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The origin and development of Chinese ceramic saggers 中国陶瓷匣钵的起源与发展
Pub Date : 2025-01-20 DOI: 10.1016/j.aia.2024.100028
Junming Wu, Chao Lei, Yimei Jiang, Riqin Shan, Jinxia Hai, Xiaoyan Xia
By combing and analyzing ancient literature, archaeological data, and test data, this paper systematically explores the origin, material, and development of the sagger firing process in ancient China. Saggers were first recorded in Tao Ji (Records on Ceramic) written by Jiang Qi in the Southern Song Dynasty. The word sagger was coined by Song Yingxing in Tian Gong Kai Wu of the Ming Dynasty. The development of saggers can be divided into three stages: the germination stage of the bowls and jars of saggers before the Eastern Jin Dynasty; the initial stage of perforated saggers from the late Eastern Jin Dynasty to the Sui Dynasty; and the development and maturity period of various saggers after the Sui Dynasty. The raw material recipe has gone from a single-component formula using refractory mud, clay, and other raw materials; to a two-component formula with clay as the matrix mixed with quartz sand or white clay; to multi-component formulas including white clay, black clay, and black and yellow sand. Loading and firing have undergone an evolution, from nested firing to single-box upward firing, to a combination of inner and outer boxes, and finally to branch ring covering firing. The evolution of saggar materials and firing methods reflects the improvement of saggar performance, which improves both the output and quality of ceramics.
本文通过对古代文献、考古资料和试验资料的梳理和分析,系统地探讨了中国古代匣钵烧制工艺的起源、材料和发展。Saggers最早见于南宋江奇的《陶记》中。“sagger”一词是宋代宋应星在《天工开悟》中创造的。匣钵的发展可分为三个阶段:东晋以前的匣钵萌发阶段;东晋末年至隋代为射孔洼地的初始阶段;以及隋朝以后各种宗教的发展和成熟期。原料配方已从单一组分配方,采用耐火泥、粘土等原料;以粘土为基质,与石英砂或白粘土混合制成双组份配方;多组分配方包括白粘土、黑粘土和黑黄沙。装填和射击经历了一个演变过程,从嵌套射击到单盒向上射击,再到内外盒结合,最后到支环覆盖射击。sagar材料和烧制方法的发展反映了sagar性能的提高,从而提高了陶瓷的产量和质量。
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引用次数: 0
Physicochemical characterization and a GIS analysis of the historical mortar of the masonry concerning a nineteenth-century monument 19世纪纪念碑砌筑砂浆的物理化学特征和GIS分析
Pub Date : 2025-01-01 DOI: 10.1016/j.aia.2025.100056
S. Lycourghiotis , N.A. Kalapodis , P.A. Kakavas-Papaniaros , I. Iliopoulos , E. Mantzana
This study provides a detailed physicochemical characterization of historical mortar from a nineteenth-century church in Ilia, near ancient Olympia (Peloponnese, Greece), a monument of high cultural and architectural significance currently undergoing restoration planning. Mortar samples were examined using polarized optical microscopy, scanning electron microscopy, X-ray fluorescence, X-ray diffraction, Fourier transform infrared spectroscopy with attenuated total reflectance, thermogravimetric analysis, nitrogen adsorption-desorption isotherms, microelectrophoresis, and equilibrium pH measurements of mortar–water suspensions. The analyses confirm that the material is a lime-based mortar with predominantly calcareous aggregates and minor aluminosilicate and iron-bearing phases. Petrographic observations revealed rounded aggregates of varying sizes, shrinkage cracks, and a layered binder microstructure that generates meso and macroporosity. This pore network facilitates capillary moisture rise, causing binder depletion and progressive deterioration, particularly in lower masonry sections. Surface chemistry data indicate a low electrical surface charge and slight acidity, suggesting limited vulnerability to direct corrosion from atmospheric pollutants such as SO₂ and NOx. These results underline the importance of using compatible repair mortars that replicate the texture, porosity, and composition of the original material, alongside moisture-management interventions at the masonry base. Petrographic and mineralogical evidence further associates the aggregates with nearby Gavrovo-Tripolis geotectonic formations, providing a local source reference for restoration materials. Combining GIS analysis with scanning electron microscopy-energy dispersive X-ray spectroscopy data also demonstrates that mortars used in the surrounding region during the same period share similar characteristics. To our knowledge, this is the first study to apply electrophoretic mobility and equilibrium pH measurements to historical mortars, offering novel insight into their surface properties. By integrating traditional mineralogical and petrographic techniques with advanced surface chemistry analyses, this work sheds light on the deterioration mechanisms of historic masonry mortars and delivers a comprehensive framework to guide the conservation and restoration of heritage structures.
这项研究提供了一个详细的物理化学特征的历史砂浆在伊利亚19世纪教堂,靠近古奥林匹亚(伯罗奔尼撒半岛,希腊),一个具有高度文化和建筑意义的纪念碑,目前正在进行修复计划。使用偏振光学显微镜、扫描电子显微镜、x射线荧光、x射线衍射、傅里叶变换红外光谱(衰减全反射)、热重分析、氮吸附-解吸等温线、微电泳和砂浆-水悬浮液平衡pH测量对砂浆样品进行了检测。分析证实,该材料为石灰基砂浆,主要含钙质集料,少量含铝硅酸盐和含铁相。岩石学观察揭示了不同大小的圆形聚集体、收缩裂缝和层状粘结剂微观结构,这些微观结构产生了介孔和宏观孔隙。这种孔隙网络促进毛细管水分上升,导致粘结剂耗竭和逐渐劣化,特别是在较低的砌体部分。表面化学数据表明,其表面电荷低,酸度低,表明其对大气污染物(如so2和NOx)的直接腐蚀的脆弱性有限。这些结果强调了使用兼容的修复砂浆的重要性,这些砂浆可以复制原始材料的纹理、孔隙度和成分,同时在砌体基础上进行水分管理干预。岩石学和矿物学证据进一步将聚集体与附近的Gavrovo-Tripolis大地构造地层联系起来,为修复材料提供了当地的参考来源。GIS分析与扫描电镜-能量色散x射线能谱数据的结合也表明,同一时期周边地区使用的迫击炮具有相似的特征。据我们所知,这是第一次将电泳迁移率和平衡pH值测量应用于历史砂浆的研究,为其表面特性提供了新的见解。通过将传统的矿物学和岩石学技术与先进的表面化学分析相结合,这项工作揭示了历史砌体砂浆的劣化机制,并提供了一个全面的框架来指导遗产结构的保护和修复。
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引用次数: 0
Comprehensive analysis and study of the stratification phenomena of painted pottery unearthed from the Banpo site in China 半坡遗址彩陶分层现象的综合分析与研究
Pub Date : 2025-01-01 DOI: 10.1016/j.aia.2025.100054
Xinyuan Su , Zhanhui Peng , Tao Tan , Huifang Liu , Huiping Xing , Baoying Liu , Xiaolian Chao
Historical information is preserved in cultural artifacts, particularly pottery, and scientific techniques are crucial for uncovering their past. This study presents a multi-method interdisciplinary analysis of painted pottery from the Banpo site of the Yangshao culture. Element profiles and XPS analyses reveal that variations in trivalent iron content, responsible for different hues, are due to diverse firing atmospheres during the kiln’s stack firing rather than the use of a masking layer or different clay types. XRD analysis revealed that the ceramic body was primarily composed of quartz and feldspar. SEM-EDS indicates that black regions at the pottery’s base resulted from carbon penetration, likely due to its use as cooking utensils. Pigment analysis shows the red pigment is mainly ocher, the black pigment is a symbiotic combination of pyrolusite and magnetite, and the white pigment is calcite. Thermal expansion analysis confirms that the pottery was fired at around 1010 °C, with color differences attributed to the kiln atmosphere rather than firing temperature, supporting a single firing process. This research provides essential data for enhancing our understanding of Banpo painted pottery, offering valuable insights into its production and usage.
历史信息保存在文物中,尤其是陶器,科学技术对于揭示它们的过去至关重要。本研究对仰韶半坡遗址彩陶进行多方法跨学科分析。元素轮廓和XPS分析显示,造成不同色调的三价铁含量的变化是由于窑堆烧制过程中不同的烧制气氛造成的,而不是由于使用了掩蔽层或不同的粘土类型。XRD分析表明,陶瓷体主要由石英和长石组成。SEM-EDS显示,陶器底部的黑色区域是碳渗透造成的,可能是由于它被用作炊具。颜料分析表明,红色颜料主要为赭石,黑色颜料为软锰矿和磁铁矿的共生组合,白色颜料为方解石。热膨胀分析证实,陶器是在1010°C左右烧制的,颜色的差异归因于窑炉的气氛,而不是烧制温度,支持单一的烧制过程。本研究为加深对半坡彩陶的认识提供了重要的资料,对半坡彩陶的生产和使用提供了有价值的见解。
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引用次数: 0
Technical ceramics from late period to Roman Kom Tuman (Memphis), Egypt, reveal collocation of multiple high-temperature industries 从晚期到罗马科姆图曼(孟菲斯),埃及的技术陶瓷,揭示了多个高温工业的搭配
Pub Date : 2025-01-01 DOI: 10.1016/j.aia.2025.100055
S. Ivanov , I. Kovalev , Th. Rehren
Apart from palatial and military archaeological contexts, the Kom Tuman sector of ancient Memphis features an industrial area formed by several high-temperature production and processing workshops of different specializations, operating from the Late period (ca. 664 BCE–ca. 332 BCE) to Hellenistic and Roman times. The study of crucible fragments from these workshops identified a range of coexisting activities, including glass working and metalworking, as well as the primary production of Egyptian blue pigment. This paper provides evidence for these high-temperature industries, discussing both their respective produce and the technical ceramics employed. Analysis of the latter showed that craftspeople in Kom Tuman deliberately selected different types of clay to better fit the requirement of high-temperature production. Both glass and Egyptian blue industries employed crucibles made of calcareous fabric with an external Nile silt coating, while metallurgical activities relied on the use of Nile silt fabric only. Evidence for pottery production is conspicuously absent from these workshops, while evidence for local faience production is very limited.
除了宫殿和军事考古背景外,古孟菲斯的Kom Tuman地区还以一个工业区为特色,该工业区由几个不同专业的高温生产和加工车间组成,从公元前664年到公元前664年。公元前332年)到希腊化和罗马时代。对这些车间的坩埚碎片的研究确定了一系列共存的活动,包括玻璃加工和金属加工,以及埃及蓝色颜料的主要生产。本文为这些高温工业提供了证据,讨论了它们各自的产品和所采用的技术陶瓷。对后者的分析表明,库姆图曼的工匠故意选择不同类型的粘土,以更好地适应高温生产的要求。玻璃和埃及蓝色工业都使用石灰质织物制成的坩埚,外部涂有尼罗河淤泥涂层,而冶金活动仅依赖于使用尼罗河淤泥织物。这些作坊明显没有陶器生产的证据,而当地陶器生产的证据也非常有限。
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引用次数: 0
Pub Date : 2024-01-19 DOI: 10.1016/j.aia.2022.10.001
Jianjun Mei
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引用次数: 0
Investigation on restoration materials and techniques on bronze artifacts using non-invasive imaging and spectroscopic methods 非侵入式成像与光谱技术对青铜器修复材料与技术的研究
Pub Date : 2024-01-01 DOI: 10.1016/j.aia.2025.100043
Wei Liu , Pengyu Zhang , Yuliang Zhao , Na Wu
Archaeological bronze artifacts are often found in fragmented or damaged states during excavation, necessitating restoration before they can be displayed in exhibitions. However, many early restoration works lack detailed documentation, posing significant challenges for museum conservators and scientists who want to reanalyze these restored artifacts. Reconstructing past restoration processes via scientific analysis is becoming a fundamental job. Previous studies on restoration materials and techniques for bronze artifacts have mostly relied on micro-analytical and invasive techniques, which are limited in providing comprehensive restoration information about artifacts as a whole. The present study employed imaging techniques, including macro X-ray fluorescence spectroscopy, X-ray radiography, and ultraviolet-induced visible luminescence imaging, in combination with Raman spectroscopy and fiber optics reflectance spectroscopy, to investigate two bronze artifacts dated to the early Spring and Autumn period (770–476 BCE) in the collection of the National Museum of China. The results indicated that one of the artifacts, a bronze vessel (yan), exhibited extensive surface cracks and a large missing piece, which had been repaired using a copper plate joined with tin-lead soldering. Both artifacts showed evidence of surface retouching with pigments such as lithopone, lazurite, phthalocyanine blue, barium white, and chrome yellow. Lithopone, in particular, helps researchers estimate the restoration period of these artifacts, providing valuable insight into their conservation history. The integration of imaging and spectroscopic techniques proves to be an effective approach for characterizing the restoration materials and techniques applied to bronze artifacts, helping conservators in assessing the condition of restored bronze artifacts.
考古青铜器在挖掘过程中经常被发现破碎或损坏,需要修复才能在展览中展出。然而,许多早期修复工作缺乏详细的文件记录,这对想要重新分析这些修复文物的博物馆管理员和科学家构成了重大挑战。通过科学分析重建过去的修复过程正在成为一项基本工作。以往对青铜器修复材料和修复技术的研究多依赖于微观分析和侵入性技术,无法全面提供文物整体修复信息。本研究采用宏观x射线荧光光谱、x射线照相术、紫外诱导可见光成像等成像技术,结合拉曼光谱和光纤反射光谱,对中国国家博物馆收藏的两件春秋早期(公元前770-476年)青铜器进行了研究。结果表明,其中一件青铜器皿(yan)的表面出现了广泛的裂缝和一大块缺失,这是用锡铅焊接的铜板修复的。这两件文物都显示了用立德粉、天青石、酞菁蓝、钡白和铬黄等颜料进行表面修饰的证据。特别是立德粉,可以帮助研究人员估计这些文物的修复时间,为他们的保护历史提供有价值的见解。事实证明,将成像技术与光谱技术相结合是表征青铜器修复材料和技术的有效方法,有助于保护人员评估修复的青铜器的状况。
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引用次数: 0
Identifying recipes of historical cupels from Yunnan, China 鉴别中国云南历史杯具的配方
Pub Date : 2024-01-01 DOI: 10.1016/j.aia.2025.100044
Ao Sun, Huimin Wu, Tian Liu, Yuchen Wang, Siran Liu
Cupellation was the most important silver extraction technology in the ancient world. No later than the Han Dynasty, China adopted cupellation in silver extraction. However, the cupel, the most significant physical evidence of this process, is not frequently identified archaeologically in China and is rarely analyzed to reconstruct the technology and material characteristics of the process. Here we present new findings from the sites of Beiyachang and Baixiangchang in Dali, Yunnan. Five used cupel fragments from the two sites were generally dated to the Ming and Qing Dynasties. Chemical and microscopic analyses show that the cupels were made primarily of a mixture of bone ash (∼30–50 wt %) and plant ash (∼50–70 wt %). Intriguingly, Chinese historical documents recorded only plant ash as the raw material of cupels and did not mention bone ash until the nineteenth century AD. Thus the current analytical result provides the first physical evidence of cupels made with a bone ash and plant ash mixture in historical China.
酒杯制银是古代世界最重要的白银提取技术。不迟于汉代,中国在白银提取中采用了杯酒。然而,作为这一过程最重要的实物证据,在中国很少被考古学家发现,也很少被分析来重建这一过程的技术和材料特征。本文报道了云南大理北崖场和白香场遗址的新发现。这两处遗址出土的五件旧刀具碎片大致可追溯到明清时期。化学和显微分析表明,这些铜杯主要由骨灰(~ 30-50 wt %)和植物骨灰(~ 50-70 wt %)的混合物制成。有趣的是,中国的历史文献只记录了植物灰烬作为铜板的原料,直到公元19世纪才提到骨灰。因此,目前的分析结果为中国历史上用骨灰和植物灰烬混合物制成的铜杯提供了第一个物理证据。
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引用次数: 0
Erratum regarding missing Declaration of Competing Interests in previously published articles 关于先前发表的文章中缺少竞争利益声明的勘误表
Pub Date : 2024-01-01 DOI: 10.1016/j.aia.2025.100045
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引用次数: 0
Ritual use, consumption, and depositional practices at Agriomernos Cave, Northwestern Samos (Greece): A ceramic analytical approach 希腊萨摩斯岛西北部 Agriomernos 洞穴的仪式使用、消费和沉积习俗:陶瓷分析方法
Pub Date : 2024-01-01 DOI: 10.1016/j.aia.2024.100041
Sergios Menelaou , Edyta Marzec , Fotis Georgiadis , Stella Katsarou , Anastasios Siros , Andreas Darlas

This study utilises pottery as a proxy to identify patterns of use and consumption, as well as depositional strategies at Agriomernos, a recently discovered cave site on Samos Island (Greece). This discovery challenges our understanding of human–landscape interaction within a marginal region across two distinct prehistoric chronological episodes. As part of a broader research project, this paper presents the results from an integrated, multiscale analysis of pottery through morpho-stylistic and macroscopic examination, thin section petrography, and wavelength dispersive X–ray fluorescence spectroscopy (WD-XRF). The analysis has revealed a compositionally diverse ceramic assemblage that represents a range of different raw material sources on the island and, by extension, different groups of people. The identification of off-island imports adds new evidence to the reconstruction of Aegean connectivity patterns. Agriomernos Cave constitutes a key archaeological site within an area previously unexplored, offering a unique opportunity to investigate ancient mobility, landscape sacrality, and ritual performances manifested through periodical and repeated acts of deposition.

本研究利用陶器作为替代品,确定希腊萨摩斯岛最近发现的洞穴遗址 Agriomernos 的使用和消费模式以及沉积策略。这一发现挑战了我们对两个不同史前时期边缘地区人类与景观互动的理解。作为更广泛研究项目的一部分,本文介绍了通过形态样式和宏观检查、薄片岩相学以及波长色散 X 射线荧光光谱(WD-XRF)对陶器进行综合、多尺度分析的结果。分析结果表明,陶瓷组合成分多样,代表了岛上不同的原材料来源,进而代表了不同的人群。对岛外进口商品的鉴定为重建爱琴海的连接模式增添了新的证据。阿格里奥梅诺斯洞穴是一个重要的考古遗址,位于以前未曾开发的地区,为研究古代流动性、景观祭祀性以及通过定期和重复的沉积行为表现出来的仪式表演提供了一个独特的机会。
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引用次数: 0
From the hills to the sea: Mineralogical and chemical characterization of a roof tile assemblage from the Byzantine church at Ashdod-Yam (Israel) 从山到海:阿什杜德-亚姆(以色列)拜占庭教堂屋顶瓦组合的矿物学和化学特征
Pub Date : 2024-01-01 DOI: 10.1016/j.aia.2024.100040
Philip Ebeling , Liora Bouzaglou , Dana Ashkenazi , Johannes H. Sterba , Alexander Fantalkin
This paper presents the results of a multidisciplinary approach characterizing roof tiles excavated at the Ashdod-Yam Byzantine church (Israel). Occupied from the late fourth/early fifth century CE, the building was destroyed by fire toward the end of the sixth century CE, sealed by tiles from the roof's collapse. The assemblage of 3846 roof tiles was initially classified through macroscopic and typological analysis. Selected samples were further subjected to optical microscopy of petrographic samples for provenance studies and ceramic technological insights, along with instrumental neutron activation analysis (INAA). The findings reveal the artifacts to be imported from the eastern Mediterranean ophiolitic complexes and from the Judean Hills. Additionally, fragments of painted ceramic roof tiles were tested using scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) to assess the composition of the pigments, examine their microstructures, and understand the manufacturing technologies used. Despite the presence of different types of roof tiles, the paint applied to some of them was found to be uniform, consisting of red, ocher-based pigment, likely sourced locally and applied during the roof's construction. This comprehensive examination on a relatively unexplored type of material sheds new light on specific construction choices during the Byzantine period in the southern Levant.
本文介绍了多学科方法表征在阿什杜德-亚姆拜占庭教堂(以色列)挖掘的屋顶瓦片的结果。这座建筑始建于公元4世纪末/ 5世纪初,在公元6世纪末的一场大火中被毁,屋顶坍塌的瓦片将其封住。通过宏观分析和类型学分析,对3846块瓦片组合进行初步分类。选定的样品进一步进行了岩石样品的光学显微镜研究,以进行来源研究和陶瓷技术见解,以及仪器中子活化分析(INAA)。研究结果表明,这些文物是从东地中海蛇绿岩复合体和犹太山进口的。此外,使用扫描电子显微镜和能量色散光谱(SEM-EDS)测试了涂漆陶瓷屋顶瓦片的碎片,以评估颜料的组成,检查其微观结构,并了解所使用的制造技术。尽管存在不同类型的屋顶瓦片,但其中一些瓦片上的油漆是统一的,由红色赭石颜料组成,可能来自当地,并在屋顶施工期间使用。这种对一种相对未开发的材料类型的全面检查揭示了在黎凡特南部拜占庭时期具体的建筑选择。
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引用次数: 0
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Advances in Archaeomaterials
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