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Effect of FeO3 nanoparticles on the thermodynamic and physico-chemical properties of nanofluid based on kernel palm oil methyl ester (KPOME) 纳米FeO3对棕榈仁油甲酯(KPOME)纳米流体热力学和理化性质的影响
Pub Date : 2022-09-01 DOI: 10.1016/j.jfueco.2022.100076
Mengata Mengounou Ghislain, Asse Jean-Bernard, Moukengue Imano Adolphe

This work presents an experimental study on the thermal conductivity, viscosity, flash point and fire point of kernel palm oil methyl esters (KPOME) in the presence of conductive magnetic nanoparticles (FeO3). The mass concentration of FeO3 ranges from 0,10 wt% to 0,20 wt %. The parameters were determined from standard methods. ASTM D7896 for thermal conductivity (λ); ISO 3104 for kinematic viscosity (η), and ASTM D92 for flash point and fire point. The experimental results obtained show that the concentration with the best thermal conductivity between 40°C and 65°C is the 0,20 wt% representing sample 3 (E3). There is an improvement of 20,5% compared to the value of the base esters. On the other hand, between 80°C and 90°C, sample E1 of the concentration that constitutes the basic esters (KPOME) presents better results. A decrease of 49.5% compared to the value of the thermal conductivity of the KPOME is noted. The kinematic viscosity decreased with increasing temperature for all samples. Moreover, in the presence of iron oxide 3, this viscosity improves. The most significant improvement is obtained at 100°C with the 0,15 wt% concentration and the least significant is at 40°C for the 0,20 wt% concentration. The tests of flash point allow us to observe that there is a deterioration of this parameter in the presence of FeO3 nanoparticles in the base bio-insulator (KPOME). The most significant deterioration comes from the sample with a concentration of 0,10 wt%. This means a variation from 155°C to 140,85°C; which gives a deterioration rate of 9,15%. However, the addition of iron nanoparticles rather improves the flash point compared to the base esters. The most important percentage improvement is that of the 0,10 wt% concentration which varies from 160°C to 165,97°C. This represents an improvement of 3,75%.

本研究对棕榈仁油甲酯(KPOME)在导电磁性纳米颗粒(FeO3)存在下的导热性、粘度、闪点和燃点进行了实验研究。FeO3的质量浓度在0.10 wt% ~ 0.20 wt%之间。参数采用标准方法测定。ASTM D7896导热系数(λ);运动粘度(η)为ISO 3104,闪点和燃点为ASTM D92。实验结果表明,样品3 (E3)在40 ~ 65℃范围内导热系数最佳的浓度为0.20 wt%。与基础酯的值相比,提高了20.5%。另一方面,在80℃~ 90℃之间,构成碱性酯(KPOME)浓度的样品E1表现出较好的结果。与kome的热导率值相比,降低了49.5%。所有样品的运动粘度随温度升高而降低。此外,在氧化铁3的存在下,这种粘度有所提高。最显著的改善是在100°C下获得的0.15 wt%的浓度,最不显著的是在40°C下获得的0.20 wt%的浓度。闪点测试允许我们观察到,在碱性生物绝缘体(KPOME)中存在FeO3纳米粒子时,该参数会恶化。最显著的变质来自浓度为0.10 wt%的样品。这意味着从155°C到140,85°C的变化;也就是说,变质率为9.15%。然而,与碱酯相比,铁纳米颗粒的加入反而提高了闪点。最重要的百分比改进是0.10 wt%的浓度,其变化范围从160°C到165.97°C。这代表了3.75%的改进。
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引用次数: 3
Determination of total sulfur in coal by ultraviolet fluorescence method based on the large capacity combustion framework 基于大容量燃烧框架的紫外荧光法测定煤中总硫
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100063
Qunwei Wang , Zhenxing Lin , Qinghua Wu , Li Lin , Qingjian Zhang

In this paper, a systematic method for determination of total sulfur in coal by ultraviolet fluorescence is established based on a self-developed large capacity combustion framework (LCCF). The simple oxidation-combustion mode is upgraded to the pyrolysis-oxidation-combustion mode with the help of LCCF. Thus, components to be analyzed is pyrolyzed slowly and the whole decomposition process of sample is prolonged, which could improve the consistence of test results. The sampling size to be sent into LCCF is significantly increased, and the representativeness of samples is secured, which promotes the improvement of accuracy of testing results. Detection limits are augmented without additional hardware or software improvements by this way. The test systems equipped with conventional combustion tube (CCT) and self-developed LCCF are established differently to test standard coal samples (SCS) and ordinary coal samples (OCS) with different total sulfur range. Accuracy and precision of the two test systems are tested and the optimal injection quantity of the system with LCCF is determined. The results show that LCCF could support the injection quantity of 1000mg and ensure stable and complete combustion of sample, which is far more than that of CCT. The accuracy and precision of the test results are better than the requirements of the existing conventional analysis standards, which shows the excellent structure of LCCF and good performance. The new analysis system can further expand the application of ultraviolet fluorescence method in field of coal and others.

本文在自行研制的大容量燃烧框架(LCCF)的基础上,建立了一种系统的紫外荧光法测定煤中总硫的方法。利用LCCF将简单的氧化-燃烧模式升级为热解-氧化-燃烧模式。这样,待分析组分的热解速度较慢,延长了样品的整个分解过程,提高了测试结果的一致性。送入LCCF的样本量显著增加,保证了样本的代表性,促进了检测结果准确性的提高。通过这种方式,无需额外的硬件或软件改进即可增强检测极限。采用常规燃烧管(CCT)和自行研制的LCCF分别建立测试系统,对不同总硫范围的标准煤样(SCS)和普通煤样(OCS)进行测试。对两种测试系统的准确度和精密度进行了测试,确定了LCCF系统的最佳注射量。结果表明,LCCF可支持1000mg的进样量,并能保证样品的稳定完全燃烧,远远超过CCT。测试结果的准确度和精密度均优于现有常规分析标准的要求,说明LCCF结构优良,性能良好。该分析系统可进一步拓展紫外荧光法在煤炭等领域的应用。
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引用次数: 1
Ignition and combustion characteristics of diesel piloted ammonia injections 柴油机操纵喷氨点火与燃烧特性
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100068
Valentin Scharl, Thomas Sattelmayer

Ammonia is considered a potential carbon-free alternative to fossil fuels. However, its unfavorable combustion characteristics and propensity to form fuel NOx pose a challenge for its use as fuel for internal combustion engines. The high-pressure dual fuel (HPDF) direct-injection of ammonia could offer the potential to reduce ammonia slip and decrease NOx formation. The feasibility of this combustion process has not yet been shown experimentally in literature. This work examines the ignition and combustion characteristics of diesel piloted liquid ammonia sprays under engine-relevant conditions in a rapid-compression-expansion-machine (RCEM). By examining heat release rates (HRRs) under a variety of spatial and temporal spray interaction configurations, charge conditions as well as different diesel pilot amounts and injection durations, the fundamental prerequisites for successful combustion of liquid ammonia sprays are revealed. Strong interaction of the two fuels is found necessary to properly ignite ammonia. Misfiring due to deterioration of the pilot mixture formation can be avoided by injecting diesel first. A strong correlation between main ignition delay and burnout rate suggests a significant influence of wall quenching effects. An investigation of less reactive charge conditions suggests poor suitability of the combustion process for low-load engine operation. While reliable ammonia ignition was achieved for diesel pilot amounts as small as 3.2% of the total injected LHV, ignition is increasingly delayed for smaller pilot amounts. For an operating point, which showed favorable ignition behavior and high conversion rates, pilot fuel amount and injection duration are found to have a major influence on the combustion process.

氨被认为是化石燃料潜在的无碳替代品。然而,其不利的燃烧特性和形成燃料NOx的倾向对其作为内燃机燃料的使用提出了挑战。高压双燃料(HPDF)直喷氨具有减少氨滑和减少NOx生成的潜力。这种燃烧过程的可行性尚未在文献中得到实验证明。本研究在快速压缩膨胀机(RCEM)中研究了柴油先导液氨喷雾器在发动机相关条件下的点火和燃烧特性。通过对不同时空喷油构型、不同装药条件、不同导油量和喷油时间下的热释放率(HRRs)的研究,揭示了液氨喷油成功燃烧的基本前提。两种燃料的强烈相互作用是正确点燃氨所必需的。由于先导混合气变质而引起的失火可以通过先注入柴油来避免。主点火延迟与燃尽率之间有很强的相关性,表明壁面淬火效应对其有显著影响。对低反应负荷条件的研究表明,燃烧过程不适合低负荷发动机运行。虽然在柴油先导量仅占总注入LHV 3.2%的情况下,实现了可靠的氨点火,但在较小的先导量下,点火越来越延迟。对于点火性能好、转化率高的工况点,先导燃油量和喷射时间对燃烧过程有重要影响。
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引用次数: 18
Corrigendum to “Numerical and Experimental Study of Product Gas Characteristics in Premixed Ammonia/Methane/Air laminar flames stabilised in a stagnation flow” [Fuel Communications, Volume 10 (2022), 100054] “在停滞流动中稳定的预混合氨/甲烷/空气层流火焰中产品气体特性的数值和实验研究”的勘误表[燃料通信,第10卷(2022),100054]
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100066
Marina Kovaleva , Akihiro Hayakawa , Sophie Colson , Ekenechukwu C. Okafor , Taku Kudo , Agustin Valera-Medina , Hideaki Kobayashi
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引用次数: 0
On the use of ammonia as a fuel – A perspective 关于使用氨作为燃料的观点
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100064
Olivier Herbinet , Pietro Bartocci , Alon Grinberg Dana

Ammonia has long been considered as a candidate vector for power generation, and has specifically gained significant interest recently. Though it is not free of drawbacks, ammonia has been identified as a promising potential alternative fuel for future power generation. Current studies and a growing body of works in this direction drive us closer to a viable solution of ammonia as an important transition into a cleaner future of the energy sector. In this perspective, we explore the use of ammonia as a fuel in combustion applications (with and without additives) and in fuel cells. The objective of this work is to show the prospects and challenges of ammonia as a fuel, and suggest significant topics that could benefit from additional studies.

长期以来,氨一直被认为是发电的候选载体,最近尤其引起了人们的极大兴趣。尽管氨并非没有缺点,但它已被确定为未来发电的一种有前途的潜在替代燃料。目前的研究和在这个方向上越来越多的工作使我们更接近可行的氨解决方案,作为能源部门向更清洁的未来的重要过渡。从这个角度来看,我们探索了氨作为燃料在燃烧应用(有和没有添加剂)和燃料电池中的使用。这项工作的目的是展示氨作为燃料的前景和挑战,并提出可能从进一步研究中受益的重要主题。
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引用次数: 22
A review on renewable energy potentials and energy usage statistics in Ghana 加纳可再生能源潜力和能源使用统计资料综述
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100065
Mohammed Takase, Michael Aboah, Rogers Kipkoech

This paper is a review of renewable energy potentials and energy usage statistics in Ghana. Principally, it covers Ghana's energy consumption from 2000 to 2020. The findings show that Ghana uses both renewable (10%) and non-renewable (90%) forms of energy, but biomass (46.667%) and oil (40.52%) are the commonly used energy resource. This is followed by natural gas (10%), hydroelectric power (7%), and solar energy (0%). The energy consumption by sector from 2000 to 2020 totaled up to 130632ktoe. Residents featured 62,736ktoe (48%) as well as industries, service, agriculture, and transport with each recording 18254ktoe, 5033ktoe, 1957ktoe, and 42652ktoe respectively. The review revealed that the energy demand of the country (Ghana) has shot up and therefore, there is the need for more sustainable energy alternatives to be employed in the energy processes of the country to offset the impacts of future energy crises.

本文回顾了加纳的可再生能源潜力和能源使用统计数据。它主要涵盖了加纳2000年至2020年的能源消耗。研究结果表明,加纳使用可再生能源(10%)和不可再生能源(90%),但生物质(46.667%)和石油(40.52%)是常用的能源。其次是天然气(10%)、水力发电(7%)和太阳能(0%)。2000年至2020年,各部门能源消耗总量达130632千吨油当量。居民为62736万吨级(48%),工业为18254万吨级,服务业为5033万吨级,农业为1957万吨级,运输业为42652万吨级。审查显示,该国(加纳)的能源需求急剧增加,因此,需要在该国的能源过程中采用更可持续的替代能源,以抵消未来能源危机的影响。
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引用次数: 9
Investigation of the acoustics of full-scale perforated liners in gas turbine combustors 燃气轮机燃烧室全尺寸穿孔衬板的声学研究
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100060
Abdullah Shahjalal, Lam Hak-Keung

In conventional gas turbine combustors, the combustion chamber linings are perforated and used for cooling. To cool the liner evenly, bias flows are introduced into the combustor at rates that depend on the operating condition. It has been found that airflow through the liner not only provides cooling but also improves sound absorption and acoustic instability. This experiment reports a unique comprehensive investigation of the influences of single and double-layer cylindrical full-scale gas turbine combustor liner sound absorption properties based on the no flow and non zero bias flows. In particular it is shown that combustor liner porosity (determined by orifice diameter and axial pitch distance) has an important influence on non-zero bias flow in that it increases the peak absorption or dissipation compared with that which occurs in the absence of flow. It is shown that the main influence of bias flow is to increase absorption compared with no flow above 600 Hz and to decrease the transmission loss measured in the absence of flow below 600 Hz but to increase it above 600 Hz. Internal resonance in the combustion liner test section influences both absorption and transmission loss spectra near 600 Hz. To create higher damping, and decrease in acoustic instability during the combustion process, gas turbine combustors require mapping between the inner and outer liner perforation to increase efficiency and lower the hydrocarbon emission. The calculated pressure ratio versus mass flow and combined discharge coefficient effect explain the non-linear distribution of the absorptive and dissipative energy measured at the gas turbine combustor.

在传统的燃气轮机燃烧室中,燃烧室内衬是穿孔的,用于冷却。为了均匀地冷却内衬,偏置流以取决于运行条件的速率引入燃烧室。研究发现,通过内衬的气流不仅提供冷却,而且改善了吸声和声不稳定性。本文报道了基于无流和非零偏流的单层和双层圆柱形全尺寸燃气轮机燃烧室衬板吸声特性影响的独特综合研究。特别是燃烧室衬垫孔隙度(由孔直径和轴向螺距决定)对非零偏置流动有重要影响,因为与无流动时相比,它增加了峰值吸收或耗散。结果表明,偏置流的主要影响是相对于600 Hz以上无流时增加吸收;相对于600 Hz以上无流时减小传输损耗,而相对于600 Hz以上无流时增大传输损耗。燃烧衬板测试截面的内部共振对600 Hz附近的吸收和透射损失谱都有影响。为了在燃烧过程中产生更高的阻尼,并减少声不稳定性,燃气轮机燃烧室需要在内胆和外胆射孔之间进行映射,以提高效率并降低碳氢化合物排放。计算得到的压流量比和综合流量系数效应解释了燃气轮机燃烧室测得的吸散能的非线性分布。
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引用次数: 1
Technologies for the production of renewable natural gas from organic wastes and their opportunities in existing Canadian pipelines 从有机废物中生产可再生天然气的技术及其在现有加拿大管道中的机会
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100056
Omid Norouzi, Mohammad Heidari, Animesh Dutta

Of all the types of renewable energy, Renewable Natural Gas (RNG) market has been more supported and developed in Canada due to the lower project cost and the existing NG pipeline infrastructure. RNG is defined as a methane-rich gas obtained through combining Anaerobic Digestion (AD) of underutilized renewable sources (organic waste streams) and upgrading technologies. Membrane separation technology is considered one of Canada's most popular upgrading technologies due to the country-old knowledge regarding gas permeation membranes widely used in the NG industry. Membrane systems are used to recover methane from biogas to a level that meets current natural gas pipeline specifications set out by gas utility companies or meets natural gas vehicle fuel standards set out by engine manufacturers. Here we review standards for gas injection into existing Canadian pipelines, commercial biogas upgrading systems in Canada, and Current biogas upgrading to RNG projects in Canada. We focus more on membrane technology and discuss the possible driving force, module, and configuration alternatives. Finally, this review comprehensively examines membrane types and advances in composite type membranes.

在所有类型的可再生能源中,由于项目成本较低和现有的天然气管道基础设施,加拿大的可再生天然气(RNG)市场得到了更多的支持和发展。RNG被定义为通过对未充分利用的可再生资源(有机废物流)进行厌氧消化(AD)和升级技术相结合而获得的富含甲烷的气体。膜分离技术被认为是加拿大最受欢迎的升级技术之一,因为这个国家对天然气工业中广泛使用的气体渗透膜有着悠久的了解。膜系统用于从沼气中回收甲烷,使其达到天然气公用事业公司制定的当前天然气管道规格或发动机制造商制定的天然气汽车燃料标准。在这里,我们回顾了加拿大现有管道的注气标准、加拿大的商业沼气升级系统以及加拿大目前的沼气升级到RNG项目。我们将更多地关注膜技术,并讨论可能的驱动力、模块和配置替代方案。最后,综述了复合膜的种类和研究进展。
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引用次数: 1
Improvement of SI engine combustion with ammonia as fuel: Effect of ammonia dissociation prior to combustion 改进以氨为燃料的内燃机燃烧:燃烧前氨解离的影响
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100058
A. Mercier , C. Mounaïm-Rousselle , P. Brequigny , J. Bouriot , C. Dumand

Although recent studies have shown the possibility of running ‘standard’ spark-ignition engines with pure ammonia, the operating range remains limited mainly due to the unfavorable characteristics of ammonia for premixed combustion and often requires the addition of a complementary fuel such as H2 to extend it. As the best way to add H2 is to crack ammonia directly on-board, this paper focuses on the impact of the upstream cracking level of ammonia on the performance and emissions of a single cylinder spark ignition engine. Experiments were performed over several equivalence ratios, dissociation rates and load conditions. It is confirmed that only a slight rate of ammonia dissociation (10%) upstream of the combustion considerably enhances the engine's operating range thanks to a better combustion stability. In terms of pollutant emissions, the partial dissociation of ammonia, especially for slightly lean mixtures induces a very clear trade-off between high NOx and high unburned ammonia level for high and low ammonia dissociation rates, respectively. Therefore, cracking NH3 does not only improve the operating range of ammonia-fueled spark ignition engines but can also help to reduce NH3. However, to reach the same engine output work, higher ammonia fuel consumption will be necessary since the global system efficiency is lower using fuel dissociation. In addition, the global warming effect is increased with dissociation level since a higher level of N2O is generated by the hydrogen contribution.

尽管最近的研究表明,使用纯氨运行“标准”火花点火发动机是可能的,但由于氨对预混燃烧的不利特性,通常需要添加H2等补充燃料来延长其运行范围,因此工作范围仍然有限。由于添加H2的最佳方式是直接在车上裂解氨,因此本文主要研究氨的上游裂解水平对单缸火花点火发动机性能和排放的影响。实验在几种等效比、解离率和负载条件下进行。经证实,仅在燃烧上游进行少量的氨解离(10%)就能显著提高发动机的工作范围,这得益于更好的燃烧稳定性。在污染物排放方面,氨的部分解离,特别是对于略稀薄的混合物,分别导致高和低氨解离率的高NOx和高未燃烧氨水平之间的非常明显的权衡。因此,裂解NH3不仅可以提高氨燃料火花点火发动机的工作范围,而且有助于降低NH3。然而,为了达到相同的发动机输出功,更高的氨燃料消耗将是必要的,因为使用燃料解离的整体系统效率较低。此外,由于氢的贡献产生了更高水平的N2O,全球变暖效应随着解离水平的增加而增加。
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引用次数: 22
Editorial for the special issue on ammonia as a fuel solution for future decarbonized energy systems 关于氨作为未来脱碳能源系统的燃料解决方案的特刊社论
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100067
Alon Grinberg Dana , Olivier Herbinet
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引用次数: 0
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Fuel Communications
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