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What is the Real ΔGr Function of Albite Dissolution? 钠长岩溶蚀的真实ΔGr功能是什么
Pub Date : 2017-01-01 Epub Date: 2017-01-18 DOI: 10.1016/j.proeps.2016.12.035
C. Gruber , I. Kutuzov , Y. Zakon , J. Ganor

One of the most significant environmental variables that affect albite dissolution rate is deviation from equilibrium (ΔGr). Most of the studies that describe the effect of ΔGr on albite dissolution rate were conducted under alkline pH (8.8-9.2), elvetad temperatures (80-300 °C) and for Amelia Courthouse (USA) albite. Comparison of the fGr) derived from those studies to the only fGr) from low temperature (25 °C), circum neutral pH and EVJE (Norway) albite leads to different ΔGr functions. Yet, except for the study of1, rate laws for silicate minerals dissolution, which are based on experiments conducted under ambient conditions, are lacking. Here we present new experimental results of single point batch experiments (SPBE) of albite dissolution in a isotopically spiked solution. The novel method that use Si isotopes2 enables detecting rates that otherwise can’t be detected under ambient conditions. Albite dissolution rates were determined under neutral-acidic pH, temperatures of 3.6, 25 and 50 °C, and a wide range of undersaturation conditions. The dependency of the dissolution rate on deviation from equilibrium (fGr)) was in agreement with the prediction of previous studies. However, the value of ΔGcrit was found to be significantly different, suggesting an effect of extrinsic properties of the environment.

影响钠长石溶解速率的最重要的环境变量之一是偏离平衡(ΔGr)。大多数描述ΔGr对钠长石溶解速率影响的研究都是在碱性pH(8.8-9.2)、低温(80-300°C)和Amelia Courthouse (USA)钠长石条件下进行的。将这些研究得出的f(ΔGr)与低温(25°C)、周围中性pH值和EVJE(挪威)钠长石得出的f(ΔGr)进行比较,可以得出不同的ΔGr功能。然而,除了对1的研究外,缺乏基于环境条件下实验的硅酸盐矿物溶解速率规律。本文报道了同位素加标溶液中钠长石溶解的单点间歇实验(SPBE)的新结果。使用Si同位素2的新方法可以检测到在环境条件下无法检测到的速率。在中酸性pH值、3.6℃、25℃和50℃温度以及各种欠饱和条件下,测定了钠长石的溶解速率。溶出速率与平衡偏差(f(ΔGr))的关系与先前研究的预测一致。然而,ΔGcrit的值被发现是显著不同的,这表明环境的外在性质的影响。
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引用次数: 3
The Effect of Fractures on Weathering of Igneous and Volcaniclastic Sedimentary Rocks in the Puerto Rican Tropical Rain Forest 裂缝对波多黎各热带雨林火成岩和火山碎屑沉积岩风化的影响
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2017.01.001
S. Hynek, X. Comas, S. Brantley
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引用次数: 13
Geochemical and Isotopic Tracing of Salt Loads into the Ramsar Listed Verlorenvlei Estuarine Lake, South Africa 南非Verlorenvlei河口湖盐负荷的地球化学和同位素示踪
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2017.01.015
N. T. Sigidi, J. Miller, A. Watson, C. Clarke, M. Butler
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引用次数: 3
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Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2017.01.041
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引用次数: 5
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Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2016.12.168
G. Schmidt, S. Najem, M. Isenbeck‐Schröter, Florian Freundt, M. Kraml, W. Aeschbach
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引用次数: 1
Laboratory-scale Interaction Between CO2-saturated H2SO4-rich Brine and Reservoir Rocks (Limestone and Sandstone)☆ 饱和co2富h2so4盐水与储集岩(石灰岩和砂岩)的相互作用
Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2016.12.164
E. Thaysen, J. Soler, J. Cama
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Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2016.12.142
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Pub Date : 2017-01-01 DOI: 10.1016/J.PROEPS.2016.12.134
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