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Pore connectivity and structure-transport relationships in rocks from the Aphrodite gas field 阿芙罗狄蒂气田岩石孔隙连通性及构造-输运关系
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-05 DOI: 10.1016/j.geoen.2025.214311
Eleni Himona , Robin S. Fletcher , Huw E.L. Williams , Sean P. Rigby
Pore structure-transport relationships greatly impact potential gas storage within, and producibility from, rocks of the Aphrodite Mediterranean gas field, but the former are difficult to discern with current typical methods. However, rarely-used gas overcondensation data have been shown here to be essential for representative and accurate invasion percolation-based determination of the pore connectivity for pore sizes over the whole range from ∼100s μm down to nanometres in these rocks. Combined gas overcondensation and scanning curves have revealed the presence of two sub-networks of large macropores, each shielded by very differently-sized necks, and enabled the separate pore body size distribution and pore connectivity to be obtained for the sub-network shielded by pore-blocking necks. A ‘pore-sifting’ strategy, implemented with either serial nitrogen and iodononane adsorption, or integrated gas sorption and mercury porosimetry, has assessed the different accessibility and/or mass transport contributions of each sub-network. Independent findings from nitrogen kinetic gas uptake suggested, perhaps counter-intuitively, that mass transport rates are faster in the sub-network ultimately shielded for desorption by smaller orifices, though explanations for this have been provided. Computerised X-ray tomography, SEM and PFG NMR have suggested that the pore bodies are associated with the cavities of planktonic foraminifera, while the shielding necks with the semi-permeable fossil shells or embedding clay matrix.
孔隙结构-输运关系极大地影响了Aphrodite地中海气田岩石的潜在储气能力和产能,但目前的典型方法难以识别孔隙结构-输运关系。然而,很少使用的气体过冷凝数据在这里被证明是至关重要的,对于这些岩石中从~ 100 μm到纳米的整个孔隙尺寸范围内的孔隙连通性的具有代表性和准确的入侵渗透测定。气体过凝曲线与扫描曲线的结合揭示了两个大孔隙子网络的存在,每一个大孔隙子网络都被不同大小的孔颈屏蔽,这使得被孔颈屏蔽的子网络可以获得单独的孔体尺寸分布和孔隙连通性。通过一系列氮和碘酮吸附,或综合气体吸附和汞孔隙度测定法实施的“孔隙筛选”策略,评估了每个子网络的不同可达性和/或质量传输贡献。来自氮气动力学气体吸收的独立研究结果表明,也许与直觉相反,质量传输速率在子网络中更快,最终被较小的孔屏蔽以解吸,尽管对此已经提供了解释。计算机x射线断层扫描、扫描电镜和PFG核磁共振表明,孔体与浮游有孔虫的孔洞有关,而屏蔽颈与半透性化石壳或嵌入粘土基质有关。
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引用次数: 0
Modeling foam flow in porous media influenced by oil: A computational framework for improved parameter estimation 模拟受石油影响的多孔介质中的泡沫流动:改进参数估计的计算框架
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-25 DOI: 10.1016/j.geoen.2025.214349
Gabriel Brandão de Miranda , Anderson de Moura Ribeiro , Grigori Chapiro , Rodrigo Weber dos Santos , Bernardo Martins Rocha
Foam has been widely employed to control gas mobility in porous media, playing a crucial role in enhanced oil recovery (EOR). However, the presence of crude oil can significantly impact foam stability through complex physico-chemical interactions, leading to reduced apparent viscosity and diminished effectiveness. While several experimental studies have investigated foam weakening mechanisms in the presence of oil, systematic approaches to estimating oil-related parameters in implicit-texture models have received limited attention. This study addresses this gap by developing a computational framework to analyze foam behavior using systematic core flooding protocols with progressive oil injection. By simulating steady-state core flooding experiments, we evaluate strategies for isolating oil-induced foam destabilization and improving parameter estimation techniques. The results provide insights into the robustness of current modeling approaches and guide experimental protocols for more accurate foam characterization in EOR applications. The results support the refinement of injection strategies, demonstrating that gradual increases in oil–water injection ratios are crucial to provide reliable parameter estimation, addressing limitations in current experimental protocols with abrupt injection increases. Simulations on heterogeneous cases illustrate the difficulties related to fitting oil-related parameters for a sparse dataset.
泡沫被广泛用于控制多孔介质中气体的流动性,在提高石油采收率(EOR)中起着至关重要的作用。然而,原油的存在会通过复杂的物理化学相互作用显著影响泡沫的稳定性,导致表观粘度降低和有效性降低。虽然一些实验研究已经研究了石油存在下泡沫的削弱机制,但在隐式结构模型中估计石油相关参数的系统方法受到的关注有限。本研究通过开发一个计算框架来分析泡沫行为,从而解决了这一差距,该框架使用系统岩心驱油方案进行递进注油。通过模拟稳态岩心驱油实验,我们评估了隔离油致泡沫失稳和改进参数估计技术的策略。该结果为当前建模方法的鲁棒性提供了见解,并指导了在EOR应用中更准确地表征泡沫的实验方案。研究结果支持了注入策略的改进,表明油水注入比的逐渐增加对于提供可靠的参数估计至关重要,解决了当前实验方案中突然注入增加的局限性。在异构情况下的模拟说明了稀疏数据集拟合石油相关参数的困难。
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引用次数: 0
Numerical analysis of heat extraction performance in fractured-karst carbonate geothermal reservoirs with thermo-hydro-mechanical-damage coupling model 基于热-水-力-损伤耦合模型的缝型岩溶型碳酸盐岩地热储层采热性能数值分析
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-20 DOI: 10.1016/j.geoen.2025.214348
Yaozeng Xie , Long Cheng , Zhifeng Luo , Luwei Qiu
A thermo-hydro-mechanical-damage coupling model is established in this study to discuss the geothermal extraction in fractured karst reservoirs. The rock deformation, Darcy-Stokes flow and heat transport coupled matrix rock system, fracture system and cavity system are solved by the extended finite element and mixed finite element methods. Then after the model validation, numerical analysis is carried out. Results reveal that the THMD process has significant impacts on the thermal extraction. Rock damage and fracture activation caused by thermo-poroelastic deformation will induce a complex fracture-cave network and enhanced permeability, thereby greatly improving the performance of fluid flow, heat transfer and thermal extraction. And increasing fluid injection rate and production pressure difference will accelerate the breakthrough of cold fluid, leading to the decline of thermal recovery. Raising the fracture aperture can effectively improve the thermal recovery, but there is a threshold that thermal recovery will reach to a limitation. Besides, high fracture-cavity density can greatly enhance the flowability and diffusivity, while early breakthrough of cold fluid is obtained, resulting a small thermal power at later stage.
建立热-水-力-损伤耦合模型,探讨裂缝性岩溶储层的地热开采。采用扩展有限元法和混合有限元法对岩石变形、达西-斯托克斯流动和热输运耦合的基质岩体系统、裂隙系统和空腔系统进行了求解。在模型验证后,进行数值分析。结果表明,THMD过程对热萃取有显著影响。热孔弹性变形引起的岩石损伤和裂缝活化会诱发复杂的缝洞网络,提高渗透率,从而大大改善流体流动、传热和热抽提性能。增加注液量和生产压差会加速冷流体的突破,导致热采收率下降。提高裂缝孔径可以有效提高热采收率,但存在热采收率达到极限的阈值。高的缝洞密度可以大大提高流动性和扩散系数,冷流体较早突破,后期热功率较小。
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引用次数: 0
Reservoir cellular automata: a lightweight method for reservoir remaining oil distribution prediction 储层元胞自动机:储层剩余油分布预测的一种轻量级方法
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-10 DOI: 10.1016/j.geoen.2025.214315
Xin Liu , Meng Sun , Qi Sun , Jiangru Yuan , Yuhao Zhou , Zheng Yuan , Shibo Gu
The remaining oil distribution plays a vital role in enhanced oil recovery (EOR), which directly guides the development of oilfields. However, efficiently predicting the remaining oil distribution is a challenge due to the complex reservoir fluid distribution after water flooding. As a popular method for remaining oil studies, reservoir numerical simulation is frequently confronted with challenges such as high computational complexity and long matching time. This paper proposes a reservoir cellular automata (RCA) to predict the remaining oil distribution during water flooding. We divide the oil reservoir into a grid space, which is mapped to a cellular space. Each grid is a cellular node in the cellular space, and its state is characterized by oil saturation. The eight nodes geographically adjacent to a node are its neighbor nodes, forming a Moore-type neighborhood. We design lightweight deduction rules that transform the remaining oil dynamic evolution into nodes state iterative updates. Based on the pressure difference, Darcy’s law calculates the volume change of two-phase fluid, which is combined with porosity to update the node state. Then, the pressure after the fluid flow is updated by the material balance equation. In addition, a data supplement method is also presented to initialize the RCA. On a sand body in northern China, we apply the RCA to predict the remaining oil distribution based on reservoir data. Experiments show that RCA reduces deduction time by 87 % compared to numerical simulation while achieving an MRE of less than 10 %.
剩余油分布对提高采收率起着至关重要的作用,直接指导油田的开发。然而,由于水驱后储层流体分布复杂,如何有效预测剩余油分布是个难题。油藏数值模拟作为一种流行的剩余油研究方法,经常面临计算复杂度高、匹配时间长等挑战。提出了一种储层元胞自动机(RCA)来预测水驱过程中剩余油的分布。我们将油藏划分为网格空间,网格空间映射为细胞空间。每个网格是细胞空间中的一个细胞节点,其状态由含油饱和度表征。在地理上与一个节点相邻的8个节点是它的邻居节点,形成一个摩尔型邻居。设计轻量级推理规则,将剩余油动态演化转化为节点状态迭代更新。基于压差,Darcy定律计算两相流体的体积变化,并结合孔隙度更新节点状态。然后,通过物料平衡方程更新流体流动后的压力。此外,还提出了一种初始化RCA的数据补充方法。在华北某砂体上,应用RCA方法对储层剩余油分布进行了预测。实验表明,与数值模拟相比,RCA减少了87%的扣除时间,而MRE小于10%。
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引用次数: 0
Salt caprock geomechanics applied to pre-salt reservoirs subjected to cold waterflooding 盐下储层冷驱盐盖层地质力学研究
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-10 DOI: 10.1016/j.geoen.2025.214338
Pedro A.L.P. Firme , Julio Rueda , Cristian Mejia , Deane Roehl , Diogo Rossi , Francisco H. Ferreira , Ricardo Chaves
The Brazilian Pre-salt reservoirs hold significant hydrocarbon (HC) reserves. Considering the decarbonization trends, a sustainable destination for the carbon dioxide (CO2) produced with the HCs is mandatory. Recovery methods such as waterflooding, including CO2 injection, are crucial for environmentally adequate continued production. However, they strongly impact reservoir geomechanics. This work analyzes the thermo-hydro-mechanical effect of cold water injection in a Pre-salt reservoir with special regard to the impact of the salt caprock response. The investigation is based on a one-way coupled numerical simulation of a conceptual model subjected to injection over 30 years. The analyses aim to assess: i) how the combined effect of cooling and pressurization affects the mechanical response of the reservoir and caprock; ii) the critically affected regions; and iii) the impact of different salt rock mechanical models (elastic, elastoplastic, and viscoelastic) on the global response. Results show that: i) the thermomechanical effect prevails over the hydromechanical effect in the cooled region; ii) the lower interval of the caprock is the most critical region in terms of horizontal stress drop, tension, and plastification; and iii) different integrity aspects are highlighted depending on the constitutive model of the caprock. The most critical drop in the horizontal stress leading to tension occurs just above the reservoir and at its top. The extension of the tension region in the lower interval of the caprock depends on the selected mechanical behavior. These findings help guide injection actions.
巴西盐下储层拥有大量的碳氢化合物(HC)储量。考虑到脱碳的趋势,碳碳化合物产生的二氧化碳(CO2)的可持续目的地是强制性的。水驱等采收率方法,包括二氧化碳注入,对于环保的持续生产至关重要。然而,它们强烈影响储层的地质力学。本文分析了盐下储层冷水注入的热-水-力学效应,特别考虑了盐盖层响应的影响。这项研究是基于一个概念模型的单向耦合数值模拟,该模型在30多年的时间里受到注入的影响。分析的目的是评估:1)冷却和加压的联合作用如何影响储层和盖层的力学响应;Ii)受严重影响的地区;不同的盐岩力学模型(弹性、弹塑性和粘弹性)对整体响应的影响。结果表明:1)在冷却区,热力学效应优于水力学效应;盖层下段是水平应力降、拉张和塑化作用最为关键的区域;iii)根据盖层的本构模型,强调了不同的完整性方面。导致拉张的水平应力最关键的下降发生在储层上方和顶部。盖层下段拉张区的延伸取决于所选择的力学行为。这些发现有助于指导注射行动。
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引用次数: 0
The application of generative adversarial networks (GANs) for petroleum exploration in deep strata—A case study on overpressure prediction 生成对抗网络在深层石油勘探中的应用——以超压预测为例
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-12 DOI: 10.1016/j.geoen.2025.214326
Qiaochu Wang , Dongxia Chen , Meijun Li , Fuwei Wang , Zijie Yang , Zaiquan Yang , Sha Li , Yuqi Wang
Petroleum resources are among the most important fossil fuels in the world. With the development of field knowledge and exploration technology, the giant potential of petroleum resources in deep strata deeper than 5000 m has been recognized. However, the complex geological environment characterized by extremely high pressure seriously constrains deep-strata petroleum resource exploration and exploitation in terms of technology, engineering and economics. In this study, the generative adversarial network (GAN) deep learning algorithm is first applied to construct a virtual exploration well dataset to compensate for the lack of wells in deep strata and then to enlarge the well log dataset. Then, a boosted back propagation neural network (BPNN) is used to predict the complex pore pressure based on the enlarged GAN dataset. Finally, the gradient descent method is utilized for the calibration of the whole model to provide a precise deep-strata pore pressure prediction model. The final results show that with the enlarged GAN dataset, the pore pressure prediction model performs well during training and validation, with the highest correlation coefficients, 0.821 and 0.755, respectively. The test results without loss function calibration show a slightly lower accuracy, with correlation coefficients ranging from 0.584 to 0.606. The cross-validation also indicates similar accuracy, with correlation coefficients ranging from 0.589 to 0.606. By applying the data-driven and physical informed loss functions, both the GAN model and BPNN model are optimized. The loss of the GAN model shows a steady status after the 2000th calibration, which indicates that the best model is constructed. The final correlation coefficient between the actual and predicted pressures also reaches 0.98 as the loss of the BPNN model decreases from 4.0 to 1.1. This study not only introduces a novel method for pore pressure prediction for deeply buried petroleum reservoirs by using the deep learning algorithms of GANs and BPNN, which is the first use in the petroleum industry field, but also provides significant guidance for the utilization of artificial intelligence in petroleum exploration and exploitation, thus further extending the application of AI to small-dataset situations.
石油资源是世界上最重要的化石燃料之一。随着油田知识和勘探技术的发展,5000 m以上深层石油资源的巨大潜力已被认识。然而,以超高压为特征的复杂地质环境在技术、工程和经济等方面严重制约了深层石油资源的勘探开发。本研究首先利用生成对抗网络(GAN)深度学习算法构建虚拟探井数据集,弥补深层井的不足,然后对测井数据集进行扩展。然后,基于放大的GAN数据集,使用增强的反向传播神经网络(BPNN)预测复杂孔隙压力。最后,利用梯度下降法对整个模型进行标定,得到了精确的深部孔隙压力预测模型。最终结果表明,在扩大的GAN数据集上,孔压预测模型在训练和验证过程中表现良好,相关系数最高,分别为0.821和0.755。未经损失函数校准的测试结果精度略低,相关系数在0.584 ~ 0.606之间。交叉验证也显示出相似的准确性,相关系数在0.589 ~ 0.606之间。通过应用数据驱动和物理通知损失函数,对GAN模型和bp神经网络模型进行了优化。在第2000次校正后,GAN模型的损耗呈现稳定状态,这表明构建了最佳模型。随着BPNN模型的损失从4.0减小到1.1,实际压力与预测压力之间的最终相关系数也达到了0.98。本研究不仅在石油工业领域首次引入了利用gan和BPNN深度学习算法进行深埋油藏孔隙压力预测的新方法,而且对人工智能在石油勘探开发中的应用具有重要的指导意义,从而进一步将人工智能的应用扩展到小数据集情况。
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引用次数: 0
Experimental detection method of lost circulation based on multivariate optimised signal processing 基于多元优化信号处理的漏失实验检测方法
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-05 DOI: 10.1016/j.geoen.2025.214303
Zhongxi Zhu , Weiting Chen , Wanneng Lei , Lei Cao
Accurately locating the leakage location can reduce the loss caused by lost circulation, and a method of detecting the leakage location using transient pressure wave is proposed for leakage location. Firstly, the pressure wave signal is denoised using the improved adaptive noise complete ensemble empirical modal decomposition (ICEEMDAN), the joint classification of preferred components by Marginal Distance (MD) and cumulative mean (MASM), the improved wavelet thresholding method, and a multivariate optimisation signal denoising method based on ICEEMDAN-MD-MASM-IWT is proposed; compared with the other four denoising Secondly, the signal features are analysed using the neighbourhood difference method, and the leakage layer is located according to the peak time of the leakage features, which avoids the problems of too strong dependence on time-domain features, difficult time-frequency correspondence, and inconspicuous feature peaks in the traditional lost circulation detection methods; compared with the other traditional lost circulation detection methods, this method has the smallest average error in location. , which is reduced by 2.03 % compared to the time domain analysis method. Further discussion, multiple sets of experiments were conducted for different borehole sizes, and the error range was 3.11 %–7.98 %. The results show that the lost circulation detection method can effectively identify the location of lost circulation.
准确定位泄漏位置可以减少漏失造成的损失,提出了一种利用瞬态压力波进行泄漏定位的方法。首先,采用改进的自适应噪声全系综经验模态分解(ICEEMDAN)对压力波信号进行去噪,采用边际距离(MD)和累积均值(MASM)联合分类优选分量、改进的小波阈值法,提出了基于ICEEMDAN-MD-MASM- iwt的多变量优化信号去噪方法;其次,采用邻域差分法对信号特征进行分析,根据泄漏特征的峰值时间定位泄漏层,避免了传统丢包检测方法对时域特征依赖性强、时频对应困难、特征峰值不明显等问题;与其他传统漏失检测方法相比,该方法具有最小的平均定位误差。,比时域分析方法降低了2.03%。进一步讨论,针对不同井眼尺寸进行了多组实验,误差范围为3.11% ~ 7.98%。结果表明,该漏失检测方法能有效识别漏失位置。
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引用次数: 0
Trends and frontiers in geothermal energy and mine geothermal energy extraction: A bibliometric study 地热能和矿山地热能开采的趋势与前沿:文献计量学研究
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-08 DOI: 10.1016/j.geoen.2025.214331
Jiale Zhao , Zijun Li , Yu Xu , Yin Chen
Geothermal energy, as a novel green energy source with high expectations, has garnered extensive research attention. The sheer volume of this research field has made it difficult for scientists to keep abreast of its development trends and cutting-edge areas. This paper utilizes bibliometric analysis to delve into the trends in the development of geothermal energy and Mine Geothermal Energy (MGE) exploitation since the 21st century. Through the Web of Science database, this paper identified 1185 and 138 documents respectively, examining the growth trends, research hotspots, and frontier issues in the Geothermal Energy Exploration (GEE) and MGE fields. The findings reveal an overall upward trend in the literature on GEE and MGE, with an increasing diversification of research directions. The focus of GEE research encompasses technologies such as Enhanced Geothermal Systems (EGS) and Ground Source Heat Pumps (GSHP), while MGE is concentrated on heat energy recovery using mine water and backfill materials. The study also delineates three developmental phases of geothermal energy exploitation and provides a prospective outlook on future trends. This research offers invaluable reference information for newcomers to the field and provides a scientific foundation for the sustainable development of geothermal energy.
地热能作为一种被寄予厚望的新型绿色能源,得到了广泛的研究关注。这个研究领域的庞大数量使得科学家们很难跟上它的发展趋势和前沿领域。本文运用文献计量学分析方法,探讨了21世纪以来地热能和矿用地热能开发的发展趋势。本文通过Web of Science数据库,对地热能勘探(GEE)和地热能勘探(MGE)领域的发展趋势、研究热点和前沿问题进行了梳理,检索文献分别为1185篇和138篇。研究结果显示,研究方向日益多样化,研究结果总体呈上升趋势。GEE的研究重点包括增强型地热系统(EGS)和地源热泵(GSHP)等技术,而MGE的研究重点是利用矿井水和回填材料回收热能。研究还划分了地热能开发的三个发展阶段,并对未来的发展趋势进行了展望。本研究为地热能领域的新手提供了宝贵的参考信息,为地热能的可持续发展提供了科学依据。
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引用次数: 0
Seepage mechanism and formation applicability of fracture-assisted waterflooding technology in low permeability reservoirs 低渗透油藏裂缝辅助水驱技术渗流机理及地层适用性
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-10 DOI: 10.1016/j.geoen.2025.214336
Qingchao Cheng , Ruixuan Bu , Jianguang Wei , Xiaofeng Zhou , Yujie Bai , Jiangtao Li , Guangsheng Cao
Unconventional reservoirs with low permeability have emerged as new mining objectives to assure the long-term development of oilfields. Fracture-assisted waterflooding (FAW) has become one of the essential technologies for more efficient and low-cost waterflooding development of low-permeability reservoirs. The steady-state and unsteady-state single-phase seepage models for FAW were derived by the potential superposition principle, the source function, and the Newman product solution in this paper. The accuracy of these models was validated using the devices that simulate hydraulic fracturing electrically. Equipotential lines and streamlines fields were calculated to exemplify the seepage mechanism of FAW. Numerical simulations of two-phase (oil-water) flow behavior under FAW conditions were conducted employing a black-oil model, with particular emphasis on production performance and water cut development. The oil production laws in the process of FAW were studied to analyze the formation adaptability of this method. The flow dynamics of oil-water displacement were experimentally investigated through a transparent physical model incorporating tracer visualization technology, enabling precise tracking of fluid front advancement. The results indicated that the equipotential lines spread gradually from the fracture tip to the fracture root, and oil was easily retained at the angle between the fracture and the oil-water well connection line. The FAW production process could be divided into the oil production natural decline stage, the FAW production increase stage, and the FAW production decline stage. Based on the oil production, both the increase in the early stage and the reduction in the subsequent stage were proportional to the increase of fracture length. When the reservoir permeability increased, the optimal fracture length decreased at any given angle. The increase of fracture angle (the angle between the oil-water well connection line and the fracture) could mitigate the water channeling effect caused by excessively long fractures. While the increase in injection pressure exacerbated the degree of water channeling. For reservoirs with permeability greater than 10 × 10−3μm2, the maximum length of the fracture generated by FAW should not exceed 20 m. The optimal range of reservoir permeability for FAW measures was between 0.1 × 10−3μm2 and 20 × 10−3μm2. The findings of this paper provide theoretical guidance for improving the application of FAW technology in low permeability reservoirs.
低渗透非常规油气藏已成为保证油田长期发展的新开采目标。裂缝辅助水驱已成为低渗透油藏高效、低成本水驱开发的关键技术之一。利用势叠加原理、源函数和纽曼积解,建立了一汽稳态和非稳态单相渗流模型。使用模拟水力压裂的设备验证了这些模型的准确性。计算等势线场和流线场,以说明一汽的渗流机理。采用黑油模型对一汽条件下油水两相流动特性进行了数值模拟,重点研究了生产动态和含水率发展情况。研究了一汽采油过程中的采油规律,分析了该方法的地层适应性。通过结合示踪可视化技术的透明物理模型对油水驱替过程的流动动力学进行了实验研究,实现了流体锋面推进的精确跟踪。结果表明:等势线从裂缝尖端向裂缝根部逐渐延伸,裂缝与油水井连接线夹角处易留油;一汽生产过程可分为石油产量自然下降阶段、一汽产量增加阶段和一汽产量下降阶段。从产油量来看,压裂初期的增产和后期的减产都与裂缝长度的增加成正比。随着储层渗透率的增加,最佳裂缝长度在任意角度下都呈减小趋势。增加裂缝角度(油水井连接线与裂缝之间的角度)可以缓解过长裂缝造成的窜水效应。而注入压力的增加则加剧了水窜的程度。对于渗透率大于10 × 10−3μm2的储层,FAW产生的裂缝最大长度不宜超过20 m。FAW措施的最佳储层渗透率范围为0.1 × 10−3μm2 ~ 20 × 10−3μm2。研究结果为提高FAW技术在低渗透油藏中的应用提供了理论指导。
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引用次数: 0
Molecular structural response of CH4-containing anthracite to Sc-CO2 pressure variations: Decoupling oxygen functionality dynamics for optimized carbon storage 含ch4无烟煤对Sc-CO2压力变化的分子结构响应:优化碳储存的解耦氧官能团动力学
IF 4.6 0 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-09 DOI: 10.1016/j.geoen.2025.214330
Wenyu Fu , Yunzhong Jia , Hao Liu , Zhaolong Ge , Chenqing Shang , Xinge Zhao
The molecular structure of coal plays a pivotal role in coalbed methane recovery and geologic carbon storage (GCS) within depleted coal seams. To investigate the molecular structure evolution resulting from interactions between CO2 and CH4-containing anthracite, we conducted a series of six experimental trials using XRD, FTIR, and Raman spectroscopy under varying pressure conditions. The results indicate that the crystalline structure parameters, including aromaticity (fa), inter-layer spacing (d002), and average stacking height (Lc) remain largely insensitive to Sc-CO2 exposure. In contrast, oxygen-containing and hydroxyl functional groups exhibit significant and systematic variations, following distinct quadratic trends with respect to CO2 pressure. Specifically, the average diameter (La) decreases significantly with increasing injection pressure. while, the ID1/IG declined consistently, suggesting enhanced structural ordering and the formation of larger aromatic ring systems. A critical pressure range of 8.32–9.38 MPa was identified, within which carboxylic groups readily decompose, promoting crosslinking. Notably, aromatic and aliphatic structures maintain remarkable stability in their proportional distribution, while oxygen-containing structures undergo a characteristic dip-and-rebound trajectory corresponding to enhanced injection pressure levels. This pattern contrasts sharply with the behavior of hydroxyl structures, which exhibit the opposite trend. Maximum structural variation occurs at 8.59 MPa, identified as the critical transition pressure. These findings reveal pressure-dependent molecular reorganization mechanisms in anthracite and provide essential insights for optimizing injection parameters in CO2-ECBM and GCS projects.
煤的分子结构在枯竭煤层煤层气开采和地质储碳中起着至关重要的作用。为了研究含CO2和ch4的无烟煤相互作用导致的分子结构演变,我们在不同压力条件下使用XRD, FTIR和Raman光谱进行了一系列的六次实验。结果表明,晶体结构参数,包括芳香度(fa)、层间距(d002)和平均堆积高度(Lc)对Sc-CO2暴露基本不敏感。相比之下,含氧官能团和羟基官能团表现出显著和系统的变化,在二氧化碳压力方面遵循明显的二次趋势。随着注入压力的增加,平均直径(La)显著减小。而ID1/IG持续下降,表明结构有序性增强,形成了更大的芳环体系。在8.32 ~ 9.38 MPa的临界压力范围内,羧基容易分解,促进交联。值得注意的是,芳香族和脂肪族结构在比例分布上保持了显著的稳定性,而含氧结构则随着注入压力水平的提高而呈现出特征的下降和反弹轨迹。这种模式与羟基结构的行为形成鲜明对比,羟基结构表现出相反的趋势。8.59 MPa时结构变化最大,为临界过渡压力。这些发现揭示了无烟煤中压力依赖的分子重组机制,并为优化CO2-ECBM和GCS项目的注入参数提供了重要见解。
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Geoenergy Science and Engineering
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