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FLOCCULATION STUDY OF NATURAL QUARTZ SAMPLE USING ANIONIC POLYACRYLAMIDE 阴离子聚丙烯酰胺对天然石英样品的絮凝研究
Pub Date : 2020-10-10 DOI: 10.7251/comen2002112s
Ljiljana Tankosić, S. Sredić, P. Tančić, Z. Nedić
The waste sludge generated during processing of iron ore in the Omarska mine (The Republic of Srpska, Bosnia and Herzegovina) is fine-grained (15μm), containing relatively high concentrations of iron, and quartz as its major impurity. The flocculation behaviour of the primary natural raw “quartz” sample from Omarska mine was studied in the present paper. This sample is composed of major quartz which dominates over minor contents of clay minerals and feldspars, and contain 92.9% of SiO2. Particle size distribution analysis confirm that it is present as fine and ultra-fine particles. The zeta potential of quartz depends on pH value. Settling experiments were performed by using three different dispersants (Na-hexamethaphosphate, Na-pyrophosphate and Na-silicate), and anionic polyacrylamide as flocculants. The best results were achieved with Nahexametaphosphate (1000 g/t) and anionic polyacrylamide A 100. The effect of a flocculant on the settling rate depends on solid concentration. Settling rates increase significantly with the increase of the liquid component in both cases (natural settling and hindered settling by addition of a flocculant).
Omarska矿(波斯尼亚和黑塞哥维那斯普斯卡共和国)铁矿加工过程中产生的废泥颗粒细(15μm),铁含量较高,主要杂质为石英。研究了奥马尔斯卡矿原生天然原料“石英”试样的絮凝性能。样品以石英为主,粘土矿物和长石含量低,SiO2含量为92.9%。粒度分布分析证实其以细颗粒和超细颗粒的形式存在。石英的zeta电位取决于pH值。采用六聚磷酸钠、焦磷酸钠和硅酸钠三种分散剂和阴离子聚丙烯酰胺作为絮凝剂进行沉降实验。使用六偏磷酸钠(1000 g/t)和阴离子聚丙烯酰胺a100的效果最好。絮凝剂对沉降速率的影响取决于固体浓度。在两种情况下(自然沉降和添加絮凝剂的阻碍沉降),随着液体成分的增加,沉降率显著增加。
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引用次数: 0
IMPACT OF CREATINE MONOHYDRATE ON BODY MASS OF SWIMMERS 一水肌酸对游泳运动员体重的影响
Pub Date : 2020-10-10 DOI: 10.7251/comen2002169g
Goran Grahovac, Bojan Guzina, Milomir Trivun, Goran Pašić
The subject of the research is impact of creatine monohydrate on a mass of swimmers. The test was performed on a sample of 60 swimmers among members of the Academic Swimming Club „22. April“ divided into two groups aged between 21 and 25. All respondents are male and in good health. The respondents belonging to this population are at the zenith of morphological and motor development and are well motivated to advance in swimming. The measurement was carried out at the end of May and half of June 2008 at the premises of the Recreation Center Srpske Toplice (water temperature 28°C). The respondents were measured for body mass at baseline and after 21 days of taking creatine. The main objective of the paper is to determine whether taking creatine for three weeks shows significant differences in a mass gain of swimmers. The results of the research show that the differences in body mass between the two measurements have statistical significance.
这项研究的主题是一水肌酸对大量游泳者的影响。该测试是在学术游泳俱乐部的60名成员中进行的。“四月”被分为两组,年龄在21到25岁之间。所有答复者均为健康状况良好的男性。属于这一人群的应答者正处于形态和运动发展的顶峰,并且很有动力在游泳方面取得进步。测量于2008年5月底和6月中旬在Srpske Toplice娱乐中心(水温28°C)进行。在基线和服用肌酸21天后,测量了受访者的体重。这篇论文的主要目的是确定连续三周服用肌酸是否会对游泳者的体重增加产生显著影响。研究结果表明,两种测量方法之间的体重差异具有统计学意义。
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引用次数: 0
STUDY OF THE BIOLOGICAL ACTIVITY DESCRIPTORS OF THE BARBITURIC ACID DERIVATIVES 巴比妥酸衍生物生物活性描述符的研究
Pub Date : 2020-10-10 DOI: 10.7251/comen2002077a
S. Apostolov, Đ. Vaštag, Borko M. Matijević, Gorana S. Mrđan, Jelena Nakomčić
Barbituric acid derivatives have been pharmacologically significant compounds for decades. The central nervous system effects are conditioned by the presence of the pyrimidine-trione ring and the nature of the substituent in position 5. Lipophilicity as one of the key molecular descriptors of biological activity for selected barbituric acid derivatives was determined experimentally, using reversed-phase thin layer chromatography (RP TLC18 F254s), in two solvent systems. The influence of the substituent’s nature and the effects of applied organic modifiers on the chromatographic behavior of the tested derivatives were examined. For the studied derivatives the values of the partition coefficient (logP) as a standard measure of lipophilicity and effective concentration (EC50) as a measure of acute toxicity for different test organisms were calculated applying the appropriate software packages. Dependence between the chromatographic parameters as assumed measures of lipophilicity and the software-derived biological activity parameters of the studied barbituric acid derivatives were studied by linear regression analysis.
巴比妥酸衍生物几十年来一直是具有药理意义的化合物。中枢神经系统的影响是由嘧啶-三酮环的存在和5位取代基的性质决定的。在两种溶剂体系中,采用反相薄层色谱法(RP TLC18 F254s)测定了巴比妥酸衍生物的亲脂性作为生物活性的关键分子描述符之一。考察了取代基性质和应用有机改性剂对被测衍生物色谱行为的影响。对于所研究的衍生物,应用适当的软件包计算了作为亲脂性标准度量的分配系数(logP)和作为急性毒性度量的有效浓度(EC50)对不同试验生物的值。通过线性回归分析,研究了巴比妥酸衍生物的亲脂性色谱参数与软件衍生的生物活性参数之间的相关性。
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引用次数: 3
STUDY OF IRON OXIDE NANOPARTICLES DOPED WITH COPPER: ANTIMICROBAL AND PHOTOCATALYTICAL ACTIVITY 掺杂铜的氧化铁纳米颗粒的研究:抗菌和光催化活性
Pub Date : 2020-10-10 DOI: 10.7251/comen2002093j
A. Šmitran, Dijana Jelić, Sanja Pržulj, Savka Vračević, D. Gajić, Mladena Malinović, L. Božić
Last decade is designated as the postantibiotic era due to increasing number of resistant and multiresistant strains of microorganisms, which developed resistance to one or more antibiotics. Antimicrobial resistance becomes a global health problem. This phenomenon of antimicrobial resistance will undoubtedly affect the efficiency and use of antibiotics in the future. Science and technological development are committed to researching and developing new antibiotics that will satisfy the missing criteria and address the problem of antimicrobial resistance. One of the possible solutions lies in nanotechnologies. Nanoparticles have been isolated as one of the most promising substances on which microorganisms rarely or even develop mechanisms of resistance. The nanoparticles may be in conjunction with already existing antibiotics structures and contribute to the improvement of physicochemical properties in order to successfully overcome the mechanism of antimicrobial resistance. By designing nanoparticles with proper physicochemical and biochemical characteristics we determine their application. The aim of this research is to dope synthesized iron oxide nanoparticles with copper ions in order to test their antimicrobial activity and to evaluate their use as potential antimicrobial agent. Extracts of green tea and ascorbic acid were used as reduction agent for the iron oxide nanoparticles doped with Cu. The antimicrobial activity of the synthesized nanoparticles on the isolates Acinetobacter baumannii and methicillin resistant Staphylococcus aureus (MRSA) was performed by the agar well diffusion method. Synthesized iron oxide nanoparticles showed activity against Acinetobacter baumannii with inhibition zone around 12 mm. Photocatalytical activity was also evaluated by UV/VIS spectrophotometry. Samples doped with copper showed much better photocatalytical performances.
由于越来越多的耐药和多重耐药微生物菌株对一种或多种抗生素产生耐药性,过去十年被指定为后抗生素时代。抗菌素耐药性已成为一个全球性的健康问题。这种抗菌素耐药性现象无疑将影响未来抗生素的效率和使用。科技发展致力于研究和开发新的抗生素,以满足缺失的标准并解决抗生素耐药性问题。一个可能的解决方案在于纳米技术。纳米颗粒已被分离出来,是微生物很少或甚至很少产生耐药性机制的最有前途的物质之一。纳米颗粒可能与已有的抗生素结构结合,有助于改善物理化学性质,以成功克服抗菌素耐药性的机制。通过设计具有适当理化生化特性的纳米颗粒,确定其应用。本研究的目的是将合成的氧化铁纳米颗粒掺杂铜离子,以测试其抗菌活性,并评价其作为潜在抗菌剂的应用价值。以绿茶提取物和抗坏血酸为还原剂,制备了掺杂铜的氧化铁纳米颗粒。采用琼脂孔扩散法测定合成的纳米颗粒对鲍曼不动杆菌和耐甲氧西林金黄色葡萄球菌的抑菌活性。合成的氧化铁纳米颗粒对鲍曼不动杆菌具有抑制作用,抑制带在12 mm左右。用紫外/可见分光光度法测定其光催化活性。掺杂铜的样品表现出更好的光催化性能。
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引用次数: 0
PROPERTIES OF THE HAND MIXED PMMA BASED CEMENT FOR BIOMEDICAL APPLICATIONS 生物医学用手混pmma基水泥的性能研究
Pub Date : 2020-10-10 DOI: 10.7251/comen2002085z
F. Živić, N. Grujovic, S. Pelemiš, D. Adamović
This paper presents insights into the recent trends in development of PMMA bone cements considering their improvements for applications in clinical practice. Experimental investigation of hand mixed PMMA bone cement was realized, aiming to determine mechanical behavior of the material during nanoindentation. Standard multi-cycle indentation tests were applied, with maximum load of 15 N and immediate load relaxation down to 5 N, with sharp Vickers indenter. Indentation curves were obtained and analyzed as the function of the normal load vs penetration depth, for three different numbers of cycles (100, 200 and 300 cycles) and different indentation positions on the sample surface. Resulting indents were analyses from the aspect of the final material structure and its subsequent mechanical behavior. Agglomeration of PMMA beads was observed in the final hardened cement in some surface zones, thus indicating non-homogenous material structure. Changes in the number of cycles did not show significant influence on the mechanical response of the sample. However, sites with agglomerated PMMA beads showed significantly different indentation curves, thus indicating that hand-mixing of PMMA bone cement can produce non-homogenous final material structure.
本文介绍了PMMA骨水泥的最新发展趋势,并考虑了其在临床应用中的改进。对手工混合PMMA骨水泥进行了实验研究,旨在确定材料在纳米压痕过程中的力学行为。采用标准的多循环压痕试验,最大载荷为15牛,载荷立即松弛至5牛,使用锋利的维氏压头。得到了三种不同循环次数(100次、200次和300次)和试样表面不同压痕位置的压痕曲线,并分析了压痕曲线作为法向载荷与渗透深度的函数。从最终材料结构及其后续力学行为的角度对产生的压痕进行了分析。在最终硬化的水泥中,在某些表面区域观察到PMMA微珠的结块,表明材料结构不均匀。循环次数的变化对试样的力学响应无显著影响。然而,PMMA微球聚集的部位呈现出明显不同的压痕曲线,这表明手工混合PMMA骨水泥会产生不均匀的最终材料结构。
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引用次数: 0
NANOTECHNOLOGY IN THE FUNCTION OF SUSTAINABLE WATER USE 纳米技术在可持续用水中的作用
Pub Date : 2020-10-10 DOI: 10.7251/comen2002102s
S. Stevović, Ž. Nestorović, N. Đurić
Nanotechnology, as contemporary field of research in forming of materials and devices on the level of molecule and atoms, is founding broad utilization in different scientific and engineering domains. The influence of nanotechnology on the development of contemporary human society has got a significant potential in domains as economy, environment protection, health and improvement of the quality of life. The need for fresh water as a necessary resource for living world, as well as the economic activity on the level of humanity is growing in the conditions of increasing population, increasing economic activities and increasing pollution. In that sense the conventional methods for water treatment may become ineffective for providing sustainable utilization of water resources in the future. Nanotechnology as a contemporary scientific and engineering field is considered efficient and potentially, the only solution for sustainable utilization of fresh water in the future. The efforts in nanotechnology utilization for sustainability of fresh water resources mean comprehensive approach and clarity in defining goals as well as the ways for their realization. The basic expectations of nanotechnology in the sense of fresh water resources utilization are directed to enhancement of fresh water availability, increase of efficiency of fresh water delivery and enabling next generation systems for fresh water quality monitoring. The increase of fresh water availability by nanotechnology means development of filtering systems and development of membrane systems, inverse osmosis for water desalinization and catalysts for water treatment. Efficiency of fresh water delivery based on nanotechnology means reducing energy necessary for its transportation, developing system of pipes and components which are easier, stronger and which will last longer as well as to provide cheap materials which improve energy efficiency for heating and cooling. All these processes for nanotechnology development aiming to provide sustainable fresh water resources utilization require significant efforts on scientific and engineering level in order to be utilized in everyday life. This paper aims to research the state of the art of nanotechnology development in the domain of sustainable utilization of fresh water resources.
纳米技术作为在分子和原子水平上形成材料和器件的当代研究领域,在不同的科学和工程领域得到了广泛的应用。纳米技术对当代人类社会发展的影响在经济、环境保护、健康和提高生活质量等领域具有巨大的潜力。在人口增加、经济活动增加和污染增加的情况下,对淡水作为生活世界和人类经济活动的必要资源的需求正在增加。从这个意义上说,传统的水处理方法可能在将来无法提供水资源的可持续利用。纳米技术作为当代科学和工程领域,被认为是未来可持续利用淡水的唯一解决方案。在利用纳米技术促进淡水资源的可持续性方面所作的努力意味着在确定目标及其实现途径方面采取全面的方法和明确的态度。纳米技术在淡水资源利用方面的基本期望是加强淡水供应,提高淡水输送的效率,并使下一代淡水质量监测系统成为可能。通过纳米技术增加淡水的可用性意味着过滤系统和膜系统的发展,水脱盐的反渗透和水处理的催化剂的发展。基于纳米技术的淡水输送效率意味着减少运输所需的能源,开发更容易、更坚固、更持久的管道和组件系统,以及提供提高加热和冷却能源效率的廉价材料。所有这些旨在提供淡水资源可持续利用的纳米技术发展过程都需要在科学和工程水平上作出重大努力,才能在日常生活中得到利用。本文旨在研究纳米技术在淡水资源可持续利用领域的发展现状。
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引用次数: 0
EVALUATION OF FLOOR COVERINGS FROM THE ECOLOGICAL AND ECONOMIC ASPECT IN THE DESIGN STAGE 从设计阶段的生态和经济角度对地板覆盖物进行评价
Pub Date : 2020-10-10 DOI: 10.7251/comen2002150n
Marina Nikolić Topalović, M. Stanković
Measures to reduce the impact of the construction sector on the environment and human health need to be taken at the design stage of the facility and evaluate building materials and products from an ecological and economic aspect. For the research needs, a comparison of floor coverings at the design stage was made to assess their impact during the life cycle. The research uses the life cycle analysis (LCA), a methodology that is the basis for analyzing the impacts during the life cycle of the analyzed construction products. The research covers the life cycle stages from A1 to C4, according to the standard ISO EN 15978: 2011. The software package BEES, the National Institute of Standardization and Technology (NIST), the United States of America is used for the turn. Five types of floor coverings were analyzed, from the aspect of their impact on the environment and human health, but also from the economic point of view. The research has shown that in the design phase, using software packages can be managed with the quality of the environment, and the project design, and hence the quality of the facility. The research also points to the need for a national software package that can analyze construction products and materials. Their application would improve the national construction industry and favored materials that are environmentally and economically acceptable in relation to materials with unfavorable effects on the environment and human health.
必须在设施的设计阶段采取措施,减少建筑部门对环境和人类健康的影响,并从生态和经济方面评价建筑材料和产品。为了研究需要,在设计阶段对地板覆盖物进行了比较,以评估其在生命周期中的影响。本研究使用了生命周期分析法(LCA),这是分析所分析的建筑产品在生命周期内的影响的基础。根据ISO EN 15978: 2011标准,研究涵盖了从A1到C4的生命周期阶段。美国国家标准化与技术研究所(NIST)所使用的软件包BEES是用于转用的。从对环境和人体健康的影响方面,以及从经济角度对五种类型的地板覆盖物进行了分析。研究表明,在设计阶段,使用软件包可以管理环境的质量,项目的设计,从而设施的质量。该研究还指出,需要一个全国性的软件包,可以分析建筑产品和材料。与对环境和人类健康有不利影响的材料相比,它们的应用将改善国家建筑工业,并有利于环境和经济上可接受的材料。
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引用次数: 0
BIOMEDICAL POTENTIAL OF SELECTED MUSHROOM SPECIES 选定菌种的生物医学潜力
Pub Date : 2020-10-10 DOI: 10.7251/comen2002162k
T. Stanojković, M. Kosanić
The aim of this study was to determine neuroprotective, antioxidant, antimicrobial and cytotoxic potential of acetone extracts of Coprinus comatus and Coprinopsis picacea mushrooms. The neuroprotetive activity was tested against acetylcholinesterase enzyme using the Ellman method. Antioxidant activity was evaluated by free radical scavenging ability, superoxide anion radical scavenging activity and reducing power. The total phenol content was examined using Folin-Ciocalteu reagent. The antimicrobial potential was determined by a microdilution method against 12 microorganisms. The cytotoxic activity was tested using MTT method on the Hela, A549 and LS174 cells. Our results indicate that C. comatus expressed a stronger neuroprotective effect (the percentage of inhibition of acetylcholinesterase was within the range 19.66-51.73%) than C. picacea. In antioxidant effect C. comatus had more potent free radical scavenging activity (IC50 = 276.69 μg/mL) and superoxide anion radical scavenging activity (IC50 = 39.40 μg/mL), while reducing power was relatively similar for both species. The total amount of phenols for C. comatus and C. picacea was 50.57 and 50.20 μg PE/mg of dry extracts, respectively. In antimicrobial activity, C. picacea showed a better effect with MIC values from 0.1 to 7.5 mg/mL. Finally, C. picacea expressed stronger cytotoxicity toward A549 and LS174 cells, while C. comatus was more active against Hela cell.
本研究的目的是测定鸡角菇和picacea鸡角菇丙酮提取物的神经保护、抗氧化、抗菌和细胞毒性。采用Ellman法测定其对乙酰胆碱酯酶的神经保护活性。通过自由基清除能力、超氧阴离子自由基清除能力和还原能力评价其抗氧化活性。用Folin-Ciocalteu试剂测定总酚含量。采用微量稀释法测定其对12种微生物的抑菌潜力。采用MTT法检测其对Hela、A549和LS174细胞的细胞毒活性。结果表明,鸡毛藤对乙酰胆碱酯酶的抑制率在19.66 ~ 51.73%之间,具有较强的神经保护作用。在抗氧化作用方面,花楸具有较强的自由基清除能力(IC50 = 276.69 μg/mL)和超氧阴离子自由基清除能力(IC50 = 39.40 μg/mL),但还原能力基本相同。comatus和picacea的总酚含量分别为50.57和50.20 μ PE/mg。在抑菌活性方面,picacea在MIC值为0.1 ~ 7.5 mg/mL时效果较好。最后,picacea对A549和LS174细胞表现出较强的细胞毒性,而comatus对Hela细胞表现出较强的细胞毒性。
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引用次数: 0
RESONANCE AS NEW METHOD IN DETERMINING THE AGE OF PAINTS 共振法是测定颜料年代的新方法
Pub Date : 2020-10-10 DOI: 10.7251/comen2002135z
V. Zorić
In this work the mechanism of resonance is proposed as the way for determining of paint age, by application of this method. This method consists in accelerated paint ageing on the basis of resonance. Measuring is concerned with humidity of paint and it is a general method since water molecules are present in every material. The molecules of water have random distribution. They oscillate in shallow potential wells so that they can be ejected from paint with low energy quanta, thus decreasing the paint humidity by evaporation process. The high energy quanta accelerate this process of the paint ageing. Since water molecule is mechanical oscillator it can be turned into resonance by application of mechanical periodical field, but since it is electric dipole it can be even more conveniently turned into resonance with periodic electric field.
本文应用该方法,提出了共振机理作为确定涂料年龄的方法。这种方法是在共振的基础上加速油漆老化。测量与油漆的湿度有关,这是一种通用的方法,因为水分子存在于每种材料中。水分子的分布是随机的。它们在浅电位阱中振荡,因此它们可以以低能量量子从油漆中喷射出来,从而通过蒸发过程降低油漆湿度。高能量子加速了涂料的老化过程。由于水分子是机械振子,可以利用机械周期场转化为共振,而由于水分子是电偶极子,可以更方便地利用周期电场转化为共振。
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引用次数: 0
ANTIMICROBIAL AND PHOTOCATALYTIC PROPERTIES OF DOPED AND UNDOPED ZINC OXIDE NANOPARTICLES 掺杂和未掺杂氧化锌纳米颗粒的抗菌和光催化性能
Pub Date : 2020-10-10 DOI: 10.7251/comen2002128v
Savka Vračević, A. Šmitran, Sanja Pržulj, D. Gajić, Mladena Malinović, L. Božić, Dijana Jelić
In this paper, zinc oxide nanoparticles doped with copper (ZnO/CuNP) were synthesized by using black and green tea, vitamin C and trisodium citrate as a reduction agent. Antimicrobial and photocatalytic properties were tested. The antimicrobial activity of the doped synthesized ZnO NP against the clinical isolates of Acinetobacter baumannii and methicillin resistant Staphylococcus aureus (MRSA) was performed by the agar well diffusion method. ZnO NP with all four reduction agents showed good antimicrobial efficiency against both microorganisms, with similar inhibition zone. Photocatalytic activity was more pronounced in case of undoped, pure ZnO nanoparticles, while the best results for doped ZnO samples were obtained for ZnO/Cu NPs using black tea.
本文以红茶、绿茶、维生素C和柠檬酸三钠为还原剂,合成了掺杂铜的氧化锌纳米颗粒(ZnO/CuNP)。测试了其抗菌和光催化性能。采用琼脂孔扩散法对临床分离的鲍曼不动杆菌和耐甲氧西林金黄色葡萄球菌(MRSA)进行了抑菌活性研究。四种还原剂的ZnO NP对两种微生物均有良好的抑菌效果,抑菌带相似。光催化活性在未掺杂的纯ZnO纳米粒子中更为明显,而在掺杂ZnO样品中,以红茶为原料制备ZnO/Cu纳米粒子的效果最好。
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引用次数: 0
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Contemporary Materials
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