. The presence of divalent iron compounds in the composition from one of the deposits also allowed us to perform a biochemical leaching experiment with preliminary oxidation using an Acidithiobacillus ferrooxidans bacterial culture adapted to the ore composition. The use of this biochemical method in the copper leaching process resulted in a significant reduction in sulfuric acid consumption, by 40%, and a copper recovery rate of 87.2%.
{"title":"Study of Factors Affecting the Copper Ore Leaching Process","authors":"A. Koizhanova, B. Kenzhaliyev, D. Magomedov, E. Kamalov, Mariya Yerdenova, A. Bakrayeva, N. Abdyldayev","doi":"10.3390/chemengineering7030054","DOIUrl":"https://doi.org/10.3390/chemengineering7030054","url":null,"abstract":"This paper provides an overview of hydrometallurgical copper extraction studies in which liquid extraction technology has been used with four copper deposits of different compositions. The sulfuric acid consumption rate and copper extraction efficiency, which are dependent on the initial content and forms of calcium compounds and other impurities in ore samples, were calculated, and the results are presented herein. It was established that during the leaching process, silicate compounds of alkaline earth metals, in addition to calcium and magnesium carbonate compounds, would affect the levels of sulfuric acid consumption, thereby actively lowering the acidity of the environment. Moreover, these compounds could partially sorb copper ions from sulfuric acid leaching solutions. Thus, the analysis of waste ore samples showed that residual copper is mainly contained in the form of complex silicate complexes. The presence of divalent iron compounds in the composition from one of the deposits also allowed us to perform a biochemical leaching experiment with preliminary oxidation using an Acidithiobacillus ferrooxidans bacterial culture adapted to the ore composition. The use of this biochemical method in the copper leaching process resulted in a significant reduction in sulfuric acid consumption, by 40%, and a copper recovery rate of 87.2%.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":" ","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-06-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48017434","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-06-02DOI: 10.3390/chemengineering7030053
C. Camacho, H. Álvarez, Jorge Espín, Oscar Camacho
This paper presents a dynamic sliding mode control (DSMC) for open-loop unstable chemical or biochemical processes with a time delay. The controller is based on the sliding mode and internal model control concepts. The proposed DSMC has an internal P/PD controller to provide systems with disturbance rejection. An identification method approximates the open-loop unstable nonlinear process to a first-order delayed unstable process (FODUP). The reduced-order model(FODUP) is used to synthesize the new controller. The performance of the controller is stable and satisfactory despite nonlinearities in the operating conditions due to set-point and process disturbance changes. In addition, the performance analysis of the control schemes was evaluated based on various indices and transient characteristics, including the integral of squared error (ISE), the total variation of control effort (TVu), the maximum overshoot (Mp), and the settling time (ts). Finally, the process output and the control action for all controllers are compared using the nonlinear process as the real plant.
{"title":"An Internal Model Based—Sliding Mode Control for Open-Loop Unstable Chemical Processes with Time Delay","authors":"C. Camacho, H. Álvarez, Jorge Espín, Oscar Camacho","doi":"10.3390/chemengineering7030053","DOIUrl":"https://doi.org/10.3390/chemengineering7030053","url":null,"abstract":"This paper presents a dynamic sliding mode control (DSMC) for open-loop unstable chemical or biochemical processes with a time delay. The controller is based on the sliding mode and internal model control concepts. The proposed DSMC has an internal P/PD controller to provide systems with disturbance rejection. An identification method approximates the open-loop unstable nonlinear process to a first-order delayed unstable process (FODUP). The reduced-order model(FODUP) is used to synthesize the new controller. The performance of the controller is stable and satisfactory despite nonlinearities in the operating conditions due to set-point and process disturbance changes. In addition, the performance analysis of the control schemes was evaluated based on various indices and transient characteristics, including the integral of squared error (ISE), the total variation of control effort (TVu), the maximum overshoot (Mp), and the settling time (ts). Finally, the process output and the control action for all controllers are compared using the nonlinear process as the real plant.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":" ","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46104487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-06-01DOI: 10.3390/chemengineering7030051
D. Matykiewicz, T. Olszewski, J. Andrzejewski
The aim of the work was to assess the possibility of utilizing the waste generated in the injection molding process for the production of new products based on polyamide 6 reinforced with glass fiber. The manufactured samples were prepared with the addition of 5, 10, 15, and 100 wt.% regrind from the runner system. The impact strength, tensile strength, and hardness of injection products were obtained directly and were assessed after conditioning in distilled water for 24 h. Moreover, the structure of the tested materials was assessed using the FTIR method and their thermal properties using the DSC method. The results of the tests confirm that the addition of regrind up to 15 wt.% to virgin polyamide does not adversely affect its impact strength, tensile strength, and hardness. The water-conditioned materials showed higher values of impact strength but lower values of tensile strength and Young’s modulus at a higher elongation at break. The obtained results are important due to the assumptions of the circular economy and the minimization of the amount of waste and material losses during the injection process.
{"title":"Waste Management after the Injection Process by Manufacturing Polyamide Products Based on Regranulate","authors":"D. Matykiewicz, T. Olszewski, J. Andrzejewski","doi":"10.3390/chemengineering7030051","DOIUrl":"https://doi.org/10.3390/chemengineering7030051","url":null,"abstract":"The aim of the work was to assess the possibility of utilizing the waste generated in the injection molding process for the production of new products based on polyamide 6 reinforced with glass fiber. The manufactured samples were prepared with the addition of 5, 10, 15, and 100 wt.% regrind from the runner system. The impact strength, tensile strength, and hardness of injection products were obtained directly and were assessed after conditioning in distilled water for 24 h. Moreover, the structure of the tested materials was assessed using the FTIR method and their thermal properties using the DSC method. The results of the tests confirm that the addition of regrind up to 15 wt.% to virgin polyamide does not adversely affect its impact strength, tensile strength, and hardness. The water-conditioned materials showed higher values of impact strength but lower values of tensile strength and Young’s modulus at a higher elongation at break. The obtained results are important due to the assumptions of the circular economy and the minimization of the amount of waste and material losses during the injection process.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":"14 1 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69566056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-06-01DOI: 10.3390/chemengineering7030052
Tanawit Sirijaree, Pornsawai Praipipat
Lead is a highly toxic heavy metal that creates a water pollutant. It can be released from industrial processes, agricultural chemistry, and community wastes, affecting creatures and human health even at a low concentration. As a result, it is advised that lead be removed before releasing wastewater into the environment. This study synthesized three chitosan bead materials from shrimp shell wastes which were chitosan powder beads (CB), chitosan powder mixed with goethite beads (CFB), and chitosan powder beads coated with goethite (CBF) for removing lead in an aqueous solution. Their surface area, pore volumes, and pore sizes were explored according to Brunauer– Emmett–Teller, and their crystalline formations were investigated using an X-ray diffractometer. Their surface structures were studied using field emission scanning electron microscopy and a focus ion beam, and their chemical compositions were determined using an energy dispersive X-ray spectrometer. Their chemical functional groups were identified via Fourier-transform infrared spectroscopy. In addition, batch experiments were conducted to investigate the effects of several factors on removing lead, and the adsorption isotherm and kinetics were also investigated for determining their adsorption pattern and mechanism. In addition, the desorption experiments were studied to confirm their possible material reusability. The CBF demonstrated the highest surface area and smallest pore size compared with the other materials. In addition, the pore sizes of the CFB and CBF were micropores, whereas those of the CB were mesopores. All materials were semicrystalline structures, and the specific goethite peaks were observed in the CFB and CBF. All materials had spherical shapes with heterogeneous surfaces. Six chemical components of O, C, Ca, N, Cl, and Na were discovered in all materials, and Fe was only found in the CFB and CBF because of the addition of goethite. Five main chemical functional groups of N–H, O–H, C–H, C–O, and –COOH were found in all materials. The optimum conditions of the CB, CFB, and CBF for removing lead were 0.5 g, 16 h, pH 5, 0.5 g, 16 h, pH 5, and 0.4 g, 14 h, pH 5, respectively. The results of the batch experiments demonstrated that the CB, CFB, and CBF were high-efficiency adsorbents for removing lead in solution by more than 95%, whereby the CBF showed the highest lead removal of 99%. The Freundlich isotherm model and pseudo-second-order kinetic model helped to well explain their adsorption pattern and mechanism. The maximum lead adsorption capacities of the CB, CFB, and CBF were 322.58, 333.33, and 344.83 mg/g, respectively. Furthermore, all chitosan materials can be reused for more than three cycles with high lead removal by more than 94%; so, they are potential materials for application in industrial applications.
{"title":"Adsorption of Lead (II) Ions onto Goethite Chitosan Beads: Isotherms, Kinetics, and Mechanism Studies","authors":"Tanawit Sirijaree, Pornsawai Praipipat","doi":"10.3390/chemengineering7030052","DOIUrl":"https://doi.org/10.3390/chemengineering7030052","url":null,"abstract":"Lead is a highly toxic heavy metal that creates a water pollutant. It can be released from industrial processes, agricultural chemistry, and community wastes, affecting creatures and human health even at a low concentration. As a result, it is advised that lead be removed before releasing wastewater into the environment. This study synthesized three chitosan bead materials from shrimp shell wastes which were chitosan powder beads (CB), chitosan powder mixed with goethite beads (CFB), and chitosan powder beads coated with goethite (CBF) for removing lead in an aqueous solution. Their surface area, pore volumes, and pore sizes were explored according to Brunauer– Emmett–Teller, and their crystalline formations were investigated using an X-ray diffractometer. Their surface structures were studied using field emission scanning electron microscopy and a focus ion beam, and their chemical compositions were determined using an energy dispersive X-ray spectrometer. Their chemical functional groups were identified via Fourier-transform infrared spectroscopy. In addition, batch experiments were conducted to investigate the effects of several factors on removing lead, and the adsorption isotherm and kinetics were also investigated for determining their adsorption pattern and mechanism. In addition, the desorption experiments were studied to confirm their possible material reusability. The CBF demonstrated the highest surface area and smallest pore size compared with the other materials. In addition, the pore sizes of the CFB and CBF were micropores, whereas those of the CB were mesopores. All materials were semicrystalline structures, and the specific goethite peaks were observed in the CFB and CBF. All materials had spherical shapes with heterogeneous surfaces. Six chemical components of O, C, Ca, N, Cl, and Na were discovered in all materials, and Fe was only found in the CFB and CBF because of the addition of goethite. Five main chemical functional groups of N–H, O–H, C–H, C–O, and –COOH were found in all materials. The optimum conditions of the CB, CFB, and CBF for removing lead were 0.5 g, 16 h, pH 5, 0.5 g, 16 h, pH 5, and 0.4 g, 14 h, pH 5, respectively. The results of the batch experiments demonstrated that the CB, CFB, and CBF were high-efficiency adsorbents for removing lead in solution by more than 95%, whereby the CBF showed the highest lead removal of 99%. The Freundlich isotherm model and pseudo-second-order kinetic model helped to well explain their adsorption pattern and mechanism. The maximum lead adsorption capacities of the CB, CFB, and CBF were 322.58, 333.33, and 344.83 mg/g, respectively. Furthermore, all chitosan materials can be reused for more than three cycles with high lead removal by more than 94%; so, they are potential materials for application in industrial applications.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":" ","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46547885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-28DOI: 10.3390/chemengineering7030050
P. Rex, K. Rahiman, M. Ismail, N. Meenakshisundaram, Praveen Barmavatu, S. L. S. Bharadwaj
Biochar has gained attention as an alternative source of solid energy and for the proper disposal of agricultural biomass waste (ABW). Microwave-assisted pyrolysis (MAP) is a promising approach for the production of biochar. This review article presents the beneficial use of biochar for soil fertilization, machine learning (ML), the circular bioeconomy, and the technology readiness level. The use of machine learning techniques helps to design, predict, and optimize the process. It can also improve the accuracy and efficacy of the biochar production process, thereby reducing costs. Furthermore, the use of biochar as a soil amendment can be an attractive option for farmers. The incorporation of biochar into soil has been shown to improve soil fertility, water retention, and crop productivity. This can lead to reduced dependence on synthetic fertilizers and increased agricultural yields. The development of a biochar economy has the potential to create new job opportunities and increase the national gross domestic product (GDP). Small-scale enterprises can play a significant role in the production and distribution of biochar, providing value-added products and helping to promote sustainable agriculture.
{"title":"Agricultural Biomass Waste to Biochar: A Review on Biochar Applications Using Machine Learning Approach and Circular Economy","authors":"P. Rex, K. Rahiman, M. Ismail, N. Meenakshisundaram, Praveen Barmavatu, S. L. S. Bharadwaj","doi":"10.3390/chemengineering7030050","DOIUrl":"https://doi.org/10.3390/chemengineering7030050","url":null,"abstract":"Biochar has gained attention as an alternative source of solid energy and for the proper disposal of agricultural biomass waste (ABW). Microwave-assisted pyrolysis (MAP) is a promising approach for the production of biochar. This review article presents the beneficial use of biochar for soil fertilization, machine learning (ML), the circular bioeconomy, and the technology readiness level. The use of machine learning techniques helps to design, predict, and optimize the process. It can also improve the accuracy and efficacy of the biochar production process, thereby reducing costs. Furthermore, the use of biochar as a soil amendment can be an attractive option for farmers. The incorporation of biochar into soil has been shown to improve soil fertility, water retention, and crop productivity. This can lead to reduced dependence on synthetic fertilizers and increased agricultural yields. The development of a biochar economy has the potential to create new job opportunities and increase the national gross domestic product (GDP). Small-scale enterprises can play a significant role in the production and distribution of biochar, providing value-added products and helping to promote sustainable agriculture.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":" ","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49130377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-22DOI: 10.3390/chemengineering7030049
Reynaldo J. Silva-Paz, Dante K. Mateo-Mendoza, Amparo Eccoña-Sota
In Peru, there are more than four thousand plants with medicinal properties, including muña, which helps digestion and improves health. The way to preserve these plants is drying up. The objective of this research was to investigate the coefficient of diffusion, enthalpy, and Gibbs free energy in the drying kinetics of muña leaves. Different pretreatments were carried out on the samples (without pretreatment, as well as treated by immersion in 1% ascorbic acid and bleaching at 60 °C for 30 s), and they were dehydrated at three temperatures (40, 50, and 60 °C). The drying kinetics were modeled using eight mathematical models to represent the drying curve. The water content was reduced by the drying process. The logarithmic model was selected, as it showed the best fit to represent the drying kinetics of the muña. Activation energy values were similar between treatments (p > 0.05). The increase in temperature decreases the enthalpy and entropy and increases the Gibbs free energy with the effective diffusion coefficient. The drying kinetics allows one to determine the drying time for the storage of the product and the thermodynamic properties for the design of the equipment.
{"title":"Mathematical Modelling of Muña Leaf Drying (Minthostachys mollis) for Determination of the Diffusion Coefficient, Enthalpy, and Gibbs Free Energy","authors":"Reynaldo J. Silva-Paz, Dante K. Mateo-Mendoza, Amparo Eccoña-Sota","doi":"10.3390/chemengineering7030049","DOIUrl":"https://doi.org/10.3390/chemengineering7030049","url":null,"abstract":"In Peru, there are more than four thousand plants with medicinal properties, including muña, which helps digestion and improves health. The way to preserve these plants is drying up. The objective of this research was to investigate the coefficient of diffusion, enthalpy, and Gibbs free energy in the drying kinetics of muña leaves. Different pretreatments were carried out on the samples (without pretreatment, as well as treated by immersion in 1% ascorbic acid and bleaching at 60 °C for 30 s), and they were dehydrated at three temperatures (40, 50, and 60 °C). The drying kinetics were modeled using eight mathematical models to represent the drying curve. The water content was reduced by the drying process. The logarithmic model was selected, as it showed the best fit to represent the drying kinetics of the muña. Activation energy values were similar between treatments (p > 0.05). The increase in temperature decreases the enthalpy and entropy and increases the Gibbs free energy with the effective diffusion coefficient. The drying kinetics allows one to determine the drying time for the storage of the product and the thermodynamic properties for the design of the equipment.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":" ","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42121940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-17DOI: 10.3390/chemengineering7030048
B. Bianchi, B. Molino, F. Catalano, F. Giametta, A. Molino, L. Ambrosone
Nanofiltration and reverse osmosis are used in the concentration of grape musts in winemaking. Both technologies offer an effective way to concentrate the grape musts, reducing the volume and the solids content to achieve desired characteristics in the final wine. The choice between nanofiltration and reverse osmosis depends on the specific needs of the winemaker and the desired characteristics. It is important to carefully consider the properties of the grape musts and the performance of the selected membranes to optimize the concentration process and ensure the desired outcome. Herein, we present a novel approach that allows us to choose a suitable membrane for an optimal industrial process for the concentration of musts, both in reverse osmosis and nanofiltration. The proposed method consists of combining the fitting equations of laboratory results with the balance equations on the industrial plant. Specifically, a full-scale plant has been designed and assembled with which grape musts of Trebbiano, Verdeca, Black Bombino, and White Bombino varieties have been concentrated through the selected best-performing membranes. Results of the proposed approach show that grape musts with sugar content commercially appreciated when the membranes work at high pressure can be obtained.
纳滤和反渗透是酿酒过程中对葡萄醪液进行浓缩的常用方法。这两种技术都提供了一种有效的方法来浓缩葡萄汁，减少体积和固体含量，以达到最终葡萄酒所需的特性。纳滤和反渗透之间的选择取决于酿酒师的具体需求和所需的特性。重要的是要仔细考虑葡萄的性质和所选膜的性能，以优化浓缩过程，确保预期的结果。在此，我们提出了一种新的方法，使我们能够选择一种合适的膜，用于反渗透和纳滤中必须浓度的最佳工业过程。本文提出的方法是将实验室结果的拟合方程与工业装置的平衡方程相结合。具体来说，一个完整的工厂已经被设计和组装，其中Trebbiano, Verdeca, Black Bombino和White Bombino品种的葡萄必须通过精选的最佳性能膜进行浓缩。该方法的结果表明，当膜在高压下工作时，可以获得具有商业价值的糖含量的葡萄。
{"title":"A Novel Approach to Optimize the Industrial Process of Membrane Concentration of Grape Musts","authors":"B. Bianchi, B. Molino, F. Catalano, F. Giametta, A. Molino, L. Ambrosone","doi":"10.3390/chemengineering7030048","DOIUrl":"https://doi.org/10.3390/chemengineering7030048","url":null,"abstract":"Nanofiltration and reverse osmosis are used in the concentration of grape musts in winemaking. Both technologies offer an effective way to concentrate the grape musts, reducing the volume and the solids content to achieve desired characteristics in the final wine. The choice between nanofiltration and reverse osmosis depends on the specific needs of the winemaker and the desired characteristics. It is important to carefully consider the properties of the grape musts and the performance of the selected membranes to optimize the concentration process and ensure the desired outcome. Herein, we present a novel approach that allows us to choose a suitable membrane for an optimal industrial process for the concentration of musts, both in reverse osmosis and nanofiltration. The proposed method consists of combining the fitting equations of laboratory results with the balance equations on the industrial plant. Specifically, a full-scale plant has been designed and assembled with which grape musts of Trebbiano, Verdeca, Black Bombino, and White Bombino varieties have been concentrated through the selected best-performing membranes. Results of the proposed approach show that grape musts with sugar content commercially appreciated when the membranes work at high pressure can be obtained.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":" ","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43224522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-15DOI: 10.3390/chemengineering7030047
A. Zouari, A. Manich, M. Martí, Sondes Gargoubi, C. Boudokhane
Recently, a significant interest in eco-friendly textile products and processes has been noted among consumers and producers. In this respect, nanobubble technology is emerging as a green alternative. In this study, water-repellent cotton fabrics were produced with exhaustion and nanobubble technology (e-flow method) using a short-chain fluoropolymer. The currently most developed substituents are based on molecules with short fluorine carbon chains. The wettability, mechanical properties, air permeability and treatment durability were evaluated. The untreated and treated cotton fabrics were analyzed with ATR-FTIR (Fourier transform infrared attenuated total reflectance) and SEM (scanning electron microscopy) to reveal chemical and morphological modifications. The obtained results show that cotton samples treated with short-chain fluoropolymers, nontoxic and eco-friendly finishing chemicals, and nanobubble technology have good water repellence and good washing durability. Due to their size and structure, nanobubbles possess distinct properties that make them particularly effective at improving water quality, enhancing water treatment processes, and improving productivity in industrial applications. Nanobubbles have a strong negative surface charge that keeps them stable in liquid, prevents them from coalescing, and enables them to physically separate small particles and droplets from water, such as emulsified fats, oils, and grease.
{"title":"Nanobubble Technology for A Water-Repellent Treatment on Cotton Fabrics: A Comparative Study","authors":"A. Zouari, A. Manich, M. Martí, Sondes Gargoubi, C. Boudokhane","doi":"10.3390/chemengineering7030047","DOIUrl":"https://doi.org/10.3390/chemengineering7030047","url":null,"abstract":"Recently, a significant interest in eco-friendly textile products and processes has been noted among consumers and producers. In this respect, nanobubble technology is emerging as a green alternative. In this study, water-repellent cotton fabrics were produced with exhaustion and nanobubble technology (e-flow method) using a short-chain fluoropolymer. The currently most developed substituents are based on molecules with short fluorine carbon chains. The wettability, mechanical properties, air permeability and treatment durability were evaluated. The untreated and treated cotton fabrics were analyzed with ATR-FTIR (Fourier transform infrared attenuated total reflectance) and SEM (scanning electron microscopy) to reveal chemical and morphological modifications. The obtained results show that cotton samples treated with short-chain fluoropolymers, nontoxic and eco-friendly finishing chemicals, and nanobubble technology have good water repellence and good washing durability. Due to their size and structure, nanobubbles possess distinct properties that make them particularly effective at improving water quality, enhancing water treatment processes, and improving productivity in industrial applications. Nanobubbles have a strong negative surface charge that keeps them stable in liquid, prevents them from coalescing, and enables them to physically separate small particles and droplets from water, such as emulsified fats, oils, and grease.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":" ","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43222492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-12DOI: 10.3390/chemengineering7030046
A. Kadhum, S. Al-Zubaidi, Salah S. Abdulkareem
This study aims to evaluate the 3D-printed parts of different materials in terms of the achieved mechanical properties and surface characteristics. Fourteen infill patterns were employed in the 3D printing of polylactic acid (PLA), enhanced polylactic acid (PLA+), and polyethylene terephthalate glycol (PETG) materials. The printed specimens’ mechanical properties and surface characteristics were evaluated and discussed. Ultimate tensile strengths, Young’s modulus, and strain at break % were determined as mechanical properties, while average, maximum, and total height of profiles (Ra, Rz, and Rt) were measured as surface characteristics of the produced specimens. The cubic, gyroid, and concentric patterns were found to be the best infill patterns in terms of the mechanical properties of PLA, PLA+, and PETG materials, where maximum ultimate tensile strengths were recorded for these materials: 15.6250, 20.8333, and 16.5483 MPa, respectively. From the other side, the best Ra, Rz, and Rt were achieved with cross, quarter cubic, and concentric patterns of the PLA, PETG, and PLA+ materials, where the best values were (2.832 µm, 8.19 µm, and 17.53), (4.759 µm, 24.113 µm, and 35.216), and (4.234 µm, 30.136 µm, and 31.896), respectively.
{"title":"Effect of the Infill Patterns on the Mechanical and Surface Characteristics of 3D Printing of PLA, PLA+ and PETG Materials","authors":"A. Kadhum, S. Al-Zubaidi, Salah S. Abdulkareem","doi":"10.3390/chemengineering7030046","DOIUrl":"https://doi.org/10.3390/chemengineering7030046","url":null,"abstract":"This study aims to evaluate the 3D-printed parts of different materials in terms of the achieved mechanical properties and surface characteristics. Fourteen infill patterns were employed in the 3D printing of polylactic acid (PLA), enhanced polylactic acid (PLA+), and polyethylene terephthalate glycol (PETG) materials. The printed specimens’ mechanical properties and surface characteristics were evaluated and discussed. Ultimate tensile strengths, Young’s modulus, and strain at break % were determined as mechanical properties, while average, maximum, and total height of profiles (Ra, Rz, and Rt) were measured as surface characteristics of the produced specimens. The cubic, gyroid, and concentric patterns were found to be the best infill patterns in terms of the mechanical properties of PLA, PLA+, and PETG materials, where maximum ultimate tensile strengths were recorded for these materials: 15.6250, 20.8333, and 16.5483 MPa, respectively. From the other side, the best Ra, Rz, and Rt were achieved with cross, quarter cubic, and concentric patterns of the PLA, PETG, and PLA+ materials, where the best values were (2.832 µm, 8.19 µm, and 17.53), (4.759 µm, 24.113 µm, and 35.216), and (4.234 µm, 30.136 µm, and 31.896), respectively.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":" ","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45856886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-11DOI: 10.3390/chemengineering7030045
A. Kalyakin, A. Volkov, L. Dunyushkina
An amperometric sensor based on CaZr0.95Sc0.05O3−δ (CZS) proton-conducting oxide for the measurement of hydrogen concentration in air was designed and tested. Dense CZS ceramics were fabricated through uniaxial pressing the powder synthesized by the solid-state method and sintering at 1650 °C for 2 h. The conductivity of CZS was shown to increase with increasing air humidity, which indicates the proton type of conductivity. The sensor was made from two CZS plates, one of which had a cavity was drilled to form an inner chamber, that were then pressed against each other and sealed around the perimeter to prevent gas leaking. The inner chamber of the sensor was connected with the outer atmosphere via an alumina ceramic capillary, which acted as a diffusion barrier. The sensor performance was studied in the temperature range of 600–700 °C in the mixtures of air with hydrogen. The sensor signal, or the limiting current, was found to linearly increase with the hydrogen concentration, which simplifies the sensor calibration. The sensor demonstrated a high sensitivity of ~60 μA per 1% H2 at 700 °C, a fast response, high reproducibility, good selectivity, and long-term stability.
{"title":"Solid-Oxide Amperometric Sensor for Hydrogen Detection in Air","authors":"A. Kalyakin, A. Volkov, L. Dunyushkina","doi":"10.3390/chemengineering7030045","DOIUrl":"https://doi.org/10.3390/chemengineering7030045","url":null,"abstract":"An amperometric sensor based on CaZr0.95Sc0.05O3−δ (CZS) proton-conducting oxide for the measurement of hydrogen concentration in air was designed and tested. Dense CZS ceramics were fabricated through uniaxial pressing the powder synthesized by the solid-state method and sintering at 1650 °C for 2 h. The conductivity of CZS was shown to increase with increasing air humidity, which indicates the proton type of conductivity. The sensor was made from two CZS plates, one of which had a cavity was drilled to form an inner chamber, that were then pressed against each other and sealed around the perimeter to prevent gas leaking. The inner chamber of the sensor was connected with the outer atmosphere via an alumina ceramic capillary, which acted as a diffusion barrier. The sensor performance was studied in the temperature range of 600–700 °C in the mixtures of air with hydrogen. The sensor signal, or the limiting current, was found to linearly increase with the hydrogen concentration, which simplifies the sensor calibration. The sensor demonstrated a high sensitivity of ~60 μA per 1% H2 at 700 °C, a fast response, high reproducibility, good selectivity, and long-term stability.","PeriodicalId":9755,"journal":{"name":"ChemEngineering","volume":" ","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45661253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：