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Accelerated lithium-ion battery cycle lifetime testing by condition-based reference performance tests 通过基于条件的参考性能测试加速锂离子电池循环寿命测试
Pub Date : 2024-09-28 DOI: 10.1016/j.meaene.2024.100019
Evelina Wikner , Johan Lesser
Lifetime testing of lithium-ion batteries is time-consuming and costly. To reduce the time-to-market, application-specific accelerated lifetime tests are conducted. The test conditions must be carefully designed and controlled, both the test environment and load profile. During the lifetime test, measurable properties of the cell, most commonly the capacity and internal resistance, are tracked by a reference performance test (RPT). The frequency of RPTs is a variable of the number of test cycles or time. Setting the wrong frequency for the RPT results in either too many RPTs or, in the worst case, too few. To mitigate this issue, a test object capacity-driven approach has been developed. This new method is described and demonstrated in this article conducting the RPTs based on the cycling capacity of the cell. The method ensured the desired numbers of RPTs during the test period at the selected intervals corresponding to steps of 1% capacity loss. When compared to the most used traditional test method, using a fixed number of 200 cycles between RPTs, the method generated 44% more cycles over the initial 100 days.
锂离子电池的寿命测试既耗时又昂贵。为了缩短产品上市时间,需要进行针对特定应用的加速寿命测试。测试条件必须经过精心设计和控制,包括测试环境和负载曲线。在寿命测试期间,电池的可测量特性(最常见的是容量和内阻)将通过参考性能测试(RPT)进行跟踪。参考性能测试的频率是测试周期或时间的变量。为参考性能测试设置错误的频率会导致参考性能测试次数过多,或者在最坏的情况下导致参考性能测试次数过少。为缓解这一问题,我们开发了一种测试对象容量驱动方法。本文介绍并演示了这种新方法,即根据电池的循环容量进行 RPT。该方法可确保在测试期间按照所选的间隔(对应于 1%容量损失的步长)进行所需的 RPT 次数。与最常用的传统测试方法(RPT 之间的循环次数固定为 200 次)相比,该方法在最初的 100 天内产生的循环次数增加了 44%。
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引用次数: 0
Analysis of transmission pathways of combustion-induced vibration in a diesel engine using wavelet cross-correlation analysis method 利用小波交叉相关分析方法分析柴油发动机燃烧诱发振动的传播途径
Pub Date : 2024-09-28 DOI: 10.1016/j.meaene.2024.100020
Hitoshi Oguchi , Daiki Hashimoto , Masato Mikami
We experimentally investigated the transmission pathways of the combustion-induced vibration by analyzing the in-cylinder pressure, the accelerations on walls near the combustion chamber and the main bearing with wavelet cross-correlation analysis which can obtain both time delay and the correlation on the time between two signals in the frequency domain. The analysis shows that there are three possible transmission pathways of vibration from the combustion impact. First is a direct transmission from the combustion chamber to a wall near the combustion chamber or a wall near the main bearing via an engine surface wall, second is the transmission from the combustion chamber to a wall near the main bearing via the piston, connecting-rod and the crankshaft, and third is a transmission from the combustion chamber to a wall near the main bearing and there is no transmission to a wall near the combustion chamber.
我们利用小波交叉相关分析法对缸内压力、燃烧室附近壁面的加速度和主轴承的加速度进行了分析,实验研究了燃烧引起的振动的传播途径。分析表明,燃烧冲击产生的振动可能有三种传播途径。第一种是通过发动机表面壁从燃烧室直接传递到燃烧室附近的墙壁或主轴承附近的墙壁;第二种是通过活塞、连杆和曲轴从燃烧室传递到主轴承附近的墙壁;第三种是从燃烧室传递到主轴承附近的墙壁,而没有传递到燃烧室附近的墙壁。
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引用次数: 0
New parameters for the capacitive accelerometer to reduce its measurement error and power consumption 电容式加速度计的新参数可减少测量误差和功耗
Pub Date : 2024-09-01 DOI: 10.1016/j.meaene.2024.100018
Zine Ghemari , Salah Belkhiri , Salah Saad

Capacitive accelerometers are essential components in a wide range of electronic devices, enabling crucial functionalities such as touch sensitivity and proximity detection. Ensuring optimal accuracy is crucial for their effective performance in various applications. A key factor in this accuracy is the frequency margin, a parameter that significantly influences the sensor's ability to detect and respond to changes in capacitance.

In this article, we will delve deeply into strategies aimed at optimizing capacitive sensors with a focus on improving their frequency margin. By exploring the methodologies and techniques that enhance the sensor's ability to operate within an ideal frequency range, we aim to improve the measurement accuracy of capacitive accelerometers by reducing measurement errors and power consumption. This optimization process involves meticulous calibration of sensor parameters such as sensitivity, resonance frequency, and damping factors to maximize performance under various environmental conditions. The new capacitive accelerometer structure improves sensitivity, linearity, and accuracy through advanced measurement setups and design, offering high-performance acceleration measurements suitable for various applications and reliable data collection and calibration.

电容式加速度计是各种电子设备的重要组件,可实现触摸灵敏度和接近检测等重要功能。要在各种应用中有效发挥其性能,确保最佳精度至关重要。频率余量是影响精度的一个关键因素,这一参数极大地影响了传感器检测和响应电容变化的能力。在本文中,我们将深入探讨旨在优化电容式传感器的策略,重点是提高其频率余量。通过探索提高传感器在理想频率范围内工作能力的方法和技术,我们旨在通过减少测量误差和功耗来提高电容式加速度计的测量精度。这一优化过程包括对灵敏度、共振频率和阻尼系数等传感器参数进行细致校准,以便在各种环境条件下最大限度地提高性能。新型电容式加速度计结构通过先进的测量设置和设计提高了灵敏度、线性度和精度,提供了适合各种应用的高性能加速度测量以及可靠的数据采集和校准。
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引用次数: 0
A quantitative comparison of economic viability, volatile organic compounds, and particle-bound carbon emissions from a diesel engine fueled with biodiesel blends 对使用生物柴油混合燃料的柴油发动机的经济可行性、挥发性有机化合物和颗粒碳排放量进行定量比较
Pub Date : 2024-08-25 DOI: 10.1016/j.meaene.2024.100017
Abdulfatah Abdu Yusuf , Ibham Veza , Zubeda Ukundimana , Adolphus Nippae , Charles Asumana , Eric Kay Jebboe Jr. , M.A. Mujtaba , Islam Md Rizwanul Fattah , Manzoore Elahi M. Soudagar

Despite the environmental advantages of biofuel blends, detailed studies on emissions of polycyclic aromatic hydrocarbons (PAHs), n-alkanes, and particle-bound carbon from diesel engines, particularly when fueled with biodiesel, remain limited. This study addresses these gaps by analyzing biodiesel blends from neem, linseed, and jatropha oils produced via mechanical extraction and assessing their impact on volatile organic compounds and particle-bound carbon emissions in diesel engine. Economic evaluations of production costs, engine modifications, and payback periods are also conducted. The result shows that jatropha biodiesel exhibits a calorific value of 35.7 MJ/kg, while neem biodiesel shows superior oxidative stability due to its low iodine value. Additionally, linseed biodiesel displays favorable cold flow properties due to its high density and cetane value. Compared to D100, the N10 and N30 blend notably reduced high molecular weight PAH emissions by 10.7 % and 38.4 %, respectively, with the N30 blend achieving a remarkable 76 % reduction in formaldehyde emissions. Conversely, the J10 blend increased specific PAHs, while the J30 blend reduced PAHs by 21.3 %. Both L10 and L30 blends showed reduced naphthalene emissions, with the J30 blend notably reducing elemental carbon (EC) by 31.4 %, although organic carbon (OC) slightly increased. In contrast, the N30 blend decreased both EC and OC emissions, demonstrating a dose-dependent relationship between biodiesel concentration and emissions reduction. Overall, Jatropha biodiesel blends offer the best balance of economic efficiency and emission reductions, resulting in shorter payback periods and lower carcinogenic risks. Neem and linseed blends also provide environmental benefits but with varying economic implications, highlighting the trade-offs between production costs and long-term sustainability.

尽管生物燃料混合物具有环保优势,但对柴油发动机(尤其是以生物柴油为燃料时)的多环芳烃 (PAH)、正烷烃和颗粒结合碳排放的详细研究仍然有限。本研究通过分析从楝树油、亚麻籽油和麻风树油中通过机械萃取生产的生物柴油混合物,并评估它们对柴油发动机中挥发性有机化合物和颗粒结合碳排放的影响,弥补了这些空白。此外,还对生产成本、发动机改装和投资回收期进行了经济评估。结果表明,麻风树生物柴油的热值为 35.7 兆焦/千克,而楝树生物柴油因其碘值低而显示出卓越的氧化稳定性。此外,亚麻籽生物柴油因其高密度和十六烷值而具有良好的低温流动性能。与 D100 相比,N10 和 N30 混合燃料的高分子量多环芳烃排放量分别显著减少了 10.7% 和 38.4%,其中 N30 混合燃料的甲醛排放量显著减少了 76%。相反,J10 混合物增加了特定的多环芳烃,而 J30 混合物则减少了 21.3 % 的多环芳烃。L10 和 L30 混合物都减少了萘的排放,其中 J30 混合物显著减少了 31.4% 的元素碳 (EC),尽管有机碳 (OC) 略有增加。相比之下,N30 混合燃料的 EC 和 OC 排放量都有所减少,这表明生物柴油浓度与减排之间存在剂量依赖关系。总体而言,麻风树生物柴油混合物在经济效益和减排之间实现了最佳平衡,从而缩短了投资回收期,降低了致癌风险。楝树和亚麻籽混合物也具有环境效益,但其经济影响各不相同,这突出表明了生产成本与长期可持续性之间的权衡。
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引用次数: 0
Assessing opportunities for enhanced lighting energy conservation via occupancy and daylight monitoring 评估通过占用和日光监测加强照明节能的机会
Pub Date : 2024-08-02 DOI: 10.1016/j.meaene.2024.100015
Dhairye Gala, Shreya Khetan, Ninad Mehendale

Efficient energy utilization in buildings is crucial for sustainability. This work proposes an intelligent system that leverages computer vision techniques and CCTV images to assess indoor lighting energy usage based on occupancy, artificial lighting, and daylight conditions. Object detection models - You Only Look Once (YOLO) version 3 (v3) and v8 are employed to detect people, lights, and windows, achieving promising accuracies of 94.9 ​%, 73.3 ​%, and 98.7 ​%, respectively. The system categorizes scenarios as energy-efficient, wasteful, or neutral by integrating these outputs, highlighting opportunities for improving efficiency by harmonizing lighting infrastructure with occupancy and daylight exposure. Performance analyses, including training and validation metrics, are presented. This study demonstrates the potential of computer vision and AI for optimizing energy utilization, enabling sustainable building operation and promoting energy-positive occupant behaviors through sensor-driven methodologies.

高效利用建筑能源对于可持续发展至关重要。这项工作提出了一种智能系统,利用计算机视觉技术和闭路电视图像,根据占用率、人工照明和日光条件评估室内照明能源使用情况。该系统采用物体检测模型--YOLO(You Only Look Once)第 3 版(v3)和第 8 版来检测人、灯光和窗户,准确率分别达到 94.9%、73.3% 和 98.7%。该系统通过整合这些输出,将场景划分为节能、浪费或中性,并通过协调照明基础设施与占用率和日光照射来突出提高效率的机会。研究还介绍了性能分析,包括训练和验证指标。这项研究展示了计算机视觉和人工智能在优化能源利用、实现可持续建筑运营以及通过传感器驱动的方法促进积极节能的用户行为方面的潜力。
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引用次数: 0
Preparation and certification of benzoic acid reference material for calorimetry analysis 制备和认证用于量热分析的苯甲酸标准物质
Pub Date : 2024-07-31 DOI: 10.1016/j.meaene.2024.100016
Arindam Sen , Rajen Kundu , Arvind Kumar Upadhyay , Savita Soni , Sanchita Chakravarty

Benzoic acid reference material is indispensable for bomb calorimeter instrument calibration and validation of gross calorific value (GCV) analysis of any substance. In this work, we demonstrated the preparation of benzoic acid reference material through a homogeneity study, round-robin analysis, and stability study. Two-factor analysis of variance (ANOVA) test for gross calorific value in the randomly selected sub-samples of benzoic acid exhibits a lower FTS value than the Fcrit value, indicating that the samples are sufficiently homogeneous. The calculated uncertainty of between-bottle (ubb) and uncertainty of homogeneity (uhom) for GCV of benzoic acid in the sub-samples were found as 1.82 and 4.42 ​cal/g respectively. We found that the observed homogeneity (uhom (Finding)) value is lower than the assumed homogeneity (uhom (Assume)) value for the prepared benzoic acid reference material. Overall observations confirm that the sub-samples are sufficiently homogeneous. Moreover, the round-robin analysis/or inter-laboratory comparison analysis was conducted to assign the gross calorific value and determine the characterization uncertainty. The seventh order of Grubbs' analysis was done using robust estimator Alogoritm A to assign the GCV of benzoic acid. Finally, the measurement uncertainty of the assigned GCV of benzoic acid was calculated with the combined uncertainties from various sources.

苯甲酸标准物质是炸弹量热仪校准和验证任何物质总热值(GCV)分析所不可或缺的。在这项工作中,我们通过均一性研究、循环分析和稳定性研究证明了苯甲酸标准物质的制备方法。在随机抽取的苯甲酸子样品中,总热值的双因素方差分析(ANOVA)检验显示 FTS 值低于 Fcrit 值,表明样品具有足够的均匀性。计算得出的苯甲酸子样品总热值的瓶间不确定度(ubb)和均质性不确定度(uhom)分别为 1.82 和 4.42 卡/克。我们发现观察到的均一性(uhom (Finding))值低于制备的苯甲酸标准物质的假定均一性(uhom (Assume))值。总体观察结果证实,子样品具有足够的均匀性。此外,还进行了循环分析/或实验室间比对分析,以确定总热值和表征不确定性。使用稳健估计器 Alogoritm A 进行格拉布斯七阶分析,以确定苯甲酸的总热值。最后,利用各种来源的综合不确定性,计算出分配的苯甲酸 GCV 的测量不确定性。
{"title":"Preparation and certification of benzoic acid reference material for calorimetry analysis","authors":"Arindam Sen ,&nbsp;Rajen Kundu ,&nbsp;Arvind Kumar Upadhyay ,&nbsp;Savita Soni ,&nbsp;Sanchita Chakravarty","doi":"10.1016/j.meaene.2024.100016","DOIUrl":"10.1016/j.meaene.2024.100016","url":null,"abstract":"<div><p>Benzoic acid reference material is indispensable for bomb calorimeter instrument calibration and validation of gross calorific value (GCV) analysis of any substance. In this work, we demonstrated the preparation of benzoic acid reference material through a homogeneity study, round-robin analysis, and stability study. Two-factor analysis of variance (ANOVA) test for gross calorific value in the randomly selected sub-samples of benzoic acid exhibits a lower <em>F</em><sub><em>TS</em></sub> value than the <em>F</em><sub><em>crit</em></sub> value, indicating that the samples are sufficiently homogeneous. The calculated uncertainty of between-bottle (<em>u</em><sub><em>bb</em></sub>) and uncertainty of homogeneity (<em>u</em><sub><em>hom</em></sub>) for GCV of benzoic acid in the sub-samples were found as 1.82 and 4.42 ​cal/g respectively. We found that the observed homogeneity (<em>u</em><sub><em>hom (Finding)</em></sub>) value is lower than the assumed homogeneity (<em>u</em><sub><em>hom (Assume)</em></sub>) value for the prepared benzoic acid reference material. Overall observations confirm that the sub-samples are sufficiently homogeneous. Moreover, the round-robin analysis/or inter-laboratory comparison analysis was conducted to assign the gross calorific value and determine the characterization uncertainty. The seventh order of Grubbs' analysis was done using robust estimator Alogoritm A to assign the GCV of benzoic acid. Finally, the measurement uncertainty of the assigned GCV of benzoic acid was calculated with the combined uncertainties from various sources.</p></div>","PeriodicalId":100897,"journal":{"name":"Measurement: Energy","volume":"3 ","pages":"Article 100016"},"PeriodicalIF":0.0,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2950345024000162/pdfft?md5=043b511c377475bdbd886ff5c0dda2c6&pid=1-s2.0-S2950345024000162-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141961940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Voltage relaxation characterization methods in lithium-ion batteries 锂离子电池的电压弛豫表征方法
Pub Date : 2024-07-18 DOI: 10.1016/j.meaene.2024.100013
Alexa Fernando , Matthias Kuipers , Georg Angenendt , Kai-Philip Kairies , Matthieu Dubarry

This study evaluated three approaches for characterizing voltage relaxation in lithium-ion batteries: voltage vs. time, the derivative of voltage vs. time, and the second derivative of voltage vs. time. The first two are well-established approaches, whereas the third was never investigated to our knowledge. To assess the potential of each approach, characterizations were performed on data with various depth-of-discharges, regimes, state of healths, temperatures, and chemistries. Findings indicate that the established approaches do not comprehensively characterize voltage relaxation whereas the novel approach demonstrated promise in providing a quantitative feature to compare relaxation behaviors. However, it was found to have severe limitations in its application due to its lack of consistency between chemistry, rates, and temperatures, reliance on heavy filtering, and inability to identify trends in capacity loss, all preventing any potential for widespread application.

本研究评估了表征锂离子电池电压弛豫的三种方法:电压与时间、电压与时间的导数以及电压与时间的二次导数。前两种都是成熟的方法,而据我们所知,第三种方法从未被研究过。为了评估每种方法的潜力,我们对不同放电深度、放电制度、健康状态、温度和化学性质的数据进行了特征描述。研究结果表明,既有方法无法全面描述电压弛豫,而新方法则有望提供定量特征来比较弛豫行为。然而,由于该方法在化学、速率和温度方面缺乏一致性,依赖于大量过滤,且无法识别容量损失趋势,因此在应用方面存在严重的局限性,这一切都阻碍了其广泛应用的潜力。
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引用次数: 0
Instrumentation of novel optical sensor technology to detect the real-time electrolyte colour change in Li-on pouch cells 利用新型光学传感器技术检测锂离子电池中电解液颜色的实时变化
Pub Date : 2024-07-17 DOI: 10.1016/j.meaene.2024.100014
Saud Sattar, Thomas Statheros, Safeer Rahman, Christopher Gardner, Quirin Kellner, Rohit Bhagat, Alexander Roberts, Yue Guo

The need for new and improved diagnostic tools becomes paramount for Li-ion batteries in order to ensure their optimum performance along with their longevity and safety and there remain aspirational targets for Li-ion batteries regarding fast-charging, energy density, safety and lifetime that must be met to achieve further growth. The study of degradation mechanisms (such as electrolyte degradation, thermal runaway, gassing and cycling aging) at the cell level contributes significantly to the understanding of the aging phenomena and will enable improvements for future generations of LIBs. Among various indicators, the colour change of the electrolyte within Li-ion cells presents a largely unexplored avenue for assessing state of health and predicting early signs of degradation. This research proposes a new methodology for the development of an innovative optical sensor technology and its incorporation into a pouch cell. The sensor comprises of a photodiode and RGB LED, mounted on a single flexible PCB, capable of the real-time detection of electrolyte colour changes inside Li-ion pouch cells. Previous studies have identified electrolyte colour change as a potential marker for battery condition through various invasive testing methods; however, the proposed optical technique represents a step change in in-situ real-time diagnostics. This study elaborates on the process of developing and incorporating the sensors precisely into pouch cells and seeks to demonstrate the capability of these sensors to accurately detect alterations in the colour of the electrolyte as the cell ages, without having adverse effects on the cell's performance and offers the potential for direct correlation of electrolyte change with battery state of health.

为了确保锂离子电池的最佳性能、使用寿命和安全性,锂离子电池对新的和改进的诊断工具的需求变得至关重要。对电池降解机制(如电解质降解、热失控、析气和循环老化)的研究极大地促进了对老化现象的理解,并有助于改进未来几代锂离子电池。在各种指标中,锂离子电池内电解液的颜色变化是评估电池健康状况和预测降解早期迹象的一个尚未开发的途径。本研究提出了一种开发创新型光学传感器技术并将其集成到袋式电池中的新方法。该传感器由光电二极管和 RGB LED 组成,安装在一块柔性印刷电路板上,能够实时检测锂离子电池袋内部电解液的颜色变化。以往的研究已通过各种侵入式检测方法将电解液颜色变化确定为电池状态的潜在标记;然而,所提出的光学技术代表了原位实时诊断的一个进步。本研究详细阐述了开发传感器并将其精确集成到袋式电池中的过程,并试图证明这些传感器有能力准确检测电池老化过程中电解液颜色的变化,而不会对电池性能产生不利影响,并提供了将电解液变化与电池健康状况直接关联起来的可能性。
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引用次数: 0
Evaluation of a cost-effective photoelectric sensor for daylight harvesting in smart public lighting systems 评估智能公共照明系统中用于日光收集的经济型光电传感器
Pub Date : 2024-07-14 DOI: 10.1016/j.meaene.2024.100012
Aytaç Gören , Fatima Khanfar , Ahmed Rachid

Global warming concerns, along with international agreements and regulations, reflect a broader effort to change the public's high energy demand in recent years. Smart public lighting systems are gaining popularity due to their energy-saving capabilities, reduction in carbon dioxide emissions, and improved public comfort. However, transitioning to smart public lighting requires careful planning and multiple stages. This is not only to accommodate public behavior, revise scenarios, and test citizen acceptance but also due to the necessary infrastructure investments. Smart public lighting incorporates new technologies, often with a breakeven point that takes several years to reach. To promote the widespread adoption of smart public lighting, it is essential to produce relatively expensive components in large quantities and explore cost-effective solutions. This research focuses on investigating a cost-effective photoelectric sensor for smart public purposes. The primary originality of this study lies in identifying a cost-effective photoelectric sensor that can replace technically equivalent but more expensive sensor solutions for indoor and outdoor lighting control purposes.

对全球变暖的担忧以及国际协议和法规,反映了近年来为改变公众对能源的高需求而做出的广泛努力。智能公共照明系统因其节能功能、减少二氧化碳排放和提高公众舒适度而越来越受欢迎。然而,向智能公共照明过渡需要精心规划和多个阶段。这不仅是为了适应公众行为、修改方案、测试市民的接受程度,也是由于必要的基础设施投资。智能公共照明采用了新技术,通常需要数年才能达到盈亏平衡点。为了促进智能公共照明的广泛应用,必须大量生产相对昂贵的组件,并探索具有成本效益的解决方案。本研究的重点是调查一种用于智能公共照明的高性价比光电传感器。这项研究的主要独创性在于找出一种经济高效的光电传感器,它可以取代技术上等同但价格更昂贵的传感器解决方案,用于室内外照明控制。
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引用次数: 0
In situ monitoring of cycling characteristics in lithium-ion battery based on a two-cavity cascade fiber-optic Fabry-Perot interferometer 基于双腔级联光纤法布里-珀罗干涉仪的锂离子电池循环特性原位监测系统
Pub Date : 2024-06-26 DOI: 10.1016/j.meaene.2024.100011
Ke Tan , Hongyu Liu , Xiaoshuang Dai, Zhiyuan Li, Xingyu Li, Weirong Gan, Junfeng Jiang, Tiegen Liu, Shuang Wang

The state characterization inside the lithium-ion battery during charge/discharge cycling is extremely crucial for understanding the electrochemical reaction mechanism. However, current methods exhibit a challenge to overcome the specific battery environment obstacles, including strong redox properties, strong electromagnetic interference, and fast reaction processes. Hence, more efforts are still needed to monitor the actual state inside the battery accurately and reliably. To address this issue, we designed and developed a compact two-cavity cascade fiber-optic Fabry-Perot interferometer (FPI) sensor that can be safely implanted in batteries to measure internal temperature and pressure simultaneously. With its high pressure and temperature sensitivity of 26.6 ​nm/kPa and 107 ​nm/°C, this sensor exhibits an ultra-low cross-sensitivity of −40 ​Pa/°C. During charge/discharge cycling tests, regular cyclic pressure and temperature signals are obtained at various rates cycling in real-time and in situ, revealing details about the actual state characterization inside the battery. From the experiment results, the pressure inside the battery is divided into reversible changes caused by respiration effects and irreversible changes caused by trace gas production. Furthermore, the FPI sensor provides a more precise temperature than thermocouples that measure the surface temperature of the battery, reflecting the internal/external temperature difference to a maximum of 3.5 ​°C at 1 ​C rate cycling. This operando FPI sensor provides a valuable technological tool for battery performance testing and safety monitoring.

锂离子电池在充放电循环过程中的状态表征对于理解电化学反应机制极为重要。然而,目前的方法在克服特定电池环境障碍方面存在挑战,包括强氧化还原特性、强电磁干扰和快速反应过程。因此,要想准确可靠地监测电池内部的实际状态,仍需付出更多努力。针对这一问题,我们设计并开发了一种紧凑型双腔级联光纤法布里-珀罗干涉仪(FPI)传感器,可以安全地植入电池,同时测量内部温度和压力。该传感器的压力和温度灵敏度分别为 26.6 nm/kPa 和 107 nm/°C,具有 -40 Pa/°C 的超低交叉灵敏度。在充放电循环测试过程中,以各种速率循环实时和原位获取定期的循环压力和温度信号,从而揭示电池内部实际状态特征的详细信息。根据实验结果,电池内部的压力可分为由呼吸作用引起的可逆变化和由微量气体产生引起的不可逆变化。此外,与测量电池表面温度的热电偶相比,FPI 传感器能提供更精确的温度,在 1 摄氏度的循环速率下,能反映最大 3.5 摄氏度的内部/外部温差。这种操作型 FPI 传感器为电池性能测试和安全监控提供了宝贵的技术工具。
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引用次数: 0
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