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On random walks and switched random walks on homogeneous spaces 随机漫步和齐次空间上的切换随机漫步
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-10-19 DOI: 10.1017/s0963548322000311
Elvira Moreno, Mauricio Velasco
We prove new mixing rate estimates for the random walks on homogeneous spaces determined by a probability distribution on a finite group $G$ . We introduce the switched random walk determined by a finite set of probability distributions on $G$ , prove that its long-term behaviour is determined by the Fourier joint spectral radius of the distributions, and give Hermitian sum-of-squares algorithms for the effective estimation of this quantity.
我们证明了有限群$G$上由概率分布决定的齐次空间上随机游动的新的混合率估计。我们引入了由$G$上的一组有限概率分布决定的开关随机漫步,证明了它的长期行为是由分布的傅里叶联合谱半径决定的,并给出了有效估计这个量的厄米平方和算法。
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引用次数: 0
Polynomials over structured grids 结构网格上的多项式
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-10-11 DOI: 10.1017/s0963548322000232
B. Nica
We study multivariate polynomials over ‘structured’ grids. Firstly, we propose an interpretation as to what it means for a finite subset of a field to be structured; we do so by means of a numerical parameter, the nullity. We then extend several results – notably, the Combinatorial Nullstellensatz and the Coefficient Theorem – to polynomials over structured grids. The main point is that the structure of a grid allows the degree constraints on polynomials to be relaxed.
我们研究“结构化”网格上的多元多项式。首先,我们提出了一个解释,这意味着一个有限的子集的场是结构化的;我们通过一个数值参数,即零点来做到这一点。然后,我们将几个结果——特别是组合Nullstellensatz和系数定理——扩展到结构化网格上的多项式。主要的一点是,网格的结构允许对多项式的程度约束是放松的。
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引用次数: 3
Short proofs for long induced paths 对长诱导路径的简短证明
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-06-16 DOI: 10.1017/s0963548322000013
N. Dragani'c, Stefan Glock, M. Krivelevich
We present a modification of the Depth first search algorithm, suited for finding long induced paths. We use it to give simple proofs of the following results. We show that the induced size-Ramsey number of paths satisfies $hat{R}_{mathrm{ind}}(P_n)leq 5 cdot 10^7n$ , thus giving an explicit constant in the linear bound, improving the previous bound with a large constant from a regularity lemma argument by Haxell, Kohayakawa and Łuczak. We also provide a bound for the k-colour version, showing that $hat{R}_{mathrm{ind}}^k(P_n)=O(k^3log^4k)n$ . Finally, we present a new short proof of the fact that the binomial random graph in the supercritical regime, $G(n,frac{1+varepsilon}{n})$ , contains typically an induced path of length $Theta(varepsilon^2) n$ .
我们提出了一种改进的深度优先搜索算法,适合于寻找长诱导路径。我们用它来给出以下结果的简单证明。我们从Haxell, Kohayakawa和Łuczak的正则引理论证中证明了诱导的路径size-Ramsey数满足$hat{R}_{mathrm{ind}}(P_n)leq 5 cdot 10^7n$,从而在线性界中给出了一个显式常数,用一个大常数改进了先前的界。我们还提供了k色版本的界,显示$hat{R}_{mathrm{ind}}^k(P_n)=O(k^3log^4k)n$。最后,我们给出了一个新的简短证明,证明了在超临界状态下,$G(n,frac{1+varepsilon}{n})$的二项随机图通常包含一条长度为$Theta(varepsilon^2) n$的诱导路径。
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引用次数: 2
Degree sequences of sufficiently dense random uniform hypergraphs 充分密集随机一致超图的度序列
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-06-15 DOI: 10.1017/s0963548322000190
Catherine S. Greenhill, M. Isaev, Tamás Makai, B. McKay
We find an asymptotic enumeration formula for the number of simple $r$ -uniform hypergraphs with a given degree sequence, when the number of edges is sufficiently large. The formula is given in terms of the solution of a system of equations. We give sufficient conditions on the degree sequence which guarantee existence of a solution to this system. Furthermore, we solve the system and give an explicit asymptotic formula when the degree sequence is close to regular. This allows us to establish several properties of the degree sequence of a random $r$ -uniform hypergraph with a given number of edges. More specifically, we compare the degree sequence of a random $r$ -uniform hypergraph with a given number edges to certain models involving sequences of binomial or hypergeometric random variables conditioned on their sum.
当边的数目足够大时,我们得到了具有给定阶序列的简单$r$ -一致超图数目的渐近枚举公式。这个公式是以方程组的解的形式给出的。给出了该系统解存在的充分条件。进一步,我们对该系统进行了求解,并给出了当阶序列接近正则时的显式渐近公式。这允许我们建立具有给定边数的随机$r$均匀超图的度序列的几个性质。更具体地说,我们将具有给定数目边的随机$r$ -均匀超图的度序列与涉及二项式或超几何随机变量序列的某些模型进行比较。
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引用次数: 0
Anticorrosive properties of theophylline on aluminium corrosion in 1M HCl: Experimental, Computational assessment and synergistic effect iodide ions 茶碱对1M HCl中铝腐蚀的防腐性能:实验、计算评价及碘离子的协同效应
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-05-26 DOI: 10.2174/1877946811666210526152314
Tigori Mougo André, Beda Reginald Henriette Blanche, Niamien Paulin Marius, Diabaté Donourou
The aim of this study is to show the anticorrosive properties of 1,3-dimethyl-7H-purine-2,6-dione on aluminium corrosion in 1M hydrochloric acid and to study the synergy effect between iodide ions and this molecule. Research of eco-friendly, low toxic and biodegradable corrosion inhibitors capable of protecting metals in order to support industrialists who spend large sums of money to replace their corroded equipment. The main objective is to study the anticorrosive properties of theophylline on aluminium corrosion in 1M HCl. The anticorrosive properties study of theophylline on aluminium corrosion in 1M HCl was evaluated using mass loss, Density Functional Theory at B3LYP/6-31G (d) and Quantitative Structure-Property Relationship methods.The results obtained show that theophylline inhibition efficiency increases with concentration but decreases with increasing temperature with a maximum value of 88% for 5.10-3M at T = 298 K. The result from absorption isotherms reveals that theophylline adsorbs to the aluminium surface according to the modified Langmuir isotherm. Adejo Ekwenshi's isotherm has shown that the molecule adsorption on aluminium is essentially of a physical nature. Thermodynamic adsorption and activation parameters were calculated and analyzed. A synergistic effect between the molecule studied and the iodide ions was found. Furthermore, global and local reactivity were analyzed through density functional theory calculations. Quantitative structure-property relationship methods model has been permitted to correlate experimental and theoretical inhibition efficiencies.Theophylline is an excellent aluminum inhibitor corrosion in the studied solution. Theoretical results were in agreement with experimental data. Finally to find the best set of parameters for modeling the inhibition efficiency.
本研究的目的是展示1,3-二甲基- 7h -嘌呤-2,6-二酮在1M盐酸中对铝腐蚀的防腐性能,并研究碘离子与该分子的协同作用。研究环保、低毒、可生物降解的能保护金属的缓蚀剂,以支持花费大笔资金更换腐蚀设备的实业家。主要目的是研究茶碱对1M HCl中铝腐蚀的防腐性能。采用质量损失、B3LYP/6-31G (d)密度泛函理论和定量构效关系方法评价了茶碱对1M HCl中铝腐蚀的防腐性能。结果表明,茶碱的抑制率随浓度的增加而增加,但随温度的升高而降低,在温度为298 K时,5.10-3M的抑制率最高,达到88%。吸附等温线结果表明,根据修正的Langmuir等温线,茶碱吸附在铝表面。Adejo Ekwenshi的等温线表明,分子在铝上的吸附本质上是物理性质的。计算并分析了吸附和活化热力学参数。所研究的分子与碘离子之间存在协同效应。此外,通过密度泛函理论计算分析了整体反应性和局部反应性。定量结构-性能关系方法模型已被允许关联实验和理论抑制效率。茶碱在研究溶液中是一种优良的铝缓蚀剂。理论结果与实验数据一致。最后找到一组最适合建模抑制效率的参数。
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引用次数: 1
Kinetic Study of Iodination of Propanone in Different Acidic Medium by using Colorimeter 用比色计研究不同酸性介质中丙酮加碘反应的动力学
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-05-25 DOI: 10.2174/1877946811666210525102725
Nitin Sharma, T. Alam, Ajay Kumar
This study aims at the Kinetic Study of Iodination of Propanone in Different Acidic Medium by using Colorimeter.The kinetic experimentation of iodination of propanone has been performed in presence of different acids such as sulphuric acid, hydrochloric acid and acetic acid. The rate law of the iodination of propanone in acidic medium is determined by observing the disappearance of the brownish yellow colour of iodine in aqueous solution.The objective of this study is the preparation of standard solution, determination of absorbance of iodine solution at λmax= 480 nm, Kinetic study of iodination of propanone with different acidic medium.The kinetic analysis of this reaction has been carried out by colorimetry. The extent of the reaction has been monitored by measuring the absorbance of the reaction mixture after a suitable time interval.The rate law expression is determined to be rate = k [〖"propanone]" 〗_0^0.728 [acid]0. The rates of iodination of propanone in presence of different acidic medium are H2SO4 > HCl > CH3COOH.The rate of the reaction is found to be independent of the concentration of iodine i.e. it is zero order reaction with respect to iodine. However, it depends on the concentration of propanone and acid catalyst.By using this experimental technique, the consumption of chemicals is very less.
本研究旨在用比色计对丙酮在不同酸性介质中碘化的动力学研究。在硫酸、盐酸和乙酸等不同酸存在下,对丙酮碘化进行了动力学实验。通过观察碘在水溶液中棕黄色的消失,确定了丙酮在酸性介质中碘化的速率规律。本研究的目的是制备标准溶液,测定碘溶液在λmax=480nm处的吸光度,以及在不同酸性介质中碘化丙酮的动力学研究。用比色法对该反应进行了动力学分析。通过在适当的时间间隔后测量反应混合物的吸光度来监测反应的程度。速率定律表达式确定为速率=k[〖丙酮〗_0^0.728[酸]0。丙酮在不同酸性介质中的碘化速率为H2SO4>HCl>CH3COOH。发现反应速率与碘浓度无关,即相对于碘为零级反应。然而,这取决于丙酮和酸催化剂的浓度。通过使用这种实验技术,化学品的消耗非常少。
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引用次数: 0
From Reduction to Oxidation: pH Controlled Reaction of 1 Hydroxyethyl Radical with Caffeic Acid Analogues. 从还原到氧化:1 -羟乙基自由基与咖啡酸类似物的pH控制反应。
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-05-09 DOI: 10.2174/1877946811666210509032002
Laboni Das, Shashi P. Shukla, S. Chatterjee, A. Satpati, S. Adhikari
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引用次数: 0
Additive bases via Fourier analysis 通过傅里叶分析的加性基
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-04-29 DOI: 10.1017/S0963548321000109
Bodan Arsovski
Extending a result by Alon, Linial, and Meshulam to abelian groups, we prove that if G is a finite abelian group of exponent m and S is a sequence of elements of G such that any subsequence of S consisting of at least $$|S| - mln |G|$$ elements generates G, then S is an additive basis of G . We also prove that the additive span of any l generating sets of G contains a coset of a subgroup of size at least $$|G{|^{1 - c{ in ^l}}}$$ for certain c=c(m) and $$ in = in (m) < 1$$ ; we use the probabilistic method to give sharper values of c(m) and $$ in (m)$$ in the case when G is a vector space; and we give new proofs of related known results.
将Alon, Linial, Meshulam的结果推广到阿贝尔群,证明了如果G是指数为m的有限阿贝尔群,且S是G的元素序列,使得S的任何子序列至少含有$$|S| - mln |G|$$个元素生成G,则S是G的可加基。我们还证明了对于c=c(m)和$$ in = in (m) < 1$$,任意l个G的生成集的加性张成包含一个至少为$$|G{|^{1 - c{ in ^l}}}$$的子群的余集;当G是向量空间时,我们使用概率方法给出更清晰的c(m)和$$ in (m)$$值;并对相关已知结果给出了新的证明。
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引用次数: 0
ANITO E O SUBORNO DE JURADOS (DEKÁZEIN) NOS PROCESSOS ATENIENSES 雅典案例中的ANITO和DEKÁZEIN
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-04-24 DOI: 10.17074/CPC.V1I40.36287
Carlos Augusto de Oliveira Carvalhar
Anito é mais conhecido por ser um dos acusadores de Sócrates, mas este político teve outra proeza: sua sagacidade o fez criar um método obscuro de identificar os jurados e assim saber exatamente a quem subornar em um processo legal, ou seja, ele conseguia identificar quem eram os dikastaí que estariam agrupados no dikastḗrion específico que julgaria determinado caso em um tribunal. Com essa metodologia ele conseguiu se safar de uma condenação em 409 a.e.c., quando por sua falha Atenas perdeu Pilos (Aristóteles, Constituição de Atenas, 27.5). A façanha desse cidadão possivelmente foi a origem de dois novos verbos (dekázein e syndekázein) e o motivo de uma nova lei contra esse método (reportada no segundo Contra Estéfano de Demóstenes, 46.26). Além disso, duas décadas depois, o sistema por sorteio para a escolha de jurados foi totalmente reformulado, justamente para evitar esse esquema corrupto que ele empregou. Este artigo fará a exposição desses aspectos legais relacionados à escolha de jurados no século V, bem como abordará a corrupção e suborno que foi feita a partir desse método de Anito, discorrendo também sobre uma alteração proposta no século IV (que aparece na Assembleia das Mulheres de Aristófanes) e a terceira reformulação, apresentada em Aristóteles, Constituição de Atenas, 63-66. Também se explorará essa temática com a Apologia de Platão, uma vez que Anito, aquele que subornou jurados, é o mesmo agente que está processando Sócrates por corromper (diaphtheírein) os jovens, aproveitando-se assim a ambiguidade deste verbo, pois pode significar tanto a corrupção moral em sentido largo, como também aquela motivada por suborno.
Anito最出名的是苏格拉底的原告之一,但这个政治:他智慧的成就,创造一个方法做的,阴暗的识别就知道到底是谁贿赂陪审团在一个法律程序,也就是说,他能确定谁是dikastaí他们分组在dikastḗ正是特定案件在法院名誉。用这种方法,他成功地逃脱了公元前409年的谴责,当时由于他的失败,雅典失去了派洛斯(亚里士多德,《雅典宪法》,27.5)。这个公民的壮举可能是两个新动词(dekazein和syndekazein)的起源,也是反对这种方法的新法律的原因(在第二篇反对司提反的德摩斯提尼46.26中报道)。此外,二十年后,选举陪审团的抽签制度被彻底改革,正是为了避免他所采用的腐败计划。这篇文章将这些相关法律方面对选择陪审团成员的展览,以及地区五世纪的腐败和贿赂,这个方法是由Anito discorrendo也大约在公元四世纪的一项修正案(出现的)和阿里斯托芬的女性在议会上第三重铸,在亚里士多德,雅典的宪法,63 - -66。还将探索这个主题和柏拉图的道歉,一旦Anito,那你贿赂陪审团控告苏格拉底的探员在向年轻人(diaphtheírein)利用这样含糊这个动词,因为可能是在广义的道德腐败受贿的,那也有积极性。
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引用次数: 0
Removal lemmas and approximate homomorphisms 去除引理与近似同态
IF 0.9 4区 数学 Q2 Mathematics Pub Date : 2021-04-23 DOI: 10.1017/s0963548321000572
J. Fox, Yufei Zhao
We study quantitative relationships between the triangle removal lemma and several of its variants. One such variant, which we call the triangle-free lemma, states that for each $epsilon>0$ there exists M such that every triangle-free graph G has an $epsilon$ -approximate homomorphism to a triangle-free graph F on at most M vertices (here an $epsilon$ -approximate homomorphism is a map $V(G) to V(F)$ where all but at most $epsilon leftlvert{V(G)}rightrvert^2$ edges of G are mapped to edges of F). One consequence of our results is that the least possible M in the triangle-free lemma grows faster than exponential in any polynomial in $epsilon^{-1}$ . We also prove more general results for arbitrary graphs, as well as arithmetic analogues over finite fields, where the bounds are close to optimal.
我们研究了三角形去除引理和它的几个变体之间的定量关系。其中一种变体,我们称之为无三角引理,说明对于每个$epsilon>0$存在M,使得每个无三角形图G在最多M个顶点上与无三角形图F具有$epsilon$ -近似同态(这里的$epsilon$ -近似同态是一个映射$V(G) to V(F)$,其中G的除最多$epsilon leftlvert{V(G)}rightrvert^2$边外的所有边都映射到F的边)。我们的结果的一个结果是,在无三角形引论中,最小可能的M比任何多项式中的指数增长更快在$epsilon^{-1}$。我们还证明了任意图的更一般的结果,以及有限域上的算术类似,其中边界接近最优。
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引用次数: 1
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Combinatorics, Probability & Computing
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