Pub Date : 2022-04-07DOI: 10.2174/2213337209666220407113453
A. Goel, Shikha
Catalytic degradation of azo dye. Azo dyes are toxic agents and pollutants and the degradation of these dyes has an important application in the treatment of textile industry wastes. Catalytic decolorization of fast yellow dye by hexacyanoferrate (III), abbreviated as HCF(III) using polyvinylpyrrolidone abbreviated as PVP stabilized Ir-Ni bimetallic nanocrystals has been evaluated by kinetic spectrophotometric method at 440nm wavelength of the reaction mixture. The impact of various operational factors such as fast yellow dye abbreviated as [FY], oxidant [HCF(III)] ions, promoter iridium-nickel bimetallic nanoparticles abbreviated as [(Ir-Ni)] BMNPs, and solution pH on the rate of the reaction have been examined. The results represent that the reaction follows first -order kinetics model with respect to [oxidant] at optimum pH 8 and fix temperature 40±0.1◦C. Thermodynamic parameters such as activation energy (Ea), enthalpy (ΔH#), entropy (ΔS#), frequency factor (A), and free energy of activation (ΔF#) have been evaluated by examining the reaction rate at four temperatures i.e. 40⁰C, 45⁰C, 50⁰C, and 55⁰C. On the basis of experimental outcomes, an appropriate mechanism involving complex formation has been proposed. Analytical techniques such as UV-Vis spectroscopy, FTIR, and LCMS of degraded products represent the formation of easier and less harmful compounds.
{"title":"Kinetic and Mechanistic Study of oxidative Degradation And Detoxification of Fast Yellow Azo Dye Using Surfactant Assisted Ir-Ni Bimetallic Nanocatalyst","authors":"A. Goel, Shikha","doi":"10.2174/2213337209666220407113453","DOIUrl":"https://doi.org/10.2174/2213337209666220407113453","url":null,"abstract":"\u0000\u0000Catalytic degradation of azo dye.\u0000\u0000\u0000\u0000Azo dyes are toxic agents and pollutants and the degradation of these dyes has an important application in the treatment of textile industry wastes. Catalytic decolorization of fast yellow dye by hexacyanoferrate (III), abbreviated as HCF(III) using polyvinylpyrrolidone abbreviated as PVP stabilized Ir-Ni bimetallic nanocrystals has been evaluated by kinetic spectrophotometric method at 440nm wavelength of the reaction mixture.\u0000\u0000\u0000\u0000The impact of various operational factors such as fast yellow dye abbreviated as [FY], oxidant [HCF(III)] ions, promoter iridium-nickel bimetallic nanoparticles abbreviated as [(Ir-Ni)] BMNPs, and solution pH on the rate of the reaction have been examined.\u0000\u0000\u0000\u0000The results represent that the reaction follows first -order kinetics model with respect to [oxidant] at optimum pH 8 and fix temperature 40±0.1◦C. Thermodynamic parameters such as activation energy (Ea), enthalpy (ΔH#), entropy (ΔS#), frequency factor (A), and free energy of activation (ΔF#) have been evaluated by examining the reaction rate at four temperatures i.e. 40⁰C, 45⁰C, 50⁰C, and 55⁰C. On the basis of experimental outcomes, an appropriate mechanism involving complex formation has been proposed.\u0000\u0000\u0000\u0000Analytical techniques such as UV-Vis spectroscopy, FTIR, and LCMS of degraded products represent the formation of easier and less harmful compounds.\u0000","PeriodicalId":10945,"journal":{"name":"Current Organocatalysis","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2022-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48808238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-04-04DOI: 10.2174/2212796816666220404151254
M. Mir
To synthesize Oxadiazole, Imidazole, Benzimidazole, and Cyclohexano Analogues of 1, 5-benzodiazepines through phenoxyl/phenylamino linkage It is worthwhile to mention that Imidazoles, benzimidazoles, oxadiazoles, are analysed extensively mainly as per their ready availability, broad chemical reactivity, and wide spectrum of biochemical activities, like antimicrobial, anti-inflammatory, antitumor, anticonvulsant drugs, anti-tubercular medicines, and having anti-HIV effect etc. The Oxadiazole, Imidazole, Benzimidazole derivatives were synthesized via Cyclohexano Analogues of 1, 5-benzodiazepines through phenoxyl/phenylamino linkage. The characteristic drift of our interest towards these molecules prompted us to think about the structural modification of [1, 5]-benzodiazepine compound by incorporating on its 2-position imidazole, benzimidazole, oxadiazole, nuclei through an aminophenyl or phenoxyl bridge to synthesize these novel heterocyclic analogues of 1, 5-benzodiazepines. These derivatives have been analysed by various spectrophometric techniques like UV, IR, NMR, and MS. The synthesis of these compounds via the mentioned methods are unique as Cyclohexano Analogues of 1, 5-benzodiazepines through phenoxyl/phenylamino is a totally new way of synthesis. The derivatives can be analysed for various properties in chemistry and pharmacology, as their parent compounds has many pharmacological properties. The synthesis of these types of compounds does provide a new hope to medicinal and pharmaceutical industries. Therefore further efforts should be taken into consideration for their synthesis and analysis of their medicinal properties.
{"title":"Synthesis of Oxadiazole, Imidazole, Benzimidazole, Cyclohexano Analogues of 1, 5-benzodiazepines through phenoxyl/phenylamino linkage","authors":"M. Mir","doi":"10.2174/2212796816666220404151254","DOIUrl":"https://doi.org/10.2174/2212796816666220404151254","url":null,"abstract":"\u0000\u0000To synthesize Oxadiazole, Imidazole, Benzimidazole, and Cyclohexano Analogues of 1, 5-benzodiazepines through phenoxyl/phenylamino linkage\u0000\u0000\u0000\u0000It is worthwhile to mention that Imidazoles, benzimidazoles, oxadiazoles, are analysed extensively mainly as per their ready availability, broad chemical reactivity, and wide spectrum of biochemical activities, like antimicrobial, anti-inflammatory, antitumor, anticonvulsant drugs, anti-tubercular medicines, and having anti-HIV effect etc.\u0000\u0000\u0000\u0000The Oxadiazole, Imidazole, Benzimidazole derivatives were synthesized via Cyclohexano Analogues of 1, 5-benzodiazepines through phenoxyl/phenylamino linkage.\u0000\u0000\u0000\u0000The characteristic drift of our interest towards these molecules prompted us to think about the structural modification of [1, 5]-benzodiazepine compound by incorporating on its 2-position imidazole, benzimidazole, oxadiazole, nuclei through an aminophenyl or phenoxyl bridge to synthesize these novel heterocyclic analogues of 1, 5-benzodiazepines.\u0000\u0000\u0000\u0000These derivatives have been analysed by various spectrophometric techniques like UV, IR, NMR, and MS. The synthesis of these compounds via the mentioned methods are unique as Cyclohexano Analogues of 1, 5-benzodiazepines through phenoxyl/phenylamino is a totally new way of synthesis. The derivatives can be analysed for various properties in chemistry and pharmacology, as their parent compounds has many pharmacological properties.\u0000\u0000\u0000\u0000The synthesis of these types of compounds does provide a new hope to medicinal and pharmaceutical industries. Therefore further efforts should be taken into consideration for their synthesis and analysis of their medicinal properties.\u0000","PeriodicalId":10945,"journal":{"name":"Current Organocatalysis","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2022-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42814058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-03-29DOI: 10.2174/2213337209666220329141541
R. Hassan, S. Ibrahim
Nicotine (NIC) is a lipid soluble alkaloid found predominately in tobacco and tobacco products including cigarettes, cigars and oral tobacco products such as snuff and chewing tobacco. Since nicotine substrate is the major constituent of tobacco smoke, it may cause negatively impacted problems to the human healthcare which keeps many users hooked. A spectrophotometric technique has been applied for investigating the kinetics of reduction of hexachloroiridiate (IV) as inert one-equivalent oxidant by carcinogenic nicotine (NIC) in aqueous perchlorate solutions. First-order in [IrCl6]2- and fractional-first-order with respect to the nicotine concentration has been revealed. Kinetic evidence for formation of 1: 1 intermediate complex between the NIC and [IrCl6]2- prior to the rate-determining step was confirmed. The ionization constants of nicotine was evaluated from the kinetic data and has been found to be 8.57x10-4 and 4.57 x 10-4 moldm-3 at ionic strength of 0.5 moldm-3 and at 30˚C and 40˚C, respectively. The activation parameters have been deduced from the kinetic results of the temperature-dependence of rate constants and a plausible reaction mechanism of the redox reaction is suggested and discussed. Nicotinic acid (Vitamin B3) was formed as oxidation product of nicotine oxidation.
{"title":"Kinetics and mechanism of reduction of hexacholoroiridate (IV) by carcinogenic nicotine as alkaloid in aqueous solutions with determination of ionization constant of nicotine","authors":"R. Hassan, S. Ibrahim","doi":"10.2174/2213337209666220329141541","DOIUrl":"https://doi.org/10.2174/2213337209666220329141541","url":null,"abstract":"\u0000\u0000Nicotine (NIC) is a lipid soluble alkaloid found predominately in tobacco and tobacco products including cigarettes, cigars and oral tobacco products such as snuff and chewing tobacco. Since nicotine substrate is the major constituent of tobacco smoke, it may cause negatively impacted problems to the human healthcare which keeps many users hooked.\u0000\u0000\u0000\u0000A spectrophotometric technique has been applied for investigating the kinetics of reduction of hexachloroiridiate (IV) as inert one-equivalent oxidant by carcinogenic nicotine (NIC) in aqueous perchlorate solutions.\u0000\u0000\u0000\u0000First-order in [IrCl6]2- and fractional-first-order with respect to the nicotine concentration has been revealed. Kinetic evidence for formation of 1: 1 intermediate complex between the NIC and [IrCl6]2- prior to the rate-determining step was confirmed.\u0000\u0000\u0000\u0000The ionization constants of nicotine was evaluated from the kinetic data and has been found to be 8.57x10-4 and 4.57 x 10-4 moldm-3 at ionic strength of 0.5 moldm-3 and at 30˚C and 40˚C, respectively. The activation parameters have been deduced from the kinetic results of the temperature-dependence of rate constants and a plausible reaction mechanism of the redox reaction is suggested and discussed. Nicotinic acid (Vitamin B3) was formed as oxidation product of nicotine oxidation.\u0000","PeriodicalId":10945,"journal":{"name":"Current Organocatalysis","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2022-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47733748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-03-29DOI: 10.2174/2213337209666220329125047
Gayatree Shinde, Jyotsna Thakur
Nanocatalysts exhibit several applications in the synthesis of many industrially important organic compounds. They manifest extremely fascinating physical and chemical properties which can be exploited in their catalytic applications. A magnetically recyclable Ag@Fe2O3 core-shell structured nanocatalyst was synthesized by a simple sol-gel technique and characterized by x-ray diffraction spectroscopy, field emission scanning electron microscope, high-resolution transmission electron microscopy, fourier transform infrared spectroscopy, vibrating sample magnetometer etc. Nanocatalyst was found to be a highly efficient heterogeneous catalyst for the synthesis of 2-aryl benzimidazoles and benzothiazoles via one-pot condensation of aromatic aldehydes and 1, 2-phenylenediamine, and 2-aminothiophenol. Ag@Fe2O3 nanocatalyst provides rapid conversion of the substrate into the desired product at room temperature within just 5-18 min in the presence of C2H5OH with good to excellent yield. The combination of Ag core with magnetic Fe2O3 shell results in improved efficiency, stability, magnetic recovery, and reusability compare to the individual nanoparticles. The synthetic protocol is featured with high yield, mild conditions, and simple work-up. Magnetic recovery of the catalyst from reaction systems and its reusability for several runs without loss of catalytic activity are additional advantages.
{"title":"Magnetically Recyclable Ag@Fe2O3 Core-shell Nanostructured Catalyst for One-pot Synthesis of 2-Aryl Benzimidazole and Benzothiazole","authors":"Gayatree Shinde, Jyotsna Thakur","doi":"10.2174/2213337209666220329125047","DOIUrl":"https://doi.org/10.2174/2213337209666220329125047","url":null,"abstract":"\u0000\u0000Nanocatalysts exhibit several applications in the synthesis of many industrially important organic compounds. They manifest extremely fascinating physical and chemical properties which can be exploited in their catalytic applications.\u0000\u0000\u0000\u0000A magnetically recyclable Ag@Fe2O3 core-shell structured nanocatalyst was synthesized by a simple sol-gel technique and characterized by x-ray diffraction spectroscopy, field emission scanning electron microscope, high-resolution transmission electron microscopy, fourier transform infrared spectroscopy, vibrating sample magnetometer etc. Nanocatalyst was found to be a highly efficient heterogeneous catalyst for the synthesis of 2-aryl benzimidazoles and benzothiazoles via one-pot condensation of aromatic aldehydes and 1, 2-phenylenediamine, and 2-aminothiophenol.\u0000\u0000\u0000\u0000Ag@Fe2O3 nanocatalyst provides rapid conversion of the substrate into the desired product at room temperature within just 5-18 min in the presence of C2H5OH with good to excellent yield. The combination of Ag core with magnetic Fe2O3 shell results in improved efficiency, stability, magnetic recovery, and reusability compare to the individual nanoparticles.\u0000\u0000\u0000\u0000The synthetic protocol is featured with high yield, mild conditions, and simple work-up. Magnetic recovery of the catalyst from reaction systems and its reusability for several runs without loss of catalytic activity are additional advantages.\u0000","PeriodicalId":10945,"journal":{"name":"Current Organocatalysis","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2022-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46429658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-03-22DOI: 10.2174/2213337209666220322115802
M. Abedini, Reyhaneh Pourhasan Kisomi, F. Shirini
The aim of this work is an overview on the application of succinimide based reagents to the promotion of some important organic reactions including protection and multicomponent ones. Mild reaction conditions, simple and easy work-up procedure, high to excellent yields, and stability, and reusability of the catalysts are noteworthy advantages of these methods.
{"title":"Succinimide based reagents: Useful catalysts for important organic reactions","authors":"M. Abedini, Reyhaneh Pourhasan Kisomi, F. Shirini","doi":"10.2174/2213337209666220322115802","DOIUrl":"https://doi.org/10.2174/2213337209666220322115802","url":null,"abstract":"\u0000\u0000The aim of this work is an overview on the application of succinimide based reagents to the promotion of some important organic reactions including protection and multicomponent ones. Mild reaction conditions, simple and easy work-up procedure, high to excellent yields, and stability, and reusability of the catalysts are noteworthy advantages of these methods.\u0000","PeriodicalId":10945,"journal":{"name":"Current Organocatalysis","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2022-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45799093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-03-01DOI: 10.2174/2213337209666220301123926
Swapnil R. Bankar
In recent times, there is an on-going interest in developing convenient and environmentally friendly synthetic methods in organic chemistry. The use of ionic liquid catalysts in organic synthesis is a developing area that allows reactions to be run at low temperature and without solvents. Literature overview revealed that room temperature supported ionic liquid catalysis is a developing field in catalytic science with huge application in organic synthesis. Hence in this current article our focus is on the one-pot synthesis of arylidene derivatives with the use of ([bmim]OH) ionic liquid. We describe here the use of an ionic liquid catalyst, 1-n-butyl-3-methylimidazolium hydroxide, [bmim]OH), in the convenient one pot synthesis of arylidene derivatives by the reaction of the active methylene compound, malononitrile, with pyrazole aromatic aldehydes under microwave irradiation. The functionalized ionic liquid, 1-n-butyl-3-methylimidazolium hydroxide ([bmim]OH) catalyzed Knoevenagel condensation reactions of pyrazole aromatic aldehydes with active methylene compound malononitrile carried out under microwave irradiation. The reaction progress was monitored by thin layer chromatography and the synthesized compounds were further characterized by NMR spectroscopy. This proposed work demonstrate the utility of the use of the ionic liquid catalyst [bmim]OH, in the suitable, high yield (80-95%) microwave assisted reactions of pyrazole aromatic aldehydes with the active methylene compound malononitrile. An eco-friendly synthesis of pyrazole derivatives has been demonstrated using ([bmim]OH) ionic liquid as a catalyst for the Knoevenagel condensation reactions of pyrazole aromatic aldehydes and malononitrile with microwave irradiation. The advantages of this green method are its convenience, mild reaction conditions, and high product yields (80-95%).
{"title":"Condensation Reactions of Aromatic Aldehydes with Active Methylene Compounds: The Beneficial Sinergy of Alkaline Ionic Liquid in One Pot Synthesis","authors":"Swapnil R. Bankar","doi":"10.2174/2213337209666220301123926","DOIUrl":"https://doi.org/10.2174/2213337209666220301123926","url":null,"abstract":"\u0000\u0000In recent times, there is an on-going interest in developing convenient and environmentally friendly synthetic methods in organic chemistry. The use of ionic liquid catalysts in organic synthesis is a developing area that allows reactions to be run at low temperature and without solvents. Literature overview revealed that room temperature supported ionic liquid catalysis is a developing field in catalytic science with huge application in organic synthesis. Hence in this current article our focus is on the one-pot synthesis of arylidene derivatives with the use of ([bmim]OH) ionic liquid.\u0000\u0000\u0000\u0000We describe here the use of an ionic liquid catalyst, 1-n-butyl-3-methylimidazolium hydroxide, [bmim]OH), in the convenient one pot synthesis of arylidene derivatives by the reaction of the active methylene compound, malononitrile, with pyrazole aromatic aldehydes under microwave irradiation.\u0000\u0000\u0000\u0000The functionalized ionic liquid, 1-n-butyl-3-methylimidazolium hydroxide ([bmim]OH) catalyzed Knoevenagel condensation reactions of pyrazole aromatic aldehydes with active methylene compound malononitrile carried out under microwave irradiation. The reaction progress was monitored by thin layer chromatography and the synthesized compounds were further characterized by NMR spectroscopy.\u0000\u0000\u0000\u0000This proposed work demonstrate the utility of the use of the ionic liquid catalyst [bmim]OH, in the suitable, high yield (80-95%) microwave assisted reactions of pyrazole aromatic aldehydes with the active methylene compound malononitrile.\u0000\u0000\u0000\u0000An eco-friendly synthesis of pyrazole derivatives has been demonstrated using ([bmim]OH) ionic liquid as a catalyst for the Knoevenagel condensation reactions of pyrazole aromatic aldehydes and malononitrile with microwave irradiation. The advantages of this green method are its convenience, mild reaction conditions, and high product yields (80-95%).\u0000","PeriodicalId":10945,"journal":{"name":"Current Organocatalysis","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47610331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-17DOI: 10.2174/2213337209666220217112937
Saida Benzerka, M. Redouane, Naima Khiri-Meribout, A. Debache
In this work, a series of pyridinium-based ionic liquids (PBILs) were synthesized. Pyridinium-based ionic liquids (PBILs) were synthesized through a simple method, which was initially evaluated as catalysts for the synthesis of tetrahydro[b]benzopyran derivatives via a one-pot three-component reaction involving aldehydes, malononitrile, and dimedone. The PBILs perform well in this condensation reaction, especially 1-methylpyridin-1-ium dimethyl phosphate (MPDMP). The advantages of this procedure are good yields, short reaction time, simplicity of implementation, and inexpensive starting materials.
{"title":"Highly efficient, reusable functionalized pyridinium salts as a catalyst for the simple and cost-effective preparation of tetrahydro[b]benzopyran derivatives","authors":"Saida Benzerka, M. Redouane, Naima Khiri-Meribout, A. Debache","doi":"10.2174/2213337209666220217112937","DOIUrl":"https://doi.org/10.2174/2213337209666220217112937","url":null,"abstract":"\u0000\u0000In this work, a series of pyridinium-based ionic liquids (PBILs) were synthesized.\u0000\u0000\u0000\u0000Pyridinium-based ionic liquids (PBILs) were synthesized through a simple method, which was initially evaluated as catalysts for the synthesis of tetrahydro[b]benzopyran derivatives via a one-pot three-component reaction involving aldehydes, malononitrile, and dimedone.\u0000\u0000\u0000\u0000The PBILs perform well in this condensation reaction, especially 1-methylpyridin-1-ium dimethyl phosphate (MPDMP).\u0000\u0000\u0000\u0000The advantages of this procedure are good yields, short reaction time, simplicity of implementation, and inexpensive starting materials.\u0000","PeriodicalId":10945,"journal":{"name":"Current Organocatalysis","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2022-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43989093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-27DOI: 10.2174/2213337209666220127142333
D. Duc, V. C. Dung
An efficient and green method for the Friedländer quinoline synthesis is described. The synthesis was performed under microwave irradiation using ionic liquid [Bmim]HSO4 as a catalyst. A diverse range of quinoline derivatives was obtained in high yields from 2‐aminoaryl aldehydes and ketones under solvent-free conditions.
{"title":"Microwave-assisted, [Bmim]HSO4-catalyzed the Friedländer quinoline synthesis of quinoline under solvent-free conditions","authors":"D. Duc, V. C. Dung","doi":"10.2174/2213337209666220127142333","DOIUrl":"https://doi.org/10.2174/2213337209666220127142333","url":null,"abstract":"\u0000\u0000An efficient and green method for the Friedländer quinoline synthesis is described. The synthesis was performed under microwave irradiation using ionic liquid [Bmim]HSO4 as a catalyst. A diverse range of quinoline derivatives was obtained in high yields from 2‐aminoaryl aldehydes and ketones under solvent-free conditions.\u0000","PeriodicalId":10945,"journal":{"name":"Current Organocatalysis","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2022-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41835167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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