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Bio-based flow improvers for waxy petroleum crude 用于含蜡石油原油的生物基流动改进剂
0 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.geoen.2024.213444
C.F. Uzoh , S.U John , H.A. Ezea , C.M. Ezechukwu , L.I. Igbonekwu , E.M. Madiebo
This study investigated the efficacy of bio-based flow improvers, soybean oil (SBO) and castor oil (CAO), in mitigating the flow challenges posed by waxy crude oil, using Bonny Light crude oil as a case study. The study evaluated the impact of these additives on viscosity, gel strength, and pour point reduction. The performance of these additives was compared with a conventional flow improver, xylene. Results indicated that both SBO and CAO effectively reduced viscosity, gel strength, and pour point of the crude oil. Castor oil demonstrated superior performance in reducing gel strength, achieving a 98% reduction at 0.1 v/v concentration. Soybean oil, on the other hand, exhibited better performance in reducing pour point, with a 56.3% reduction at 1.9 v/v concentration. Xylene showed the highest viscosity reduction but had a less pronounced effect on gel strength and pour point. Optimum viscosity reduction of 85%, 83%, and 87% was achieved for SBO, CAO, and xylene, respectively, at specific process conditions. Similarly, gel strength reduction reached 94.36%, 94.89%, and 95.79% for SBO, CAO, and xylene, respectively. Pour point reduction was 56.3%, 52.7%, and 45.5% for SBO, CAO, and xylene, respectively, at the highest concentration tested. The study demonstrated the potential of bio-based additives as viable alternatives to conventional flow improvers for waxy crude oil. Further research is necessary to optimize their performance and explore their application in different crude oil systems.
本研究以邦尼轻质原油(Bonny Light crude oil)为案例,调查了生物基流动性改进剂大豆油(SBO)和蓖麻油(CAO)在减轻含蜡原油带来的流动性挑战方面的功效。研究评估了这些添加剂对粘度、凝胶强度和倾点降低的影响。将这些添加剂的性能与传统的流动性改进剂二甲苯进行了比较。结果表明,SBO 和 CAO 都能有效降低原油的粘度、凝胶强度和倾点。蓖麻油在降低凝胶强度方面表现出色,0.1 v/v 浓度时可降低 98%。另一方面,大豆油在降低倾点方面表现更佳,在 1.9 v/v 浓度下降低了 56.3%。二甲苯的降粘效果最好,但对凝胶强度和倾点的影响不明显。在特定的工艺条件下,SBO、CAO 和二甲苯的最佳降粘效果分别为 85%、83% 和 87%。同样,SBO、CAO 和二甲苯的凝胶强度分别降低了 94.36%、94.89% 和 95.79%。在测试的最高浓度下,SBO、CAO 和二甲苯的倾点分别降低了 56.3%、52.7% 和 45.5%。这项研究证明了生物基添加剂作为传统流动性改进剂的可行替代品在蜡质原油中的应用潜力。有必要开展进一步研究,以优化其性能并探索其在不同原油体系中的应用。
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引用次数: 0
The influential factors on electric breakdown damage of insulator in electric pulse rock breaking drill bits 电脉冲破岩钻头绝缘体电击穿损伤的影响因素
0 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.geoen.2024.213504
Xiaohua Zhu , Wuji Tang , Weiji Liu , Siqi Liu
In the working process of the Electric Pulse rock Breaking (EPB) drill bit, the insulator will have electrical breakdown failure under the action of long-term strong voltage, resulting in the loss of rock breaking ability of the EPB drill bit. Based on the simplified circuit analysis and the electric breakdown PDM (Probability Development Model), numerical simulation and laboratory experiment were conducted to study the electric field strength distribution in the insulation and the evolution law of the breakdown path. In this paper, nylon (PA), epoxy resin (EP), crosslinked polyethylene (XLPE), polytetrafluoroethylene (PTFE) as the base material, boron nitride (BN), glass fiber (GFR) as the filler to construct 8 kinds of electrical insulation composite materials, considering the material properties of different components and particle size. The effects of different insulators, filling particles, load voltage and insulator thickness on the breakdown path, growth rate and deterioration area in the insulation were analyzed. The results show that the breakdown path of the electric branches develops along the direction of electric field distortion. Using GFR as filler can effectively inhibit the diffusion capacity and development speed of the breakdown channel, reduce the deterioration area, but the breakdown voltage will be reduced. The research results have certain guiding significance for the engineering application of EPB and the optimization design of EPB drill bit.
在电脉冲破岩(EPB)钻头的工作过程中,绝缘体在长期强电压的作用下会发生电击穿故障,导致电脉冲破岩钻头失去破岩能力。基于简化电路分析和电击穿 PDM(概率发展模型),通过数值模拟和实验室实验研究了绝缘体中的电场强度分布和击穿路径的演化规律。本文以尼龙(PA)、环氧树脂(EP)、交联聚乙烯(XLPE)、聚四氟乙烯(PTFE)为基材,以氮化硼(BN)、玻璃纤维(GFR)为填料,构建了 8 种电气绝缘复合材料,考虑了不同组分的材料特性和粒度。分析了不同绝缘体、填充颗粒、负载电压和绝缘体厚度对绝缘体击穿路径、增长率和劣化面积的影响。结果表明,电分支的击穿路径沿着电场畸变的方向发展。使用 GFR 作为填料能有效抑制击穿通道的扩散能力和发展速度,减少劣化面积,但击穿电压会降低。该研究成果对 EPB 的工程应用和 EPB 钻头的优化设计具有一定的指导意义。
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引用次数: 0
A three-phase dispersion profile model for stratified pipe flow: Effects of gas bubbles on the distribution of oil and water droplets 分层管道流动的三相分散剖面模型:气泡对油滴和水滴分布的影响
0 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.geoen.2024.213469
R. Skartlien , J. Nossen , G.W. Johnson , T.K. Kjeldby
A three-phase dispersion profile model for stratified gas/oil/water pipe flow was developed. The main goal was to incorporate the effects of gas bubbles on the cross-sectional distribution of oil and water droplets in the continuous liquids. Gas bubbles entrain from the gas layer above the oil/water layers and modify the oil and water dispersion profiles in several different ways. Increased hindered settling due to gas bubbles, reduction of the effective background mixing density that affects buoyancy, turbulence suppression due to droplets and bubbles and finally reduction of oil and water droplet entrainment rate due to area blocking by gas bubbles at the oil/water interface. All three dispersion profiles were modelled consistently with respect to their mutual coupling. The tuned model qualitatively reproduced the shapes and magnitude of the volume fraction profile data obtained from X-ray measurements. Several areas where identified where more fundamental experimental research would be needed.
开发了分层气/油/水管流三相分散剖面模型。主要目标是将气泡对连续液体中油和水滴横截面分布的影响纳入其中。气泡从油层/水层上方的气层进入,并以几种不同的方式改变油和水的分散曲线。气泡增加了阻碍沉降的程度,降低了影响浮力的有效背景混合密度,液滴和气泡抑制了湍流,最后,由于气泡在油/水界面上的面积阻挡,降低了油和水滴的夹带率。所有这三种分散剖面的建模方法在相互耦合方面都是一致的。调整后的模型定性地再现了通过 X 射线测量获得的体积分数剖面数据的形状和大小。确定了需要进行更多基础实验研究的几个领域。
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引用次数: 0
Hydrochemistry of hot springs from Caldas Novas Thermal Complex, Brazil 巴西卡尔达斯诺瓦斯温泉综合体温泉的水化学特征
0 ENERGY & FUELS Pub Date : 2024-11-14 DOI: 10.1016/j.geoen.2024.213502
Marina Lunardi, Daniel Marcos Bonotto
Central Brazil is home to the world's greatest geothermal water complex that is unrelated to magmatism. Hot springs arise along a metamorphic terrain in two main locations 35 km apart, i.e. Caldas Novas and Rio Quente cities. A large-scale dome of 20 × 12 km oval feature with a long axis going NNW-SSE, primarily made of quartzite from the Paranoá Group and surrounded by schists of the younger Araxá Group, works as the aquifer's main recharge area for rainwater. This geological structure separates both cities by a few kilometers and grants its waters a few chemical differences. Three groups of samples from the area, consisting of rainwater, surface water, and groundwater have been analyzed for major and minor constituents. Two major types of groundwater composition have been identified. The first occurs at Rio Quente city, featuring a moderate temperature (37.5 °C), slightly acidic pH (mean = 6.3 ± 0.3), lower total dissolved solids (TDS, mean = 59.6 ± 9.8 mg/L), and lower dissolved concentrations of Ca2+ (mean = 5.7 ± 3.1 mg/L), Mg2+ (mean = 2.0 ± 1.1 mg/L), and HCO3 (mean = 20.0 ± 2.2 mg/L). The second arises at Caldas Novas city, exhibiting relatively higher temperature (mean = 41.9 °C), pH (mean = 7.3 ± 0.6), TDS (mean = 147.1 ± 28.6 mg/L), and dissolved concentrations of Ca2+ (mean = 16.4 ± 8.4 mg/L), Mg2+ (mean = 7.4 ± 2.6 mg/L), and HCO3 (mean = 99.8 ± 23.5 mg/L). The crystalline rocks terrain, while extensively weathered, also provide a wide range of minor elements to those waters, which are chiefly found on the suspended solids fraction rather than in its dissolved form. Dissolved Pb and Fe exceeded the maximum contaminant levels for drinking water in some surface and groundwater samples, whilst some calculations indicated that P, K, Mn, Fe, Ni, Cu, Zn, Rb, Pb, Br and Ba tend to remain adsorbed in the particulate matter. However, the use of the USSL salinity diagram pointed out that all analyzed water samples offer no hazard to irrigation in most soil types. Subsurface reservoir temperatures were also estimated by means of different solute geothermometers and, among them, the quartz geothermometer yielded the most reasonable values.
巴西中部拥有世界上最大的地热水综合体,它与岩浆活动无关。在相距 35 公里的两个主要地点,即卡尔达斯诺瓦斯和里约昆特市,沿着变质地形出现了温泉。一个 20 × 12 千米的大型穹顶呈椭圆形,长轴呈西北-东南走向,主要由帕拉诺亚组的石英岩构成,周围是较年轻的阿拉萨组的片岩,是含水层的主要雨水补给区。这种地质结构将两座城市隔开几公里,并使其水体具有一些化学差异。对该地区的三组样本(包括雨水、地表水和地下水)进行了主要和次要成分分析。已经确定了两种主要的地下水成分。第一种出现在里奥昆特市,温度适中(37.5 °C),pH 值呈弱酸性(平均值 = 6.3 ± 0.3),溶解固体总量(TDS,平均值 = 59.6 ± 9.8 mg/L)较低,Ca2+(平均值 = 5.7 ± 3.1 mg/L)、Mg2+(平均值 = 2.0 ± 1.1 mg/L)和 HCO3-(平均值 = 20.0 ± 2.2 mg/L)的溶解浓度较低。第二种出现在卡尔达斯诺瓦斯市,温度(平均 = 41.9 °C)、pH 值(平均 = 7.3 ± 0.6)、TDS(平均 = 147.1 ± 28.6 mg/L)和 Ca2+(平均 = 16.4 ± 8.4 mg/L)、Mg2+(平均 = 7.4 ± 2.6 mg/L)和 HCO3-(平均 = 99.8 ± 23.5 mg/L)的溶解浓度相对较高。结晶岩地形虽然广泛风化,但也为这些水域提供了多种微量元素,这些微量元素主要存在于悬浮固体部分,而非溶解形式。在一些地表水和地下水样本中,溶解的铅和铁超过了饮用水的最高污染物含量,而一些计算表明,P、K、Mn、Fe、Ni、Cu、Zn、Rb、Pb、Br 和 Ba 往往会吸附在颗粒物质中。不过,使用 USSL 盐度图可以看出,所有分析过的水样对大多数土壤类型的灌溉都没有危害。此外,还利用不同的溶质地温仪估算了地下水库的温度,其中石英地温仪得出的数值最为合理。
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引用次数: 0
A compound real options framework for optimal project portfolio allocation under uncertainty: The case of marginal field development under reservoir and price uncertainty 不确定性条件下优化项目组合分配的复合实物期权框架:储层和价格不确定条件下的边际油田开发案例
0 ENERGY & FUELS Pub Date : 2024-11-14 DOI: 10.1016/j.geoen.2024.213472
S. Fedorov , V. Hagspiel , S. Haseldonckx , T. Hyldmo , M.H. Skudal
The decreasing average size of oil and gas (O&G) discoveries on the Norwegian continental shelf (NCS) has increased interest in mitigating the uncertainties involved in O&G investment decisions. Marginal fields, in particular, will not be able to support the same data gathering as larger fields, as the cost of appraisal wells may outweigh the potential revenues of the field. This lack of information increases subsurface uncertainty, making the investment decision more complex. Therefore, modeling this uncertainty and accounting for managerial flexibility is essential when evaluating O&G investments. Using existing infrastructure through tiebacks is one of the most cost-efficient solutions for developing smaller O&G discoveries. With spare capacities opening up on maturing production facilities, tiebacks from marginal fields to these facilities can be an appropriate investment option.
This paper presents a compound real options analysis (CROA) that allows us to evaluate a portfolio of two marginal fields under reservoir- and oil price uncertainty. The proposed methodology allows identification of additional value from managerial flexibility when investing in tiebacks to an existing host. The methodology is applied to a case where a decision-maker has to choose which field should be tied back first while knowing there is an option to develop the other field afterwards. Based on updates of crude spot prices and sizes of the reservoirs, the decision maker can evaluate whether to exercise the option to invest in either field or wait and reevaluate in consecutive years. We analyze what drives this choice and propose decision rules considering a portfolio view of O&G projects. The CROA approach is applied to a realistic case study resulting in improved decisions and, thereby, a return on investment of 25.4 % higher than the value resulting from the industry standard myopic valuation approach.
挪威大陆架(NCS)上发现的石油和天然气(O&G)的平均规模不断缩小,这使得人们更加关注如何减少 O&G 投资决策中的不确定性。特别是边缘油田,由于评估井的成本可能超过油田的潜在收益,因此无法像大型油田那样支持数据收集。信息的缺乏增加了地下的不确定性,使投资决策变得更加复杂。因此,在评估 O&G 投资时,必须对这种不确定性进行建模,并考虑到管理的灵活性。通过回接利用现有基础设施是开发较小的 O&G 发现的最具成本效益的解决方案之一。本文提出了一种复合实物期权分析(CROA)方法,使我们能够在储层和油价不确定的情况下评估两个边际油田的投资组合。本文提出了复合实物期权分析(CROA)方法,使我们能够在储层和油价不确定的情况下对两个边际油田的投资组合进行评估。该方法适用于这样一种情况,即决策者必须选择哪个油田应首先回接,同时知道之后可以选择开发另一个油田。根据最新的原油现货价格和储层规模,决策者可以评估是行使投资任一油田的选择权,还是等待并在连续几年后重新评估。我们分析了这种选择的驱动因素,并提出了考虑 O&G 项目组合观点的决策规则。我们将 CROA 方法应用于一个现实案例研究,结果改进了决策,从而使投资回报率比行业标准近视估值法得出的价值高出 25.4%。
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引用次数: 0
Transmission model and analysis of characteristics of downhole wireless RFID signal based on FSK modulation 基于 FSK 调制的井下无线 RFID 信号传输模型及特征分析
0 ENERGY & FUELS Pub Date : 2024-11-14 DOI: 10.1016/j.geoen.2024.213503
Jiafeng Wu , Anni Wang , Dongli Qin , Xiaocan Du , Shujun Wang , Zaisheng Hao , Guangze Li
Radio frequency identification (RFID) technology is a new type of intelligent drilling and completion technology that can be used for remote control of downhole tools. In RF modulation, frequency shift keying (FSK) has stronger anti-interference ability compared to amplitude shift keying (ASK), but its transmission characteristics for downhole RF signal are not yet clear, which cannot provide theoretical support for designing downhole RFID systems. In this paper, a transmission model for downhole wireless RF signals based on FSK modulation is established by combining Maxwell's equations, Biot-Savart's law, and the proposed model was verified through the simulation results and the experimental results, and the influence of the excitation intensity, the transmission distance, and the conductivity of drilling fluid on transmission attenuation was deeply studied. This study highlights the influence of conductivity on drilling or completion fluids by integrating 2FSK modulation, excitation, propagation, and induction reception of downhole electromagnetic waves into the proposed model. The mathematical model proposed in this study has been proven to predict transmission characteristic values close to experimental results with an average accuracy of over 90%. The results show that the excitation voltage, the transmission distance and conductivity of drilling and completion fluids have a significant impact on the propagation and reception of downhole RF signals. These analysis results can provide effective guidance and inspiration for the design and application of digital drilling and completion instruments.
射频识别(RFID)技术是一种新型的智能钻完井技术,可用于井下工具的远程控制。在射频调制中,频移键控(FSK)与幅移键控(ASK)相比具有更强的抗干扰能力,但其对井下射频信号的传输特性尚不明确,无法为设计井下射频识别(RFID)系统提供理论支持。本文结合麦克斯韦方程、Biot-Savart 定律,建立了基于 FSK 调制的井下无线射频信号传输模型,并通过仿真结果和实验结果验证了所提出的模型,深入研究了激励强度、传输距离和钻井液电导率对传输衰减的影响。本研究通过将井下电磁波的 2FSK 调制、激励、传播和感应接收集成到所提出的模型中,强调了电导率对钻井液或完井液的影响。事实证明,本研究提出的数学模型可以预测接近实验结果的传输特性值,平均准确率超过 90%。结果表明,激励电压、传输距离以及钻井液和完井液的电导率对井下射频信号的传播和接收有显著影响。这些分析结果可为数字钻完井仪器的设计和应用提供有效的指导和启发。
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引用次数: 0
Underground compressed air energy storage (CAES) in naturally fractured depleted oil reservoir: Influence of fracture 天然裂缝枯竭油藏中的地下压缩空气储能(CAES):裂缝的影响
0 ENERGY & FUELS Pub Date : 2024-11-12 DOI: 10.1016/j.geoen.2024.213496
Fatemeh Aghababaei, Behnam Sedaee
In the last decade, the sources of clean energy supply to meet human needs have been given much attention by researchers worldwide. Compressed air storage in underground formations is an excellent way to balance energy production and consumption. During off-peak hours, with the consumption of excess electrical energy, the air is temporarily stored at high pressure in the desired environment. The stored compressed air produces recovered electrical power during the needed hours and peak energy consumption. Compressed air energy storage in underground structures, including depleted hydrocarbon reservoirs, due to having a suitable storage capacity for air and because their geological characteristics have already been well identified, is one of the storage methods. In order to underground storage of compressed air in aquifers and salt caverns, research have been carried out, but so far, studies have yet to be carried out regarding the storage of compressed air in depleted natural fractured oil reservoirs. This study simulated the storage of compressed air in a naturally fractured depleted oil reservoir, the effect of fracture on the rate of oxidation reactions, air dissolution and air diffusion in the oil and water phases. Also, for the first time, an examination of the fracture properties, including porosity, permeability, and fracture spacing on the amount of air recovery during CAES, was numerically simulated. Significantly Increasing the fracture porosity and permeability improves the air recovery and leads to a 19% and 16% respectively increase in the air recovery factor. In the fractured reservoir, increasing the fracture porosity has the most significant effect on reducing the air recovery factor and reducing the fracture spacing has the most negligible effect on the air recovery. Finally, the results of this study showed that due to the consumption and loss of air in the fractured reservoir compared to the conventional reservoir, the air recovery factor in the fractured reservoirs is less than the conventional reservoirs.
近十年来,满足人类需求的清洁能源一直备受全球研究人员的关注。将压缩空气储存在地下是平衡能源生产和消费的绝佳方法。在非用电高峰时段,随着多余电能的消耗,空气被暂时高压储存在所需的环境中。在需要的时间和能源消耗高峰期,储存的压缩空气可产生回收电能。在地下结构(包括枯竭的碳氢化合物储层)中储存压缩空气能源是其中一种储存方法,因为这些地下结构具有合适的空气储存能力,而且其地质特征已经得到很好的确认。针对压缩空气在含水层和盐洞中的地下存储,已经开展了一些研究,但迄今为止,关于压缩空气在枯竭天然裂缝油藏中的存储还没有开展研究。本研究模拟了压缩空气在天然裂缝枯竭油藏中的存储情况,以及裂缝对油水相中氧化反应速率、空气溶解和空气扩散的影响。此外,还首次对裂缝特性(包括孔隙度、渗透率和裂缝间距)对 CAES 期间空气回收量的影响进行了数值模拟。提高裂缝孔隙度和渗透率可显著提高空气回收率,使空气回收系数分别提高 19% 和 16%。在裂缝储层中,增加裂缝孔隙度对降低空气回收率的影响最大,而减小裂缝间距对空气回收率的影响最小,可以忽略不计。最后,研究结果表明,与常规储层相比,由于压裂储层中空气的消耗和损失,压裂储层的空气回收率低于常规储层。
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引用次数: 0
Vibration analysis of push-the-bit rotary steerable bottom hole assembly 推入式钻头旋转转向底孔组件的振动分析
0 ENERGY & FUELS Pub Date : 2024-11-09 DOI: 10.1016/j.geoen.2024.213429
Jianbo Jia, Qilong Xue, Yafeng Li, Xinze Li, Bing Li
With the development of oil and gas fields to the deep-sea, the rotary steerable system is widely used. Downhole vibration is an important factor affecting the performance of rotary steerable system. Currently, the lack of research on vibration during operation of rotary steerable system has affected the development of deep-sea oil and gas field development technology. In this paper, the dynamic model of the push-pull rotary steerable system is established based on the similarity principle. The model includes Bit-rock interaction model, Drillstring-borehole contact model and guiding force model of rotary steerable system, the trajectory and vibration of drill bit under different guiding forces are simulated. Then, the actual drilling experiment of the full-scale Push-The-Bit Rotary Steerable System (PTB-RSS) in the horizontal section is carried out. The acceleration and speed signals of the push-pull rotary steerable system in the process of applying guiding force are collected and verified with the calculation results of the dynamic model. It is found that the vibration frequency and amplitude of the Bottom Hole Assembly (BHA) gradually increase with the increase of the guiding force of the PTB-RSS during the drilling stage, which induce high-frequency torsional vibration to a certain extent. In addition, the dynamic simulation shows that when the guiding force of the rotary steerable system is increased to a certain extent, the vibration of the BHA gradually stabilizes, but the vibration amplitude does not decrease.
随着油气田向深海发展,旋转转向系统得到了广泛应用。井下振动是影响旋转操舵系统性能的重要因素。目前,由于缺乏对旋转操舵系统运行过程中振动的研究,影响了深海油气田开发技术的发展。本文基于相似性原理,建立了推拉式旋转操舵系统的动态模型。该模型包括钻头-岩石相互作用模型、钻杆-井眼接触模型和旋转转向系统导向力模型,模拟了不同导向力作用下钻头的运动轨迹和振动。然后,进行了全尺寸推钻头旋转导向系统(PTB-RSS)在水平段的实际钻进实验。采集了推拉式旋转导向系统在施加导向力过程中的加速度和速度信号,并与动力学模型的计算结果进行了验证。结果发现,在钻进阶段,随着 PTB-RSS 导向力的增加,孔底组件(BHA)的振动频率和振幅逐渐增大,在一定程度上诱发了高频扭转振动。此外,动态模拟结果表明,当旋转转向系统的导向力增加到一定程度时,BHA 的振动逐渐趋于稳定,但振动幅度并没有减小。
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引用次数: 0
Frictional loss and permeability estimation of sediment in salt cavern: A combined approach of mathematical model, experimental validation, and numerical simulations 盐穴中沉积物的摩擦损失和渗透率估算:数学模型、实验验证和数值模拟相结合的方法
0 ENERGY & FUELS Pub Date : 2024-11-08 DOI: 10.1016/j.geoen.2024.213497
Peng Li , Yinping Li , Xilin Shi , Kun Yang , Xinghui Fu , Hongling Ma , Chunhe Yang
Harnessing gas storage in sediment voids presents a promising trajectory for the future construction of large-scale underground gas reservoirs in low-grade salt mines. This approach not only augments the effective gas volume but also enhances the stability of the cavern. In contrast to traditional gas injection and brine discharge process, where brine is expelled from the upper pure brine space without involving brine seepage in sediment voids, gas storage in sediment voids entails expelling brine from these spaces, thus necessitating an understanding of the brine seepage characteristics in the sediment, which remains unclear. This study presents a comprehensive approach for estimating sediment frictional loss and permeability in interconnected wells, integrating mathematical modeling, experimental validation, and numerical simulation. The mathematical principles governing sediment behavior during in-situ gas/brine injection and brine discharge tests are theoretically elucidated, accompanied by derived formulas. Experimental verification is conducted in the horizontal interconnected wells (Ha4-5) of the Huaian salt mine in Jiangsu, yielding the sediment frictional loss (0.53 MPa) and permeability (6.9 × 10−11 m2). Subsequently, a 2D cross-sectional numerical model is established using the COMSOL software, considering the measured and predicted well morphologies. The model provides insights into the relationship between sediment frictional losses and permeability, yielding an inverse calculation of the average permeability (1.016 × 10−10 m2). Simulation results depict laminar brine flow characteristics in the cavern during gas/brine injection and brine discharge processes, with frictional loss occurring as brine passes through sediment. Examination of the brine seepage and pressure fields in the sediment reveals consistent brine flow velocity after passing through the sediment. This combined approach focuses on investigating the seepage characteristics of sediment at the bottom of salt caverns, offering valuable insights for estimating frictional losses and permeability in similar salt mines.
利用沉积物空隙中的气体存储为未来在低品位盐矿中建造大型地下储气库提供了一条前景广阔的道路。这种方法不仅能增加有效气量,还能增强岩洞的稳定性。与传统的注气和排卤工艺不同,注气和排卤工艺是将卤水从上部纯卤水空间排出,不涉及沉积物空隙中的卤水渗流,而在沉积物空隙中储存气体则需要将卤水从这些空间排出,因此有必要了解沉积物中的卤水渗流特性,而这一点目前仍不清楚。本研究提出了一种估算互联井中沉积物摩擦损失和渗透率的综合方法,将数学建模、实验验证和数值模拟融为一体。从理论上阐明了原位注气/注卤和盐水排放试验过程中沉积物行为的数学原理,并给出了推导公式。在江苏淮安盐矿水平互联井(Ha4-5)中进行了实验验证,得出了沉积物摩擦损失(0.53 兆帕)和渗透率(6.9 × 10-11 m2)。随后,利用 COMSOL 软件建立了二维横截面数值模型,并考虑了测量和预测的井形态。该模型深入揭示了沉积物摩擦损失与渗透率之间的关系,得出了平均渗透率(1.016 × 10-10 m2)的反演计算结果。模拟结果表明,在注入天然气/盐水和排放盐水的过程中,岩洞内的盐水具有层流特征,盐水通过沉积物时会产生摩擦损失。对沉积物中的盐水渗流场和压力场的研究表明,盐水通过沉积物后的流速是一致的。这种综合方法侧重于研究盐穴底部沉积物的渗流特性,为估算类似盐矿的摩擦损失和渗透率提供了宝贵的见解。
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引用次数: 0
Evaluation of acid retardation based on acid-etched fracture morphology 根据酸蚀断口形貌评估酸缓蚀性
0 ENERGY & FUELS Pub Date : 2024-11-08 DOI: 10.1016/j.geoen.2024.213492
Pingli Liu , Jinlong Li , Juan Du , Jinming Liu , Gang Xiong , Pengfei Chen , Yaochen Li , Xiang Chen
Acid fracturing is the most effective production enhancement measure for carbonate reservoir stimulation. The retardation performance of acid systems is one of the key parameters influencing the effectiveness of acid fracturing. However, current methods for evaluating acid retardation, based on static dissolution experiments and acid-rock reaction kinetics, have certain limitations. This study introduces a new method for evaluating acid retardation by simulating acid flow in formation fractures. The morphology of acid-etched fractures was obtained, and the depth and width distribution of the etched fractures were quantitatively analyzed to assess the acid retardation performance. In addition, high-temperature dissolution experiments were used to evaluate the acid's dissolution capacity, and acid-rock reaction kinetics experiments were conducted to determine the acid-rock reaction rate and activation energy of the acid systems. The results show that at 130 °C, the reaction rate between hydrochloric (HCl) acid and rock (2.12 × 10−5 mol/(s·cm2)) was the fastest, followed by Diverting acid, while G acid had the slowest reaction rate (1.51 × 10−6 mol/(s·cm2)). The activation energy of weak acid systems was much higher than that of strong acid systems. The new evaluation method revealed that the average fracture width and depth etched by HCl acid were the largest (7.57 mm and 6.39 mm, respectively), while the fracture depth etched by G acid was the smallest (0.87 mm), and the average fracture width etched by Acetic acid was the smallest (2.30 mm). This indicates that acetic acid has a stronger etching ability along the fracture length compared to G acid. Additionally, the fracture width and depth curves of strong acids (e.g., HCl acid and Diverting acid) showed a downward trend, whereas those of weak acids (Acetic acid and G acid) showed an upward trend. This suggests that Diverting acid has poor retardation performance, while G acid has the best retardation performance. Furthermore, the roughness of fractures etched by strong acids was much greater than that of fractures etched by weak acids, indicating that strong acids have a stronger non-uniform etching ability. To balance the non-uniform fracture etching morphology and the effective reach of the acid, a combination of strong and weak acids can be used.
酸性压裂是碳酸盐岩储层增产的最有效措施。酸性体系的缓效性能是影响酸性压裂效果的关键参数之一。然而,目前基于静态溶解实验和酸-岩反应动力学的酸迟滞评价方法存在一定的局限性。本研究通过模拟酸液在地层裂缝中的流动,引入了一种新的酸液迟滞评估方法。研究获得了酸蚀裂缝的形态,并定量分析了酸蚀裂缝的深度和宽度分布,以评估酸缓性能。此外,还通过高温溶解实验评估了酸的溶解能力,并通过酸岩反应动力学实验确定了酸体系的酸岩反应速率和活化能。结果表明,在 130 °C 下,盐酸与岩石的反应速率(2.12 × 10-5 mol/(s-cm2))最快,其次是憩息酸,而 G 酸的反应速率(1.51 × 10-6 mol/(s-cm2))最慢。弱酸体系的活化能远高于强酸体系。新的评价方法显示,盐酸蚀刻的平均断口宽度和深度最大(分别为 7.57 毫米和 6.39 毫米),而 G 酸蚀刻的断口深度最小(0.87 毫米),醋酸蚀刻的平均断口宽度最小(2.30 毫米)。这表明,与 G 酸相比,醋酸在断裂长度上的蚀刻能力更强。此外,强酸(如 HCl 酸和 Diverting 酸)的断口宽度和深度曲线呈下降趋势,而弱酸(醋酸和 G 酸)的断口宽度和深度曲线呈上升趋势。这表明 Diverting 酸的缓凝性能较差,而 G 酸的缓凝性能最好。此外,强酸蚀刻的断口粗糙度远大于弱酸蚀刻的断口粗糙度,这表明强酸具有更强的非均匀蚀刻能力。为了平衡断口蚀刻形态的不均匀性和酸的有效范围,可以将强酸和弱酸结合使用。
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引用次数: 0
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Geoenergy Science and Engineering
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