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Compressed air and hydrogen storage experimental facilities for sustainable energy storage technologies at Yunlong Lake Laboratory (CAPABLE) 云龙湖实验室可持续储能技术压缩空气和储氢实验设施
IF 5 Pub Date : 2025-06-25 DOI: 10.1002/dug2.70043
Xiaozhao Li, Yukun Ji, Kai Zhang, Chengguo Hu, Jianguo Wang, Lixin He, Lihua Hu, Bangguo Jia

In March 2022, construction was started at Yunlong Lake Laboratory of Deep Underground Science and Engineering, China, on an underground gas storage experimental facility with the capacity to achieve composite structure design and material development. Underground gas storage can provide a solution to address the intermittency of renewable energy supply. Currently, lined rock caverns (LRCs) are regarded as the best option for compressed air and hydrogen storage, since they have excellent sealing properties and minimum environmental impacts. However, the load transfer, damage, and failure mechanisms of LRCs are not clear. This prevents the design and selection of mechanical structures. Particularly, the gas sealing capacity in specific gas conditions (e.g., stored hydrogen-induced chemical reaction) remains poorly understood, and advanced materials to adapt the storage conditions of different gases should be developed. This experimental facility aims at providing a solution to these technical issues. This facility has several different types of LRCs, and study of the mechanical behavior of various structures and evaluation of the gas-tight performance of the sealing material can be carried out using a distributed fiberoptic sensing approach. The focus of this study is on the challenges in sealing material development and structure design. This facility facilitates large-scale and long-term energy storage for stable and continuous energy supply, and enables repurposing of underground space and acceleration of the realization of green energy ambitions in the context of Paris Agreement and China's carbon neutralization plan.

2022年3月,中国深地下科学与工程云龙湖实验室开始建设地下储气库实验设施,具有实现复合结构设计和材料开发的能力。地下储气库可以为解决可再生能源供应的间歇性提供一种解决方案。目前,内衬岩洞(lrc)被认为是压缩空气和氢气储存的最佳选择,因为它们具有优异的密封性能和最小的环境影响。然而,lrc的载荷传递、损伤和破坏机制尚不清楚。这就妨碍了机械结构的设计和选择。特别是,在特定气体条件下(如储存氢诱导的化学反应)的气体密封能力仍然知之甚少,需要开发适应不同气体储存条件的先进材料。该实验设施旨在为这些技术问题提供解决方案。该设施有几种不同类型的lrc,可以使用分布式光纤传感方法研究各种结构的力学行为和评估密封材料的气密性能。本研究的重点是密封材料开发和结构设计的挑战。该设施有助于大规模和长期的能源储存,以实现稳定和持续的能源供应,并在巴黎协定和中国碳中和计划的背景下实现地下空间的再利用和加速实现绿色能源的雄心。
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引用次数: 0
Tri-axial compressive behavior of high-water material for deep underground spaces 深埋地下空间高水材料的三轴压缩特性
IF 5 Pub Date : 2025-06-16 DOI: 10.1002/dug2.70040
Honglin Liu, Yang Xia, Jianbiao Bai, Zhongzong Cao, Zizheng Zhang, Hongchao Zhao

Attributed to its superior water-to-solid ratio and quick setting time, the high-water material is widely adopted in underground spaces as a cost-effective and environmentally friendly backfill material. To elucidate the bleeding mechanism of high-water material under the high confining pressure, a total of 57 tubular specimens were prepared and tested, critical parameters of which included the water-to-solid ratio, curing time, and lateral confinement pressure. Test results showed that no obvious cracks were observed from the surface of confined high-water material, which is different from that of unconfined high-water material, which featured shear cracks. Moreover, the volume of these confined high-water materials under compaction exhibited a continuous shrinkage associated with the water bleeding. The threshold values of the water bleeding are significantly affected by the water-to-solid ratio, followed by the confining pressure and curing time. When other parameters are constant, the higher confinement is requested for these specimens with a small water-to-solid ratio. Meanwhile, the mass of bleeding water increased with the lateral confinement, showing a quick increase at the initial stage. During the bleeding process, the free water stored in the pores was compacted, the evidence of which is the transformation of the hydration products (calcium aluminate hydrate) from its natural fibrous structure into the rod-shaped or dense agglomerate structures. These research outcomes provide an in-depth insight into the fundamental mechanics of the high-water material under the high lateral confinement when it is used for underground spaces.

由于其优越的水固比和快速的凝结时间,高水位材料作为一种经济环保的回填材料被广泛应用于地下空间。为阐明高围压条件下高水材料的泄水机理,采用水固比、养护时间、侧围压等关键参数,制备了57个管状试件并进行了试验。试验结果表明,承压高水位材料表面未观察到明显的裂缝,而非承压高水位材料表面则以剪切裂缝为主。此外,这些受限高水材料在压实作用下的体积表现出与水出血相关的连续收缩。水固比对水出血阈值的影响显著,其次是围压和养护时间。当其他参数不变时,对于水固比较小的试样,要求较高的约束。同时,泌水质量随着侧卧的增加而增加,且在初始阶段增加较快。在出血性过程中,孔隙中储存的自由水被压实,其证据是水化产物(水合铝酸钙)由其天然纤维结构转变为棒状或致密的团块结构。这些研究成果提供了对高侧向约束下高水位材料用于地下空间的基本力学的深入了解。
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引用次数: 0
Damage modeling of CO2 injection well interfaces under coupled thermal, hydraulic and mechanical behavior 热、水力和力学耦合作用下CO2注水井界面损伤建模
IF 5 Pub Date : 2025-05-28 DOI: 10.1002/dug2.70014
Lee J. Hosking, Xiangming Zhou

This paper presents an investigation of well integrity during low-temperature CO2 injection using a model of thermo-poroelasticity with interface damage mechanics. The casing–cement and cement–formation interfaces are described using cohesive interface elements and a bilinear traction–separation law. Verification testing is performed to establish the correct implementation of the coupled thermal, hydraulic, and mechanical equations. Simulation scenarios are developed to determine well interface damage initiation and development for intact wells and wells with an initial defect in the form of a 45� � ° debonded azimuth. Each intact and defective well was simulated for 30 days of CO2 injection at selected temperatures. Under the conditions considered, tensile radial stress developed at both the casing–cement and cement–formation interfaces. Hoop stress in the cement sheath remained compressive after 30 days but with reduced magnitude at the lower injection temperature, indicating greater risk of tensile stress and radial cracking as the injection temperature was reduced. Damage occurred in two of four scenarios considered, namely, the intact and defective wells at an injection temperature of 10� � °� � C, and was limited to the casing–cement interface, with no damage to the cement–formation interface. Inclusion of the pre-existing defect led to earlier damage initiation, at 2.75 days compared to 4 days, and produced a microannulus with over double the peak aperture at 0.077 mm compared to 0.037 mm. These findings emphasize the importance of accounting for initial defects and damage evolution when investigating the integrity of CO2 injection wells.

本文采用含界面损伤力学的热孔弹性模型,研究了低温CO2注入过程中油井的完整性。使用内聚界面元素和双线性牵引分离定律描述了套管-水泥和水泥-地层界面。进行验证测试以建立正确的耦合热、水力和力学方程的实现。开发了模拟场景,以确定完整井和初始缺陷为45°脱粘方位角的井的井界面损伤发生和发展情况。在选定的温度下,对每口完好和有缺陷的井进行了30天的CO2注入模拟。在此条件下,套管-水泥和水泥-地层界面均出现径向拉应力。30天后,水泥环中的环向应力仍保持压缩状态,但在较低的注入温度下,环向应力的大小有所减小,这表明随着注入温度的降低,出现拉应力和径向开裂的风险更大。在注入温度为10℃的四种情况中,完好井和缺陷井发生了两种破坏,并且只限于套管-水泥界面,没有对水泥-地层界面造成破坏。先前存在的缺陷的加入导致了更早的损伤发生时间(2.75天),而不是4天,并且产生了一个微环,其峰值孔径为0.077 mm,是0.037 mm的两倍多。这些发现强调了在研究二氧化碳注水井完整性时,考虑初始缺陷和损伤演变的重要性。
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引用次数: 0
Gels for CO2 geo-storage and conformance control: A systemic review of behavior and performance 用于CO2地质储存和一致性控制的凝胶:行为和性能的系统回顾
IF 5 Pub Date : 2025-05-28 DOI: 10.1002/dug2.70027
Funsho Afolabi, Iskandar Dzulkarnain, Sunil Kwon, Dmitriy A. Martyushev, Jang H. Lee, Shiferaw R. Jufar, Fahd Al-Akbari

Carbon capture and storage (CCS) remains one of the most feasible techniques for the control of Greenhouse gas emission levels. However, there will always be risks attached to the subsurface injection of CO2. These could be in the form of leakages from the injection wellbore due to completion failure; escape of the injected CO2 to neighboring aquifers due to the heterogeneous or fractured nature of the storage site; or seepage at the surface due to inadequacy of the sealing cap rock. While all these may occur, the most cost-effective and timely way to reduce the risk of leakages is by plugging the pathways. This is done using either traditional Cementous materials or more augmented sealants like organic gels and resins. A lot of studies in the literature have described this collection of materials within the context of CO2 conformance control. So also, there are reviews on the classification and description of these chemicals. This review provides a more systemic evaluation of these classes of chemicals. This is by providing critical analyses of how external factors like CO2, pH, brine salinity and hardness, rock mineralogy, pressure, temperature, and injectivity could affect the performance of different sealants that can be utilized. Based on these assessments, best practices for the application of the sealants, both at the testing stage in the laboratory and the pilot stage and field deployment, are suggested.

碳捕集与封存技术(CCS)仍然是控制温室气体排放水平最可行的技术之一。然而,向地下注入二氧化碳总是有风险的。这些问题可能是由于完井失败导致注入井眼泄漏;由于储存地点的非均匀性或裂缝性,注入的二氧化碳逸出到邻近的含水层;或由于密封盖层不充分导致地表渗漏。虽然所有这些都可能发生,但减少泄漏风险的最具成本效益和最及时的方法是堵塞管道。这可以使用传统的胶凝材料或有机凝胶和树脂等增强型密封剂来完成。许多文献中的研究都在二氧化碳一致性控制的背景下描述了这些材料的收集。还有关于这些化学物质的分类和描述的综述。这篇综述对这类化学品进行了更系统的评价。这是通过对CO2、pH、盐水盐度和硬度、岩石矿物学、压力、温度和注入性等外部因素如何影响不同密封胶性能的关键分析来实现的。根据这些评估,建议了在实验室测试阶段、试点阶段和现场部署阶段应用密封剂的最佳做法。
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引用次数: 0
Review of artificial intelligence applications in geothermal energy extraction from hot dry rock 人工智能在干热岩地热能开采中的应用综述
IF 5 Pub Date : 2025-05-09 DOI: 10.1002/dug2.70018
Kun Ji, Hong Li, Yu Zhao, Kaoshan Dai, Sai Liu, Chun'an Tang

The geothermal resources in hot dry rock (HDR) are considered the future trend in geothermal energy extraction due to their abundant reserves. However, exploitation of the resources is fraught with complexity and technical challenges arising from their unique characteristics of high temperature, high strength, and low permeability. With the continuous advancement of artificial intelligence (AI) technology, intelligent algorithms such as machine learning and evolutionary algorithms are gradually replacing or assisting traditional research methods, providing new solutions for HDR geothermal resource exploitation. This study first provides an overview of HDR geothermal resource exploitation technologies and AI methods. Then, the latest research progress is systematically reviewed in AI applications in HDR geothermal reservoir characterization, deep drilling, heat production, and operational parameter optimization. Additionally, this study discusses the potential limitations of AI methods in HDR geothermal resource exploitation and highlights the corresponding opportunities for AI's application. Notably, the study proposes the framework of an intelligent HDR exploitation system, offering a valuable reference for future research and practice.

干热岩地热资源以其丰富的储量被认为是地热能源开发的未来趋势。然而,由于其高温、高强、低渗等特点,其开发难度较大,技术难度较大。随着人工智能技术的不断进步,机器学习、进化算法等智能算法正在逐步取代或辅助传统的研究方法,为HDR地热资源开发提供新的解决方案。本研究首先概述了HDR地热资源开发技术和人工智能方法。系统综述了人工智能在HDR地热储层表征、深钻、采热、操作参数优化等方面的最新研究进展。此外,本研究还讨论了人工智能方法在HDR地热资源开发中的潜在局限性,并强调了人工智能应用的相应机会。值得注意的是,本文提出了智能HDR开发系统的框架,为未来的研究和实践提供了有价值的参考。
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引用次数: 0
Groundwater and stability in deep mining 地下水与深部开采稳定性
Pub Date : 2025-05-05 DOI: 10.1002/dug2.70025
Wanghua Sui, Jianguo Wang
<p><i>Deep Underground Science and Engineering</i> (DUSE) is pleased to present this special issue on Groundwater and Stability in Deep Mining. As mining operations progress to greater depths to meet the growing global demand for mineral resources and energy, the challenges associated with groundwater control and rock mass stability have grown increasingly critical. These challenges are exacerbated by complex geological conditions, structural heterogeneity, and intense mining-induced disturbances. This special issue seeks to address these challenges by showcasing cutting-edge research and technological advancements in the field.</p><p>This special issue features a collection of 12 articles (seven articles for this special theme and five articles for regular submission) exploring diverse aspects of groundwater and rock stability in deep mining. The contributions span a broad range of topics, from experimental investigations of thermo-mechanical properties of cement grouts to comprehensive reviews of shear behaviors in bolted rock joints under varying stress conditions, along with field-based studies on grout propagation in engineering applications. One article (Title: Field investigation of grout propagation within a caving mass under flowing water condition in a metal mine, DOI:10.1002/dug2.70001) is particularly noteworthy, examining the complex dynamics of grout propagation within a metal mine's caving mass under active water flow conditions. This study provides critical insights for mitigating water–sand mixture inrush hazards and advancing mining safety practices. Another article (Title: A comprehensive review of experimental studies on shear behavior of bolted rock joints with varying rock joint and bolt parameters and normal stress, DOI:10.1002/dug2.12091) presents a systematic review of experimental investigations into shear behaviors of bolted rock joints, emphasizing the effects of joint roughness coefficient (JRC) and normal stress on shear strength. Further study analyzes permeability coefficient variations in soil-rock mixtures within fault zones under varying stress states, establishing quantitative relationships between permeability coefficients and stress conditions (Title: Study on the variation of the permeability coefficient of soil-rock mixtures in fault zones under different stress states, DOI:10.1002/dug2.12100).</p><p>This special issue further encompasses several critical investigations, including: (1) the thermal degradation effects on cement grout properties in deep rock grouting applications under elevated ground temperatures (Title: Effects of elevated ground temperatures on properties of cement grouts for deep rock grouting, DOI:10.1002/dug2.12073); (2) the characteristic evolution of in situ stress fields and associated rock mechanical property alterations in deep mining environments (Title: A comprehensive study on in situ stress field characteristics and changes in rock mechanical properties in deep mines in northea
深地下科学与工程(DUSE)很高兴地发表了这篇关于深部开采地下水和稳定性的特刊。随着采矿作业向更深的深度发展,以满足全球对矿产资源和能源日益增长的需求,与地下水控制和岩体稳定有关的挑战变得越来越严峻。复杂的地质条件、结构非均质性和剧烈的采矿引起的扰动加剧了这些挑战。本期特刊旨在通过展示该领域的前沿研究和技术进步来应对这些挑战。本期特刊收录了12篇文章(7篇为专题文章,5篇为定期投稿文章),探讨了深部开采中地下水和岩石稳定性的各个方面。他们的贡献涵盖了广泛的主题,从水泥灌浆的热力学特性的实验研究,到不同应力条件下锚固岩石节理剪切行为的综合综述,以及工程应用中灌浆扩展的现场研究。其中一篇文章(标题:流动水条件下金属矿山崩落体中注浆扩展的现场调查,DOI:10.1002/dug2.70001)特别值得注意,该文章研究了活跃水流条件下金属矿山崩落体中注浆扩展的复杂动力学。该研究为减轻水砂混合物突水危害和推进采矿安全实践提供了重要见解。另一篇文章(标题:对不同岩石节理和锚杆参数及法向应力下锚固岩石节理剪切行为的实验研究的综合回顾,DOI:10.1002/dug2.12091)对锚固岩石节理剪切行为的实验研究进行了系统回顾,强调了节理粗糙度系数(JRC)和法向应力对抗剪强度的影响。进一步研究分析了不同应力状态下断裂带内土石混合体渗透系数的变化,建立了渗透系数与应力条件之间的定量关系(题目:不同应力状态下断裂带土石混合体渗透系数变化研究,DOI:10.1002/dug2.12100)。本期特刊进一步涵盖了几项关键研究,包括:(1)高温下深部岩石注浆应用中水泥浆液性能的热降解效应(题目:高温对深部岩石注浆水泥浆液性能的影响,DOI:10.1002/dug2.12073);(2)深部开采环境下地应力场特征演化及岩石力学性质变化(题目:滇东北深部矿山地应力场特征及岩石力学性质变化综合研究,DOI:10.1002/dug2.12124);(3)应用分布式光纤传感技术提高煤矿地质条件透明度(题目:基于分布式光纤传感技术的煤矿地质条件透明度研究,DOI:10.1002/dug2.12134)。本期特刊收录了六篇不同方向的创新研究文章:(1)爆破岩石裂隙表面微观结构表征的数字三维重建技术(题目:三维轮廓的数字重建及其在爆破后岩石裂隙表面微观结构评价中的应用,DOI:10.1002/dug2.12111);(2)将数字图像处理(DIP)技术与离散元法相结合,建立了动载荷作用下有缺陷花岗岩的数值模型。这些构建的模型可以与实际岩石图像非常接近(题目:动态加载诱导有缺陷花岗岩的破裂行为:基于DIP和PFC的研究,DOI:10.1002/dug2.12088);(3)改造矿山地下储气库开采过程中砂岩层在循环注回采荷载作用下的损伤演化过程(题目:基于离散元法的废弃矿山天然气库充放循环荷载作用下围岩损伤演化,DOI:10.1002/dug2.12099);(4)深部开采环境下地下水动态流动条件下,热-水-力耦合对单个裂隙注浆行为的影响(题目:煤矿流水条件下,热-水-力耦合对单个裂隙注浆的影响,DOI:10.1002/dug2。 12144);(5)深部矿山砂岩在循环荷载作用下的损伤演化特征、声发射模式及动荷载作用下有缺陷花岗岩的裂缝扩展行为(题目:深部矿山不同类型砂岩在高应力作用下的循环扰动损伤特征及声发射特征试验研究,DOI:10.1002/dug2.12093);(6)层间剪切带切割大型地下洞室稳定性评价案例研究(题目:中国白鹤滩水电站层间剪切带切割大型地下厂房洞室稳定性案例研究,DOI:10.1002/dug2.12094)。本文报道了一项历时9年的大型地下深洞室变形与稳定问题研究。为地下洞室稳定性分析提供了一个完整的链条:通过现场调查和实验室试验确定参数,非均质岩体稳定性数值模拟,现场监测和数值模型验证,创意替代洞室稳定性控制和现场评估。所有这些文章都提供了该领域的多学科视角和前沿见解。新闻部高度赞赏特邀编辑为本期特刊的成功所作的努力。特邀编辑:隋望华教授(中国矿业大学)、杨晓从教授(BGRIMM科技集团)、Ravi Jain院士(美国加州太平洋大学)、Dmytro Rudakov教授(乌克兰第聂伯罗理工大学)、孙亚军教授(中国矿业大学)、张斌教授(北京中国地质大学)、谭文辉教授(北京科技大学)。这期特刊所介绍的研究的广度强调了在深部开采中对地下水和岩石稳定性挑战日益增长的科学和实践关注。通过汇编这些前沿研究,DUSE旨在刺激该领域的进一步创新。我们诚挚地邀请研究人员和行业专业人士通过高质量的贡献继续推进这一关键话语,最终在全球范围内促进更安全、更可持续的深部采矿实践。
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引用次数: 0
Simulation of CO2–water two-phase fluid displacement characteristics based on the phase field method 基于相场法的co2 -水两相流体驱替特性模拟
IF 5 Pub Date : 2025-04-22 DOI: 10.1002/dug2.70019
Changnü Zeng, Yiyang Zhang, Hu Lu, Zhao Lu

The two-phase flow in porous media is affected by multiple factors. In the present study, a two-dimensional numerical model of porous media was developed using the actual pore structure of the core sample. The phase field method was utilized to simulate the impact of displacement velocity, the water–gas viscosity ratio, and the density ratio on the flow behavior of two-phase fluids in porous media. The effectiveness of displacement was evaluated by analyzing CO2 saturation levels. The results indicate that the saturation of CO2 in porous media increased as the displacement velocity increased. When the displacement velocity exceeded 0.01 m/s, there was a corresponding increase in CO2 saturation. Conversely, when the displacement velocity was below this threshold, the impact on CO2 saturation was minimal. An “inflection point,” M3, was present in the viscosity ratio. When the viscosity of CO2 is less than 8.937 × 10−5 Pa·s (viscosity ratio below M3), variations in the viscosity of CO2 had little impact on its saturation. Conversely, when the viscosity of CO2 exceeded 8.937 × 10−5 Pa·s (viscosity ratio greater than M3), saturation increased with an increase in the viscosity ratio. In terms of the density ratio, the saturation of CO2 increased monotonically with an increase in the density ratio. Similarly, increasing density ratios resulted in a monotonic increase in CO2 saturation, though this trend was less pronounced in numerical simulations. Analysis results of displacement within dead-end pores using pressure and velocity diagrams reveal eddy currents as contributing factors. Finally, the impact of pore throat structure on the formation of dominant channels was examined.

多孔介质中的两相流动受多种因素的影响。在本研究中,利用岩心样品的实际孔隙结构建立了多孔介质的二维数值模型。采用相场法模拟了驱替速度、水气黏度比和密度比对两相流体在多孔介质中流动特性的影响。通过分析CO2饱和度来评价驱替的有效性。结果表明:随着驱替速度的增加,多孔介质中CO2的饱和度增大;当驱替速度超过0.01 m/s时,CO2饱和度相应增加。相反,当驱替速度低于该阈值时,对CO2饱和度的影响最小。粘度比中存在一个“拐点”M3。当CO2粘度小于8.937 × 10−5 Pa·s(粘度比小于M3)时,CO2粘度变化对其饱和度影响不大。相反,当CO2的黏度超过8.937 × 10−5 Pa·s(黏度比大于M3)时,饱和度随黏度比的增加而增加。在密度比方面,CO2的饱和度随密度比的增加而单调增加。同样,密度比的增加导致二氧化碳饱和度单调增加,尽管这种趋势在数值模拟中不太明显。利用压力图和速度图对死角孔内位移进行分析,结果表明涡流是影响位移的因素。最后,分析了孔喉结构对优势通道形成的影响。
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引用次数: 0
Challenges, models, and algorithms for flow and transport simulations in deep reservoirs 深层油藏流动和输运模拟的挑战、模型和算法
IF 5 Pub Date : 2025-04-13 DOI: 10.1002/dug2.70006
Tao Zhang, Jie Liu, Shuyu Sun

The development of deep reservoirs is an emerging topic in the energy industry. This paper analyzes the challenges in simulations of flow and transport in deep reservoirs and introduces models and algorithms aimed at resolving these challenges. A fast, accurate, and robust phase equilibrium model is developed with the aid of deep learning algorithms to accelerate the thermodynamic analysis of deep reservoir fluids. A pixel-free search algorithm is developed to generate a pore-network model that describes pore connectivity and porous media fluidity. A fully conservative Implicit Pressure Explicit Saturation algorithm is developed to simulate the Darcy-scale two-phase flow while achieving a reliable result for production evaluation. Numerical examples are presented to validate the performance of the developed models and algorithms. This paper also presents suggestions for future studies on deep reservoirs to achieve both scientific and engineering progress.

深层储层的开发是能源行业的新兴课题。本文分析了深层水库流动输运模拟面临的挑战,介绍了解决这些挑战的模型和算法。在深度学习算法的帮助下,建立了一个快速、准确、鲁棒的相平衡模型,以加速深部储层流体的热力学分析。开发了一种无像素搜索算法来生成描述孔隙连通性和多孔介质流动性的孔隙网络模型。提出了一种完全保守的隐式压力显式饱和算法,以模拟达西尺度的两相流,同时获得可靠的生产评价结果。数值算例验证了所建模型和算法的性能。本文还对今后深部储层研究提出了建议,以期取得科学和工程上的双重进展。
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引用次数: 0
Leakage risk assessment system for salt cavern hydrogen storage 盐穴储氢泄漏风险评估系统
IF 5 Pub Date : 2025-03-31 DOI: 10.1002/dug2.70011
Weizheng Bai, Xilin Shi, Shijie Zhu, Xinxing Wei, Yashuai Huang

Salt cavern hydrogen storage (SCHS) is an important component of large-scale underground hydrogen storage, with advantages such as large hydrogen storage capacity and economic feasibility. However, the uniqueness of the salt cavern structure and the inherent high risk of hydrogen storage pose a potential leakage risk. This study aims to assess the leakage risk of salt cavern hydrogen storage through a comprehensive assessment. First, the three major influencing factors of leakage risk are summarized, taking into account the unique engineering, geological conditions, and operating conditions of salt cavern storage. Subsequently, the salt cavern hydrogen storage leakage risk evaluation index system was established, and the weights of the evaluation indexes were assigned using the combination assignment method. On the basis of the two-dimensional cloud model, a new leakage risk assessment method was proposed. In addition, the risk level assessment of the salt cavern hydrogen storage facility proposed to be constructed in Pingdingshan City, Henan Province, was carried out. Finally, corresponding risk control and preventive measures are proposed. The results of the study are useful and instructive for the safe construction of deep salt cavern hydrogen storage.

盐穴储氢是大型地下储氢的重要组成部分,具有储氢容量大、经济可行等优点。然而,盐洞结构的独特性和储氢固有的高风险构成了潜在的泄漏风险。本研究旨在通过综合评估来评估盐穴储氢的泄漏风险。首先,结合盐洞库独特的工程、地质条件和运行条件,总结了泄漏风险的三大影响因素;随后,建立了盐穴储氢泄漏风险评价指标体系,并采用组合赋值法对评价指标进行权重赋值。在二维云模型的基础上,提出了一种新的泄漏风险评估方法。此外,还对河南省平顶山市拟建设的盐穴式储氢设施进行了风险等级评价。最后,提出了相应的风险控制和防范措施。研究结果对深盐穴储氢库的安全施工具有一定的指导意义。
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引用次数: 0
Study on the diffusion and migration law of CO2 sequestrated in abandoned coal mine goaf 煤矿废弃地采空区CO2固存扩散迁移规律研究
IF 5 Pub Date : 2025-03-21 DOI: 10.1002/dug2.70002
Haiyang Zhou, Yu Wu, Chunhui Liu, Haozhe Geng, Chenyu Yao

The potential for CO2 sequestration in the goaf of abandoned coal mines is significant due to the extensive fracture spaces and substantial residual coal present. Firstly, the adsorption characteristics of residual coal in goaf on CO2 were studied by the isothermal adsorption test of CO2. Then, to accurately calculate the amount of adsorbed CO2 within the residual coal in the goaf, the bidisperse diffusion numerical model considering only Fick diffusion was modified in combination with the diffusion mechanisms. The simulation results showed that the modified model can well describe the diffusion behavior of CO2 in the residual coal matrix. Finally, the numerical simulation of CO2 sequestration in the goaf of abandoned coal mines was carried out, and the influence of different injection well deployment positions and various thicknesses of residual coal on the migration law and storage effect of CO2 in goaf was analyzed. The results showed that CO2 preferentially flowed into the caving zone with higher permeability. The distribution of CO2 streamlines in the goaf was the most dense in the caving zone and the streamlines in the fracture zone were gradually sparse from bottom to top. When the injection well was deployed at the interface of the two zones, the CO2 had the best seepage path. The total storage capacity within 90 days was 7.702754 × 106 kg, of which the free state storage capacity in the fracture of the goaf and the adsorbed state storage capacity in the residual coal were 6.611451 × 106 and 1.091303 × 106 kg, respectively. When the injection well was deployed in the middle of the residual coal seam in the goaf and the middle of the fracture zone, the total storage capacity at the same time was 7.613508 × 106 and 6.021495 × 106 kg, respectively. The coal with different thicknesses remaining at the bottom of the goaf significantly affected the adsorbed state storage, but had little effect on the free state storage. When the thickness of the residual coal seam was 0.20, 0.35, and 0.50 m, the adsorbed state storage capacity within 130 days was 4.37623 × 105, 7.65791 × 105, and 1.093406 × 106 kg, respectively.

废弃煤矿的采空区由于存在广泛的裂隙空间和大量的残余煤,因此具有很大的二氧化碳封存潜力。首先,通过CO2等温吸附试验,研究了采空区残余煤对CO2的吸附特性。然后,结合扩散机理,对仅考虑菲克扩散的双分散扩散数值模型进行修正,以准确计算采空区残余煤吸附CO2量。仿真结果表明,修正后的模型能较好地描述CO2在残余煤基体中的扩散行为。最后,对废弃煤矿采空区CO2封存进行了数值模拟,分析了不同注水井部署位置和不同残煤厚度对采空区CO2迁移规律和封存效果的影响。结果表明:CO2优先流向渗透率较高的崩落带;采空区CO2流线分布在垮落带最为密集,破碎带的流线自下而上逐渐稀疏。注水井位于两层的界面处时,CO2渗流路径最佳。90 d内总库容为7.702754 × 106 kg,其中采空区裂隙游离态库容为6.611451 × 106 kg,残煤吸附态库容为1.091303 × 106 kg。注水井部署在采空区残余煤层中部和裂隙带中部时,同时总库容分别为7.613508 × 106和6.021495 × 106 kg。不同厚度的煤在采空区底部残留对吸附态储存量有显著影响,对自由态储存量影响不大。当残余煤层厚度为0.20、0.35、0.50 m时,130 d内吸附态库容分别为4.37623 × 105、7.65791 × 105、1.093406 × 106 kg。
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Deep Underground Science and Engineering
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