首页 > 最新文献

Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers最新文献

英文 中文
Preparation and characterization of 3D printed hydroxyapatite-whisker-strengthened hydroxyapatite scaffold coated with biphasic calcium phosphate 3D打印双相磷酸钙包覆羟基磷灰石-晶须增强羟基磷灰石支架的制备与表征
Pub Date : 2023-10-18 DOI: 10.1016/j.cjmeam.2023.100097
Chenyu Ma , Qingfeng Zeng , Luwang Yu , Shuyin Yu , Jiayin Song , Yongjie Ma , Xieping Dong

This study investigates the in vitro degradation of calcium-deficient hydroxyapatite powder after heat treatment at different temperatures and analyzes the calculated phase composition, particle size distribution, degradation rate, and bioactivity of the powder after heat treatment. A mixture of hydroxyapatite and β-tricalcium phosphate (BCP) coatings was prepared on the surface of a 3D-printed hydroxyapatite-whisker-strengthened hydroxyapatite scaffold (HAw/HA) by vacuum impregnation and ultraviolet light curing combined with an optimized heat treatment process. The performance of the coatings under different methods was characterized. The composite scaffolds with highly interconnected pores and excellent mechanical properties were prepared, and their biodegradation performance, bioactivity, osteoconductivity, and osteoinductivity of the scaffolds were improved. The results showed that calcium-deficient hydroxyapatite began to transform into BCP between 600 °C and 800 °C, and the powder treated at 800 °C has better bioactivity. The BCP coating prepared by light curing was more uniform, resulting in a higher interfacial bonding strength, and has better osteoconductivity and osteoinductivity than that prepared by vacuum impregnation.

本研究研究了缺钙羟基磷灰石粉末在不同温度下热处理后的体外降解,并分析了热处理后粉末的计算相组成、粒度分布、降解率和生物活性。采用真空浸渍和紫外光固化结合优化热处理工艺,在3d打印羟基磷灰石-晶须增强羟基磷灰石支架(HAw/HA)表面制备了羟基磷灰石和β-磷酸三钙(BCP)混合物涂层。对不同处理方法下涂层的性能进行了表征。制备了孔隙高度连通、力学性能优异的复合支架,提高了支架的生物降解性能、生物活性、骨导电性和骨诱导性。结果表明,缺钙羟基磷灰石在600℃~ 800℃之间开始向BCP转化,800℃处理后的粉体具有更好的生物活性。光固化制备的BCP涂层更加均匀,界面结合强度更高,具有比真空浸渍制备的BCP涂层更好的骨导电性和骨诱导性。
{"title":"Preparation and characterization of 3D printed hydroxyapatite-whisker-strengthened hydroxyapatite scaffold coated with biphasic calcium phosphate","authors":"Chenyu Ma ,&nbsp;Qingfeng Zeng ,&nbsp;Luwang Yu ,&nbsp;Shuyin Yu ,&nbsp;Jiayin Song ,&nbsp;Yongjie Ma ,&nbsp;Xieping Dong","doi":"10.1016/j.cjmeam.2023.100097","DOIUrl":"10.1016/j.cjmeam.2023.100097","url":null,"abstract":"<div><p>This study investigates the <em>in vitro</em> degradation of calcium-deficient hydroxyapatite powder after heat treatment at different temperatures and analyzes the calculated phase composition, particle size distribution, degradation rate, and bioactivity of the powder after heat treatment. A mixture of hydroxyapatite and β-tricalcium phosphate (BCP) coatings was prepared on the surface of a 3D-printed hydroxyapatite-whisker-strengthened hydroxyapatite scaffold (HA<sub>w</sub>/HA) by vacuum impregnation and ultraviolet light curing combined with an optimized heat treatment process. The performance of the coatings under different methods was characterized. The composite scaffolds with highly interconnected pores and excellent mechanical properties were prepared, and their biodegradation performance, bioactivity, osteoconductivity, and osteoinductivity of the scaffolds were improved. The results showed that calcium-deficient hydroxyapatite began to transform into BCP between 600 °C and 800 °C, and the powder treated at 800 °C has better bioactivity. The BCP coating prepared by light curing was more uniform, resulting in a higher interfacial bonding strength, and has better osteoconductivity and osteoinductivity than that prepared by vacuum impregnation.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 4","pages":"Article 100097"},"PeriodicalIF":0.0,"publicationDate":"2023-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772665723000363/pdfft?md5=c89f68c002dfc5f1ca678f05b87c71d4&pid=1-s2.0-S2772665723000363-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135849005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Broadband and High-temperature-resistant Microwave Absorber Using Additively Manufactured Ceramic Substrate 增材制造陶瓷基板的宽带耐高温微波吸收器
Pub Date : 2023-10-18 DOI: 10.1016/j.cjmeam.2023.100096
Baihong Chi , Kuan Lu , Pengfei Wang , Mengzhu Li , Yuanyuan Li , Xinyu Geng , Guangsheng Deng

This paper presents an approach to achieve broadband absorption and temperature resistance using ceramic substrates. A specially formulated slurry suitable for additive manufacturing technology was developed to fabricate ceramic substrates with lattice structures. The lattice structure not only reduces the weight of the absorber but also facilitates the broadening of the absorption bandwidth. The experimental results demonstrate that the proposed structure exhibits absorption rates exceeding 88% within the frequency range of 19.9–30.41 GHz, with a relative absorption bandwidth of 41.8% under normal incidence. Furthermore, the absorber's performance was assessed under high temperatures of up to 200 ℃, revealing absorption spectra that closely match the initially measured spectrum. Additive-manufactured ceramic lattice structures present a promising avenue for designing multifunctional broadband microwave absorbers capable of withstanding elevated temperatures.

本文提出了一种利用陶瓷衬底实现宽带吸收和耐温的方法。开发了一种适用于增材制造技术的专用浆料,用于制备具有晶格结构的陶瓷基板。晶格结构不仅减轻了吸收剂的重量,而且有利于吸收带宽的拓宽。实验结果表明,该结构在19.9 ~ 30.41 GHz频率范围内的吸收率超过88%,正常入射下的相对吸收带宽为41.8%。此外,在高达200℃的高温下对吸收剂的性能进行了评估,揭示了与最初测量的光谱密切匹配的吸收光谱。增材制造的陶瓷晶格结构为设计能够承受高温的多功能宽带微波吸收器提供了一条有前途的途径。
{"title":"Broadband and High-temperature-resistant Microwave Absorber Using Additively Manufactured Ceramic Substrate","authors":"Baihong Chi ,&nbsp;Kuan Lu ,&nbsp;Pengfei Wang ,&nbsp;Mengzhu Li ,&nbsp;Yuanyuan Li ,&nbsp;Xinyu Geng ,&nbsp;Guangsheng Deng","doi":"10.1016/j.cjmeam.2023.100096","DOIUrl":"https://doi.org/10.1016/j.cjmeam.2023.100096","url":null,"abstract":"<div><p>This paper presents an approach to achieve broadband absorption and temperature resistance using ceramic substrates. A specially formulated slurry suitable for additive manufacturing technology was developed to fabricate ceramic substrates with lattice structures. The lattice structure not only reduces the weight of the absorber but also facilitates the broadening of the absorption bandwidth. The experimental results demonstrate that the proposed structure exhibits absorption rates exceeding 88% within the frequency range of 19.9–30.41 GHz, with a relative absorption bandwidth of 41.8% under normal incidence. Furthermore, the absorber's performance was assessed under high temperatures of up to 200 ℃, revealing absorption spectra that closely match the initially measured spectrum. Additive-manufactured ceramic lattice structures present a promising avenue for designing multifunctional broadband microwave absorbers capable of withstanding elevated temperatures.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 4","pages":"Article 100096"},"PeriodicalIF":0.0,"publicationDate":"2023-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772665723000351/pdfft?md5=044aa7334bafc28c87856c7bc2cea5a1&pid=1-s2.0-S2772665723000351-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134688327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Additive Manufacturing of Large-scale Metal Mesh with Core-shell Composite Structure for Transparent Electromagnetic Shielding/glass Heater 透明电磁屏蔽/玻璃加热器用大型芯壳复合结构金属网的增材制造
Pub Date : 2023-09-01 DOI: 10.1016/j.cjmeam.2023.100089
Yuping Tai , Junyi Zhou , Xiaoyang Zhu , Houchao Zhang , Hongke Li , Zhenghao Li , Rui Wang , Fan Zhang , Guangming Zhang , Chaohong Liu , Hongbo Lan

Transparent electromagnetic (EM) shielding glass with a metal mesh has significant potential for application in different fields of EM radiation and anti-EM interference light-transmitting observation windows. In particular, a transparent EM-shielding glass with a large-aspect-ratio metal mesh can effectively alleviate the contradictory problems of shielding effectiveness and light-transmission performance constraints. However, the fabrication of high-aspect-ratio metal meshes on glass substrates has problems such as high cost, complex processes, low efficiency, small area, and easy damage issues, which limit their application in the field of high-performance, transparent EM-shielding glass. Therefore, this paper proposes a composite additive manufacturing process based on electric-field-driven microjet 3D printing and electroplating. By fabricating metal meshes with an Ag-Cu core-shell structure on a glass substrate, EM-shielding glass with high shielding efficiency and light transmission can be manufactured without increasing the aspect ratio of the metal meshes. The prepared Ag-Cu composite metal mesh has excellent optoelectronic properties (period 250 μm, line width 10 μm, 90.1% transmission at 550 nm visible light, square resistance 0.21 Ω/sq), efficient electrothermal effect (3 V DC voltage can reach 189 °C steady-state temperature), stable EM-shielding effectiveness (average shielding effectiveness 23 dB at X-band), and acceptable mechanical and environmental stability (less than 3% change in square resistance after 150-times adhesion test and less than 6% and 0.6% change in resistance after 72 h in acid and alkali environments, respectively). This method provides a new solution for the mass production of high-performance large-area transparent electric heating/EM-shielding glass.

带有金属网的透明电磁屏蔽玻璃在不同的电磁辐射和抗电磁干扰透光观察窗领域具有巨大的应用潜力。特别是,具有大纵横比金属网的透明EM屏蔽玻璃可以有效地缓解屏蔽效果和光传输性能约束的矛盾问题。然而,在玻璃基板上制备高纵横比金属网存在成本高、工艺复杂、效率低、面积小、易损坏等问题,限制了其在高性能透明EM屏蔽玻璃领域的应用。因此,本文提出了一种基于电场驱动的微射流3D打印和电镀的复合增材制造工艺。通过在玻璃基板上制造具有Ag-Cu核壳结构的金属网,可以在不增加金属网的纵横比的情况下制造具有高屏蔽效率和光透射的EM屏蔽玻璃。所制备的Ag-Cu复合金属网具有优异的光电性能(周期250μm,线宽10μm,在550nm可见光下90.1%的透射率,方电阻0.21Ω/sq)、高效的电热效应(3V直流电压可达到189°C稳态温度)、稳定的EM屏蔽效果(X波段平均屏蔽效果23dB),以及可接受的机械和环境稳定性(150次粘合试验后方块电阻变化小于3%,在酸性和碱性环境中72小时后电阻变化分别小于6%和0.6%)。该方法为大规模生产高性能大面积透明电热/EM屏蔽玻璃提供了新的解决方案。
{"title":"Additive Manufacturing of Large-scale Metal Mesh with Core-shell Composite Structure for Transparent Electromagnetic Shielding/glass Heater","authors":"Yuping Tai ,&nbsp;Junyi Zhou ,&nbsp;Xiaoyang Zhu ,&nbsp;Houchao Zhang ,&nbsp;Hongke Li ,&nbsp;Zhenghao Li ,&nbsp;Rui Wang ,&nbsp;Fan Zhang ,&nbsp;Guangming Zhang ,&nbsp;Chaohong Liu ,&nbsp;Hongbo Lan","doi":"10.1016/j.cjmeam.2023.100089","DOIUrl":"https://doi.org/10.1016/j.cjmeam.2023.100089","url":null,"abstract":"<div><p>Transparent electromagnetic (EM) shielding glass with a metal mesh has significant potential for application in different fields of EM radiation and anti-EM interference light-transmitting observation windows. In particular, a transparent EM-shielding glass with a large-aspect-ratio metal mesh can effectively alleviate the contradictory problems of shielding effectiveness and light-transmission performance constraints. However, the fabrication of high-aspect-ratio metal meshes on glass substrates has problems such as high cost, complex processes, low efficiency, small area, and easy damage issues, which limit their application in the field of high-performance, transparent EM-shielding glass. Therefore, this paper proposes a composite additive manufacturing process based on electric-field-driven microjet 3D printing and electroplating. By fabricating metal meshes with an Ag-Cu core-shell structure on a glass substrate, EM-shielding glass with high shielding efficiency and light transmission can be manufactured without increasing the aspect ratio of the metal meshes. The prepared Ag-Cu composite metal mesh has excellent optoelectronic properties (period 250 μm, line width 10 μm, 90.1% transmission at 550 nm visible light, square resistance 0.21 Ω/sq), efficient electrothermal effect (3 V DC voltage can reach 189 °C steady-state temperature), stable EM-shielding effectiveness (average shielding effectiveness 23 dB at X-band), and acceptable mechanical and environmental stability (less than 3% change in square resistance after 150-times adhesion test and less than 6% and 0.6% change in resistance after 72 h in acid and alkali environments, respectively). This method provides a new solution for the mass production of high-performance large-area transparent electric heating/EM-shielding glass.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 3","pages":"Article 100089"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49701879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Additive Manufacturing of Continuous Fiber-Reinforced Polymer Composite Sandwich Structures with Multiscale Cellular Cores 多尺度蜂窝芯连续纤维增强聚合物复合材料夹层结构的增材制造
Pub Date : 2023-09-01 DOI: 10.1016/j.cjmeam.2023.100088
Zhenhu Wang , Yaohui Wang , Jian He , Ke Dong , Guoquan Zhang , Wenhao Li , Yi Xiong

The use of composite sandwich structures with cellular cores is prevalent in lightweight designs owing to their superior energy-absorbing abilities. However, current manufacturing processes, such as hot-press molding and mold pressing, require multiple steps and complex tools, thus limiting the exploration of advanced sandwich structure designs. This study reports a novel multi-material additive manufacturing (AM) process that allows the single-step production of continuous fiber-reinforced polymer composite (CFRPC) sandwich structures with multiscale cellular cores. Specifically, the integration of CFRPC-AM and in situ foam AM processes provides effective and efficient fabrication of CFRPC panels and multiscale cellular cores with intricate designs. The cellular core design spans three levels: microcellular, unit-cell, and graded structures. Sandwich structures with a diverse set of unit-cell designs, that is, rhombus, square, honeycomb, and re-entrant honeycomb, were fabricated and their flexural behaviors were studied experimentally. The results showed that the sandwich structure with a rhombus core design possessed the highest flexural stiffness, strength, and specific energy absorption. In addition, the effect of the unit-cell assembly on the flexural performance of the CFRP composite sandwich structure was examined. The proposed design and fabrication methods open new avenues for constructing novel and high-performance CFRPC structures with multiscale cellular cores that cannot be obtained using existing approaches.

具有蜂窝芯的复合材料夹层结构由于其优异的能量吸收能力而在轻质设计中普遍使用。然而,目前的制造工艺,如热压成型和模压,需要多个步骤和复杂的工具,从而限制了对先进夹层结构设计的探索。本研究报告了一种新的多材料增材制造(AM)工艺,该工艺允许一步生产具有多尺度蜂窝芯的连续纤维增强聚合物复合材料(CFRPC)夹层结构。具体而言,CFRPC-AM和原位泡沫AM工艺的集成提供了具有复杂设计的CFRPC面板和多尺度蜂窝芯的有效和高效制造。蜂窝核心设计跨越三个层次:微蜂窝、单元蜂窝和分级结构。制作了一套不同单元设计的夹层结构,即菱形、方形、蜂窝和凹入式蜂窝,并对其弯曲性能进行了实验研究。结果表明,菱形芯设计的夹层结构具有最高的抗弯刚度、强度和比能量吸收。此外,还考察了单元组合对CFRP复合材料夹层结构抗弯性能的影响。所提出的设计和制造方法为构建具有多尺度蜂窝芯的新型高性能CFRPC结构开辟了新的途径,而使用现有方法无法获得这些结构。
{"title":"Additive Manufacturing of Continuous Fiber-Reinforced Polymer Composite Sandwich Structures with Multiscale Cellular Cores","authors":"Zhenhu Wang ,&nbsp;Yaohui Wang ,&nbsp;Jian He ,&nbsp;Ke Dong ,&nbsp;Guoquan Zhang ,&nbsp;Wenhao Li ,&nbsp;Yi Xiong","doi":"10.1016/j.cjmeam.2023.100088","DOIUrl":"https://doi.org/10.1016/j.cjmeam.2023.100088","url":null,"abstract":"<div><p>The use of composite sandwich structures with cellular cores is prevalent in lightweight designs owing to their superior energy-absorbing abilities. However, current manufacturing processes, such as hot-press molding and mold pressing, require multiple steps and complex tools, thus limiting the exploration of advanced sandwich structure designs. This study reports a novel multi-material additive manufacturing (AM) process that allows the single-step production of continuous fiber-reinforced polymer composite (CFRPC) sandwich structures with multiscale cellular cores. Specifically, the integration of CFRPC-AM and in situ foam AM processes provides effective and efficient fabrication of CFRPC panels and multiscale cellular cores with intricate designs. The cellular core design spans three levels: microcellular, unit-cell, and graded structures. Sandwich structures with a diverse set of unit-cell designs, that is, rhombus, square, honeycomb, and re-entrant honeycomb, were fabricated and their flexural behaviors were studied experimentally. The results showed that the sandwich structure with a rhombus core design possessed the highest flexural stiffness, strength, and specific energy absorption. In addition, the effect of the unit-cell assembly on the flexural performance of the CFRP composite sandwich structure was examined. The proposed design and fabrication methods open new avenues for constructing novel and high-performance CFRPC structures with multiscale cellular cores that cannot be obtained using existing approaches.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 3","pages":"Article 100088"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49701820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-fidelity Modeling of Multilayer Building Process in Electron Beam Powder Bed Fusion: Build-quality Prediction and Formation-Mechanism Investigation 电子束粉末床熔合多层构建过程的高保真建模:构建质量预测和形成机制研究
Pub Date : 2023-09-01 DOI: 10.1016/j.cjmeam.2023.100086
Chaochao Wu , Pu Xie , Muhammad Qasim Zafar , Haiyan Zhao

High-fidelity simulations of powder bed fusion (PBF) additive manufacturing have made significant progress over the past decade. In this study, an efficient two-dimensional frame was developed for simulating the electron beam PBF process with hundreds of tracks for the direct prediction of the build quality. The applicable parameter range of the developed model was determined by comparing the heat transfer with that in three-dimensional cases. Subsequently, powder deposition and selective melting were coupled for a continuous simulation of the multilayer process. Three powder deposition models were utilized to generate random powder particles, and their effects on the packing structure and the resultant simulated build quality were investigated. The predicted build quality was validated using experimental results from independent studies. By reproducing the building process, the defect development mechanism in a multilayer process was revealed for the coalescence behaviors of randomly distributed powder particles, which also confirmed the importance of simulation at the high-fidelity powder scale. The effects of key process parameters during multilayer and multi-track processes on the build quality were systematically investigated. In particular, the formation statuses of all tracks during the simulated building process were recorded and analyzed statistically, which provided crucial information on the printing process for understanding the building mechanism or performing uncertainty analysis.

在过去的十年里,粉末床聚变(PBF)增材制造的高保真度模拟取得了重大进展。在这项研究中,开发了一个有效的二维框架来模拟具有数百个轨道的电子束PBF过程,用于直接预测构建质量。通过与三维情况下的传热比较,确定了所开发模型的适用参数范围。随后,将粉末沉积和选择性熔融相结合,对多层工艺进行连续模拟。利用三个粉末沉积模型生成随机粉末颗粒,并研究了它们对填料结构和模拟构建质量的影响。使用独立研究的实验结果验证了预测的构建质量。通过再现构建过程,揭示了随机分布的粉末颗粒聚结行为在多层过程中的缺陷发展机制,这也证实了高保真度粉末尺度模拟的重要性。系统地研究了多层和多轨道工艺中关键工艺参数对构建质量的影响。特别是,对模拟建造过程中所有轨道的形成状态进行了记录和统计分析,为了解建造机理或进行不确定性分析提供了有关印刷过程的关键信息。
{"title":"High-fidelity Modeling of Multilayer Building Process in Electron Beam Powder Bed Fusion: Build-quality Prediction and Formation-Mechanism Investigation","authors":"Chaochao Wu ,&nbsp;Pu Xie ,&nbsp;Muhammad Qasim Zafar ,&nbsp;Haiyan Zhao","doi":"10.1016/j.cjmeam.2023.100086","DOIUrl":"https://doi.org/10.1016/j.cjmeam.2023.100086","url":null,"abstract":"<div><p>High-fidelity simulations of powder bed fusion (PBF) additive manufacturing have made significant progress over the past decade. In this study, an efficient two-dimensional frame was developed for simulating the electron beam PBF process with hundreds of tracks for the direct prediction of the build quality. The applicable parameter range of the developed model was determined by comparing the heat transfer with that in three-dimensional cases. Subsequently, powder deposition and selective melting were coupled for a continuous simulation of the multilayer process. Three powder deposition models were utilized to generate random powder particles, and their effects on the packing structure and the resultant simulated build quality were investigated. The predicted build quality was validated using experimental results from independent studies. By reproducing the building process, the defect development mechanism in a multilayer process was revealed for the coalescence behaviors of randomly distributed powder particles, which also confirmed the importance of simulation at the high-fidelity powder scale. The effects of key process parameters during multilayer and multi-track processes on the build quality were systematically investigated. In particular, the formation statuses of all tracks during the simulated building process were recorded and analyzed statistically, which provided crucial information on the printing process for understanding the building mechanism or performing uncertainty analysis.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 3","pages":"Article 100086"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49701788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D Printing Technology for Short-continuous Carbon Fiber Synchronous Reinforced Thermoplastic Composites: A Comparison between Towpreg Extrusion and In Situ Impregnation Processes 短连续碳纤维同步增强热塑性复合材料的3D打印技术——Towpreg挤出和原位浸渍工艺的比较
Pub Date : 2023-09-01 DOI: 10.1016/j.cjmeam.2023.100092
Fuji Wang , Gongshuo Wang , Hongquan Wang , Rao Fu , Yajing Lei , Jianing He

Three-dimensional (3D) printing of carbon fiber-reinforced thermoplastic composites (CFRTPs) provides an effective method for manufacturing the CFRTPs parts with complex structures. To increase the mechanical performance of these parts, a 3D printing technology for short-continuous carbon fiber synchronous-reinforced thermoplastic composites (S/C-CFRTPs) has been proposed. However, the synchronous reinforcement that existed only at particular positions led to a limited improvement in the mechanical performance of the 3D-printed S/C-CFRTP part, which made it challenging to meet the engineering requirements. To solve this problem, two methods for achieving synchronous reinforcement at all the positions of the 3D-printed S/C-CFRTP part are proposed. To determine a suitable printing process for the S/C-CFRTP part, a comprehensive comparison between the two methods was conducted through theoretical analysis and experimental verification, involving the printing mechanism, fiber content, impregnation percentage, and mechanical performance. The results indicated that the towpreg extrusion process was suitable for manufacturing the 3D-printed S/C-CFRTP part. Compared with the in situ impregnation process, the towpreg extrusion process led to a fiber content increase of approximately 7% and void rate reduction of approximately 6%, resulting in 19% and 20% increases in the tensile and flexural strengths of the 3D-printed S/C-CFRTPs, respectively. Additionally, an optimized process parameter setting for fabricating an S/C-CFRTP prepreg filament with excellent mechanical performance was proposed. The findings of this study can provide a new approach for further improving the mechanical performance of the 3D-printed advanced composites.

碳纤维增强热塑性复合材料(CFRTP)的三维(3D)打印为制造具有复杂结构的CFRTP零件提供了一种有效的方法。为了提高这些零件的力学性能,提出了一种短连续碳纤维同步增强热塑性复合材料(S/C-CFRTP)的3D打印技术。然而,仅存在于特定位置的同步补强导致3D打印S/C-CFRTP零件的机械性能得到有限的改善,这使得满足工程要求具有挑战性。为了解决这个问题,提出了两种在3D打印S/C-CFRTP零件的所有位置实现同步加固的方法。为了确定S/C-CFRTP零件的合适印刷工艺,通过理论分析和实验验证,对两种方法进行了全面的比较,包括印刷机理、纤维含量、浸渍率和机械性能。结果表明,丝束预浸料挤出工艺适用于制造3D打印S/C-CFRTP零件。与原位浸渍工艺相比,丝束预浸料挤出工艺使纤维含量增加了约7%,空隙率降低了约6%,使3D打印的S/C-CFRTP的拉伸和弯曲强度分别提高了19%和20%。此外,还提出了制备具有优异机械性能的S/C-CFRTP预浸料长丝的优化工艺参数设置。这项研究的发现可以为进一步提高3D打印先进复合材料的力学性能提供一种新的方法。
{"title":"3D Printing Technology for Short-continuous Carbon Fiber Synchronous Reinforced Thermoplastic Composites: A Comparison between Towpreg Extrusion and In Situ Impregnation Processes","authors":"Fuji Wang ,&nbsp;Gongshuo Wang ,&nbsp;Hongquan Wang ,&nbsp;Rao Fu ,&nbsp;Yajing Lei ,&nbsp;Jianing He","doi":"10.1016/j.cjmeam.2023.100092","DOIUrl":"https://doi.org/10.1016/j.cjmeam.2023.100092","url":null,"abstract":"<div><p>Three-dimensional (3D) printing of carbon fiber-reinforced thermoplastic composites (CFRTPs) provides an effective method for manufacturing the CFRTPs parts with complex structures. To increase the mechanical performance of these parts, a 3D printing technology for short-continuous carbon fiber synchronous-reinforced thermoplastic composites (S/C-CFRTPs) has been proposed. However, the synchronous reinforcement that existed only at particular positions led to a limited improvement in the mechanical performance of the 3D-printed S/C-CFRTP part, which made it challenging to meet the engineering requirements. To solve this problem, two methods for achieving synchronous reinforcement at all the positions of the 3D-printed S/C-CFRTP part are proposed. To determine a suitable printing process for the S/C-CFRTP part, a comprehensive comparison between the two methods was conducted through theoretical analysis and experimental verification, involving the printing mechanism, fiber content, impregnation percentage, and mechanical performance. The results indicated that the towpreg extrusion process was suitable for manufacturing the 3D-printed S/C-CFRTP part. Compared with the <em>in situ</em> impregnation process, the towpreg extrusion process led to a fiber content increase of approximately 7% and void rate reduction of approximately 6%, resulting in 19% and 20% increases in the tensile and flexural strengths of the 3D-printed S/C-CFRTPs, respectively. Additionally, an optimized process parameter setting for fabricating an S/C-CFRTP prepreg filament with excellent mechanical performance was proposed. The findings of this study can provide a new approach for further improving the mechanical performance of the 3D-printed advanced composites.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 3","pages":"Article 100092"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49728958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Customized Design for Ergonomic Products via Additive Manufacturing Considering Joint Biomechanics 考虑关节生物力学的增材制造人体工学产品定制设计
Pub Date : 2023-09-01 DOI: 10.1016/j.cjmeam.2023.100085
Jinghua Xu , Zhengxin Tu , Shuyou Zhang , Jianrong Tan , Guanyun Wang

This paper presents a customized design method for ergonomic products via additive manufacturing (AM) considering joint biomechanics. An ergonomic customized design model can be built based on kinesiology involving human joint biomechanics. Manifolds of the human bone can be reconstructed from X-rays, computed tomography (CT), magnetic resonance imaging (MRI), and direct 3D scanning. The conceptual and detailed design of customized products were implemented on ergonomic shoes and insoles. A lightweight lattice structure with variable porosity was generated via structural topology optimization for an ergonomic customized design. Notably, the upper surface of the custom-made insole may adhere perfectly to the plantar surface of the patient, resulting in a lower peak plantar pressure. Finite element analysis (FEA) can be employed to simulate the static or dynamic biomechanical characteristics. The conceptual ergonomic products were forwarded to the machine and fabricated via AM, driven by visual digital twin techniques. The experiments proved that a customized design suitability method for wearable ergonomic products via 3D printing is specifically tailored to the rehabilitation needs of individual customers, while consuming the least cost, time, and materials.

本文提出了一种基于关节生物力学的增材制造(AM)人体工程学产品定制设计方法。人体工程学定制设计模型可以建立在涉及人体关节生物力学的运动学基础上。人体骨骼的歧管可以通过X射线、计算机断层扫描(CT)、磁共振成像(MRI)和直接3D扫描重建。定制产品的概念和详细设计是在符合人体工程学的鞋子和鞋垫上实现的。通过结构拓扑优化,为符合人体工程学的定制设计生成了具有可变孔隙率的轻质晶格结构。值得注意的是,定制鞋垫的上表面可以完美地粘附到患者的足底表面,从而导致更低的足底压力峰值。有限元分析(FEA)可用于模拟静态或动态生物力学特性。概念上的人体工程学产品被转发到机器上,并通过AM制造,由视觉数字孪生技术驱动。实验证明,通过3D打印为可穿戴人体工程学产品定制的设计适用性方法是专门为个人客户的康复需求量身定制的,同时消耗最少的成本、时间和材料。
{"title":"Customized Design for Ergonomic Products via Additive Manufacturing Considering Joint Biomechanics","authors":"Jinghua Xu ,&nbsp;Zhengxin Tu ,&nbsp;Shuyou Zhang ,&nbsp;Jianrong Tan ,&nbsp;Guanyun Wang","doi":"10.1016/j.cjmeam.2023.100085","DOIUrl":"https://doi.org/10.1016/j.cjmeam.2023.100085","url":null,"abstract":"<div><p>This paper presents a customized design method for ergonomic products via additive manufacturing (AM) considering joint biomechanics. An ergonomic customized design model can be built based on kinesiology involving human joint biomechanics. Manifolds of the human bone can be reconstructed from X-rays, computed tomography (CT), magnetic resonance imaging (MRI), and direct 3D scanning. The conceptual and detailed design of customized products were implemented on ergonomic shoes and insoles. A lightweight lattice structure with variable porosity was generated via structural topology optimization for an ergonomic customized design. Notably, the upper surface of the custom-made insole may adhere perfectly to the plantar surface of the patient, resulting in a lower peak plantar pressure. Finite element analysis (FEA) can be employed to simulate the static or dynamic biomechanical characteristics. The conceptual ergonomic products were forwarded to the machine and fabricated via AM, driven by visual digital twin techniques. The experiments proved that a customized design suitability method for wearable ergonomic products via 3D printing is specifically tailored to the rehabilitation needs of individual customers, while consuming the least cost, time, and materials.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 3","pages":"Article 100085"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49701789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D/4D Printed Functional Continuous Fiber-reinforced Polymer Composites: Progress and Perspectives 3D/4D打印功能连续纤维增强聚合物复合材料:进展与展望
Pub Date : 2023-09-01 DOI: 10.1016/j.cjmeam.2023.100090
Ping Cheng , Shixian Li , Yong Peng , Antoine Le Duigou , Kui Wang , Said Ahzi

In recent years, innovations in 3D/4D printing techniques for continuous fiber-reinforced polymer composites (CFRPCs) have opened new perspectives for the integrated design and manufacture of composites with customized functions. This paper reviews the current state of 3D/4D printed functional composites, including the materials, shape memory/changing effects, self-monitoring/healing behaviors, and challenges surrounding additive-manufactured functional composites. Specifically, continuous fibers and matrices that provide functional roles are classified and discussed in detail. 4D printed shape memory and changing CFRPCs can retain their original shapes from a designed shape upon exposure to different external stimuli, including heat, electricity, humidity, and multi-stimuli activation. Furthermore, self-monitoring of structural health is achieved through the piezoresistive features of reinforced fibers in 3D printed CFRPCs. Finally, this review concludes with an outlook on the future research opportunities for 3D/4D printed functional CFRPCs.

近年来,连续纤维增强聚合物复合材料3D/4D打印技术的创新为具有定制功能的复合材料的集成设计和制造开辟了新的视角。本文综述了3D/4D打印功能复合材料的现状,包括材料、形状记忆/改变效应、自我监测/愈合行为,以及添加剂制造的功能复合材料面临的挑战。具体而言,对提供功能作用的连续纤维和基质进行了分类和详细讨论。4D打印的形状记忆和变化的CFRPC在暴露于不同的外部刺激(包括热、电、湿度和多刺激激活)时可以从设计的形状保持其原始形状。此外,通过3D打印的CFRPC中增强纤维的压阻特性,可以实现结构健康的自我监测。最后,本文对3D/4D打印功能性CFRPC的未来研究机会进行了展望。
{"title":"3D/4D Printed Functional Continuous Fiber-reinforced Polymer Composites: Progress and Perspectives","authors":"Ping Cheng ,&nbsp;Shixian Li ,&nbsp;Yong Peng ,&nbsp;Antoine Le Duigou ,&nbsp;Kui Wang ,&nbsp;Said Ahzi","doi":"10.1016/j.cjmeam.2023.100090","DOIUrl":"https://doi.org/10.1016/j.cjmeam.2023.100090","url":null,"abstract":"<div><p>In recent years, innovations in 3D/4D printing techniques for continuous fiber-reinforced polymer composites (CFRPCs) have opened new perspectives for the integrated design and manufacture of composites with customized functions. This paper reviews the current state of 3D/4D printed functional composites, including the materials, shape memory/changing effects, self-monitoring/healing behaviors, and challenges surrounding additive-manufactured functional composites. Specifically, continuous fibers and matrices that provide functional roles are classified and discussed in detail. 4D printed shape memory and changing CFRPCs can retain their original shapes from a designed shape upon exposure to different external stimuli, including heat, electricity, humidity, and multi-stimuli activation. Furthermore, self-monitoring of structural health is achieved through the piezoresistive features of reinforced fibers in 3D printed CFRPCs. Finally, this review concludes with an outlook on the future research opportunities for 3D/4D printed functional CFRPCs.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 3","pages":"Article 100090"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49701875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Heat-treated Nickel Alloys Produced Using Laser Powder Bed Fusion-based Additive Manufacturing Methods: A Review 基于激光粉末床熔敷的增材制造技术制备热处理镍合金的研究进展
Pub Date : 2023-09-01 DOI: 10.1016/j.cjmeam.2023.100087
Aman Dwivedi, M K Khurana, Y G Bala

Laser powder bed fusion (LPBF) is the most widely used metal additive manufacturing process. It is a novel layer-by-layer manufacturing technique based on a geometrical model that provides a suitable alternative for material processing. This mode is widely used in laser and electron beam welding. Nickel (Ni) alloy preparation using the LPBF method has attracted considerable attention in several areas, owing to the high corrosion resistance and good mechanical properties of the prepared alloys. The specific conditions of solidification through the metal fused during the selective laser fusion process and its layer deposition induces microstructural peculiarities, including the formation of a supersaturated solid solution,extreme microstructural refinement, and the generation of residual stress. Consequently, heat treatment and hot isostatic pressing, which are generally applied to conventionally manufactured Ni alloys, may need to be altered to adapt to the metallurgical properties of Ni alloys manufactured using direct metal laser deposition and address particular issues resulting from the process itself. Several studies have been conducted on this topic over the past few years, suggesting different approaches for addressing different alloying systems. This review summarizes the latest scientific findings in the area of thermal treatment for selective laser sintering of additively manufactured Ni alloys.

激光粉末床熔融(LPBF)是应用最广泛的金属增材制造工艺。这是一种基于几何模型的新型逐层制造技术,为材料加工提供了合适的替代方案。这种模式广泛应用于激光和电子束焊接。使用LPBF方法制备镍(Ni)合金由于其高耐腐蚀性和良好的机械性能而在多个领域引起了相当大的关注。在选择性激光熔接过程中熔接的金属凝固的特定条件及其层沉积引起了微观结构的特殊性,包括过饱和固溶体的形成、极端的微观结构细化和残余应力的产生。因此,通常应用于传统制造的镍合金的热处理和热等静压可能需要改变,以适应使用直接金属激光沉积制造的镍的冶金性能,并解决由工艺本身产生的特定问题。在过去的几年里,已经就这一主题进行了几项研究,提出了解决不同合金体系的不同方法。这篇综述总结了在选择性激光烧结添加制造的镍合金的热处理领域的最新科学发现。
{"title":"Heat-treated Nickel Alloys Produced Using Laser Powder Bed Fusion-based Additive Manufacturing Methods: A Review","authors":"Aman Dwivedi,&nbsp;M K Khurana,&nbsp;Y G Bala","doi":"10.1016/j.cjmeam.2023.100087","DOIUrl":"https://doi.org/10.1016/j.cjmeam.2023.100087","url":null,"abstract":"<div><p>Laser powder bed fusion (LPBF) is the most widely used metal additive manufacturing process. It is a novel layer-by-layer manufacturing technique based on a geometrical model that provides a suitable alternative for material processing. This mode is widely used in laser and electron beam welding. Nickel (Ni) alloy preparation using the LPBF method has attracted considerable attention in several areas, owing to the high corrosion resistance and good mechanical properties of the prepared alloys. The specific conditions of solidification through the metal fused during the selective laser fusion process and its layer deposition induces microstructural peculiarities, including the formation of a supersaturated solid solution,extreme microstructural refinement, and the generation of residual stress. Consequently, heat treatment and hot isostatic pressing, which are generally applied to conventionally manufactured Ni alloys, may need to be altered to adapt to the metallurgical properties of Ni alloys manufactured using direct metal laser deposition and address particular issues resulting from the process itself. Several studies have been conducted on this topic over the past few years, suggesting different approaches for addressing different alloying systems. This review summarizes the latest scientific findings in the area of thermal treatment for selective laser sintering of additively manufactured Ni alloys.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 3","pages":"Article 100087"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49701786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D-printed Metamaterials with Versatile Functionalities 具有多功能的3d打印超材料
Pub Date : 2023-09-01 DOI: 10.1016/j.cjmeam.2023.100091
Lingling Wu, Jiacheng Xue, Xiaoyong Tian, Tengfei Liu, Dichen Li

Metamaterials are artificial structures that have been engineered to exhibit properties that do not occur naturally in conventional materials. They were firstly made up of periodic unit cells that interact with electromagnetic (EM) waves to manipulate their behavior, showing extraordinary phenomena like EM cloaking, negative index, beam deflection and so on. In recent years, the concept of metamaterial has been penetrating in various physical domain and various metamaterials with versatile functionalities have been proposed and fabricated by 3D printing technology to manipulate the interactions between matter and electromagnetic, thermal, acoustic, and mechanical energy. With the increasing of structural complexity, material types, precision additive manufacturing serve as a powerful tool to achieve novel metamaterials with extraordinary performance and fusion of functionalities. In this paper, we reviewed the remarkable properties enabled by 3D printed metamaterials in different fields, and analyzed the consilience relationship between structure, function, and manufacturing process.

超材料是一种人工结构,经过设计,其性能与传统材料不同。它们最初是由周期性的单元细胞组成的,这些单元细胞与电磁波相互作用以操纵它们的行为,表现出EM掩蔽、负指数、光束偏转等异常现象。近年来,超材料的概念已经渗透到各个物理领域,并且已经提出并通过3D打印技术制造了各种具有多功能的超材料,以操纵物质与电磁能、热能、声学和机械能之间的相互作用。随着结构复杂性、材料类型的增加,精密增材制造成为实现具有非凡性能和功能融合的新型超材料的有力工具。在本文中,我们回顾了3D打印超材料在不同领域所具有的显著性能,并分析了结构、功能和制造工艺之间的一致性关系。
{"title":"3D-printed Metamaterials with Versatile Functionalities","authors":"Lingling Wu,&nbsp;Jiacheng Xue,&nbsp;Xiaoyong Tian,&nbsp;Tengfei Liu,&nbsp;Dichen Li","doi":"10.1016/j.cjmeam.2023.100091","DOIUrl":"https://doi.org/10.1016/j.cjmeam.2023.100091","url":null,"abstract":"<div><p>Metamaterials are artificial structures that have been engineered to exhibit properties that do not occur naturally in conventional materials. They were firstly made up of periodic unit cells that interact with electromagnetic (EM) waves to manipulate their behavior, showing extraordinary phenomena like EM cloaking, negative index, beam deflection and so on. In recent years, the concept of metamaterial has been penetrating in various physical domain and various metamaterials with versatile functionalities have been proposed and fabricated by 3D printing technology to manipulate the interactions between matter and electromagnetic, thermal, acoustic, and mechanical energy. With the increasing of structural complexity, material types, precision additive manufacturing serve as a powerful tool to achieve novel metamaterials with extraordinary performance and fusion of functionalities. In this paper, we reviewed the remarkable properties enabled by 3D printed metamaterials in different fields, and analyzed the consilience relationship between structure, function, and manufacturing process.</p></div>","PeriodicalId":100243,"journal":{"name":"Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers","volume":"2 3","pages":"Article 100091"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49701915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Chinese Journal of Mechanical Engineering: Additive Manufacturing Frontiers
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1