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Sugar detection using drop evaporation 液滴蒸发法测糖
Pub Date : 2025-01-05 DOI: 10.1002/dro2.150
Yixiao Qu, Zhengyuan Ma, Min Zhang, Xing Huang, Lujia Xuan, Rui Ding, Wenya Liao, Zhiqiang Wu, Yihe Lin, Kami Hu, Zheng Liu, Ruoyang Chen, Hui He

Evaporation deposition of a spilt sugary drop on the supporting surface can attract ants to surround it. People have a long history of using this phenomenon as an implication of sugar in the drop. Unfortunately, it is hard to detect sugar concentration and has to depend exclusively on ants. Here, we show a facile strategy for the eye-naked detection on sugar concentrations in common liquid mixtures, based on their evaporation depositions. Our experiments show that evaporation drops without any sugar form clear ring-like depositions, and the width of the ring area enlarges with the increase in sugar concentration. We demonstrate that the increase in sugar concentration can increase the liquid viscosity and decrease the capillary flow velocity, thus weakening the “coffee ring” effect. Our further experiments indicate that the temperature has insignificant effects on the correlation between sugar concentrations and ring-like depositions, but the substrate wettability impacts on the correlation by promoting the formation of ring-like depositions. Based on the mechanism study, we develop a strategy for detecting sugar concentrations via quantitatively correlating them with the width of the ring area, and demonstrate that it is valid for various liquid mixtures, for example, carbonate beverage, liquid medicine, and plant nutrient. Our findings not only present new insights into the understanding of the sugary drop evaporation, but also provide a facile strategy of detecting sugar concentration that promises great applications in food safety, pharmaceutical detection, and agricultural product measurements.

溢出的糖滴在支撑表面的蒸发沉积可以吸引蚂蚁围绕它。人们使用这种现象作为糖滴的暗示已经有很长的历史了。不幸的是,很难检测到糖的浓度,只能依靠蚂蚁。在这里,我们展示了一种简单的策略,用于肉眼检测普通液体混合物中的糖浓度,基于它们的蒸发沉积。实验表明,在不添加糖的情况下,蒸发下降形成清晰的环状沉积,且随着糖浓度的增加,环状区域的宽度增大。研究表明,糖浓度的增加会增加液体粘度,降低毛细管流速,从而减弱“咖啡环”效应。我们进一步的实验表明,温度对糖浓度与环状沉积之间的相关性影响不显著,但基质的润湿性通过促进环状沉积的形成来影响相关性。在机理研究的基础上,我们开发了一种通过将糖浓度与环区宽度定量相关来检测糖浓度的策略,并证明了它对各种液体混合物(如碳酸饮料、液体药物和植物营养素)的有效性。我们的发现不仅为糖滴蒸发的理解提供了新的见解,而且还提供了一种简便的糖浓度检测策略,有望在食品安全、药物检测和农产品测量中得到广泛应用。
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引用次数: 0
Integrated copper-based Janus thermal system for efficient water harvesting around the clock 集成铜基Janus热系统,可全天候高效收集水
Pub Date : 2025-01-05 DOI: 10.1002/dro2.152
Congji Zhang, Guopeng Chen, Shangzhen Xie, Shuo Li, Ke Feng, Zhiguang Guo

Many regions across the globe are grappling with water scarcity issues, prompting the exploration of innovative water harvesting techniques. While the development of high-performance water harvesting materials has been widely documented, these technologies often rely on a singular source with limited efficiency. This study presents a dual-functional copper Janus system that facilitates continuous freshwater harvesting by integrating seawater desalination powered by solar energy during daylight hours and fog collection during night and morning time. The Janus system consists of a copper sheet and copper foam substrate, featuring superhydrophilic pores arranged on the superhydrophobic surface, as well as superhydrophilic flake-like structures made of soot-carbon particles, which are deposited on the framework of the copper foam. The fog collection rate of this system has been measured at 210.65 kg m−2 h−1, while the solar-driven evaporation rate of seawater under 1-sun conditions is reported at 1.44 kg m−2 h−1. The fog collection and evaporation efficiency have been enhanced by 28.72% and 183.27%, respectively. Furthermore, the system demonstrates strong and consistent performance even after repeated use, ensuring sustained water collection over prolonged periods. Therefore, this study presents a promising avenue for water collection technologies and offers valuable insights for the advancement of sustainable freshwater production methods.

全球许多地区都在努力解决水资源短缺问题,促使人们探索创新的集水技术。虽然高性能集水材料的开发已被广泛记录,但这些技术往往依赖于单一来源,效率有限。这项研究提出了一个双功能的铜Janus系统,通过集成白天由太阳能供电的海水淡化和夜间和早晨的雾收集,促进了连续的淡水收集。Janus系统由铜片和泡沫铜衬底组成,其超疏水表面上排列着超亲水孔隙,泡沫铜的框架上沉积着由炭黑颗粒构成的超亲水片状结构。该系统的雾收集速率为210.65 kg m−2 h−1,而单太阳条件下太阳驱动的海水蒸发速率为1.44 kg m−2 h−1。雾的收集效率和蒸发效率分别提高了28.72%和183.27%。此外,即使在重复使用后,该系统也表现出强大和一致的性能,确保长时间持续收集水。因此,该研究为水收集技术提供了一条有前途的途径,并为可持续淡水生产方法的发展提供了有价值的见解。
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引用次数: 0
Front Cover, Volume 3, Number 4, October 2024 封面,第 3 卷第 4 号,2024 年 10 月
Pub Date : 2024-10-23 DOI: 10.1002/dro2.154
Chuanning Zhao, Youngjoon Suh, Yoonjin Won

Front Cover: The cover image is based on the Research Article DropletMask: Leveraging visual data for droplet impact analysis by Zhao et al.

Cover description: Capturing the dynamic movements of droplet impacts is critical in thermal science and applications involving droplets. We propose a framework that leverages machine learning-assisted computer vision tools that quantitatively analyze their impacts. The interconnected network on the image background represents digital droplets, enabling precise measurements of the spatiotemporal data involving droplet movements, sizes, and impact forces on various surfaces. (DOI: 10.1002/dro2.137)

封面:封面图像基于研究文章 DropletMask:利用视觉数据进行液滴撞击分析》(由 Zhao 等人撰写)的封面描述:捕捉液滴撞击的动态运动对于热科学和涉及液滴的应用至关重要。我们提出了一个框架,利用机器学习辅助计算机视觉工具定量分析液滴的冲击。图像背景上相互连接的网络代表了数字液滴,可精确测量液滴运动的时空数据、尺寸以及对各种表面的冲击力。(DOI: 10.1002/dro2.137)
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引用次数: 0
Inside Back Cover, Volume 3, Number 4, October 2024 封底内页,第 3 卷第 4 号,2024 年 10 月
Pub Date : 2024-10-23 DOI: 10.1002/dro2.157
Zhi Tao, Weidong Fang, Haiwang Li, Shuai Yin, Tiantong Xu, Teckneng Wong, Yi Huang

Inside Back Cover: The cover image is based on the Research Article Electro-coalescence of heterogeneous paired-droplets under AC electric field by Tao et al.

Cover description: Electro-coalescence of heterogeneous paired-droplets is achieved within milliseconds under AC electric fields on a lab-on-a-chip platform. The physical mechanisms are examined by parameters such as conductivity, surface tension, non-Newtonian properties. This technique could be applied to the droplet-based chemical reaction at microscale, including the efficient and additive-free fabrication of hydrogel microspheres. (DOI: 10.1002/dro2.145)

封底内页:封面图片取材于 Tao 等人的研究文章《异质成对液滴在交流电场下的电凝聚》(Electro-coalescence of heterogeneous paired-droplets under AC electric field):在片上实验室平台上,异质成对液滴在交流电场下几毫秒内实现了电凝聚。通过电导率、表面张力、非牛顿性质等参数对物理机制进行了研究。该技术可应用于微米级基于液滴的化学反应,包括水凝胶微球的高效无添加制造。(DOI: 10.1002/dro2.145)
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引用次数: 0
Inside Front Cover, Volume 3, Number 4, October 2024 封面内页,第 3 卷第 4 号,2024 年 10 月
Pub Date : 2024-10-23 DOI: 10.1002/dro2.156
Ratima Suntornnond, Wei Long Ng, Viktor Shkolnikov, Wai Yee Yeong

Inside Front Cover: The cover image is based on the Research Article A facile method to fabricate cell-laden hydrogel microparticles of tunable sizes using thermal inkjet bioprinting by Suntornnond et al.

Cover description: We demonstrate a novel approach for fabricating hydrogel microparticles (HMPs) using thermal inkjet-based bioprinting. The technique enables precise control over HMP size, porosity, and modularity, with potential applications in tissue engineering and regenerative medicine. Cell-laden HMPs of tunable sizes can be fabricated by adjusting surfactant concentration and jetting volume, highlighting their versatility for advanced biomedical applications. (DOI: 10.1002/dro2.144)

封面内页:封面图片基于 Suntornnond 等人撰写的研究文章《利用热喷墨生物打印技术制造可调尺寸的细胞负载水凝胶微颗粒的简便方法》:我们展示了一种利用热喷墨生物打印技术制造水凝胶微颗粒(HMP)的新方法。该技术可精确控制水凝胶微颗粒的尺寸、孔隙率和模块化程度,有望应用于组织工程和再生医学。通过调整表面活性剂的浓度和喷射量,可以制造出尺寸可调的细胞负载型 HMP,从而突出了其在先进生物医学应用中的多功能性。(DOI: 10.1002/dro2.144)
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引用次数: 0
Back Cover, Volume 3, Number 4, October 2024 封底,第 3 卷第 4 号,2024 年 10 月
Pub Date : 2024-10-23 DOI: 10.1002/dro2.155
Shile Feng, Yongping Hou, Yongmei Zheng

Back Cover: The cover image is based on the Research Article Programmable curvilinear self-propelling of droplets without preset channels by Feng et al.

Cover description: We propose a programmable curvilinear self-propelling strategy for droplets based on the collaboration of curvilinear wetting gradient and the Leidenfrost effect. This design achieves a well-controlled manner in motion trajectory, as well as high velocity and long distance of droplet transport independent on the pre-set channel. (DOI: 10.1002/dro2.138)

封底:封面图片是根据 Feng 等人的研究文章《无预设通道的液滴可编程曲线自推进》制作的:我们提出了一种基于曲线润湿梯度和莱顿弗罗斯特效应的可编程液滴曲线自推进策略。这种设计实现了对运动轨迹的良好控制,以及不受预设通道影响的高速和长距离液滴传输。(DOI: 10.1002/dro2.138)
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引用次数: 0
Aerodynamic breakup of emulsion droplets in airflow 气流中乳化液液滴的气动破碎
Pub Date : 2024-09-24 DOI: 10.1002/dro2.146
Zhikun Xu, Jinzhao Liu, Houpeng Zhang, Tianyou Wang, Zhizhao Che

Aerodynamic breakup refers to the process where large droplets are fragmented into small droplets by the aerodynamic force in airflow, which plays a vital role in fluid atomization and spray applications. Previous research has primarily concentrated on the aerodynamic breakup of single-component droplets, but investigations into the breakup of emulsion droplets are limited. This study experimentally investigated the aerodynamic breakup of water-in-oil emulsions in airflow, utilizing high-speed photography to observe the breakup process and digital in-line holography to measure fragment sizes. Comparative analyses between emulsion droplets and single-component droplets are conducted to examine the breakup morphology, breakup regime, deformation characteristics, and fragment size distributions. The emulsion droplets exhibit higher apparent viscosity and shorter stretching lengths of the bag film and peripheral rim due to the presence of a dispersed phase. The breakup regime transitions of emulsions are modeled by integrating the viscosity model of emulsions and the transition model of the pure fluid. The fragment sizes of emulsion droplets are larger due to the shorter lengths of the bag film and peripheral rim.

空气动力碎裂是指大液滴在气流中受空气动力作用碎裂成小液滴的过程,在流体雾化和喷雾应用中起着至关重要的作用。以往的研究主要集中在单组分液滴的气动破碎上,但对乳液液滴破碎的研究还很有限。本研究通过实验研究了油包水型乳液在气流中的气动破裂,利用高速摄影观察破裂过程,并采用数字在线全息技术测量碎片尺寸。对乳液液滴和单组分液滴进行了比较分析,以研究其破裂形态、破裂机制、变形特征和碎片尺寸分布。由于存在分散相,乳液液滴的表观粘度更高,袋膜和外围边缘的拉伸长度更短。通过整合乳液的粘度模型和纯流体的过渡模型,建立了乳液的破裂体系转换模型。由于袋膜和外围边缘的长度较短,乳液液滴的碎片尺寸较大。
{"title":"Aerodynamic breakup of emulsion droplets in airflow","authors":"Zhikun Xu,&nbsp;Jinzhao Liu,&nbsp;Houpeng Zhang,&nbsp;Tianyou Wang,&nbsp;Zhizhao Che","doi":"10.1002/dro2.146","DOIUrl":"https://doi.org/10.1002/dro2.146","url":null,"abstract":"<p>Aerodynamic breakup refers to the process where large droplets are fragmented into small droplets by the aerodynamic force in airflow, which plays a vital role in fluid atomization and spray applications. Previous research has primarily concentrated on the aerodynamic breakup of single-component droplets, but investigations into the breakup of emulsion droplets are limited. This study experimentally investigated the aerodynamic breakup of water-in-oil emulsions in airflow, utilizing high-speed photography to observe the breakup process and digital in-line holography to measure fragment sizes. Comparative analyses between emulsion droplets and single-component droplets are conducted to examine the breakup morphology, breakup regime, deformation characteristics, and fragment size distributions. The emulsion droplets exhibit higher apparent viscosity and shorter stretching lengths of the bag film and peripheral rim due to the presence of a dispersed phase. The breakup regime transitions of emulsions are modeled by integrating the viscosity model of emulsions and the transition model of the pure fluid. The fragment sizes of emulsion droplets are larger due to the shorter lengths of the bag film and peripheral rim.</p>","PeriodicalId":100381,"journal":{"name":"Droplet","volume":"3 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dro2.146","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142555364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electro-coalescence of heterogeneous paired-droplets under AC electric field 交流电场下异质成对液滴的电凝聚
Pub Date : 2024-09-13 DOI: 10.1002/dro2.145
Zhi Tao, Weidong Fang, Haiwang Li, Shuai Yin, Tiantong Xu, Teckneng Wong, Yi Huang

Controllable droplet coalescence exhibits unique advantages and intriguing prospect in chemical synthesis and biological engineering. Current researches focusing on the droplets of the same physics are, however, limited in terms of the interaction between different reactants. In this work, the electro-coalescence of heterogeneous paired-droplets is investigated in a microfluidic chip controlled by an AC electric field. The characteristics of merging dynamics are analyzed under different electric conditions and fluid properties, and an on-chip cross-linking reaction is conducted to enable the instantaneous production of hydrogel microspheres. We find that the coalescence of heterogeneous paired-droplets expands the range of start positions and prolongs the merging time compared to homogeneous paired-droplets. The evolution process of interfaces is accelerated with the increasing voltage, which contributes to the mixing of diverse components. Different electrical conductivities lead to distinct internal mechanisms within droplets. The voltage across the droplet is reduced with the increasing conductivity, while the enhanced attraction between free charges plays a complimentary role in interface instability. Lowering the surface tension reduced the required electric conditions for coalescence. Endowed with the non-Newtonian property, the droplet presents a non-linear relationship in the coalescence region, triggering coalescence with filaments at low voltages and showcasing superior performance at high frequencies. Based on above findings, we successfully produce alginate hydrogel microspheres with a wide range of concentrations in high monodispersity, achieving a clean fabrication of pure hydrogel without any additives and no need for subsequent cleaning. These results reveal the electro-hydrodynamics of heterogeneous paired-droplets, promoting the development of droplet coalescence in chemical and material science.

可控液滴凝聚在化学合成和生物工程领域具有独特的优势和广阔的前景。然而,目前针对相同物理特性液滴的研究仅限于不同反应物之间的相互作用。本研究在交流电场控制的微流控芯片中研究了异质成对液滴的电凝聚。分析了不同电场条件和流体性质下的合并动力学特征,并进行了片上交联反应,以实现水凝胶微球的瞬时生产。我们发现,与同质成对液滴相比,异质成对液滴的凝聚扩大了起始位置的范围,延长了合并时间。随着电压的增加,界面的演化过程加快,这有助于不同成分的混合。不同的导电率导致液滴内部机制的不同。液滴上的电压随着电导率的增加而降低,而自由电荷之间的吸引力增强则对界面的不稳定性起到了辅助作用。降低表面张力可减少凝聚所需的电条件。由于液滴具有非牛顿特性,因此在凝聚区域呈现出非线性关系,在低电压下可引发与丝状物的凝聚,在高频率下则表现出卓越的性能。基于上述发现,我们成功制备出浓度范围宽、单分散性高的海藻酸盐水凝胶微球,实现了纯水凝胶的清洁制造,不含任何添加剂,也无需后续清洗。这些成果揭示了异质成对液滴的电流体力学,促进了液滴凝聚在化学和材料科学领域的发展。
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引用次数: 0
DropletMask: Leveraging visual data for droplet impact analysis DropletMask:利用可视化数据进行液滴影响分析
Pub Date : 2024-09-03 DOI: 10.1002/dro2.137
Chuanning Zhao, Youngjoon Suh, Yoonjin Won

Machine learning-assisted computer vision represents a state-of-the-art technique for extracting meaningful features from visual data autonomously. This approach facilitates the quantitative analysis of images, enabling object detection and tracking. In this study, we utilize advanced computer vision to precisely identify droplet motions and quantify their impact forces with spatiotemporal resolution at the picoliter or millisecond scale. Droplets, captured by a high-speed camera, are denoised through neuromorphic image processing. These processed images are employed to train convolutional neural networks, allowing the creation of segmented masks and bounding boxes around moving droplets. The trained networks further digitize time-varying multi-dimensional droplet features, such as droplet diameters, spreading and sliding motions, and corresponding impact forces. Our innovative method offers accurate measurement of small impact forces with a resolution of approximately 10 pico-newtons for droplets in the micrometer range across various configurations with the time resolution at hundreds of microseconds.

机器学习辅助计算机视觉技术是一种自主从视觉数据中提取有意义特征的先进技术。这种方法有助于对图像进行定量分析,从而实现物体检测和跟踪。在这项研究中,我们利用先进的计算机视觉技术精确识别液滴运动,并以皮升或毫秒级的时空分辨率量化其冲击力。通过神经形态图像处理对高速摄像机捕捉到的液滴进行去噪处理。这些经过处理的图像被用于训练卷积神经网络,从而可以创建移动液滴周围的分段掩码和边界框。经过训练的网络可进一步数字化随时间变化的多维液滴特征,如液滴直径、扩散和滑动运动以及相应的冲击力。我们的创新方法可精确测量微米级液滴在各种配置下的微小冲击力,分辨率约为 10 皮牛顿,时间分辨率为数百微秒。
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引用次数: 0
A facile method to fabricate cell-laden hydrogel microparticles of tunable sizes using thermal inkjet bioprinting 利用热喷墨生物打印技术制造尺寸可调的细胞负载水凝胶微颗粒的简便方法
Pub Date : 2024-08-28 DOI: 10.1002/dro2.144
Ratima Suntornnond, Wei Long Ng, Viktor Shkolnikov, Wai Yee Yeong

This study investigates the application of a drop-on-demand (DOD) thermal inkjet (TIJ)-based bioprinting system for the fabrication of cell-laden hydrogel microparticles (HMPs) with tunable sizes. The TIJ bioprinting technique involves the formation of vapor bubbles within the print chamber through thermal energy, expelling small droplets of bio-ink onto a substrate. The study employs a heat-treated saponified gelatin-based bio-ink, HSP-GelMA. This bio-ink is modified through methacrylic anhydride functionalization and undergoes subsequent saponification and heat treatment processes. Various concentrations of SPAN 80 surfactant in mineral oil were evaluated to assess their influence on HMP size and stability. The results indicate a direct correlation, with higher SPAN 80 concentrations resulting in smaller and more stable HMPs. The study further investigates the influence of jetting volume on HMP size distribution, revealing that larger jetting volumes lead to increased HMP sizes, attributed to droplet coalescence. This is supported by our further study via a Monte Carlo simulation, which shows that the mean droplet diameter grows approximately linear with the number of dispensed droplets. In addition, the study demonstrates the capability of the TIJ bioprinting system to achieve multimaterial encapsulation within HMPs, exemplified by staining living cells with distinct cytoplasmic membrane dyes. The presented approach provides insights into the controlled fabrication of cell-laden HMPs, highlighting the versatility of the TIJ bioprinting system for potential applications in tissue engineering and drug delivery.

本研究探讨了基于热喷墨(TIJ)的按需滴墨(DOD)生物打印系统在制造可调尺寸的细胞负载水凝胶微颗粒(HMPs)中的应用。TIJ 生物打印技术通过热能在打印室中形成气泡,将生物墨水小液滴喷射到基底上。这项研究采用了一种经过热处理的皂化明胶基生物墨水 HSP-GelMA。这种生物墨水通过甲基丙烯酸酐功能化改性,并经过后续的皂化和热处理过程。对矿物油中不同浓度的 SPAN 80 表面活性剂进行了评估,以评估它们对 HMP 尺寸和稳定性的影响。结果表明,SPAN 80 浓度越高,HMP 的尺寸越小,稳定性越好,两者之间存在直接的相关性。研究还进一步调查了喷射量对 HMP 尺寸分布的影响,结果表明,喷射量越大,HMP 尺寸越大,这归因于液滴凝聚。我们通过蒙特卡罗模拟进行的进一步研究证实了这一点,该模拟显示,液滴的平均直径与分配液滴的数量呈近似线性增长。此外,该研究还证明了 TIJ 生物打印系统在 HMP 内实现多材料封装的能力,用不同的细胞质膜染料对活细胞进行染色就是例证。所介绍的方法为细胞负载 HMP 的受控制造提供了见解,突出了 TIJ 生物打印系统在组织工程和药物输送领域潜在应用的多功能性。
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引用次数: 0
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