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Mixed magnesium, cobalt, nickel, copper, and zinc sulfates as thermochemical heat storage materials
Pub Date : 2024-12-01 DOI: 10.1016/j.meaene.2024.100027
Jakob Smith , Peter Weinberger , Andreas Werner
Thermochemical energy storage is an emerging technology being researched for harvesting waste heat and promoting integration of renewable energy in order to combat climate change. While many simple salts such as MgSO4⋅7H2O have been investigated thoroughly, there remains much work to be done in the domain of materials that take advantage of synergetic effects of multiple different cations located in the same crystal. To this end, a solid solution library of divalent metal sulfates of the formula M1-xM2xSO4·nH2O (M, M2 = Mg, Co, Ni, Cu, Zn) has been synthesized. Following X-ray powder diffraction to confirm phase purity, scanning electron microscopy provided insight into particle morphology. One of the most conspicuous features was the presence of star-shaped cracks in some of the materials, which may contribute to increased surface area and enhance reaction kinetics. The simultaneous thermal analysis of the mixed salt sulfates led to several conclusions. Corresponding to the high initial dehydration barrier of NiSO4⋅6H2O, incorporation of nickel into other sulfates led to lower degrees of dehydration at low temperatures. The opposite effect was observed with the addition of copper. Of great interest was the surprisingly facile dehydration of hydrated Mg0.25Zn0.75SO4, which exceeded that of both pure MgSO4⋅7H2O and ZnSO4⋅7H2O. This promising compound is one representative of three different compounds with 75 % zinc which all have the highest dehydration activity up to 100 °C of all compounds in the series of hydrates of M1-xZnxSO4·nH2O (M = Mg, Ni, Cu).
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引用次数: 0
Optimization and kinetic study of glucose production from agricultural waste 利用农业废弃物生产葡萄糖的优化和动力学研究
Pub Date : 2024-11-16 DOI: 10.1016/j.meaene.2024.100026
Kiman Silas , Habiba D. Mohammed , Thlama Mperiju Mainta , Mohammed Modu Aji , Jerome Undiandeye
Agricultural waste consisting of sugarcane bagasse (SB), cassava peels (RH) and rice husk (RH) were characterized in this study by EDXRF, SEM/EDX, XRD, FTIR, proximate and ultimate analyses. The SB waste showed the highest potential for glucose yield production and was utilized in a Response Surface Methodology (RSM) optimization and kinetic study of enzymatic hydrolysis using isolated Aspergillus niger. An optimized glucose yield of maximum concentration of 92.522 mg/mL was achieved under specific conditions such as time (55.3 min), pH (4.4) and biomass (0.89g). In the kinetic study, the enzymic hydrolysis obeyed the Michaelis-Menten kinetic model, the Vmax value was measured at 1.06 mg/mL/h, indicating the maximum rate of reaction achievable under the given experimental conditions. Additionally, the KM (0.28), representing the substrate concentration at which the reaction rate is half of Vmax. This study demonstrates the potential of agricultural waste, as efficient biofuel feedstocks, achieving high glucose yields through optimized enzymatic hydrolysis, crucial for advancing sustainable bioenergy production.
本研究通过 EDXRF、SEM/EDX、XRD、傅立叶变换红外光谱、近物分析和终极分析对甘蔗渣(SB)、木薯皮(RH)和稻壳(RH)等农业废弃物进行了表征。SB 废物显示出最高的葡萄糖生产潜力,并被用于响应面法(RSM)优化和使用分离的黑曲霉进行酶水解的动力学研究。在特定条件下,如时间(55.3 分钟)、pH 值(4.4)和生物量(0.89 克),葡萄糖产量达到最大浓度 92.522 毫克/毫升。在动力学研究中,酶水解遵循 Michaelis-Menten 动力学模型,测得 Vmax 值为 1.06 mg/mL/h,表明在给定的实验条件下可实现的最大反应速率。此外,KM(0.28)代表反应速率为 Vmax 的一半时的底物浓度。这项研究证明了农业废弃物作为高效生物燃料原料的潜力,通过优化酶水解可获得高葡萄糖产量,这对推进可持续生物能源生产至关重要。
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引用次数: 0
Virtual inertia extraction from a DC bus capacitor in a three−phase DC/AC inverter-based microgrid with seamless synchronisation operation modes 采用无缝同步运行模式的三相直流/交流逆变器微电网中直流母线电容器的虚拟惯性提取
Pub Date : 2024-11-08 DOI: 10.1016/j.meaene.2024.100024
Ali Salam Al-Khayyat, Waleed Abdulrazzaq Oraibi, Mustafa Jameel Hameed, Alyaa Muhsen Manati
It is crucial to employ power electronics converters for energy transfer in distributed energy resources such as photovoltaics, and wind energy system. Thus, parameters such as voltage, current, active and reactive powers, and frequency referred to the AC side need to be controlled. The local load could be operated either from converter itself or grid, hence the system could be called microgrid. In this paper, the active and reactive powers would be controlled separately when the inverter is connected to the grid. While in the islanded or autonomous mode, the proposed control would support the voltage and frequency. The proposed controller would be designed and function as the synchronous machine's voltage regulator and governor. The virtual synchronous machine is adopted to obtain the inertia and the concept is that the frequency of the grid is linked to the virtual frequency or so called the virtual speed of the rotor. The virtual frequency is obtained directly from the DC bus voltage of the inverter and this is achieved by allowing the DC link capacitor voltage to swing boarder than the grid frequency by making the capacitor voltage imitating frequency of grid. Where the frequency of grid is associated to the virtual frequency which is derived directly from DC capacitor voltage, thus, large level of inertia is extracted. The basic formulation, supervisory control, extraction the inertia from DC capacitor voltage, coordination transition, and evaluation the stability is presented in this paper. The mimic operation of the inverter as Synchronous Machine SM can make the distributed energy resources to be operated in either grid connected or islanded modes without the need to adopt control structure for the required mode. In addition, it provides robust performance in comparison with the traditional current, voltage and frequency control approaches. Moreover, the controller would be implemented for inverter having any type of filters and it is resilient to any variations in the filter and grid parameters. Furthermore, there is no concerning regarding instability problems, where it achieves the synchronisation smoothly and swiftly, and it is appropriate for implemented digitally.
在分布式能源(如光伏和风能系统)中,采用电力电子变流器进行能量传输至关重要。因此,需要控制交流侧的电压、电流、有功功率、无功功率和频率等参数。本地负载可由变流器本身或电网操作,因此该系统可称为微电网。在本文中,当逆变器与电网连接时,有功功率和无功功率将分别控制。在孤岛或自主模式下,建议的控制将支持电压和频率。建议的控制器将被设计为同步机的电压调节器和调速器。采用虚拟同步机来获得惯性,其概念是电网频率与虚拟频率或转子的虚拟速度相关联。虚拟频率直接从逆变器的直流母线电压中获得,这是通过让直流链路电容器电压的摆动范围大于电网频率,使电容器电压模仿电网频率来实现的。电网频率与虚拟频率相关联,而虚拟频率直接来自直流电容电压,因此可以提取较大的惯性。本文介绍了基本公式、监督控制、从直流电容电压中提取惯性、协调过渡和稳定性评估。将逆变器模拟为同步机 SM 运行,可使分布式能源资源在并网或孤岛模式下运行,而无需针对所需模式采用控制结构。此外,与传统的电流、电压和频率控制方法相比,它还能提供稳健的性能。此外,该控制器适用于具有任何类型滤波器的逆变器,并能抵御滤波器和电网参数的任何变化。此外,它不存在不稳定性问题,能平稳、迅速地实现同步,适合以数字方式实施。
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引用次数: 0
Special issue on advanced measurements of batteries, fuel cells and other energy storage devices 电池、燃料电池和其他储能设备的先进测量特刊
Pub Date : 2024-11-08 DOI: 10.1016/j.meaene.2024.100025
Tuan Guo, Yifei Yu, Emanuele Rizzuto
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引用次数: 0
Biosynthesis of NiO nanoparticles using Senna occidentalis leaves extract: Effects of annealing temperature and antibacterial activity 利用番泻叶提取物生物合成氧化镍纳米粒子:退火温度和抗菌活性的影响
Pub Date : 2024-10-22 DOI: 10.1016/j.meaene.2024.100023
Monisha Ganesan , Ambrose Rejo Jeice , Prammitha Rajaram
In this work a cost effective and ecofriendly green method for the preparation of NiO nanostructures employing Senna occidentalis (S. occidentalis) leaves extract has been reported. XRD studies show that the 400 °C and 500 °C annealed nanostructures were authenticated as pure face centered cubic phase with an average crystallite size are about 27 nm and 15 nm, respectively. The SEM results show that both the annealed samples were nearly spherical with grain sizes ranging between 65 and 74 nm. The band gap of 400 °C and 500 °C annealed NiO nanoparticles (NPs) was estimated to be 5.28 eV and 5.40 eV, respectively from UV–visible studies while the occurrence of Ni-O stretching in the FTIR spectra validates the formation of NiO. Further this work witnesses that the NiO NPs synthesized from the green route offer better antibacterial activity. The observed maximum zone of inhibition of 500 °C annealed NiO NPs was found to be 20 mm and 19 mm for Serratia marcescens and Bacillus cereus strains and indicates that this material can serve as a prospective drug for biomedical application.
本研究采用番泻叶提取物制备氧化镍纳米结构,是一种经济有效且环保的绿色方法。XRD 研究表明,400 °C 和 500 °C 退火后的纳米结构为纯面心立方相,平均晶粒大小分别约为 27 nm 和 15 nm。扫描电镜结果表明,两种退火样品都接近球形,晶粒大小在 65 纳米到 74 纳米之间。通过紫外可见光研究,400 ℃ 和 500 ℃ 退火的氧化镍纳米粒子(NPs)的带隙分别估计为 5.28 eV 和 5.40 eV,而傅立叶变换红外光谱中出现的 Ni-O 伸展则验证了氧化镍的形成。此外,这项工作还证明了通过绿色途径合成的氧化镍 NPs 具有更好的抗菌活性。对 Serratia marcescens 和 Bacillus cereus 菌株而言,500 °C 退火后的 NiO NPs 的最大抑菌区分别为 20 毫米和 19 毫米,这表明这种材料可作为生物医学应用的前瞻性药物。
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引用次数: 0
An optimization approach for enhancing energy efficiency, reducing CO2 emission, and improving lubrication reliability in roller bearings using ABC algorithm 使用 ABC 算法提高滚子轴承能效、减少二氧化碳排放和提高润滑可靠性的优化方法
Pub Date : 2024-10-10 DOI: 10.1016/j.meaene.2024.100021
Davood Beyralvand , Farzad Banazadeh
Friction and energy waste pose significant challenges in various industrial processes. Lubrication plays a crucial role in reducing friction and optimizing energy consumption. This study focuses on analyzing, simulating and calculation the oil film thickness, friction levels, energy losses, and CO2 emissions. The objective is to optimize lubrication conditions to enhance performance, improve energy consumption, and maximize lubrication efficiency for rolling bearings in a centrifugal fan. The simulation utilizes ANSYS CFX software, MATLAB programming. The optimal oil viscosity grade is determined based on two objectives by using artificial bee colony algorithm (ABC): minimizing energy consumption (thus reducing CO2 emission) and achieving the optimal oil film thickness and viscosity ratio. The findings reveal that, under the current lubrication conditions and normal fan operation, energy losses due to oil friction amount to 36.3 MWh per year, with CO2 emissions resulting from power losses reaching 18,750 kg per year. By transitioning to the optimized oil grade, energy savings of 1.08 MWh per year and a corresponding reduction of 557 kg in CO2 emissions per year can be achieved.
摩擦和能源浪费是各种工业流程面临的重大挑战。润滑在减少摩擦和优化能源消耗方面发挥着至关重要的作用。本研究的重点是分析、模拟和计算油膜厚度、摩擦水平、能量损失和二氧化碳排放。目的是优化润滑条件,以提高离心风机滚动轴承的性能、改善能耗并最大限度地提高润滑效率。模拟采用 ANSYS CFX 软件和 MATLAB 编程。通过人工蜂群算法(ABC),基于两个目标确定了最佳润滑油粘度等级:能耗最小化(从而减少二氧化碳排放)以及达到最佳油膜厚度和粘度比。研究结果表明,在当前的润滑条件和风机正常运行的情况下,每年因油摩擦造成的能量损失达 36.3 兆瓦时,每年因功率损失造成的二氧化碳排放量达 18,750 千克。通过过渡到优化的机油等级,每年可节约 1.08 兆瓦时的能源,并相应减少 557 千克的二氧化碳排放量。
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引用次数: 0
PMU-based voltage estimation and distributed generation effects in active distribution networks 主动配电网中基于 PMU 的电压估算和分布式发电效应
Pub Date : 2024-10-10 DOI: 10.1016/j.meaene.2024.100022
Nida Khanam, Mohd Rihan , Salman Hameed
The integration of distributed generation (DG) and phasor measuring units (PMUs) has significantly impacted electrical distribution networks. This study focuses on real-time control of renewable energy intermittency and strategic PMU deployment. By optimizing the placement of PMUs and DGs, the study aims to achieve several goals: maximize power loss reduction, increase DG penetration, and maintain acceptable voltage profiles. The recommended PMU-based approach incorporates the optimal number of DGs into the distribution network for load flow analysis. Testing this technique on 12-bus, 33-bus, and 69-bus networks yielded substantial gains. For example, power loss was 81.044 % lower in the 33-bus system and 79.256 % lower in the 69-bus test system compared to the base-case scenario. We also compared these results with other methods found in the literature. The developed algorithm is recommended for application in a real electrical power distribution network for more efficient integration of PMUs and new distributed generation units. Integrating PMUs with DG benefits active distribution network management, enabling proactive grid management and stability.
分布式发电(DG)与相位测量单元(PMU)的集成对配电网络产生了重大影响。本研究侧重于可再生能源间歇性的实时控制和 PMU 的战略部署。通过优化 PMU 和 DG 的布置,本研究旨在实现以下几个目标:最大限度地减少功率损耗、提高 DG 渗透率并保持可接受的电压曲线。推荐的基于 PMU 的方法将 DG 的最佳数量纳入配电网络,用于负荷流分析。在 12 总线、33 总线和 69 总线网络上测试该技术,结果显示收益显著。例如,与基本情况相比,33 总线系统的功率损耗降低了 81.044%,69 总线测试系统的功率损耗降低了 79.256%。我们还将这些结果与文献中的其他方法进行了比较。建议将所开发的算法应用于实际配电网络,以更有效地集成 PMU 和新的分布式发电装置。将 PMU 与分布式发电机组整合在一起有利于主动配电网络管理,实现主动电网管理和稳定性。
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引用次数: 0
Accelerated lithium-ion battery cycle lifetime testing by condition-based reference performance tests 通过基于条件的参考性能测试加速锂离子电池循环寿命测试
Pub Date : 2024-09-28 DOI: 10.1016/j.meaene.2024.100019
Evelina Wikner , Johan Lesser
Lifetime testing of lithium-ion batteries is time-consuming and costly. To reduce the time-to-market, application-specific accelerated lifetime tests are conducted. The test conditions must be carefully designed and controlled, both the test environment and load profile. During the lifetime test, measurable properties of the cell, most commonly the capacity and internal resistance, are tracked by a reference performance test (RPT). The frequency of RPTs is a variable of the number of test cycles or time. Setting the wrong frequency for the RPT results in either too many RPTs or, in the worst case, too few. To mitigate this issue, a test object capacity-driven approach has been developed. This new method is described and demonstrated in this article conducting the RPTs based on the cycling capacity of the cell. The method ensured the desired numbers of RPTs during the test period at the selected intervals corresponding to steps of 1% capacity loss. When compared to the most used traditional test method, using a fixed number of 200 cycles between RPTs, the method generated 44% more cycles over the initial 100 days.
锂离子电池的寿命测试既耗时又昂贵。为了缩短产品上市时间,需要进行针对特定应用的加速寿命测试。测试条件必须经过精心设计和控制,包括测试环境和负载曲线。在寿命测试期间,电池的可测量特性(最常见的是容量和内阻)将通过参考性能测试(RPT)进行跟踪。参考性能测试的频率是测试周期或时间的变量。为参考性能测试设置错误的频率会导致参考性能测试次数过多,或者在最坏的情况下导致参考性能测试次数过少。为缓解这一问题,我们开发了一种测试对象容量驱动方法。本文介绍并演示了这种新方法,即根据电池的循环容量进行 RPT。该方法可确保在测试期间按照所选的间隔(对应于 1%容量损失的步长)进行所需的 RPT 次数。与最常用的传统测试方法(RPT 之间的循环次数固定为 200 次)相比,该方法在最初的 100 天内产生的循环次数增加了 44%。
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引用次数: 0
Analysis of transmission pathways of combustion-induced vibration in a diesel engine using wavelet cross-correlation analysis method 利用小波交叉相关分析方法分析柴油发动机燃烧诱发振动的传播途径
Pub Date : 2024-09-28 DOI: 10.1016/j.meaene.2024.100020
Hitoshi Oguchi , Daiki Hashimoto , Masato Mikami
We experimentally investigated the transmission pathways of the combustion-induced vibration by analyzing the in-cylinder pressure, the accelerations on walls near the combustion chamber and the main bearing with wavelet cross-correlation analysis which can obtain both time delay and the correlation on the time between two signals in the frequency domain. The analysis shows that there are three possible transmission pathways of vibration from the combustion impact. First is a direct transmission from the combustion chamber to a wall near the combustion chamber or a wall near the main bearing via an engine surface wall, second is the transmission from the combustion chamber to a wall near the main bearing via the piston, connecting-rod and the crankshaft, and third is a transmission from the combustion chamber to a wall near the main bearing and there is no transmission to a wall near the combustion chamber.
我们利用小波交叉相关分析法对缸内压力、燃烧室附近壁面的加速度和主轴承的加速度进行了分析,实验研究了燃烧引起的振动的传播途径。分析表明,燃烧冲击产生的振动可能有三种传播途径。第一种是通过发动机表面壁从燃烧室直接传递到燃烧室附近的墙壁或主轴承附近的墙壁;第二种是通过活塞、连杆和曲轴从燃烧室传递到主轴承附近的墙壁;第三种是从燃烧室传递到主轴承附近的墙壁,而没有传递到燃烧室附近的墙壁。
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引用次数: 0
New parameters for the capacitive accelerometer to reduce its measurement error and power consumption 电容式加速度计的新参数可减少测量误差和功耗
Pub Date : 2024-09-01 DOI: 10.1016/j.meaene.2024.100018
Zine Ghemari , Salah Belkhiri , Salah Saad

Capacitive accelerometers are essential components in a wide range of electronic devices, enabling crucial functionalities such as touch sensitivity and proximity detection. Ensuring optimal accuracy is crucial for their effective performance in various applications. A key factor in this accuracy is the frequency margin, a parameter that significantly influences the sensor's ability to detect and respond to changes in capacitance.

In this article, we will delve deeply into strategies aimed at optimizing capacitive sensors with a focus on improving their frequency margin. By exploring the methodologies and techniques that enhance the sensor's ability to operate within an ideal frequency range, we aim to improve the measurement accuracy of capacitive accelerometers by reducing measurement errors and power consumption. This optimization process involves meticulous calibration of sensor parameters such as sensitivity, resonance frequency, and damping factors to maximize performance under various environmental conditions. The new capacitive accelerometer structure improves sensitivity, linearity, and accuracy through advanced measurement setups and design, offering high-performance acceleration measurements suitable for various applications and reliable data collection and calibration.

电容式加速度计是各种电子设备的重要组件,可实现触摸灵敏度和接近检测等重要功能。要在各种应用中有效发挥其性能,确保最佳精度至关重要。频率余量是影响精度的一个关键因素,这一参数极大地影响了传感器检测和响应电容变化的能力。在本文中,我们将深入探讨旨在优化电容式传感器的策略,重点是提高其频率余量。通过探索提高传感器在理想频率范围内工作能力的方法和技术,我们旨在通过减少测量误差和功耗来提高电容式加速度计的测量精度。这一优化过程包括对灵敏度、共振频率和阻尼系数等传感器参数进行细致校准,以便在各种环境条件下最大限度地提高性能。新型电容式加速度计结构通过先进的测量设置和设计提高了灵敏度、线性度和精度,提供了适合各种应用的高性能加速度测量以及可靠的数据采集和校准。
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引用次数: 0
期刊
Measurement: Energy
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