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Sr Isotopes as Mixing and Lithological Tracers; The Ebro River Basin☆ Sr同位素混合示踪及岩性示踪埃布罗河流域
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2017.01.028
P. Négrel, E. Petelet-Giraud, R. Millot
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引用次数: 3
The Geochemistry of Hydraulic Fracturing Fluids 水力压裂液的地球化学研究
Pub Date : 2017-01-01 DOI: 10.1016/j.proeps.2016.12.011
Avner Vengosh , Andrew Kondash , Jennie Harkness , Nancy Lauer , Nathaniel Warner , Thomas H. Darrah

The inorganic geochemistry of hydraulic fracturing fluids is reviewed with new insights on the role of entrapped formation waters in unconventional shale gas and tight sand formations on the quality of flowback and produced waters that are extracted with hydrocarbons. The rapid increase of the salinity of flowback fluids during production, combined with geochemical and isotopic changes, indicate mixing of the highly saline formation water with the injected water. The salinity increase suggests that the volume of the injected water that is returned to the surface with the flowback water is much smaller than previous estimates, and thus the majority of the injected water is retained within the shale formations. The high salinity of the flowback and produced water is associated with high concentrations of halides, ammonium, metals, metalloids, and radium nuclides that pose environmental and human health risks upon the release of the hydraulic fracturing fluids to the environment.

综述了水力压裂液的无机地球化学特征,并对非常规页岩气和致密砂岩地层中圈闭地层水对返排和采出水质量的影响有了新的认识。在生产过程中,返排液矿化度的快速升高,结合地球化学和同位素变化,表明高盐地层水与注入水混合。盐度的增加表明,与返排水一起返回地表的注入水量比之前估计的要小得多,因此大部分注入水被保留在页岩地层中。返排水和采出水的高盐度与高浓度的卤化物、铵、金属、类金属和镭核素有关,在将水力压裂液释放到环境中时,这些物质会对环境和人类健康构成风险。
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引用次数: 43
Hydrogeochemical Assessment of Tibães Waters (NW Portugal) tib<s:1>水域(葡萄牙西北部)水文地球化学评价
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2017.01.030
M. Afonso, M. E. Lopes, H. Chaminé
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引用次数: 1
Great Role of W.M. Edmunds in the Development of Hydrogeochemistry in Russia 埃德蒙兹在俄罗斯水文地球化学发展中的重要作用
Pub Date : 2017-01-01 DOI: 10.1016/j.proeps.2016.12.054
O.V. Chudaev, V.A. Chudaeva

This article discusses the joint work of Professor W.M. Edmunds (UK) with his Russian colleagues. He had an important role in the development of hydrogeochemistry in Russia. He was an initiator of the joint research projects with Russian scientists and was actively supporting the idea of holding international conferences on the territory of Russia. In addition, as a follower of V.I. Vernadsky, he was actively promoting Vernadsky's ideas outside of Russia.

本文讨论了英国埃德蒙兹教授与俄罗斯同事的合作工作。他在俄罗斯水文地球化学的发展中发挥了重要作用。他是与俄罗斯科学家联合研究项目的发起人,并积极支持在俄罗斯领土上举行国际会议的想法。此外,作为维尔纳德斯基的追随者,他在俄罗斯境外积极推广维尔纳德斯基的思想。
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引用次数: 0
The Occurrences of Ca2UO2(CO3)3 Complex in Fe(II) Containing Deep Groundwater at Forsmark, Eastern Sweden☆ 瑞典东部Forsmark含铁(II)深层地下水中Ca2UO2(CO3)3络合物的赋存特征[j]
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2016.12.111
E. Tullborg, J. Suksi, G. Geipel, Lindsay Krall, L. Auqué, M. Gimeno, I. Puigdomenech
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引用次数: 17
Laboratory Insights into Water-rock-CO2 Interactions Controlling the Isotopic Composition of CO2 Leaking from Storage Sites 水-岩石-二氧化碳相互作用控制二氧化碳从储存地点泄漏的同位素组成的实验室见解
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2017.01.052
M. Nightingale, B. Mayer, M. Shevalier, S. Yun
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引用次数: 0
FEBEX In-Situ Test: Preliminary Results of the Geochemical Characterization of the Metal/Bentonite Interface FEBEX原位测试:金属/膨润土界面地球化学表征的初步结果
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2017.01.045
E. Torres, M. Turrero, D. Moreno, L. Sanchez, A. Garralón
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引用次数: 4
Impact on Streams and Sea Water of a Near-neutral Drainage from a Flooded Mine in Sardinia, Italy 意大利撒丁岛矿井淹水对河流和海水的影响
Pub Date : 2017-01-01 DOI: 10.1016/j.proeps.2016.12.074
Franco Frau, Stefania Da Pelo, Roberta Atzori, Rosa Cidu

After mine closure and subsequent shutdown of the dewatering system, groundwater rebound led to drainage outflow from the Casargiu gallery (Montevecchio mine, SW Sardinia, Italy) since 1997. As compared with the first discharge, a very high contamination level still persists after almost 20 years of flushing. Mine drainage (20-70 L s-1; pH 6.0±0.2; Zn-Mg-Ca-SO4 composition) flows into the Rio Irvi. Abundant precipitation of amorphous Fe(III)-(oxy)hydroxides occurs. Moreover, sulfate-bearing green rust is observed to flocculate in the reach of the Rio Irvi where pH is still circumneutral. Water sampling along this stream shows a pH decrease from 6.0 to 4.0 and a significant removal of Fe (46%) and As (96%), while sulfate, Zn, Mn, Co, Ni and Cd show small variations downstream. Lead is initially adsorbed onto Fe(III)-(oxy)hydroxides, then desorbed as pH drops below 5.4. A conservative estimation of dissolved metals discharged into the Mediterranean Sea is significant (e.g. 900 kg day-1 Zn, 1.4 kg day-1 Cd, 5 kg day-1 Ni).

自1997年起,在关闭矿井和随后关闭脱水系统后,地下水反弹导致Casargiu矿(意大利撒丁岛西南部Montevecchio矿)排水流出。与首次排放的污水相比,经过近20年的冲厕后,污染程度仍然非常高。矿井排水(20-70 L s-1;pH值6.0±0.2;Zn-Mg-Ca-SO4组成)流入Rio Irvi。大量无定形铁(III)-(氧)氢氧化物析出。此外,在pH值仍为环中性的里奥伊尔维河段,观察到含硫酸盐绿锈絮凝。沿河水样pH值从6.0降至4.0,Fe(46%)和As(96%)被显著去除,而硫酸盐、Zn、Mn、Co、Ni和Cd在下游变化较小。铅最初吸附在Fe(III)-(氧)氢氧化物上,然后在pH值低于5.4时解吸。对排入地中海的溶解金属的保守估计是重要的(例如,每天900公斤锌,每天1.4公斤镉,每天5公斤镍)。
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引用次数: 4
CO2 Trapping State in Saline Aquifers and its Implications for Site-scale Storage Capacity Assessment ☆ 盐碱层CO2捕获状态及其对站点尺度储存量评价的意义[j]
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2016.12.123
Yiman Li, Z. Pang
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引用次数: 0
Anhydrite-dissolution Porosity in the Upper Muschelkalk Carbonate Aquifer, NE-Switzerland: Implications for Geothermal Energy and Geological Storage of Gas 瑞士东北部Muschelkalk碳酸盐岩含水层上部硬石膏溶蚀孔隙:对地热能和天然气地质储存的影响
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2017.01.011
Lukas Aschwanden, L. Diamond, A. Adams, M. Mazurek
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引用次数: 3
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Procedia Earth and Planetary Science
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