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Maximizing net fuel economy improvement from fusel alcohol blends in gasoline using multivariate optimization 使用多元优化,最大限度地提高汽油中杂醇酒混合物的净燃油经济性
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2022.100059
Lily Behnke , Eric Monroe , Bernard Nguyen , Alexander Landera , Anthe George , Zhibin Yang , Joshua Heyne , Ryan W. Davis

Fusel alcohol mixtures containing ethanol, isobutanol, isopentanol, and 2-phenylethanol have been shown to be a promising means to maximize renewable fuel yield from various biomass feedstocks and waste streams. We hypothesized that use of these fusel alcohol mixtures as a blending agent with gasoline can significantly lower the greenhouse gas emissions from the light-duty fleet. Since the composition of fusel alcohol mixtures derived from fermentation is dependent on a variety of factors such as biocatalyst selection and feedstock composition, multi-objective optimization was performed to identify optimal fusel alcohol blends in gasoline that simultaneously maximize thermodynamic efficiency gain and energy density. Pareto front analysis combined with fuel property predictions and a Merit Score-based metric led to prediction of optimal fusel alcohol-gasoline blends over a range of blending volumes. The optimal fusel blends were analyzed based on a Net Fuel Economy Improvement Potential metric for volumetric blending in a gasoline base fuel. The results demonstrate that various fusel alcohol blends provide the ability to maximize efficiency improvement while minimizing increases to blending vapor pressure and decreases to energy density compared to an ethanol-only bioblendstock. Fusel blends exhibit predicted Net Fuel Economy Improvement Potential comparable to neat ethanol when blended with gasoline in all scenarios, with increased improvement over ethanol at moderate to high bio-blendstock blending levels. The optimal fusel blend that was identified was a mixture of 90% v/v isobutanol and 10% v/v 2-phenylethanol, blended at 45% v/v with gasoline, yielding a predicted 4.67% increase in Net Fuel Economy Improvement Potential. These findings suggest that incorporation of fusel alcohols as a gasoline bioblendstock can improve both fuel performance and the net fuel yield of the bioethanol industry.

含有乙醇、异丁醇、异戊醇和2-苯乙醇的杂醇酒混合物已被证明是一种有前途的方法,可以最大限度地从各种生物质原料和废物流中获得可再生燃料的产量。我们假设使用这些杂醇混合物作为汽油的混合剂可以显著降低轻型车队的温室气体排放。由于发酵产生的杂醇醇混合物的组成取决于多种因素,如生物催化剂的选择和原料的组成,因此进行了多目标优化,以确定汽油中最优的杂醇醇混合物,同时最大化热力学效率增益和能量密度。帕累托前沿分析结合燃料性能预测和基于绩效评分的指标,可以在一定的混合量范围内预测出最佳的燃料醇-汽油混合物。基于净燃油经济性改进潜力指标,分析了汽油基燃料体积混合燃料的最佳混合燃料。结果表明,与纯乙醇生物混合物相比,各种杂醇酒混合物提供了最大限度提高效率的能力,同时最大限度地减少了混合蒸汽压的增加和能量密度的降低。在所有情况下,与纯乙醇混合汽油时,混合燃料的净燃料经济性改善潜力可与纯乙醇相媲美,在中高生物混合燃料混合水平下,其改善程度高于乙醇。最终确定的最佳混合燃料为90% v/v的异丁醇和10% v/v的2-苯乙醇的混合物,与汽油以45% v/v的比例混合,预计净燃油经济性改善潜力将提高4.67%。这些发现表明,将杂醇醇作为汽油生物混合物可以提高燃料性能和生物乙醇工业的净燃料产量。
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引用次数: 0
The effect of air-fuel ratio on tailpipe exhaust emission of motorcycles 空燃比对摩托车尾气排放的影响
Pub Date : 2022-06-01 DOI: 10.1016/j.jfueco.2021.100040
O.A. Odunlami , O.K. Oderinde , F.A. Akeredolu , J.A. Sonibare , O.R. Obanla , M.E. Ojewumi

This article presents the actual AFR of the vehicular emission from the tailpipe data of motorcycles with petrol engine in Southwest Nigeria. It also presents the ratio between the actual air-fuel ratio (AFRactual) and the ideal/stoichiometric air-fuel ratio (AFRideal) known as the equivalence air-fuel ratio or lambda (λ). This was compared with the expected value for lambda by the catalytic technology for exhaust gases emission, which is 1 (± 5%). In this study, over 95% of the sampled motorcycles have higher lambda values than expected, thereby emitting very high concentrations of carbon monoxide (CO), hydrocarbon (HC), and carbon dioxide (CO2). The Portable, Hand-Held, battery-operated Kane automotive 4-gas analyser with detector tube (Model Auto 4-1) was used to measure the automobile emissions. The air-fuel ratio is a significant indicator and very important measure for gasoline engine performance controlling and tuning, and anti vehicles exhaust emissions pollution reasons [1]. Internal combustion (IC) gasoline fuelled engines exhaust gases emission depend heavily and mainly on the air-fuel ratio. For a gasoline fuelled engine, carbon monoxide (CO), hydrocarbons (HC), and nitrogen oxides (NOx) exhaust gases emission are significantly influenced by air-fuel ratio. CO and HC are majorly generated or produced with rich air–fuel mixture, while NOx with lean air-fuel mixtures which mean that there is no fixed air-fuel mixture for which it can obtain the minimum for all exhaust gases emission [2]. This study can help in reducing fuel consumption, improving the quality of fuel combustion and reducing vehicle exhaust emissions in Nigeria.

本文从尼日利亚西南部汽油发动机摩托车的排气管数据出发,给出了车辆排放的实际AFR。它还表示实际空气燃料比(AFRactual)和理想/化学计量空气燃料比(AFRideal)之间的比率,称为等效空气燃料比或lambda (λ)。这与废气排放催化技术的lambda期望值(1(±5%))进行了比较。在这项研究中,超过95%的抽样摩托车的lambda值高于预期,从而排放出非常高浓度的一氧化碳(CO)、碳氢化合物(HC)和二氧化碳(CO2)。便携式,手持式,电池供电的凯恩汽车4-气体分析仪与检测管(模型汽车4-1)被用来测量汽车排放。空燃比是汽油机性能控制与调校、防治汽车尾气排放污染原因的重要指标和重要措施[1]。内燃汽油发动机的废气排放在很大程度上主要取决于空燃比。对于以汽油为燃料的发动机,一氧化碳(CO)、碳氢化合物(HC)和氮氧化物(NOx)废气的排放受空燃比的显著影响。CO和HC主要是在富空气燃料混合物中产生或产生的,而NOx则是在贫空气燃料混合物中产生的,这意味着没有一种固定的空气燃料混合物可以使其在所有废气排放中达到最小[2]。这项研究可以帮助减少燃料消耗,提高燃料燃烧质量,减少尼日利亚的汽车尾气排放。
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引用次数: 9
nOn the Use of Ammonia as a Fuel – A Perspective 氨作为燃料的非使用-展望
Pub Date : 2022-04-01 DOI: 10.1016/j.jfueco.2022.100064
O. Herbinet, P. Bartocci, A. G. Dana
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引用次数: 26
Performance improvement of R600a with graphene nanolubricant in a domestic refrigerator as a potential substitute for R134a 石墨烯纳米润滑剂对R600a性能的改进,可作为R134a的潜在替代品
Pub Date : 2022-03-01 DOI: 10.1016/j.jfueco.2021.100034
D. M Madyira , T. O Babarinde , P. M Mashinini

The efficiency of R600a an eco-friendly refrigerant with graphene nanolubricant was investigated and compared in a domestic refrigerator with R134a refrigerant a zero Ozone Depleting Potential (ODP) but higher Global Warming Potential (GWP) refrigerant. Type K thermocouples were attached to the refrigerator components to track the temperature of the system. Two pressure gauges were also attached to the compressor to determine the pressure at suction and discharge of the domestic refrigerator. A digital wattmeter was used to measure the refrigerator's compressor power consumption. The results showed the evaporator air temperature and pull-down time of R600a with graphene nanolubricant were lower compared to R134a. A higher COP was achieved with R600a in graphene nanaolubricant with an increase in cooling capacity within the range of 5.2% to 14.2% and the power consumption reduced within the range of 8.8% to 26.4%. Hence, R600a/graphene nano lubricant can successfully replace R134a/POE oil in a domestic refrigerator system.

研究了含石墨烯纳米润滑剂的环保型制冷剂R600a与零臭氧消耗潜能值(ODP)、高全球变暖潜能值(GWP)制冷剂R134a在家用冰箱中的制冷效率。K型热电偶连接在冰箱组件上,以跟踪系统的温度。压缩机上还安装了两个压力表,以确定家用冰箱吸入和排出时的压力。数字式电能表用于测量冰箱压缩机的耗电量。结果表明,与R134a相比,添加石墨烯纳米润滑剂的R600a蒸发器空气温度和下拉时间均较低。R600a在石墨烯纳米润滑剂中获得了更高的COP,冷却能力提高了5.2% ~ 14.2%,功耗降低了8.8% ~ 26.4%。因此,R600a/石墨烯纳米润滑油可以成功取代R134a/POE油在家用冰箱系统中的应用。
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引用次数: 6
Three classes of Earliness-Tardiness (E/T) scheduling problems 三类早-迟(E/T)调度问题
Pub Date : 2022-03-01 DOI: 10.1016/j.jfueco.2021.100047
Saheed Akande , Ganiyu Ajisegiri

In this work, the tolerance window defined as the variations of gains and penalty associated with the earliness component of the Linear Composite Objective Function (LCOF) of Earliness–Tardiness (E/T) scheduling problems were explored to establish three different classes of the problem. Two variants of E/T problems has been established in the literature; the problems with unknown due-date with the objective of optimizing jobs due-date and the problems with a known due-date for optimizing the E/T cost function. The latter variant considered in this work applies the concept of Just-In-Time (JIT) as the basis for optimizing the E/T cost function. However, while the ideal JIT schedule which tends towards zero LCOF is notional, the deviation is a function of the tolerance window. To the best of the researchers’ knowledge, there is a gap between the measures of the deviation called the delivery reliability or penalty cost function and the tolerance window. This work closes the gap. A numerical example was solved to demonstrate the three problem classes’ utility using the Early Due Date (EDD) algorithm as the hypothetical solution.

本文研究了线性复合目标函数(LCOF)的提前-延迟调度问题的增益和惩罚变化的容忍窗口,建立了三种不同类型的提前-延迟调度问题。E/T问题的两种变体已在文献中建立;以优化作业截止日期为目标的未知问题和以优化E/T成本函数为目标的已知截止日期问题。本文考虑的后一种变体应用了准时制(JIT)的概念,作为优化E/T成本函数的基础。然而,虽然趋向于零LCOF的理想JIT计划是理论上的,但偏差是公差窗口的函数。据研究人员所知,偏差的度量称为交付可靠性或惩罚成本函数与容忍窗口之间存在差距。这项工作弥补了这一差距。通过一个数值算例,以提前到期日(EDD)算法为假设解,说明了这三种问题的实用性。
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引用次数: 0
Friction factor effect and heat transfer enhancement in combined dimple geometry arrange in different angle to flow direction 复合韧窝几何形状与流动方向成不同角度排列时的摩擦因数效应和换热强化作用
Pub Date : 2022-03-01 DOI: 10.1016/j.jfueco.2021.100043
S.A. Aasa , A.S. Shote , S.O. Giwa , M. Sharifpur

One of the most effective passive techniques for heat transfer enhancement in heat exchanger devices is the surface roughness flow augmentation model. In this study, the surface pressure and heat transfer are measured using experimental and computational methods in a rectangular channel. Three aspect ratios, AR, 0.05, 0.035, and 0.025, dimple channel with pitch to depth ratios, P/δ = 6 are tested in this study. The angled dimple surface comprises of two cases; case 1 0 °Circular - 45°Oval dimple (0 °C – 45°O) and Case2 45° Oval - 0° Circular dimple (45° O – 0 °C). The computational study is conducted for Reynolds number, Re 600–11000. The data from the compound-dimple channel is normalized with the smooth channel data of heat transfer and friction factor parameters. It is revealed that friction factors, f, friction factors ratio, f/fo, average Nusselt number, Nuavg, Nusselt number ratios, Nu/Nuo, are dependent on Re. The performance index on the compound dimple surface using the ratio of Nusselt numbers, Nu/Nuo, to friction factors, f/fo. The arrangement and location of the dimple have momentous consequences for the pressure drop parameters f and f/fo. The surface pressure and temperature show that the flow is uniformly distributed in the channel. The performance index improves and Re has strong influence on it. The compound dimple geometry does indicate a strong model for application in heat exchanger devices. Optimum performance of 49% for case 1 and 23% for case 2 are observed.

在换热器装置中,最有效的被动强化传热技术之一是表面粗糙度流增强模型。在本研究中,采用实验和计算方法测量了矩形通道中的表面压力和传热。在P/δ = 6的情况下,对三种纵横比AR、0.05、0.035和0.025的酒窝通道进行了测试。所述角度凹陷面包括两种情况;病例1 0°圆形- 45°椭圆形酒窝(0°C - 45°O)和病例2 45°椭圆形- 0°圆形酒窝(45°O - 0°C)。对雷诺数Re 600 ~ 11000进行了计算研究。将复合凹陷通道的数据与光滑通道的传热和摩擦系数参数进行归一化。结果表明,摩擦因数f、摩擦因数比f/fo、平均努塞尔数、努塞尔数比Nuavg、努塞尔数比Nu/Nuo均与Re有关。用努塞尔数Nu/Nuo与摩擦因数f/fo之比来表征复合凹痕表面的性能指标。压窝的布置和位置对压降参数f和f/fo有重要影响。表面压力和温度表明流动在通道内分布均匀。性能指标提高,Re对其影响较大。复合韧窝的几何形状为换热器的应用提供了一个强有力的模型。情况1的最佳性能为49%,情况2的最佳性能为23%。
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引用次数: 0
Challenges in Kinetic modeling of ammonia pyrolysis 氨热解动力学建模的挑战
Pub Date : 2022-03-01 DOI: 10.1016/j.jfueco.2022.100049
Peter Glarborg , Hamid Hashemi , Paul Marshall

Ammonia pyrolysis reactions have implications for its ignition and oxidation in engines and gas turbines. In the present work, the chemistry of ammonia pyrolysis is investigated by kinetic modeling and theory. Rate constants for key reactions are carefully evaluated based on available experimental and theoretical results. The high pressure limit k1, for NH2 + H (+M) NH3 (+M) (R1) is calculated to be essentially the collision frequency, indicating that dissociation of ammonia in combustion processes will be at or close to the low pressure limit even at engine and gas turbine conditions. The chemical kinetic model is validated against reported shock tube measurements of NH3, NH2, and NH in ammonia pyrolysis. Predictions are in good agreement with observations for dilute conditions ( 0.5% NH3), but the model appears to underpredict the NH3 consumption rate at longer times in less dilute mixtures. At short reaction times, thermal dissociation of NH3, together with the NH3 + H reaction, controls conversion. At longer times, secondary reactions involving NH2 and NH become important due to their impact on the radical pool. Predictions become sensitive to formation and consumption of diazene (tHNNH and cHNNH). Several of the key steps in the ammonia pyrolysis mechanism are radical-radical reactions that are difficult to measure accurately and challenging to calculate theoretically, and a more comprehensive experimental characterization is desirable to support further model development.

氨热解反应对氨在发动机和燃气轮机中的点火和氧化具有重要意义。本文从动力学模型和理论两方面研究了氨热解的化学过程。根据现有的实验和理论结果,对关键反应的速率常数进行了仔细的评估。NH2 + H (+M) (R1)的高压极限k1,∞被计算为本质上的碰撞频率,表明即使在发动机和燃气轮机工况下,燃烧过程中氨的解离也将处于或接近低压极限。化学动力学模型通过对氨热解过程中NH3、NH2和NH的激波管测量进行了验证。对于稀释条件(NH3≤0.5%),预测结果与观测结果非常吻合,但该模型似乎低估了在较低稀释混合物中较长时间的NH3消耗率。在较短的反应时间内,NH3的热解离和NH3 + H反应控制了转化。在较长的时间内,涉及NH2和NH的二次反应因其对自由基池的影响而变得重要。预测对二氮烯(tHNNH和cHNNH)的形成和消耗变得敏感。氨热解机理的几个关键步骤是自由基-自由基反应,这些反应很难精确测量,理论上也很难计算,需要更全面的实验表征来支持进一步的模型开发。
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引用次数: 18
Human health risk evaluation of sodium and ironic elements variability in ground water: A case study of Abuja North, Nigeria 地下水中钠和讽刺元素变异的人类健康风险评价:以尼日利亚北部阿布贾为例研究
Pub Date : 2022-03-01 DOI: 10.1016/j.jfueco.2021.100041
Olugbenga Oludolapo Amu , Eyitope Oluseyi Amu , Ehizemhen Christopher Igibah , Lucia Omolayo Agashua

Harmful substance tends to come into water bodies through geodesic and human-induced sources, therefore persistent drinking water monitoring schemes are crucial. The goal of this paper was to estimate the human health threat posed through high sodium and iron accumulation in borehole water used for both consumption and domestic activities. As this will help in the prevention of water-related sicknesses and maintenance of good health for human being that rely on water to survive. Specially, rural region need to be enlightened about biochemistry of the mineral elements ingested, since excessive intake of some minerals can upset homeostatic balance and cause toxic side effects. For instance, excess sodium ingestion ensuing from daily intake of saline origins is associated with high blood pressure, while excess iron intake can stimulate liver impairment or brain damage which connected to aging and protein-misfolding neurodegenerative ailments. More importantly, when an individual suffering from a chronic sickness take prescriptions with water of unknown quality as human being believes that groundwater possess safe water quality, the health situation becomes worst. In this paper, iron accumulation in borehole water varied at distinct sites, span between 0.01 mg/L and 2.95 mg/L with a mean value of 1.02 mg/L whereas that of sodium range from 55.98 mg/L to 515.45 mg/L with mean value of 260.19 mg/L. The Hierarchical cluster scrutiny revealed three common clusters wherein the samplings could be grouped. The non-carcinogenic threat was calculated and the Total Threat Index above 1.0 for sodium ingestion in the scrutinized sites was gotten from all locations.

有害物质往往通过测地线和人为来源进入水体,因此持久的饮用水监测方案至关重要。本文的目的是估计用于消费和家庭活动的井水中高钠和高铁积累对人类健康造成的威胁。因为这将有助于预防与水有关的疾病,并维持依赖水生存的人类的良好健康。特别是农村地区需要了解摄入矿物质元素的生物化学,因为过量摄入某些矿物质会破坏体内平衡并产生毒副作用。例如,每天摄入盐水导致的过量钠摄入与高血压有关,而过量的铁摄入会刺激肝损伤或脑损伤,这与衰老和蛋白质错误折叠神经退行性疾病有关。更重要的是,当患有慢性疾病的人服用水质不明的水时,人类认为地下水具有安全的水质,健康状况变得最糟糕。不同地点井水铁积累量不同,在0.01 ~ 2.95 mg/L之间,平均值为1.02 mg/L;钠积累量在55.98 ~ 515.45 mg/L之间,平均值为260.19 mg/L。分层聚类审查揭示了三个常见的聚类,其中的样本可以分组。计算非致癌性威胁,并从所有地点获得审查地点钠摄入的总威胁指数大于1.0。
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引用次数: 0
Performance charateristics of a conventional spark ignition petrol engine powered by biogas 以沼气为动力的传统火花点火汽油发动机的性能特性
Pub Date : 2022-03-01 DOI: 10.1016/j.jfueco.2021.100032
Eseoghene Daniel Karakitie, Chisom Emmanuel Aralu, Abimbola David Fadare

This research investigates the use of biogas to run a spark ignition petrol engine and test for the engine performance. Conventional spark ignition petrol engine was modified into a dual fuel engine by changing the engine single fuel carburettor to dual fuel carburettor. The air orifice was closed by 50% to enable cooled start with natural biogas as the low calorific value won't facilitate combustion. The speed, torque, and other engine parameters where measured using a TD200 small engine test set (hydraulic brake dynamometer) interface and emissions of SO2, CO were measured using an emissions analyser. The torque, brake power was higher for petrol by 39% than the biogas due to the lower calorific value of biogas. The exhaust temperature, SO2 and CO was 49% lower for the biogas than the petrol. The comparative analysis of the modified engine showed that petrol can be substituted partly with biogas and the engine used for varying applications because it offers window escape on the hydrocarbon reservoir depletion, green gasses emission from the use of these petrol and landfill emission as well.

本文研究了利用沼气驱动火花点火汽油发动机,并对发动机性能进行了测试。将传统的火花点火式汽油发动机由单燃油器改为双燃油器,改造为双燃油器发动机。由于天然沼气的热值低,不利于燃烧,因此将空气孔关闭50%,使其能够冷却启动。使用TD200小型发动机测试装置(液压制动测力仪)接口测量发动机的转速、扭矩和其他参数,使用排放分析仪测量SO2、CO的排放量。由于沼气的热值较低,汽油的扭矩和制动功率比沼气高39%。沼气的排气温度、SO2和CO比汽油低49%。通过对改良后的发动机的对比分析表明,汽油可以部分地被沼气所取代,并且该发动机可用于各种用途,因为它为烃类储层枯竭、使用这些汽油产生的绿色气体排放和垃圾填埋排放提供了逃逸窗口。
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引用次数: 3
Sustainable energy for national climate change, food security and employment opportunities: Implications for Nigeria 可持续能源促进国家气候变化、粮食安全和就业机会:对尼日利亚的影响
Pub Date : 2022-03-01 DOI: 10.1016/j.jfueco.2021.100045
Oluseyi O. Ajayi , Geev Mokryani , Bose M. Edun

This paper looks into the issues around renewable energy with a view to identify the opportunities for Nigeria and critically review the nation's renewable energy policy vis-à-vis the efforts and achievement of governments and indigenous practitioners. It identified the inherent opportunities of renewable energy resources at ameliorating the incidents of climate change and global warming and also surveyed international statistics on the relationships between energy and renewable energy adoption, national development, population explosion, job creation and rural-urban integration. It found out that for Nigeria to sustain economic growth especially as it relates to agriculture and food security, renewable energy for power generation must be included in the nation's rural development plan. It also demonstrated that renewable energy poses an opportunity for mitigating the nation's contributions to anthropogenic climate change.

本文着眼于围绕可再生能源的问题,以确定尼日利亚的机会,并通过-à-vis政府和土著从业者的努力和成就批判性地审查该国的可再生能源政策。它确定了可再生能源在减轻气候变化和全球变暖事件方面的固有机会,并调查了关于能源和可再生能源采用、国家发展、人口爆炸、创造就业机会和城乡一体化之间关系的国际统计数字。报告发现,尼日利亚要维持经济增长,特别是在农业和粮食安全方面,必须将可再生能源发电纳入该国的农村发展计划。它还表明,可再生能源为减轻国家对人为气候变化的贡献提供了一个机会。
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引用次数: 14
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