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On the use of ammonia as a fuel – A perspective 关于使用氨作为燃料的观点
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100064
Olivier Herbinet , Pietro Bartocci , Alon Grinberg Dana

Ammonia has long been considered as a candidate vector for power generation, and has specifically gained significant interest recently. Though it is not free of drawbacks, ammonia has been identified as a promising potential alternative fuel for future power generation. Current studies and a growing body of works in this direction drive us closer to a viable solution of ammonia as an important transition into a cleaner future of the energy sector. In this perspective, we explore the use of ammonia as a fuel in combustion applications (with and without additives) and in fuel cells. The objective of this work is to show the prospects and challenges of ammonia as a fuel, and suggest significant topics that could benefit from additional studies.

长期以来,氨一直被认为是发电的候选载体,最近尤其引起了人们的极大兴趣。尽管氨并非没有缺点,但它已被确定为未来发电的一种有前途的潜在替代燃料。目前的研究和在这个方向上越来越多的工作使我们更接近可行的氨解决方案,作为能源部门向更清洁的未来的重要过渡。从这个角度来看,我们探索了氨作为燃料在燃烧应用(有和没有添加剂)和燃料电池中的使用。这项工作的目的是展示氨作为燃料的前景和挑战,并提出可能从进一步研究中受益的重要主题。
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引用次数: 22
A review on renewable energy potentials and energy usage statistics in Ghana 加纳可再生能源潜力和能源使用统计资料综述
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100065
Mohammed Takase, Michael Aboah, Rogers Kipkoech

This paper is a review of renewable energy potentials and energy usage statistics in Ghana. Principally, it covers Ghana's energy consumption from 2000 to 2020. The findings show that Ghana uses both renewable (10%) and non-renewable (90%) forms of energy, but biomass (46.667%) and oil (40.52%) are the commonly used energy resource. This is followed by natural gas (10%), hydroelectric power (7%), and solar energy (0%). The energy consumption by sector from 2000 to 2020 totaled up to 130632ktoe. Residents featured 62,736ktoe (48%) as well as industries, service, agriculture, and transport with each recording 18254ktoe, 5033ktoe, 1957ktoe, and 42652ktoe respectively. The review revealed that the energy demand of the country (Ghana) has shot up and therefore, there is the need for more sustainable energy alternatives to be employed in the energy processes of the country to offset the impacts of future energy crises.

本文回顾了加纳的可再生能源潜力和能源使用统计数据。它主要涵盖了加纳2000年至2020年的能源消耗。研究结果表明,加纳使用可再生能源(10%)和不可再生能源(90%),但生物质(46.667%)和石油(40.52%)是常用的能源。其次是天然气(10%)、水力发电(7%)和太阳能(0%)。2000年至2020年,各部门能源消耗总量达130632千吨油当量。居民为62736万吨级(48%),工业为18254万吨级,服务业为5033万吨级,农业为1957万吨级,运输业为42652万吨级。审查显示,该国(加纳)的能源需求急剧增加,因此,需要在该国的能源过程中采用更可持续的替代能源,以抵消未来能源危机的影响。
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引用次数: 9
Investigation of the acoustics of full-scale perforated liners in gas turbine combustors 燃气轮机燃烧室全尺寸穿孔衬板的声学研究
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100060
Abdullah Shahjalal, Lam Hak-Keung

In conventional gas turbine combustors, the combustion chamber linings are perforated and used for cooling. To cool the liner evenly, bias flows are introduced into the combustor at rates that depend on the operating condition. It has been found that airflow through the liner not only provides cooling but also improves sound absorption and acoustic instability. This experiment reports a unique comprehensive investigation of the influences of single and double-layer cylindrical full-scale gas turbine combustor liner sound absorption properties based on the no flow and non zero bias flows. In particular it is shown that combustor liner porosity (determined by orifice diameter and axial pitch distance) has an important influence on non-zero bias flow in that it increases the peak absorption or dissipation compared with that which occurs in the absence of flow. It is shown that the main influence of bias flow is to increase absorption compared with no flow above 600 Hz and to decrease the transmission loss measured in the absence of flow below 600 Hz but to increase it above 600 Hz. Internal resonance in the combustion liner test section influences both absorption and transmission loss spectra near 600 Hz. To create higher damping, and decrease in acoustic instability during the combustion process, gas turbine combustors require mapping between the inner and outer liner perforation to increase efficiency and lower the hydrocarbon emission. The calculated pressure ratio versus mass flow and combined discharge coefficient effect explain the non-linear distribution of the absorptive and dissipative energy measured at the gas turbine combustor.

在传统的燃气轮机燃烧室中,燃烧室内衬是穿孔的,用于冷却。为了均匀地冷却内衬,偏置流以取决于运行条件的速率引入燃烧室。研究发现,通过内衬的气流不仅提供冷却,而且改善了吸声和声不稳定性。本文报道了基于无流和非零偏流的单层和双层圆柱形全尺寸燃气轮机燃烧室衬板吸声特性影响的独特综合研究。特别是燃烧室衬垫孔隙度(由孔直径和轴向螺距决定)对非零偏置流动有重要影响,因为与无流动时相比,它增加了峰值吸收或耗散。结果表明,偏置流的主要影响是相对于600 Hz以上无流时增加吸收;相对于600 Hz以上无流时减小传输损耗,而相对于600 Hz以上无流时增大传输损耗。燃烧衬板测试截面的内部共振对600 Hz附近的吸收和透射损失谱都有影响。为了在燃烧过程中产生更高的阻尼,并减少声不稳定性,燃气轮机燃烧室需要在内胆和外胆射孔之间进行映射,以提高效率并降低碳氢化合物排放。计算得到的压流量比和综合流量系数效应解释了燃气轮机燃烧室测得的吸散能的非线性分布。
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引用次数: 1
Technologies for the production of renewable natural gas from organic wastes and their opportunities in existing Canadian pipelines 从有机废物中生产可再生天然气的技术及其在现有加拿大管道中的机会
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100056
Omid Norouzi, Mohammad Heidari, Animesh Dutta

Of all the types of renewable energy, Renewable Natural Gas (RNG) market has been more supported and developed in Canada due to the lower project cost and the existing NG pipeline infrastructure. RNG is defined as a methane-rich gas obtained through combining Anaerobic Digestion (AD) of underutilized renewable sources (organic waste streams) and upgrading technologies. Membrane separation technology is considered one of Canada's most popular upgrading technologies due to the country-old knowledge regarding gas permeation membranes widely used in the NG industry. Membrane systems are used to recover methane from biogas to a level that meets current natural gas pipeline specifications set out by gas utility companies or meets natural gas vehicle fuel standards set out by engine manufacturers. Here we review standards for gas injection into existing Canadian pipelines, commercial biogas upgrading systems in Canada, and Current biogas upgrading to RNG projects in Canada. We focus more on membrane technology and discuss the possible driving force, module, and configuration alternatives. Finally, this review comprehensively examines membrane types and advances in composite type membranes.

在所有类型的可再生能源中,由于项目成本较低和现有的天然气管道基础设施,加拿大的可再生天然气(RNG)市场得到了更多的支持和发展。RNG被定义为通过对未充分利用的可再生资源(有机废物流)进行厌氧消化(AD)和升级技术相结合而获得的富含甲烷的气体。膜分离技术被认为是加拿大最受欢迎的升级技术之一,因为这个国家对天然气工业中广泛使用的气体渗透膜有着悠久的了解。膜系统用于从沼气中回收甲烷,使其达到天然气公用事业公司制定的当前天然气管道规格或发动机制造商制定的天然气汽车燃料标准。在这里,我们回顾了加拿大现有管道的注气标准、加拿大的商业沼气升级系统以及加拿大目前的沼气升级到RNG项目。我们将更多地关注膜技术,并讨论可能的驱动力、模块和配置替代方案。最后,综述了复合膜的种类和研究进展。
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引用次数: 1
Improvement of SI engine combustion with ammonia as fuel: Effect of ammonia dissociation prior to combustion 改进以氨为燃料的内燃机燃烧:燃烧前氨解离的影响
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100058
A. Mercier , C. Mounaïm-Rousselle , P. Brequigny , J. Bouriot , C. Dumand

Although recent studies have shown the possibility of running ‘standard’ spark-ignition engines with pure ammonia, the operating range remains limited mainly due to the unfavorable characteristics of ammonia for premixed combustion and often requires the addition of a complementary fuel such as H2 to extend it. As the best way to add H2 is to crack ammonia directly on-board, this paper focuses on the impact of the upstream cracking level of ammonia on the performance and emissions of a single cylinder spark ignition engine. Experiments were performed over several equivalence ratios, dissociation rates and load conditions. It is confirmed that only a slight rate of ammonia dissociation (10%) upstream of the combustion considerably enhances the engine's operating range thanks to a better combustion stability. In terms of pollutant emissions, the partial dissociation of ammonia, especially for slightly lean mixtures induces a very clear trade-off between high NOx and high unburned ammonia level for high and low ammonia dissociation rates, respectively. Therefore, cracking NH3 does not only improve the operating range of ammonia-fueled spark ignition engines but can also help to reduce NH3. However, to reach the same engine output work, higher ammonia fuel consumption will be necessary since the global system efficiency is lower using fuel dissociation. In addition, the global warming effect is increased with dissociation level since a higher level of N2O is generated by the hydrogen contribution.

尽管最近的研究表明,使用纯氨运行“标准”火花点火发动机是可能的,但由于氨对预混燃烧的不利特性,通常需要添加H2等补充燃料来延长其运行范围,因此工作范围仍然有限。由于添加H2的最佳方式是直接在车上裂解氨,因此本文主要研究氨的上游裂解水平对单缸火花点火发动机性能和排放的影响。实验在几种等效比、解离率和负载条件下进行。经证实,仅在燃烧上游进行少量的氨解离(10%)就能显著提高发动机的工作范围,这得益于更好的燃烧稳定性。在污染物排放方面,氨的部分解离,特别是对于略稀薄的混合物,分别导致高和低氨解离率的高NOx和高未燃烧氨水平之间的非常明显的权衡。因此,裂解NH3不仅可以提高氨燃料火花点火发动机的工作范围,而且有助于降低NH3。然而,为了达到相同的发动机输出功,更高的氨燃料消耗将是必要的,因为使用燃料解离的整体系统效率较低。此外,由于氢的贡献产生了更高水平的N2O,全球变暖效应随着解离水平的增加而增加。
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引用次数: 22
Editorial for the special issue on ammonia as a fuel solution for future decarbonized energy systems 关于氨作为未来脱碳能源系统的燃料解决方案的特刊社论
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100067
Alon Grinberg Dana , Olivier Herbinet
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引用次数: 0
Maximizing net fuel economy improvement from fusel alcohol blends in gasoline using multivariate optimization 使用多元优化,最大限度地提高汽油中杂醇酒混合物的净燃油经济性
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100059
Lily Behnke , Eric Monroe , Bernard Nguyen , Alexander Landera , Anthe George , Zhibin Yang , Joshua Heyne , Ryan W. Davis

Fusel alcohol mixtures containing ethanol, isobutanol, isopentanol, and 2-phenylethanol have been shown to be a promising means to maximize renewable fuel yield from various biomass feedstocks and waste streams. We hypothesized that use of these fusel alcohol mixtures as a blending agent with gasoline can significantly lower the greenhouse gas emissions from the light-duty fleet. Since the composition of fusel alcohol mixtures derived from fermentation is dependent on a variety of factors such as biocatalyst selection and feedstock composition, multi-objective optimization was performed to identify optimal fusel alcohol blends in gasoline that simultaneously maximize thermodynamic efficiency gain and energy density. Pareto front analysis combined with fuel property predictions and a Merit Score-based metric led to prediction of optimal fusel alcohol-gasoline blends over a range of blending volumes. The optimal fusel blends were analyzed based on a Net Fuel Economy Improvement Potential metric for volumetric blending in a gasoline base fuel. The results demonstrate that various fusel alcohol blends provide the ability to maximize efficiency improvement while minimizing increases to blending vapor pressure and decreases to energy density compared to an ethanol-only bioblendstock. Fusel blends exhibit predicted Net Fuel Economy Improvement Potential comparable to neat ethanol when blended with gasoline in all scenarios, with increased improvement over ethanol at moderate to high bio-blendstock blending levels. The optimal fusel blend that was identified was a mixture of 90% v/v isobutanol and 10% v/v 2-phenylethanol, blended at 45% v/v with gasoline, yielding a predicted 4.67% increase in Net Fuel Economy Improvement Potential. These findings suggest that incorporation of fusel alcohols as a gasoline bioblendstock can improve both fuel performance and the net fuel yield of the bioethanol industry.

含有乙醇、异丁醇、异戊醇和2-苯乙醇的杂醇酒混合物已被证明是一种有前途的方法,可以最大限度地从各种生物质原料和废物流中获得可再生燃料的产量。我们假设使用这些杂醇混合物作为汽油的混合剂可以显著降低轻型车队的温室气体排放。由于发酵产生的杂醇醇混合物的组成取决于多种因素,如生物催化剂的选择和原料的组成,因此进行了多目标优化,以确定汽油中最优的杂醇醇混合物,同时最大化热力学效率增益和能量密度。帕累托前沿分析结合燃料性能预测和基于绩效评分的指标,可以在一定的混合量范围内预测出最佳的燃料醇-汽油混合物。基于净燃油经济性改进潜力指标,分析了汽油基燃料体积混合燃料的最佳混合燃料。结果表明,与纯乙醇生物混合物相比,各种杂醇酒混合物提供了最大限度提高效率的能力,同时最大限度地减少了混合蒸汽压的增加和能量密度的降低。在所有情况下,与纯乙醇混合汽油时,混合燃料的净燃料经济性改善潜力可与纯乙醇相媲美,在中高生物混合燃料混合水平下,其改善程度高于乙醇。最终确定的最佳混合燃料为90% v/v的异丁醇和10% v/v的2-苯乙醇的混合物,与汽油以45% v/v的比例混合,预计净燃油经济性改善潜力将提高4.67%。这些发现表明,将杂醇醇作为汽油生物混合物可以提高燃料性能和生物乙醇工业的净燃料产量。
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引用次数: 0
The effect of air-fuel ratio on tailpipe exhaust emission of motorcycles 空燃比对摩托车尾气排放的影响
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2021.100040
O.A. Odunlami , O.K. Oderinde , F.A. Akeredolu , J.A. Sonibare , O.R. Obanla , M.E. Ojewumi

This article presents the actual AFR of the vehicular emission from the tailpipe data of motorcycles with petrol engine in Southwest Nigeria. It also presents the ratio between the actual air-fuel ratio (AFRactual) and the ideal/stoichiometric air-fuel ratio (AFRideal) known as the equivalence air-fuel ratio or lambda (λ). This was compared with the expected value for lambda by the catalytic technology for exhaust gases emission, which is 1 (± 5%). In this study, over 95% of the sampled motorcycles have higher lambda values than expected, thereby emitting very high concentrations of carbon monoxide (CO), hydrocarbon (HC), and carbon dioxide (CO2). The Portable, Hand-Held, battery-operated Kane automotive 4-gas analyser with detector tube (Model Auto 4-1) was used to measure the automobile emissions. The air-fuel ratio is a significant indicator and very important measure for gasoline engine performance controlling and tuning, and anti vehicles exhaust emissions pollution reasons [1]. Internal combustion (IC) gasoline fuelled engines exhaust gases emission depend heavily and mainly on the air-fuel ratio. For a gasoline fuelled engine, carbon monoxide (CO), hydrocarbons (HC), and nitrogen oxides (NOx) exhaust gases emission are significantly influenced by air-fuel ratio. CO and HC are majorly generated or produced with rich air–fuel mixture, while NOx with lean air-fuel mixtures which mean that there is no fixed air-fuel mixture for which it can obtain the minimum for all exhaust gases emission [2]. This study can help in reducing fuel consumption, improving the quality of fuel combustion and reducing vehicle exhaust emissions in Nigeria.

本文从尼日利亚西南部汽油发动机摩托车的排气管数据出发,给出了车辆排放的实际AFR。它还表示实际空气燃料比(AFRactual)和理想/化学计量空气燃料比(AFRideal)之间的比率,称为等效空气燃料比或lambda (λ)。这与废气排放催化技术的lambda期望值(1(±5%))进行了比较。在这项研究中,超过95%的抽样摩托车的lambda值高于预期,从而排放出非常高浓度的一氧化碳(CO)、碳氢化合物(HC)和二氧化碳(CO2)。便携式,手持式,电池供电的凯恩汽车4-气体分析仪与检测管(模型汽车4-1)被用来测量汽车排放。空燃比是汽油机性能控制与调校、防治汽车尾气排放污染原因的重要指标和重要措施[1]。内燃汽油发动机的废气排放在很大程度上主要取决于空燃比。对于以汽油为燃料的发动机,一氧化碳(CO)、碳氢化合物(HC)和氮氧化物(NOx)废气的排放受空燃比的显著影响。CO和HC主要是在富空气燃料混合物中产生或产生的,而NOx则是在贫空气燃料混合物中产生的,这意味着没有一种固定的空气燃料混合物可以使其在所有废气排放中达到最小[2]。这项研究可以帮助减少燃料消耗,提高燃料燃烧质量,减少尼日利亚的汽车尾气排放。
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引用次数: 9
nOn the Use of Ammonia as a Fuel – A Perspective 氨作为燃料的非使用-展望
Pub Date : 2022-04-01 DOI: 10.1016/j.jfueco.2022.100064
O. Herbinet, P. Bartocci, A. G. Dana
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引用次数: 26
Performance improvement of R600a with graphene nanolubricant in a domestic refrigerator as a potential substitute for R134a 石墨烯纳米润滑剂对R600a性能的改进,可作为R134a的潜在替代品
Pub Date : 2022-03-01 DOI: 10.1016/j.jfueco.2021.100034
D. M Madyira , T. O Babarinde , P. M Mashinini

The efficiency of R600a an eco-friendly refrigerant with graphene nanolubricant was investigated and compared in a domestic refrigerator with R134a refrigerant a zero Ozone Depleting Potential (ODP) but higher Global Warming Potential (GWP) refrigerant. Type K thermocouples were attached to the refrigerator components to track the temperature of the system. Two pressure gauges were also attached to the compressor to determine the pressure at suction and discharge of the domestic refrigerator. A digital wattmeter was used to measure the refrigerator's compressor power consumption. The results showed the evaporator air temperature and pull-down time of R600a with graphene nanolubricant were lower compared to R134a. A higher COP was achieved with R600a in graphene nanaolubricant with an increase in cooling capacity within the range of 5.2% to 14.2% and the power consumption reduced within the range of 8.8% to 26.4%. Hence, R600a/graphene nano lubricant can successfully replace R134a/POE oil in a domestic refrigerator system.

研究了含石墨烯纳米润滑剂的环保型制冷剂R600a与零臭氧消耗潜能值(ODP)、高全球变暖潜能值(GWP)制冷剂R134a在家用冰箱中的制冷效率。K型热电偶连接在冰箱组件上,以跟踪系统的温度。压缩机上还安装了两个压力表,以确定家用冰箱吸入和排出时的压力。数字式电能表用于测量冰箱压缩机的耗电量。结果表明,与R134a相比,添加石墨烯纳米润滑剂的R600a蒸发器空气温度和下拉时间均较低。R600a在石墨烯纳米润滑剂中获得了更高的COP,冷却能力提高了5.2% ~ 14.2%,功耗降低了8.8% ~ 26.4%。因此,R600a/石墨烯纳米润滑油可以成功取代R134a/POE油在家用冰箱系统中的应用。
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引用次数: 6
期刊
Fuel Communications
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