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Analysis of Temperature-dependent Extended X-ray Absorption Fine Structure Oscillation of Distorted Crystalline Cadmium 畸变结晶镉的温度依赖扩展x射线吸收精细结构振荡分析
Pub Date : 2022-08-17 DOI: 10.15625/0868-3166/16890
Tong Sy Tien
In this paper, the temperature-dependent extended X-ray absorption fine structure (EXAFS) of distorted crystalline cadmium has been analyzed using an efficient calculation-model. The analysis procedure is based on evaluating the influence of temperature on the phase shift and amplitude reduction of EXAFS oscillation that is expressed in terms of the EXAFS Debye-Waller factor. The anharmonic EXAFS cumulants are calculated by expanding the anharmonic correlated Debye model based on the anharmonic effective potential that depends on the structural characteristics of distorted crystalline cadmium. The numerical results satisfy well with those obtained using the experimental data and other models at various temperatures. The obtained results indicate that this theoretical model is useful for calculating and analyzing the experimental EXAFS data of distorted crystalline metals.
本文用一种有效的计算模型分析了变形结晶镉的温度依赖扩展x射线吸收精细结构(EXAFS)。分析过程是基于评估温度对EXAFS振荡相移和幅度减小的影响,该影响用EXAFS Debye-Waller因子表示。基于畸变结晶镉的非调和有效势,通过扩展非调和相关Debye模型,计算了非调和EXAFS累积量。数值计算结果与实验数据和其他模型在不同温度下的计算结果吻合较好。结果表明,该理论模型可用于畸变结晶金属的EXAFS实验数据的计算和分析。
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引用次数: 0
Estimation of Atmospheric NO(_2) Volume Mixing Ratio in Hanoi Using Multi-axis Differential Optical Absorption Spectroscopy Technique 利用多轴差分光学吸收光谱技术估算河内市大气NO (_2)体积混合比
Pub Date : 2022-08-09 DOI: 10.15625/0868-3166/17173
D. Trung, H. Bui Van, Thi Thanh Bao Nguyen, Thi Kim Oanh Vu, Xuan Tu Nguyen, V. Phung, Hong Minh Pham
Monitoring the concentration and distribution of nitrogen dioxide NO2 in urban environment is of great interest because of the importance of this gaseous pollutant in affecting air quality. In this paper we present the development of a multi-axis differential optical absorption spectroscopy instrument capable of sensitively detecting NO2. The passive instrument collects the sun light scattered by the air molecules and aerosols in the atmosphere and measures the spectrum using a highly sensitive portable spectrometer. The viewing direction of the instrument is controlled through a motor and can be changed continuously. Data analysis of the measured spectra allows us to simultaneously determine the differential scant column density of NO2 and oxygen dimer O4. From the accurately known concentration of O4, the effective optical path length of scattered sun light near the horizontal direction could be derived, which in turn provides an estimate the concentration of NO2. The measured data show that the concentration of NO2 in Hanoi is in the range ~1.5 ppb. We also present the detection of formaldehyde HCHO and possible detection of glyoxal CHOCHO. Our sensitive instrument opens up the possibility to monitor the concentration of other molecular species of interest in urban environment of Hanoi.
二氧化氮NO2是影响空气质量的重要气体污染物,因此监测城市环境中二氧化氮NO2的浓度和分布具有重要意义。本文介绍了一种能灵敏检测二氧化氮的多轴差分光学吸收光谱仪的研制。被动式仪器收集被大气中的空气分子和气溶胶散射的太阳光,并使用高灵敏度的便携式光谱仪测量光谱。仪器的观察方向通过电机控制,可连续改变。测量光谱的数据分析使我们能够同时确定NO2和氧二聚体O4的差异稀疏柱密度。根据准确已知的O4浓度,可以推导出太阳散射光在水平方向附近的有效光程长度,从而估计NO2的浓度。实测数据表明,河内市NO2浓度在~1.5 ppb范围内。我们还介绍了甲醛HCHO的检测和乙二醛CHOCHO的可能检测。我们的灵敏仪器为监测河内城市环境中其他感兴趣的分子物种的浓度开辟了可能性。
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引用次数: 0
Silica-based Photonic Crystal Fiber for Supercontinuum Generation in the Anomalous Dispersion Region: Measurement and Simulation 在异常色散区产生超连续谱的硅基光子晶体光纤:测量与模拟
Pub Date : 2022-07-25 DOI: 10.15625/0868-3166/17121
D. Ho, V. B. Chu, V. Le, Van Chin Hoang, Thi Thao Nguyen, V. Hoang, Longgui Cao
We report on numerical simulation and experimental study of the supercontinuum (SC) generation in the anomalous dispersion region of photonic crystal fiber (PCF). The results show that a flat and stable spectrum with bandwidth of 130 nm around the central pump wavelength was achieved with an input power of 4.0 W. Although the measured spectrum is slightly different from the numerical ones, a good consistency can be recognized in the major sideband positions and spectral width. In addition, the chromatic dispersion of air silica PCF was measured at visible and near-infrared wavelengths using the Mach-Zehnder interferometer configuration and then verified by comparison with simulated results.
本文报道了光子晶体光纤(PCF)异常色散区超连续谱(SC)产生的数值模拟和实验研究。结果表明,当输入功率为4.0 W时,在中心泵浦波长附近获得了带宽为130 nm的平坦稳定光谱。虽然实测光谱与数值光谱略有差异,但在主要边带位置和谱宽上均能识别出较好的一致性。此外,利用Mach-Zehnder干涉仪配置测量了空气二氧化硅PCF在可见光和近红外波段的色散,并与模拟结果进行了对比验证。
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引用次数: 0
Study of Charge Transfer Contribution to Surface-Enhanced Raman Scattering Activity of Cu(_2)O Nano-octahedral Substrate Cu (_2) O纳米八面体基板表面增强拉曼散射活性的电荷转移研究
Pub Date : 2022-07-07 DOI: 10.15625/0868-3166/16787
Thu Trang Tran, Xuan Hoa Vu, Thi Thu Ha Pham, Trọng-Nghĩa Nguyễn, D. D. Nguyen
In this study, a surface-enhanced Raman scattering (SERS) substrate based on an octahedral cuprous oxide (Cu2O) nanostructure to probe methylene blue (MB) molecules as an analyte chemical has been implemented. Octahedral Cu2O nanocrystals were synthesized by a novel hydrothermal process using only ethylene glycol as both a reductant and organic solvent. The characteristics of Cu2O nanocrystals were well recognized by scanning electron microscope (SEM), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), FTIR, and Raman spectroscopy. The mechanism of the SERS surface has been thoroughly investigated and has been shown to involve the contributions of both surface plasmon resonance and charge transfer effects. Using a simple collection rule for SERS bands, the portion of charge transfer processes was estimated to be about 46%.
在这项研究中,基于八面体氧化亚铜(Cu2O)纳米结构的表面增强拉曼散射(SERS)衬底已实现探测亚甲基蓝(MB)分子作为分析物的化学物质。以乙二醇为还原剂和有机溶剂,采用水热合成法合成了八面体Cu2O纳米晶体。通过扫描电镜(SEM)、x射线衍射(XRD)、能量色散x射线能谱(EDX)、红外光谱(FTIR)和拉曼光谱(Raman)对Cu2O纳米晶体的特征进行了较好的识别。SERS表面的机制已经被深入研究,并被证明涉及表面等离子体共振和电荷转移效应的贡献。使用简单的SERS谱带收集规则,估计电荷转移过程的比例约为46%。
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引用次数: 0
Opto-electronic Properties of Small ZnO(_2) Nanoparticles: First-Principles Insights 小ZnO (_2)纳米粒子的光电性质:第一性原理的见解
Pub Date : 2022-07-05 DOI: 10.15625/0868-3166/16674
N. Tien, Dang Minh Triet, Pham Thi Bich Thao
We performed density functional theory based first-principles calculations to investigate the opto-electronic properties of small ZnO2 nanoparticles. We have shown that these ZnO2 nanoparticles can exhibit either semiconductor or metallic properties depending on the morphology and sizes of the nanoparticles defined by Miller indices. The absorption spectra computedfrom the real and imaginary parts of the dielectric functions demonstrate that these nanoparticles exhibit rich optical features with highly spatial anisotropy in the visible light range, suggesting that these newly obtained configurations strongly influence the electronic structures of ZnO2 nanoparticles. Our results propose the potential application of using Zinc peroxide nanopariclesas prospective building blocks for developing early diagnosis nanodevices in drug industry.
采用密度泛函理论为基础的第一性原理计算方法,研究了zno纳米颗粒的光电性质。我们已经证明,这些ZnO2纳米颗粒可以表现出半导体或金属性质,这取决于由米勒指数定义的纳米颗粒的形态和尺寸。从介电函数的实部和虚部计算的吸收光谱表明,这些纳米粒子在可见光范围内表现出丰富的光学特征,具有高度的空间各向异性,表明这些新获得的构型对ZnO2纳米粒子的电子结构有强烈的影响。我们的研究结果提出了过氧化锌纳米颗粒作为药物工业早期诊断纳米器件的潜在应用前景。
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引用次数: 0
Optical Properties of 1D ZnO/MoS(_2) Heterostructures Synthesized by Thermal Evaporation Method 热蒸发法制备一维ZnO/MoS (_2)异质结构的光学性质
Pub Date : 2022-06-22 DOI: 10.15625/0868-3166/16867
Thi Thu Giang Luu, Q. Do, M. Tran, T. Nguyen, D. H. Nguyen, T. Pham
MoS2 material attracts a great attention from researchers due to its graphene-like structure and the bandgap difference between its hexagonal monolayer and bulks. Recently, ZnO/MoS2 heterostructures have been received significant interest due to their distinguished properties. In this study, one-dimensional ZnO and ZnO/MoS2 heterostructures were successfully synthesized by a thermal co-evaporation method. Compare with ZnO, the band-to-band emission of ZnO/MoS2 heterostructures establishes a “blueshift” towards a shorter wavelength. It could be explained by the lattice strain in ZnO/MoS2 heterostructures due to the difference of primitive cell of ZnO and MoS2. Additionally, the quench in the visible region of the PL spectrum of ZnO/MoS2 heterostructures also explains the reduction of the defect in ZnO due to the presence of MoS2.
二硫化钼材料由于其类石墨烯结构以及其六方单层与块体之间的带隙差异而备受关注。近年来,氧化锌/二硫化钼异质结构因其独特的性能而受到广泛关注。在本研究中,通过热共蒸发方法成功合成了一维ZnO和ZnO/MoS2异质结构。与ZnO相比,ZnO/MoS2异质结构的波段间发射形成了向短波长的“蓝移”。这可以解释为ZnO/MoS2异质结构中的晶格应变,这是由于ZnO和MoS2的原始细胞不同造成的。此外,ZnO/MoS2异质结构的PL光谱可见区域的猝灭也解释了由于MoS2的存在而导致ZnO缺陷的减少。
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引用次数: 0
Heat Conductance Oscillations in Two Weakly Connected Charge Kondo Circuits 两个弱连接电荷近藤电路的热传导振荡
Pub Date : 2022-06-14 DOI: 10.15625/0868-3166/17169
T. Nguyen, M. Kiselev
We revisit a model describing Seebeck effect on a weak link between two charge Kondo circuits, which has been proposed in the [Phys. Rev. B 97 (2018) 085403]. We calculate the thermoelectric coefficients in the perturbation theory assuming smallness of the reflection amplitudes of the quantum point contacts. We focus on the linear response equations for the heat conductance in three different scenarios as: Fermi liquid vs Fermi liquid, Fermi liquid vs non-Fermi liquid, non-Fermi liquid vs non-Fermi liquid. The oscillations of the heat conductance as a function of the gate voltage of each quantum dot are analysed in both Fermi liquid and non-Fermi liquid regimes. We discuss possible experimental realizations of the model to observe the signatures of the non-Fermi liquid behaviour in the heat conductance measurements.
我们重新审视了在两个电荷近藤电路之间的弱链路上描述塞贝克效应的模型,该模型已在《物理学》中提出。修订版B 97(2018) 085403]。假设量子点接触的反射振幅较小,我们计算了微扰理论中的热电系数。我们重点研究了费米液体与费米液体、费米液体与非费米液体、非费米液体与非费米液体三种不同情况下热传导的线性响应方程。在费米液体和非费米液体状态下,分析了热传导振荡作为每个量子点栅电压的函数。我们讨论了该模型在热导测量中观察非费米液体行为特征的可能实验实现。
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引用次数: 0
Temperature-mediated Phase Transformation and Optical Properties of Tungsten Oxide Nanostructures Prepared by Facile Hydrothermal Method 易溶水热法制备氧化钨纳米结构的温度介导相变和光学性质
Pub Date : 2022-06-03 DOI: 10.15625/0868-3166/16754
N. L. Pham, T. Luu, Thi Tuyet Mai Nguyen, V. Pham, H. L. Nguyen, C. Nguyen
Different tungsten oxide nanocrystals were synthesized via facile hydrothermal process – one-step and free of additives - at different reaction temperatures and a highly acidic environment. The phase transformation of samples, followed by the change of morphology and optical properties, was observed as the reaction temperature varied from room temperature to 220oC. The crystal phase transformed from monoclinic WO3∙2H2O to orthorhombic WO3∙H2O, then to monoclinic WO3 as the reaction temperature increased from room temperature to 100 ⁰C, then to 220 ⁰C. Corresponding to the phase transformation, the optical bandgap increased from 2.43 eV to 2.71 eV, and the morphology varied from nanoplate to nanocuboid. The effect of the reaction temperature on the phase transformation was assigned to the dehydration process, which became stronger as the reaction temperature increased. These results gave an insight into the phase transformation and implied a simple method for manipulating the crystal phase and morphology of tungsten oxide nanostructure for various applications.
在不同的反应温度和强酸性环境下,采用无添加剂的简易水热法一步合成了不同的氧化钨纳米晶体。在室温至220℃的反应温度范围内,观察到样品的相变、形貌和光学性质的变化。随着反应温度从室温升高到100⁰C,再到220⁰C,晶相从单斜WO3∙2H2O转变为正交WO3∙H2O,然后转变为单斜WO3。与相变相对应,光带隙由2.43 eV增大到2.71 eV,形貌由纳米板变为纳米立方体。反应温度对相变的影响主要体现在脱水过程中,随着反应温度的升高,反应温度对相变的影响越来越大。这些结果提供了对相变的深入了解,并暗示了一种用于各种应用的操纵氧化钨纳米结构的晶相和形貌的简单方法。
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引用次数: 0
Pyrolytic Carbon Electrodes and Their Potential Application in Electrochemical Sensors 热解碳电极及其在电化学传感器中的潜在应用
Pub Date : 2022-06-01 DOI: 10.15625/0868-3166/16829
Thi Tuyet Ngan Nguyen, Thanh Giang Bui, D. T. Nguyen, Duc Thanh Nguyen, H. Nguyen, T. H. Nguyen, Thanh Binh Dang, T. T. Vu
In this work, pyrolytic carbon electrodes were prepared through pyrolysis of well-patterned AZ 1505 positive photoresist films. The designed electrodes firstly were prepared via photolithography technique, then the polymer was thermally broken-down into carbon skeletons in an oxygen-free environment using pyrolysis technique. The effect of the highest temperature and ramping rate on the electrical properties of the carbon films were investigated. The results show that the pyrolysis process was optimal at the ramping rate of 3 °C/minute, annealing temperature of 900 °C, and annealing time of one hour. The lowest resistivity was obtained at 6.3 ´ 10-5 Wm for pyrolytic films prepared at the optimal pyrolysis conditions. Electrochemical measurements confirm the potential of this electrode for electrochemical sensing applications.
本文通过对az1505正极光刻胶薄膜的热解,制备了具有良好图案化的热解碳电极。设计的电极首先通过光刻技术制备,然后在无氧环境下使用热解技术将聚合物热分解成碳骨架。研究了最高升温温度和升温速率对碳膜电性能的影响。结果表明,升温速率为3℃/min、退火温度为900℃、退火时间为1 h时,热解工艺最优。在最佳热解条件下制备的热解膜在6.3´10-5 Wm处电阻率最低。电化学测量证实了这种电极在电化学传感应用中的潜力。
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引用次数: 0
The Excitonic Susceptibility Function in Semimetal/semiconductor Materials: Formation of the Excitonic Condensate State 半金属/半导体材料中的激子磁化率函数:激子凝聚态的形成
Pub Date : 2022-05-11 DOI: 10.15625/0868-3166/16748
T. Do
The condensate state of excitons in semimetal/semiconductor materials has been considered by analyzing the excitonic susceptibility function in the 2D extended Falicov-Kimbol model including electron-phonon interaction. The excitonic susceptibility in the system has calculated by using the Hartree-Fock approximation. From numerical results, we have set up phase diagrams ofthe excitonic condensate state. Phase diagrams confirm that the electron-phonon coupling plays an important role as well as the Coulomb attraction does in establishing the excitonic condensed phase at low temperature. The condensate phase of excitons is found within a limited range of the Coulomb attraction as the electron-phonon coupling is large enough. Depending on theelectron-phonon coupling and the Coulomb attraction, the BCS-BEC crossover of the excitonic condensation phase has also been pointed out.
通过分析包含电子-声子相互作用的二维扩展Falicov-Kimbol模型中的激子磁化率函数,研究了半金属/半导体材料中激子的凝聚态。利用Hartree-Fock近似计算了系统的激子磁化率。根据数值结果,建立了激子凝聚态的相图。相图证实了电子-声子耦合和库仑吸引在低温下建立激子凝聚相中起着重要的作用。当电子-声子耦合足够大时,激子的凝聚相在库仑吸引的有限范围内存在。根据电子-声子耦合和库仑吸引,还指出了激子凝聚相的BCS-BEC交叉。
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引用次数: 0
期刊
Communications in Physics
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