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Annular cement sheath characterization and hydraulic aperture assessment through single- and two-phase seepage tests 通过单阶段和两阶段渗流试验对环空水泥环进行表征和水力孔径评价
0 ENERGY & FUELS Pub Date : 2024-11-23 DOI: 10.1016/j.geoen.2024.213515
Victor Nogueira Lima , Amir Taheri , Erlend Randeberg , Hans Joakim Skadsem
The integrity of well barriers is critical throughout the life cycle of oil and gas wells, with annular cement as a key component in maintaining the structural integrity of the barrier system. In this study, an annular cemented section with a well-defined microannulus was systematically constructed and characterized, and both single- and two-phase seepage tests were conducted to gain a deeper understanding of how relative permeability impacts the estimation of hydraulic aperture in potential leakage pathways. The test cell design allows modification of the microannulus gap size by changing the pressure applied inside the inner casing. This enables studying different microannulus sizes throughout the conducted tests. The single-phase seepage tests showed consistent measurements of hydraulic aperture for both gas and water, despite variations in fluid type and applied pressure, with surface roughness likely affecting the non-linear behavior of the hydraulic aperture under stress. The two-phase seepage tests demonstrated a clear relationship between breakthrough pressure and microannulus size, with the van Genuchten model providing a better fit for relative permeability and capillary pressure data. Breakthrough time experiments revealed that initial permeability estimations were significantly lower than those obtained from single-phase tests; however, once relative permeability at breakthrough was accounted for, the estimated absolute permeability values aligned closely with the single-phase experimental data. These findings offer valuable insights into the complex interactions between cement sheath integrity and gas migration, potentially contributing to developing new well integrity assessment technologies, including tracer gas below the well barrier element, as well as insights relevant for both gas migration and sustained casing pressure analysis.
在油气井的整个生命周期中,井眼屏障的完整性至关重要,环空水泥是保持井眼屏障系统结构完整性的关键组成部分。在这项研究中,系统地构建了一个具有明确微环空的环空胶结段,并对其进行了表征,并进行了单相和两相渗流试验,以更深入地了解相对渗透率如何影响潜在泄漏路径中水力孔径的估计。测试单元的设计允许通过改变内层套管内施加的压力来改变微环空间隙的大小。这样就可以在整个测试过程中研究不同的微环空尺寸。单相渗流试验显示,尽管流体类型和施加压力不同,但气体和水的水力孔径测量结果一致,表面粗糙度可能会影响应力作用下水力孔径的非线性行为。两相渗流试验表明,突破压力与微环空尺寸之间存在明显的关系,van Genuchten模型可以更好地拟合相对渗透率和毛管压力数据。突破时间实验表明,初始渗透率估计值明显低于单相试验结果;然而,一旦考虑了突破处的相对渗透率,估计的绝对渗透率值与单相实验数据非常吻合。这些发现为水泥环完整性与气体运移之间的复杂相互作用提供了有价值的见解,可能有助于开发新的井完整性评估技术,包括井屏障元件下的示踪气体,以及与气体运移和持续套管压力分析相关的见解。
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引用次数: 0
Controlling parameters of co-current and counter-current imbibition in naturally fractured reservoirs 天然裂缝储层中同流和逆流浸润的控制参数
0 ENERGY & FUELS Pub Date : 2024-11-22 DOI: 10.1016/j.geoen.2024.213520
Marzhan Karimova, Assylzhan Zhetpissov, Randy Hazlett, Peyman Pourafshary
Naturally fractured formations are complex petroleum reservoirs that are poor candidates for waterflooding due to difficulties in controlling sweep. Injected water can readily propagate through the fracture system, bypassing the hydrocarbon stored in the matrix. Instead, such systems rely on spontaneous imbibition (SI) from the matrix into the extensive fracture gathering system. SI is a crucial recovery mechanism that relies on capillary pressure-dominated fluid movement. SI can occur through two modes, co-current (COSI) and counter-current (COUSI), depending on the relative direction of fluid movement in response to prevailing boundary conditions. Analytical solutions that incorporate the diffusivity coefficient, which combines relative permeability and capillary pressure curves, are used to describe co-current and counter-current imbibition mechanisms. The perturbation method is one approach in solving these analytical equations. In-situ water saturation profiles, ascertained through experimental CT scanning, serve as validation benchmarks for both co-current and counter-current models. The understanding of the SI process can give more details about the fracture-matrix interactions and the exchange function. Sensitivity studies with respect to the parameterization of the driving force for imbibition, capillary pressure, and the resistive forces, captured in relative permeability curves, can guide experimental study planning and aid in inverse problem analysis in the characterization of naturally fractured reservoirs. The results of a parametric study show that capillary pressure curve parameters, such as capillary entry pressure and capillary exponent, significantly affect the position of the waterfront which indicates the imbibition rate. In addition, the water relative permeability exponent has greater impact on both shape and position of water profile than other relative permeability parameters. The nonwetting phase parameters, like oil endpoint relative permeability and oil exponent, have the least influence on water saturation profile.
天然裂缝地层是复杂的石油储层,由于难以控制扫描,因此不适合注水。注入的水很容易在裂缝系统中传播,绕过基质中储存的碳氢化合物。取而代之的是,此类系统依靠基质自发浸润(SI)进入广泛的裂缝聚集系统。SI 是一种重要的采收机制,依赖于毛细管压力主导的流体运动。SI 可通过两种模式发生,即同流(COSI)和逆流(COUSI),这取决于流体运动的相对方向对当时边界条件的反应。结合相对渗透率和毛细管压力曲线的扩散系数的分析解决方案可用于描述同流和逆流浸润机制。扰动法是求解这些分析方程的一种方法。通过 CT 扫描实验确定的原位水饱和度曲线可作为同流和逆流模型的验证基准。对 SI 过程的了解可以提供有关裂缝-基质相互作用和交换功能的更多细节。关于浸润驱动力、毛细管压力和相对渗透率曲线所反映的阻力参数化的敏感性研究,可以指导实验研究规划,并有助于天然裂缝储层特征描述中的反问题分析。参数研究结果表明,毛细管进入压力和毛细管指数等毛细管压力曲线参数会显著影响表示浸润率的水线位置。此外,与其他相对渗透性参数相比,水的相对渗透性指数对水剖面的形状和位置影响更大。非润湿相参数,如油端点相对渗透率和油指数,对水饱和剖面的影响最小。
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引用次数: 0
Flow Characteristics of Gas and Liquid in Pipeline Revealed by Machine Learning on Distributed Acoustic Sensing Data 通过分布式声学传感数据的机器学习揭示管道中气体和液体的流动特性
0 ENERGY & FUELS Pub Date : 2024-11-20 DOI: 10.1016/j.geoen.2024.213518
Haochu Ku , Kun-peng Zhang , Xiang-ge He , Min Zhang , Hai-long Lu , Yi Zhang , Lin Cong
The two-phase flow rates of gas and liquid in a pipeline are crucial parameters for optimizing gas-oil production strategies and ensuring the reliability of gas-oil transportation systems. Although available measurement techniques, such as various flow meters, offer accurate flow rate data, they might face limitations in providing distributed and real-time information at multiple points. Distributed Acoustic Sensing (DAS) offers a viable alternative for long-term, multipoint dynamic monitoring of the flow. However, the data acquired through fiber optic monitoring techniques are often difficult to analyze and process in real-time, while machine learning offers automatic identification of complex patterns and relationships within the data, enabling more precise predictions and classifications. To evaluate the feasibility of DAS technology combined with machine learning methods to estimate the gas-liquid flow rate in pipelines, an experimental loop that utilized DAS was developed to measure gas-liquid two-phase flow signals in pipelines. The machine learning method was then applied to analyze the DAS signals, based on which models were established to predict flow rates and regimes. Furthermore, validation experiments were conducted to assess the predictive performance of these models. Compared to the actual flow rates measured by electronic flowmeters, the results by integration of DAS and machine learning show the predictive accuracy of two models reach 97%. In the subsequent validation experiments, both the goodness of fit for the flow rate prediction model and accuracy for the flow regime prediction model exceeded 85%. Thus, compared to current flow measurement methods, the integration of DAS and machine learning not only provides accurate flow rate estimations but also offers available prediction of flow regimes, enhancing the measurement capabilities and technology insights.
管道中气体和液体的两相流速是优化天然气-石油生产策略和确保天然气-石油运输系统可靠性的关键参数。虽然现有的测量技术(如各种流量计)可以提供精确的流速数据,但在提供多点分布式实时信息方面可能会受到限制。分布式声学传感(DAS)为流量的长期、多点动态监测提供了一个可行的替代方案。然而,通过光纤监测技术获取的数据往往难以实时分析和处理,而机器学习可自动识别数据中的复杂模式和关系,从而进行更精确的预测和分类。为了评估 DAS 技术与机器学习方法相结合估算管道中气液流量的可行性,开发了一个利用 DAS 测量管道中气液两相流信号的实验环路。然后应用机器学习方法对 DAS 信号进行分析,并在此基础上建立模型来预测流速和流态。此外,还进行了验证实验,以评估这些模型的预测性能。与电子流量计测得的实际流量相比,DAS 与机器学习相结合的结果显示,两个模型的预测准确率达到了 97%。在随后的验证实验中,流量预测模型的拟合度和流态预测模型的准确度均超过了 85%。因此,与当前的流量测量方法相比,DAS 与机器学习的集成不仅能提供精确的流量估计,还能提供流态预测,从而提高测量能力和技术洞察力。
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引用次数: 0
Analytical procedure for tracing acrylamide and sulfonated co-polymers in groundwater affected by chemical enhanced oil recovery activities 追踪受化学强化采油活动影响的地下水中丙烯酰胺和磺化共聚物的分析程序
0 ENERGY & FUELS Pub Date : 2024-11-19 DOI: 10.1016/j.geoen.2024.213528
Wannida Sapyen, Narong Praphairaksit, Apichat Imyim
Polymer flooding emerges as one of the most utilized chemical enhanced oil recovery (cEOR) techniques. The implementation of acrylamide and sulfonated co-polymers holds promise in polymer flooding due to their capacity to withstand high temperatures and salinities. Taking environmental concerns into account, monitoring the quality and contamination of groundwater becomes crucial and challenging after the cEOR processes. In this study, we developed a method for the determination of acrylamide and sulfonated co-polymers potentially contaminating groundwater using high-performance liquid chromatography with diode-array detection (HPLC-DAD). To achieve the sensitivity required for such a demanding task, key parameters including the detection wavelength, mobile phase ratio, injection volume, flow rate, and temperature were optimized, which resulted in the values of 195 nm, 70% acetonitrile in pure water, 20 μL, 1 mL/min, and 30 °C, respectively. The chromatographic process was completed within a short 5-min analysis time, allowing for readily increased sample throughput. Moreover, the accuracy and precision of the proposed method for the determination of target polymers in groundwater samples were demonstrated, and the criteria were satisfactorily met in accordance with AOAC guidelines.
聚合物淹没是最常用的化学提高石油采收率(cEOR)技术之一。丙烯酰胺和磺化共聚物具有耐高温和耐盐碱的能力,因此在聚合物淹没中的应用前景广阔。考虑到环境问题,监测 cEOR 过程后地下水的质量和污染变得至关重要且具有挑战性。在本研究中,我们采用高效液相色谱-二极管阵列检测法(HPLC-DAD)开发了一种测定可能污染地下水的丙烯酰胺和磺化共聚物的方法。为了达到这项高要求任务所需的灵敏度,对检测波长、流动相比例、进样量、流速和温度等关键参数进行了优化,优化后的值分别为 195 nm、纯水中 70% 的乙腈、20 μL、1 mL/min 和 30 °C。色谱过程在短短 5 分钟的分析时间内即可完成,从而大大提高了样品处理量。此外,该方法在测定地下水样品中目标聚合物时的准确度和精密度均符合 AOAC 准则的要求。
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引用次数: 0
A phase-field modeling study for reaction instability and localized fluid flow in carbonate rocks 碳酸盐岩中反应不稳定性和局部流体流动的相场模型研究
0 ENERGY & FUELS Pub Date : 2024-11-19 DOI: 10.1016/j.geoen.2024.213438
Kenji Furui , Keita Yoshioka
As acidic fluids flow and dissolve minerals in carbonate formations, the reaction may localize into a dendritic pattern under certain conditions known as wormhole. Wormhole is considered to be triggered by pore-scale heterogeneity in the rock that promotes preferential flow paths. Therefore, in macroscale (Darcy scale) simulation, numerical models usually need to prescribe a certain degree of macroscopic heterogeneous permeability to promote localized dissolution (wormhole). However, experimental studies have shown that wormholes form in synthetic plasters without apparent heterogeneity, implying that macroscopic heterogeneity is not a necessary prerequisite for wormhole formation and prescribed heterogeneity may impose unnecessary biases. Here, we applied a macroscale wormhole model based on a phase-field approach to demonstrate that wormhole can form in macroscopically homogeneous media as long as the inlet velocity meets the infiltration-reaction instability condition obtained from perturbation analysis. Furthermore, we simulated wormhole growth behaviors in homogeneous and heterogeneous permeability fields with the standard variance values of 0.5, 1.0 and 2.0. The simulation results showed that the normalized injectivity decreases from 3.90 to 3.15 when the standard variance changed from 0.5 to 2.0 indicating that heterogeneity may actually suppress the wormhole growth because an increasing amount of acid infiltrates into the branched wormholes. These findings suggest that permeability heterogeneities should not be treated as a trigger for wormholes in the macroscale numerical simulation. Instead, they should be regarded as parameters that influence the nucleation and growth of wormholes because the permeability field has significant effects on post-acid wormhole geometry and resultant well productivity and injectivity.
当酸性流体在碳酸盐岩层中流动并溶解矿物质时,在某些条件下,反应可能会局部形成树枝状模式,这就是所谓的虫洞。虫洞被认为是由岩石中的孔隙尺度异质性引发的,这种异质性会促进优先流动路径。因此,在宏观(达西尺度)模拟中,数值模型通常需要预设一定程度的宏观异质渗透性,以促进局部溶解(虫洞)。然而,实验研究表明,虫孔是在没有明显异质性的情况下在合成石膏中形成的,这意味着宏观异质性并不是虫孔形成的必要前提,预设异质性可能会带来不必要的偏差。在此,我们应用了基于相场方法的宏观虫孔模型,证明了只要入口速度满足扰动分析得到的渗透-反应不稳定性条件,虫孔就能在宏观均质介质中形成。此外,我们还模拟了虫洞在标准方差值为 0.5、1.0 和 2.0 的均质和异质渗透场中的生长行为。模拟结果表明,当标准方差从 0.5 变为 2.0 时,归一化注入率从 3.90 降至 3.15,这表明异质性实际上可能会抑制虫孔的生长,因为越来越多的酸渗入到分支虫孔中。这些发现表明,在宏观数值模拟中,不应将渗透性异质性视为虫洞的触发因素。相反,它们应被视为影响虫洞成核和生长的参数,因为渗透率场对酸化后虫洞的几何形状以及由此产生的油井产能和注入率有重大影响。
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引用次数: 0
Research on mass transfer mechanisms due to short-term water-rock interactions between granite cuttings and alkaline NaCl solution and their patterns 花岗岩切屑与碱性氯化钠溶液之间短期水岩相互作用的传质机制及其规律研究
0 ENERGY & FUELS Pub Date : 2024-11-19 DOI: 10.1016/j.geoen.2024.213512
Ou Jiang , Xiuhua Zheng , Qingjie Gong , Haidong Wu , Baozhen Chu
Water-rock interactions induced by working fluids in hot dry rock (HDR) reservoirs lead to reservoir damages through mass transfer. Therefore, investigating the mass transfer mechanisms due to the interactions between working fluids and reservoir rocks contributes to minimizing HDR reservoir damages. Drilling fluid is an important working fluid, yet the interactions between drilling fluids and HDR reservoir rocks lack understandings. Here, interaction experiments were conducted using a high-temperature and high-pressure flow reactor under temperatures of 180 °C and 240 °C, a pressure of 24 MPa, and a flow rate of 0.05 mL/min for 7 days. Pure water and an alkaline NaCl solution, which is referred to a HDR reservoir drilling fluid, were prepared to interact with granite cuttings from the HDR reservoir at Qiabuqia site in Gonghe Basin, Qinghai Province, China. Mineral characteristics, mass and chemical changes in the cuttings, solution element content concentrations, micro-morphology and element contents on the cuttings surface, as well as the size of suspending fines in the solutions were determined to reveal the mass transfer mechanisms. The results indicate that the mass transfer mechanisms include mineral reactions and fines migration, and fines migration is the dominating mechanism. The mineral reactions, including feldspar dissolution, quartz dissolution and feldspar alteration, are strong at the front section, while are weak at the end section. At the middle section, the released element contents by mineral reactions form various precipitates, mainly including aluminosilicate, silicate and silica. Strong mineral reactions at the front section lead to fines migration, while the precipitation of Na-bearing minerals at the middle section inhibits fines migration through a coating effect. Suspending fines are identified in the solutions, with a diameter of 100–300 nm, and settled fines are observed at the end section, with a diameter of hundreds of nanometers to a few microns. Simulations of reaction equilibrium show that the precipitation of quartz and biotite increases with a higher NaCl concentration and a lower temperature, while albite changes from dissolution to precipitation as NaCl concentration rises from 6 wt% to 12 wt%. The formation of halite by simulations supports the coating effect. This study provides theoretical basis to minimize HDR reservoir damage induced by working fluids.
在干热岩(HDR)储层中,工作流体引起的水岩相互作用会通过质量传递导致储层破坏。因此,研究工作流体与储层岩石相互作用引起的传质机制有助于最大限度地减少热干岩储层的损害。钻井液是一种重要的工作流体,但人们对钻井液与 HDR 储层岩石之间的相互作用缺乏了解。在此,使用高温高压流动反应器在 180 °C 和 240 °C 温度、24 MPa 压力和 0.05 mL/min 流速条件下进行了为期 7 天的相互作用实验。制备了纯水和碱性氯化钠溶液(即 HDR 储层钻井液),与来自中国青海省共和盆地七步桥矿区 HDR 储层的花岗岩切屑相互作用。测定了岩屑中的矿物特征、质量和化学变化、溶液中的元素含量浓度、岩屑表面的微观形态和元素含量,以及溶液中悬浮细粒的大小,以揭示其传质机理。结果表明,传质机制包括矿物反应和细粒迁移,其中细粒迁移是主要机制。矿物反应包括长石溶解、石英溶解和长石蚀变,在前段较强,而在后段较弱。在中段,矿物反应释放的元素含量形成各种沉淀物,主要包括铝硅酸盐、硅酸盐和二氧化硅。前段强烈的矿物反应会导致细粒的迁移,而中段含 Na 矿物的沉淀则会通过包覆效应抑制细粒的迁移。在溶液中发现了直径为 100-300 纳米的悬浮细粒,在末段观察到了直径为几百纳米到几微米的沉降细粒。对反应平衡的模拟显示,石英和黑云母的沉淀随着 NaCl 浓度的升高和温度的降低而增加,而白云石则随着 NaCl 浓度从 6 wt% 升至 12 wt% 而从溶解变为沉淀。模拟形成的海绿石支持了涂层效应。这项研究为最大限度地减少工作流体对 HDR 储层的损害提供了理论依据。
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引用次数: 0
Committee machine learning: A breakthrough in the precise prediction of CO2 storage mass and oil production volumes in unconventional reservoirs 委员会机器学习:在精确预测非常规储层二氧化碳封存质量和石油产量方面取得突破
0 ENERGY & FUELS Pub Date : 2024-11-19 DOI: 10.1016/j.geoen.2024.213533
Shadfar Davoodi , Hung Vo Thanh , David A. Wood , Mohammad Mehrad , Mohammed Al-Shargabid , Valeriy S. Rukavishnikov
Accurate prediction of CO2 storage mass and cumulative oil production is critical in the context of combining subsurface carbon capture with enhanced oil recovery (CCS-EOR). This study introduces a novel committee machine-learning Gaussian Process Regression (CML-GPR) model, which integrates three well-established machine-learning algorithms—Random Forest (RF), Multi-Layer Extreme Learning Machine (MELM), and Generalized Regression Neural Network (GRNN). The combination of these models leverages the strengths of each algorithm: RF captures nonlinear relationships, MELM enhances computational efficiency, and GRNN provides smooth, generalized predictions. By integrating these complementary techniques, the CML-GPR model demonstrates significant improvements in predictive accuracy over individual models, addressing limitations in their performance. The model predicts CO2 storage mass and cumulative oil production based on nine key reservoir input variables, including depth, porosity, and CO2 injection rate, among others. Utilizing a large dataset of 21,193 data points from reservoir simulations, a Mahalanobis distance-based outlier detection method further refines the input data quality. The CML-GPR model achieves root mean square error (RMSE) values of 0.49 million metric tons for CO2 storage mass and 13.68 million barrels for cumulative oil production, significantly outperforming individual models. The CML-GPR model provides a robust tool for optimizing CO2 storage capacity and oil recovery, with practical implications for real-world reservoir management, ensuring more efficient and reliable CCS-EOR operations. This study represents a pioneering advancement in predictive modeling, offering valuable insights for optimizing both CO2 storage and enhanced oil recovery in complex reservoirs.
在将地下碳捕集与提高石油采收率(CCS-EOR)相结合的背景下,准确预测二氧化碳封存质量和累积石油产量至关重要。本研究介绍了一种新颖的委员会机器学习高斯过程回归(CML-GPR)模型,该模型集成了三种成熟的机器学习算法--随机森林(RF)、多层极端学习机(MELM)和广义回归神经网络(GRNN)。这些模型的组合充分利用了每种算法的优势:RF 可捕捉非线性关系,MELM 可提高计算效率,而 GRNN 则可提供平滑的广义预测。通过整合这些互补技术,CML-GPR 模型在预测准确性方面比单个模型有了显著提高,解决了单个模型在性能方面的局限性。该模型根据九个关键的储层输入变量(包括深度、孔隙度和二氧化碳注入率等)预测二氧化碳储量和累积石油产量。利用由 21193 个储油层模拟数据点组成的大型数据集,基于 Mahalanobis 距离的离群点检测方法进一步提高了输入数据的质量。CML-GPR 模型的二氧化碳封存质量均方根误差 (RMSE) 值为 0.49 百万公吨,累计石油产量均方根误差 (RMSE) 值为 13.68 百万桶,明显优于单个模型。CML-GPR 模型为优化二氧化碳封存容量和石油采收率提供了一个强大的工具,对现实世界的油藏管理具有实际意义,可确保更高效、更可靠的 CCS-EOR 操作。这项研究是预测建模领域的开创性进展,为优化复杂储层的二氧化碳封存和提高石油采收率提供了宝贵的见解。
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引用次数: 0
Analysis of enhanced geothermal system flowback and circulation test data for fracture and reservoir characterization 分析强化地热系统回流和循环测试数据以确定裂缝和储层特征
0 ENERGY & FUELS Pub Date : 2024-11-19 DOI: 10.1016/j.geoen.2024.213532
A.-L.L. Benson , C.R. Clarkson , D. Zeinabady
Geothermal energy has gained increasing attention worldwide, driven by the need for clean energy sources. Evaluation of subsurface properties in geothermal systems is critical for determining resource potential, optimizing energy production, and evaluating the risk of induced seismicity, amongst other applications. However, the thermal and hydraulic properties of geothermal systems are generally unknown or highly uncertain.
This study develops three models to characterize subsurface reservoirs and hydraulic fractures in EGS. A semi-analytical heat transfer model, based on thermal energy balance, and an analytical flow model, derived from material balance, are presented for history matching produced water temperatures and production rates/pressures from an EGS well doublet. Additionally, an analytical flowback model is proposed for analyzing early-time flowback data from the injection well. The models were verified through history matching simulated EGS examples, demonstrating accuracy within a ±5% error range. A geothermal doublet with reservoir heterogeneity was also simulated numerically and history-matched using the semi-analytical model, proving its broader applicability.
To demonstrate practical application of the proposed models, data from the Utah Frontier Observatory for Research in Geothermal Energy (FORGE) site were analyzed. Early time flowback production data from three different stages of hydraulic fracturing of the injection well [Well 16A(78)-32] were evaluated as was data recorded at the production well [Well 16B(78)-32] during circulation testing. The outlet produced water temperatures obtained from the production well were history matched using the semi-analytical heat transfer model to estimate hydraulic fracture (fracture permeability and half-length) and reservoir thermal properties (average subsurface thermal conductivity and specific heat capacity). The early-time flowback data from the injection well were history matched using the analytical flowback model, and the resulting derived fracture properties were compared with microseismic data collected during each stage of hydraulic fracturing. The microseismic data suggest that the half-fracture height for Stage 1, Stage 2 and Stage 3 increased for each subsequent stage. This increasing trend is in agreement with the flowback model-derived fracture heights (205 ft for Stage 1; 315 ft for Stage 2 and 375 ft for Stage 3). These results underscore the need for continued research on analytical models to improve geothermal system characterization and support the advancement of geothermal energy as a sustainable power source.
由于对清洁能源的需求,地热能源在全球范围内受到越来越多的关注。评估地热系统的地下属性对于确定资源潜力、优化能源生产和评估诱发地震风险等应用至关重要。然而,地热系统的热和水力特性通常是未知的或高度不确定的。本研究开发了三种模型来描述 EGS 中地下储层和水力裂缝的特征。基于热能平衡的半解析传热模型和基于物料平衡的解析流动模型,用于匹配 EGS 双井的产水温度和生产率/压力。此外,还提出了一个分析回流模型,用于分析注入井的早期回流数据。通过历史匹配模拟 EGS 实例对模型进行了验证,结果表明精确度在 ±5% 误差范围内。为了证明所提模型的实际应用,我们分析了犹他州地热能研究前沿观测站(FORGE)的数据。评估了注入井[16A(78)-32 号井]水力压裂三个不同阶段的早期回流生产数据,以及循环测试期间生产井[16B(78)-32 号井]记录的数据。使用半解析传热模型对生产井获得的出水温度进行历史匹配,以估算水力压裂(压裂渗透率和半长)和储层热特性(地下平均导热率和比热容)。使用回流分析模型对注入井的早期回流数据进行历史匹配,并将得出的压裂属性与水力压裂各阶段收集的微震数据进行比较。微震数据表明,第一阶段、第二阶段和第三阶段的半裂缝高度在随后的每个阶段都有所增加。这种增加趋势与回流模型得出的裂缝高度(第一阶段 205 英尺;第二阶段 315 英尺;第三阶段 375 英尺)一致。这些结果突出表明,有必要继续对分析模型进行研究,以改进地热系统的特征描述,支持地热能源作为可持续能源的发展。
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引用次数: 0
Fast mass transfer processes of interfering trapped CO2-clusters at reservoir conditions: Experiment and theory 水库条件下干扰捕获co2团簇的快速传质过程:实验与理论
0 ENERGY & FUELS Pub Date : 2024-11-19 DOI: 10.1016/j.geoen.2024.213509
Helmut Geistlinger , Bilal Zulfiqar , John Maximilian Koehne , Steffen Schlueter , Bernd Apelt , Mohammed Amro
The gas-to-oil ratio (GOR) of a reservoir fluid plays a critical role in optimizing oil recovery and oil production strategies, improving oil recovery efficiency, and predicting reservoir behavior. Understanding the complicated kinetics of multicomponent mass transfer at the pore scale after gas injection into petroleum reservoirs is of great importance for estimating GOR and enhanced oil recovery (EOR). However, to date, there is a significant gap in the fundamental process understanding of the complex mass transfer process at reservoir conditions. Using micro-CT technology, we investigate the time dependence of CO2 mass transfer and cluster growth after high pressure CO2 injection into sedimented porous media (sintered 0.2 mm glass beads).
Surprisingly, the CO2 partitioning equilibrium is already reached after 2 h. To the best of our knowledge, such a fast CO2 transport through water-saturated porous media, which cannot be explained by linear diffusion models (time scale 100 days for a diffusion length of 10 cm), has not been reported in the literature before. We proposed a conceptual model that assumes CO2 inflation of interfering gas clusters drives cascading CO2 transport. We verified this conceptual model through a time series of experiments at different initial gas saturation, analyzing in each case the spatial cluster distribution, cluster size distribution, and pore occupancy frequency.
Whether CO2 inflation of the gas clusters occurs depends on the critical initial gas saturation, which is about 10%. Our main conclusion is that CO2 migration should be considered as gas phase diffusion cascading along a quasi-percolating cluster, since CO2 inflation leads to a high gas saturation of about 26%, which is close to the percolation threshold. Our experimental results support this physical hypothesis. We show for the first time that CO2 clusters can expand over large pore spaces and thus are close to the critical percolation threshold (mobility threshold). The cluster size distribution can be described by a power distribution with the critical exponent 2.19, i.e., it shows universal scaling.
We model the interfering mass transfer processes of neighboring gas clusters with a multi-sphere model. Exploring different scenarios for the dissolution kinetics of an ensemble of interfering gas clusters allow a deeper understanding of the complicated mass transfer kinetics and agree well with experimental cluster analyses at specific times.
储层流体的气油比(GOR)在优化采收率和采油策略、提高采收率和预测储层动态等方面起着至关重要的作用。了解气藏注气后孔隙尺度上复杂的多组分传质动力学,对于提高GOR和提高采收率具有重要意义。然而,到目前为止,在油藏条件下复杂的传质过程的基本过程的理解有很大的差距。利用微ct技术,我们研究了向沉积多孔介质(烧结0.2 mm玻璃微珠)注入高压CO2后,CO2传质和团簇生长的时间依赖性。令人惊讶的是,CO2在2小时后就已经达到了分配平衡。据我们所知,在线性扩散模型(时间尺度为100天,扩散长度为10厘米)无法解释的情况下,如此快速的CO2在饱和水多孔介质中的传输在文献中还没有报道过。我们提出了一个概念模型,假设干扰气团的二氧化碳膨胀驱动级联二氧化碳运输。我们通过不同初始含气饱和度的时间序列实验验证了这一概念模型,分析了每种情况下的空间簇分布、簇大小分布和孔隙占用频率。气团是否发生CO2膨胀取决于临界初始气饱和度,约为10%。我们的主要结论是,CO2迁移应被视为沿准渗透簇级联的气相扩散,因为CO2膨胀导致约26%的高气饱和度,接近渗透阈值。我们的实验结果支持这个物理假设。我们首次表明CO2簇可以在大孔隙空间上扩展,因此接近临界渗透阈值(迁移率阈值)。聚类大小的分布可以用临界指数为2.19的幂分布来描述,即它具有普遍的标度。我们用一个多球模型来模拟邻近气团的干扰传质过程。探索不同情况下的溶解动力学的干扰气团集合允许更深入地了解复杂的传质动力学,并与特定时间的实验聚类分析很好地一致。
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引用次数: 0
A mechanistic investigation on NP-stabilized foam three phase displacement characteristics in low permeable porous media 低渗透多孔介质中 NP 稳定泡沫三相位移特性的机理研究
0 ENERGY & FUELS Pub Date : 2024-11-19 DOI: 10.1016/j.geoen.2024.213526
Dong Wang, Mingsheng Yang, Xiang Su, Yingge Li, Dongxing Du
Nanopartical (NP)-stabilized foam has found potential applications in unconventional oil recovery as well as greenhouse gas geological storage practices. In this paper, laboratory works were performed on NP-stabilized Supercritical CO2 (ScCO2) foam and N2 foam three phase displacement processes in 49.5 mm length core samples with permeability around 50 mD. Experimental results show the pressure drop in NP-stabilized N2 foam flooding process is 4.45 MPa, which is higher than 3.85 MPa in NP-stabilized ScCO2 foam flow case. The oil recovery rate of 7.1% after NP-stabilized N2 foam flooding, on the other hand, is lower than 9.1% after the NP-stabilized ScCO2 foam displacement. To understand the mechanisms behind the laboratory results, numerical simulations were carried out with help of the mechanistic Stochastic Bubble Population Balance (SBPB) model. By taking into account the distinct differences on bubble densities as well as the rheological characteristics between NP-stabilized ScCO2 foam and N2 foam, together with the additional resistance factors to the water and oil phases in foam flooding processes, the numerical results reproduce satisfactorily the experimental findings on flooding pressure drops as well as oil recovery rates in both foam systems. At last, the foam three phase displacement characteristics, including the dynamic variation behavior of the three phase fluid saturation, the inlet pressure and the bubble density, were numerically investigated. It is expected this study could help understand the NP-stabilized foam flooding behaviors in low permeability porous media.
纳米粒子(NP)稳定泡沫在非常规石油开采和温室气体地质储存实践中具有潜在的应用价值。本文在渗透率约为 50 mD、长度为 49.5 mm 的岩心样品中,对 NP 稳定超临界 CO2(ScCO2)泡沫和 N2 泡沫三相置换过程进行了实验室研究。实验结果表明,在 NP 稳定 N2 泡沫淹没过程中的压降为 4.45 MPa,高于 NP 稳定 ScCO2 泡沫流动情况下的 3.85 MPa。另一方面,NP 稳定 N2 泡沫充注后的采油率为 7.1%,低于 NP 稳定 ScCO2 泡沫置换后的 9.1%。为了解实验室结果背后的机理,利用机理随机气泡数量平衡(SBPB)模型进行了数值模拟。考虑到 NP 稳定的 ScCO2 泡沫和 N2 泡沫在泡沫密度和流变特性上的明显差异,以及泡沫淹没过程中水相和油相的额外阻力因素,数值模拟结果令人满意地再现了两种泡沫系统中淹没压降和采油率的实验结果。最后,数值研究了泡沫三相位移特性,包括三相流体饱和度、入口压力和泡沫密度的动态变化行为。这项研究有望帮助理解 NP 稳定泡沫在低渗透多孔介质中的淹没行为。
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引用次数: 0
期刊
Geoenergy Science and Engineering
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