首页 > 最新文献

Digest Journal of Nanomaterials and Biostructures最新文献

英文 中文
Hydrogen production from hydrolysis of NaBH4-NH3BH3 composite catalyzed by porous spherical Co3O4 多孔球形Co3O4催化NaBH4-NH3BH3复合物水解制氢
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-01 DOI: 10.15251/djnb.2023.182.495
Mijia Yang, Y. C. Wu, Y. H. Liu, Z. H. Li, M. Cheng, C. Wu, W. Feng, W. Cai, X. L. Wang
NaBH4-NH3BH3 composite (xSB-AB, x is the molar ratio of SB to AB) has better hydrolysis performance than its monomer, but the hydrogen generation rate (HGR) and hydrogen yield (HY) are still not ideal at room temperature. In this work, a low cost and easily available commercial porous spherical Co3O4 was successfully used to catalyze the hydrolysis of xSB-AB composite. It was found that Co3O4 showed good catalytic performance for the hydrolysis of xSB-AB, and the HY and hydrogen release efficiency (HRE) of 4SB-AB/10 wt%Co3O4 at 40 ℃ reached 2,279.71 mL·g-1 and 89.13%, respectively.
NaBH4-NH3BH3复合材料(xSB-AB,x为SB/AB的摩尔比)具有比其单体更好的水解性能,但在室温下的产氢速率(HGR)和产氢率(HY)仍然不理想。在这项工作中,一种低成本且易于获得的商业多孔球形Co3O4成功地用于催化xSB-AB复合材料的水解。结果表明,Co3O4对xSB-AB的水解具有良好的催化性能,4SB-AB/10wt%Co3O4在40℃时的HY和释氢效率分别达到2279.71mL·g-1和89.13%。
{"title":"Hydrogen production from hydrolysis of NaBH4-NH3BH3 composite catalyzed by porous spherical Co3O4","authors":"Mijia Yang, Y. C. Wu, Y. H. Liu, Z. H. Li, M. Cheng, C. Wu, W. Feng, W. Cai, X. L. Wang","doi":"10.15251/djnb.2023.182.495","DOIUrl":"https://doi.org/10.15251/djnb.2023.182.495","url":null,"abstract":"NaBH4-NH3BH3 composite (xSB-AB, x is the molar ratio of SB to AB) has better hydrolysis performance than its monomer, but the hydrogen generation rate (HGR) and hydrogen yield (HY) are still not ideal at room temperature. In this work, a low cost and easily available commercial porous spherical Co3O4 was successfully used to catalyze the hydrolysis of xSB-AB composite. It was found that Co3O4 showed good catalytic performance for the hydrolysis of xSB-AB, and the HY and hydrogen release efficiency (HRE) of 4SB-AB/10 wt%Co3O4 at 40 ℃ reached 2,279.71 mL·g-1 and 89.13%, respectively.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44574792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simulation design and optimization of amorphous silicon/crystalline silicon heterojunction solar cells based on localized p-n junctions 基于局域p-n结的非晶硅/晶体硅异质结太阳能电池的仿真设计与优化
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-04-01 DOI: 10.15251/djnb.2023.182.423
J. S. Wang, Junsong Yuan, S. Q. Liu, X. Deng
Hydrogenated amorphous silicon/crystalline silicon heterojunction solar cells are currently a hot research topic in the field of photovoltaics, where parasitic absorption due to hydrogenated amorphous silicon layers has not been effectively addressed. For this reason, amorphous silicon/crystalline silicon heterojunction solar cells with localized p-n junctions (HACL cells) have been designed, which can significantly improve the parasitic absorption losses while maintaining the original advantages such as high open-circuit voltage. In this paper, we mainly use ATLAS 2D simulation software to conduct device simulation and parameter optimization of HACL cells, and simulate the effects of factors such as passivation inlet region width, insulation layer width, emitter width, passivation inlet region doping concentration and substrate doping concentration on the cell performance, respectively.
氢化非晶硅/晶体硅异质结太阳能电池是目前光伏领域的研究热点,但由于氢化非晶硅层的寄生吸收尚未得到有效解决。因此,设计了具有局域p-n结的非晶硅/晶体硅异质结太阳能电池(HACL电池),该电池可以在保持高开路电压等原有优势的同时显著改善寄生吸收损失。本文主要利用ATLAS 2D仿真软件对HACL电池进行器件仿真和参数优化,分别模拟钝化入口区宽度、绝缘层宽度、发射极宽度、钝化入口区掺杂浓度和衬底掺杂浓度等因素对电池性能的影响。
{"title":"Simulation design and optimization of amorphous silicon/crystalline silicon heterojunction solar cells based on localized p-n junctions","authors":"J. S. Wang, Junsong Yuan, S. Q. Liu, X. Deng","doi":"10.15251/djnb.2023.182.423","DOIUrl":"https://doi.org/10.15251/djnb.2023.182.423","url":null,"abstract":"Hydrogenated amorphous silicon/crystalline silicon heterojunction solar cells are currently a hot research topic in the field of photovoltaics, where parasitic absorption due to hydrogenated amorphous silicon layers has not been effectively addressed. For this reason, amorphous silicon/crystalline silicon heterojunction solar cells with localized p-n junctions (HACL cells) have been designed, which can significantly improve the parasitic absorption losses while maintaining the original advantages such as high open-circuit voltage. In this paper, we mainly use ATLAS 2D simulation software to conduct device simulation and parameter optimization of HACL cells, and simulate the effects of factors such as passivation inlet region width, insulation layer width, emitter width, passivation inlet region doping concentration and substrate doping concentration on the cell performance, respectively.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42882650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of TiO2 nanoparticles filler on structural, optical, thermal, and mechanical properties of TiO2/LDPE nanocomposites films TiO2纳米粒子填料对TiO2/LDPE纳米复合薄膜结构、光学、热学和力学性能的影响
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.15251/djnb.2023.181.273
V. Thongpool, A. Phunpueok, S. Jaiyen, T. Sornkwan, W. Jakarbutr, P. Minyong
This study blended low-density polyethylene (LDPE) polymer matrix with titanium dioxide (TiO2) nanoparticles as UV blocking filler to create a greenhouse cover film. The best properties for greenhouse application were discovered in TiO2/LDPE nanocomposites films with 5% wt TiO2 nanoparticles, according to the results. TiO2/LDPE nanocomposites films prepared in all conditions can block almost 100% of the UV (200- 400 nm) radiation and show good thermal stability. The TiO2/LDPE nanocomposites films with 5% wt TiO2 nanoparticles has a light transmittance in the visible range of about 80%, sufficient for plant photosynthesis. In addition, it showed good mechanical properties with 12.142 MPa of tensile strength and 319.274% of elongation at break.
本研究将低密度聚乙烯(LDPE)聚合物基质与二氧化钛(TiO2)纳米颗粒混合作为紫外线阻隔填料,制成温室覆盖膜。结果表明,TiO2/LDPE纳米复合材料薄膜中含有5%重量的TiO2纳米粒子,具有最佳的温室应用性能。在所有条件下制备的TiO2/LDPE纳米复合材料薄膜几乎可以100%阻挡紫外线(200- 400 nm)辐射,并表现出良好的热稳定性。含有5% wt TiO2纳米粒子的TiO2/LDPE纳米复合膜在可见光范围内的透光率约为80%,足以满足植物的光合作用。拉伸强度为12.142 MPa,断裂伸长率为319.274%,力学性能良好。
{"title":"Effect of TiO2 nanoparticles filler on structural, optical, thermal, and mechanical properties of TiO2/LDPE nanocomposites films","authors":"V. Thongpool, A. Phunpueok, S. Jaiyen, T. Sornkwan, W. Jakarbutr, P. Minyong","doi":"10.15251/djnb.2023.181.273","DOIUrl":"https://doi.org/10.15251/djnb.2023.181.273","url":null,"abstract":"This study blended low-density polyethylene (LDPE) polymer matrix with titanium dioxide (TiO2) nanoparticles as UV blocking filler to create a greenhouse cover film. The best properties for greenhouse application were discovered in TiO2/LDPE nanocomposites films with 5% wt TiO2 nanoparticles, according to the results. TiO2/LDPE nanocomposites films prepared in all conditions can block almost 100% of the UV (200- 400 nm) radiation and show good thermal stability. The TiO2/LDPE nanocomposites films with 5% wt TiO2 nanoparticles has a light transmittance in the visible range of about 80%, sufficient for plant photosynthesis. In addition, it showed good mechanical properties with 12.142 MPa of tensile strength and 319.274% of elongation at break.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":"13 2","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41302160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and luminescence properties of Mg2Sr2-XTiO4: Eu3+, Gd3+ red phosphors Mg2Sr2-XTiO4: Eu3+, Gd3+红色荧光粉的制备及发光性能
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.15251/djnb.2023.181.253
You-Dong Li, Hengjian Huang, Limin Dong, Dan Li, Wenhua Shi, J. Yin
Titanate-based luminescent materials have a strong absorption capacity for blue and near-ultraviolet light. Here, a sol-gel method is used to prepare a high-efficiency red phosphor of magnesium titanate Mg2Sr2-xTiO4: Eu3+, Gd3+ doped with rare-earth ions. The optimal doping concentrations of the activator rare earth ion Eu3+ and the sensitizer Gd3+ were investigated. Furthermore, the doping of a certain amount of Sr2+ and Na+ effectively improves the luminescence properties of silicate luminescent materials. The luminescence spectrum shows that the luminescent material has red monochromaticity and the strongest red-light emission is 614nm, which can be used for WLED.
钛酸盐基发光材料对蓝光和近紫外光具有很强的吸收能力。本文采用溶胶-凝胶法制备了掺杂稀土离子的钛酸镁Mg2Sr2-xTiO4: Eu3+, Gd3+的高效红色荧光粉。研究了激活剂稀土离子Eu3+和敏化剂Gd3+的最佳掺杂浓度。此外,一定量的Sr2+和Na+的掺杂有效地改善了硅酸盐发光材料的发光性能。发光光谱表明,该发光材料具有红色单色性,最强红光发射为614nm,可用于WLED。
{"title":"Preparation and luminescence properties of Mg2Sr2-XTiO4: Eu3+, Gd3+ red phosphors","authors":"You-Dong Li, Hengjian Huang, Limin Dong, Dan Li, Wenhua Shi, J. Yin","doi":"10.15251/djnb.2023.181.253","DOIUrl":"https://doi.org/10.15251/djnb.2023.181.253","url":null,"abstract":"Titanate-based luminescent materials have a strong absorption capacity for blue and near-ultraviolet light. Here, a sol-gel method is used to prepare a high-efficiency red phosphor of magnesium titanate Mg2Sr2-xTiO4: Eu3+, Gd3+ doped with rare-earth ions. The optimal doping concentrations of the activator rare earth ion Eu3+ and the sensitizer Gd3+ were investigated. Furthermore, the doping of a certain amount of Sr2+ and Na+ effectively improves the luminescence properties of silicate luminescent materials. The luminescence spectrum shows that the luminescent material has red monochromaticity and the strongest red-light emission is 614nm, which can be used for WLED.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43378899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, AC conductivity, dielectric and impedance studies of polypyrrole/praseodymium calcium manganite nanocomposites 聚吡咯/镨钕钙锰酸盐纳米复合材料的结构、交流电导率、介电和阻抗研究
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.15251/djnb.2023.181.343
M. Bharathi, K. Anuradha, M. Murugendrappa
In-situ polymerization of a series of nanocomposites viz. 10, 20, 30, 40 and 50 wt % of Praseodymium Calcium Manganite Oxide (Pr0.75Ca0.25MnO3) (PCM) nano manganites in polypyrrole (PPy) were prepared by chemical polymerization technique. The crystalline nature of all the nanocomposites was confirmed by powder X-ray diffraction (XRD). The orthorhombic structure with space group Pnma was confirmed by the well-fitted Rietveld refined XRD data. The average particle size was observed to be in the range of 42 to 60 nm. Scanning Electron Microscope (SEM) confirmed the spherical nature of the particles. The TEM confirmed the crystallinity and Fourier Transform Infra-Red Spectroscopy (FTIR) showed that the stretching frequencies shifted towards higher frequencies for the nanocomposites suggesting better conjugation due to chemical interaction between the PPy and PCM particles. AC conductivity versus frequency showed that at higher frequencies the AC increases obeying Jonscher’s power law. The correlated barrier hopping (CBH) model is therefore used to describe the conduction mechanism. For all composites, the dielectric constant and tangent loss revealed a frequency- and temperaturedependent character. The real and imaginary impedance were both frequency and temperature dependent. The impedance data were analyzed by fitting Nyquist plots using ZsimpWin software which confirmed non Debye type of behavior. This study highlights on the interactions between conduction processes, grain boundaries, and grains.
采用化学聚合技术,在聚吡啶(PPy)中原位聚合制备了重量为10、20、30、40、50 wt %的氧化镨钙锰酸盐(Pr0.75Ca0.25MnO3) (PCM)纳米锰酸盐系列复合材料。通过粉末x射线衍射(XRD)证实了复合材料的结晶性。通过拟合良好的Rietveld细化XRD数据证实了具有空间群Pnma的正交结构。平均粒径在42 ~ 60 nm之间。扫描电子显微镜(SEM)证实了颗粒的球形性质。透射电镜(TEM)和傅里叶变换红外光谱(FTIR)显示,纳米复合材料的拉伸频率向更高的频率移动,表明由于PPy和PCM颗粒之间的化学相互作用,纳米复合材料具有更好的共轭性。交流电导率随频率的变化表明,在较高的频率下,交流电的增加符合琼舍尔幂定律。因此,相关势垒跳跃(CBH)模型被用来描述传导机制。对于所有复合材料,介电常数和切线损耗显示出频率和温度依赖的特征。实阻抗和虚阻抗都与频率和温度有关。利用ZsimpWin软件拟合Nyquist图对阻抗数据进行分析,证实非Debye型行为。本研究重点研究了传导过程、晶界和晶粒之间的相互作用。
{"title":"Structural, AC conductivity, dielectric and impedance studies of polypyrrole/praseodymium calcium manganite nanocomposites","authors":"M. Bharathi, K. Anuradha, M. Murugendrappa","doi":"10.15251/djnb.2023.181.343","DOIUrl":"https://doi.org/10.15251/djnb.2023.181.343","url":null,"abstract":"In-situ polymerization of a series of nanocomposites viz. 10, 20, 30, 40 and 50 wt % of Praseodymium Calcium Manganite Oxide (Pr0.75Ca0.25MnO3) (PCM) nano manganites in polypyrrole (PPy) were prepared by chemical polymerization technique. The crystalline nature of all the nanocomposites was confirmed by powder X-ray diffraction (XRD). The orthorhombic structure with space group Pnma was confirmed by the well-fitted Rietveld refined XRD data. The average particle size was observed to be in the range of 42 to 60 nm. Scanning Electron Microscope (SEM) confirmed the spherical nature of the particles. The TEM confirmed the crystallinity and Fourier Transform Infra-Red Spectroscopy (FTIR) showed that the stretching frequencies shifted towards higher frequencies for the nanocomposites suggesting better conjugation due to chemical interaction between the PPy and PCM particles. AC conductivity versus frequency showed that at higher frequencies the AC increases obeying Jonscher’s power law. The correlated barrier hopping (CBH) model is therefore used to describe the conduction mechanism. For all composites, the dielectric constant and tangent loss revealed a frequency- and temperaturedependent character. The real and imaginary impedance were both frequency and temperature dependent. The impedance data were analyzed by fitting Nyquist plots using ZsimpWin software which confirmed non Debye type of behavior. This study highlights on the interactions between conduction processes, grain boundaries, and grains.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43563804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploration of third order nonlinear optical features of CuO/PVA-PEG polymer nanocomposites CuO/PVA-PEG聚合物纳米复合材料三阶非线性光学特性的探索
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.15251/djnb.2023.181.367
K. Kannan, S. Agilan, P. Peulakumari, G. Saveetha
CuO/PVA-PEG nanocomposites were prepared by solvent casting method. In XRD spectra, the shifting of peak position and the absence of remaining characteristics peaks of CuO nanoparticles in CuO/PVA-PEG indicates the formation exfoliated nanocomposites. The SEM image reveals the complete dispersion of the nanofillers in polymer matrix. FTIR spectra revealed the formation of strong H-bonds between PVA and PEG during mixing. The absorption and transmission properties of the sample were studied by UV-Vis studies. Z-scan analysis confirms the presence of two-photon absorption in the sample. The synthesized polymer nanocomposite exhibits optical nonlinearity due to the excitonexciton interaction.
采用溶剂铸造法制备了CuO/PVA-PEG纳米复合材料。在XRD谱图中,CuO/PVA-PEG中CuO纳米颗粒的峰位移位和特征峰缺失表明CuO/PVA-PEG中形成了剥落的纳米复合材料。SEM图像显示纳米填料在聚合物基体中的完全分散。FTIR光谱显示PVA和PEG在混合过程中形成了强氢键。用紫外-可见光谱法研究了样品的吸收和透射特性。z扫描分析证实样品中存在双光子吸收。所合成的聚合物纳米复合材料由于激子-激子相互作用而表现出光学非线性。
{"title":"Exploration of third order nonlinear optical features of CuO/PVA-PEG polymer nanocomposites","authors":"K. Kannan, S. Agilan, P. Peulakumari, G. Saveetha","doi":"10.15251/djnb.2023.181.367","DOIUrl":"https://doi.org/10.15251/djnb.2023.181.367","url":null,"abstract":"CuO/PVA-PEG nanocomposites were prepared by solvent casting method. In XRD spectra, the shifting of peak position and the absence of remaining characteristics peaks of CuO nanoparticles in CuO/PVA-PEG indicates the formation exfoliated nanocomposites. The SEM image reveals the complete dispersion of the nanofillers in polymer matrix. FTIR spectra revealed the formation of strong H-bonds between PVA and PEG during mixing. The absorption and transmission properties of the sample were studied by UV-Vis studies. Z-scan analysis confirms the presence of two-photon absorption in the sample. The synthesized polymer nanocomposite exhibits optical nonlinearity due to the excitonexciton interaction.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42839532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elastic properties of SiO2 nanostructure in high-pressure conditions 高压条件下SiO2纳米结构的弹性性能
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.15251/djnb.2023.181.263
Z. Radi, S. Tlili, K. Layadi, L. Louail, A. Yells-Chaouche, Y. Madhekour, S. Guettouche
In this study, the elastic properties of two high-pressure polymorphs SiO2 nanostructure, stishovite and CaCl2-type, are obtained using Density Functional Theory in 0-80 GPa high pressure domain at zero temperature, based on reducing an interacting many-electron problem to a single-electron problem. It is shown that below 40 GPa, the stishovite phase is more stable; superior to this limit, the CaCl2-type phase becomes more stable, using Gibbs free energy method. Furthermore, the pressure dependence of the density, volume, bulk, and shear moduli were defined in the selected pressure domain.
本研究在将多电子相互作用问题简化为单电子问题的基础上,利用密度泛函理论,在0-80 GPa高压域,获得了两种高压多晶SiO2纳米结构(辉石型和cacl2型)的弹性性质。结果表明:在40 GPa以下,石长石相较为稳定;用吉布斯自由能法计算,超过这个极限后,cacl2型相变得更加稳定。此外,在选择的压力域中定义了密度、体积、体积和剪切模量的压力依赖性。
{"title":"Elastic properties of SiO2 nanostructure in high-pressure conditions","authors":"Z. Radi, S. Tlili, K. Layadi, L. Louail, A. Yells-Chaouche, Y. Madhekour, S. Guettouche","doi":"10.15251/djnb.2023.181.263","DOIUrl":"https://doi.org/10.15251/djnb.2023.181.263","url":null,"abstract":"In this study, the elastic properties of two high-pressure polymorphs SiO2 nanostructure, stishovite and CaCl2-type, are obtained using Density Functional Theory in 0-80 GPa high pressure domain at zero temperature, based on reducing an interacting many-electron problem to a single-electron problem. It is shown that below 40 GPa, the stishovite phase is more stable; superior to this limit, the CaCl2-type phase becomes more stable, using Gibbs free energy method. Furthermore, the pressure dependence of the density, volume, bulk, and shear moduli were defined in the selected pressure domain.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44061932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Electrochemical, structural, optical, and morphological characteristics of Cu-loaded ZnO nanostructures synthesized from bio-waste (maize) using a green synthesis technique 利用绿色合成技术从生物废料(玉米)中合成Cu负载ZnO纳米结构的电化学、结构、光学和形态特征
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.15251/djnb.2023.181.291
R. Jagadeeswari, G. Rathika, K. Satheesh kumar, P. Selvakumar
The study reports feasibility to synthesis copper loaded ZnO nanoparticles using a green synthesis approach influenced by natural extracts from waste maize materials is explored. Different methods were used to investigate the physicochemical characteristics of Cu-ZnO nanoparticles. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) studies were used to investigate the structural behavior of Cu-ZnO nanoparticles. XRD analysis shows that Cu-ZnO has a typical crystallite size of 23.5nm and a confirmed hexagonal structure. In the wavenumber range 400–600 cm-1 , FT-IR confirmed the presence of metallic elements in Cu-ZnO samples. Through the use of UV–vis spectroscopy, we were able to investigate the optical characteristics of Cu-ZnO. The samples' surface morphology was recorded by FESEM, and their elemental content was evaluated by EDX. This verifies the spherical shape of prepared samples with homogeneous size distributions across their structures. The nanostructured redox behaviour of electroactive Cu-ZnO has been investigated by cyclic voltammetry
本研究报告了在废玉米材料中天然提取物的影响下,采用绿色合成方法合成负载铜的ZnO纳米颗粒的可行性。采用不同的方法研究了纳米Cu-ZnO的物理化学性质。利用X射线衍射(XRD)和傅立叶变换红外光谱(FTIR)研究了Cu-ZnO纳米颗粒的结构行为。XRD分析表明,Cu-ZnO具有23.5nm的典型晶粒尺寸和证实的六方结构。在400–600 cm-1的波数范围内,FT-IR证实了Cu-ZnO样品中存在金属元素。通过使用紫外-可见光谱,我们能够研究Cu-ZnO的光学特性。通过FESEM记录样品的表面形貌,并通过EDX评估其元素含量。这验证了制备的样品在其结构上具有均匀尺寸分布的球形。用循环伏安法研究了电活性Cu-ZnO的纳米氧化还原行为
{"title":"Electrochemical, structural, optical, and morphological characteristics of Cu-loaded ZnO nanostructures synthesized from bio-waste (maize) using a green synthesis technique","authors":"R. Jagadeeswari, G. Rathika, K. Satheesh kumar, P. Selvakumar","doi":"10.15251/djnb.2023.181.291","DOIUrl":"https://doi.org/10.15251/djnb.2023.181.291","url":null,"abstract":"The study reports feasibility to synthesis copper loaded ZnO nanoparticles using a green synthesis approach influenced by natural extracts from waste maize materials is explored. Different methods were used to investigate the physicochemical characteristics of Cu-ZnO nanoparticles. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) studies were used to investigate the structural behavior of Cu-ZnO nanoparticles. XRD analysis shows that Cu-ZnO has a typical crystallite size of 23.5nm and a confirmed hexagonal structure. In the wavenumber range 400–600 cm-1 , FT-IR confirmed the presence of metallic elements in Cu-ZnO samples. Through the use of UV–vis spectroscopy, we were able to investigate the optical characteristics of Cu-ZnO. The samples' surface morphology was recorded by FESEM, and their elemental content was evaluated by EDX. This verifies the spherical shape of prepared samples with homogeneous size distributions across their structures. The nanostructured redox behaviour of electroactive Cu-ZnO has been investigated by cyclic voltammetry","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42741322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation the effect of Co3O4 doping on structural and mechanical properties of ZnO pallets synthesized by powder metallurgy method and their biological evaluation Co3O4掺杂对粉末冶金法合成ZnO托盘结构和力学性能的影响及其生物学评价
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.15251/djnb.2023.181.307
A. Shuaib, F. Mannan, Z. Ali, H. Rehman, M. H. Farooq, T. G. Shahzady
ZnO is an important semiconductor due to its unique structural, mechanical and optical properties. In this study pure ZnO pallets and Co3O4 doped ZnO pallets with varying molar concentration of dopant i.e 2% 4% 6% 8% and 10% were prepared by using hydraulic press. X-ray diffraction (XRD), FTIR and Vickers indentation method is used for pallets characterization. The XRD analysis revealed that the pure ZnO and doped ZnO pallet samples have hexagonal wurtzite structure. Vickers Hardness test showed that pure ZnO pallet has maximum hardness as compared to the Co3O4 doped ZnO pallets. FTIR analysis used to examine the bonding properties of synthesized Co doped ZnO. Doped materials with varying concentration were applied against different gram positive and gram negative bacterial strains. A considerable increase in antibacterial activity was observed by increasing the concentration of Co3O4 dopant.
ZnO由于其独特的结构、机械和光学性能而成为一种重要的半导体。在本研究中,使用液压机制备了掺杂剂摩尔浓度为2%、4%、6%、8%和10%的纯ZnO托盘和Co3O4掺杂的ZnO托盘。使用X射线衍射(XRD)、FTIR和维氏压痕法对托盘进行表征。XRD分析表明,纯ZnO和掺杂ZnO托盘样品具有六方纤锌矿结构。维氏硬度测试表明,与掺杂Co3O4的ZnO托盘相比,纯ZnO托盘具有最大硬度。FTIR分析用于检测合成的Co掺杂ZnO的键合性能。将不同浓度的掺杂材料应用于不同的革兰氏阳性和革兰氏阴性菌株。通过增加Co3O4掺杂剂的浓度,观察到抗菌活性的显著增加。
{"title":"Investigation the effect of Co3O4 doping on structural and mechanical properties of ZnO pallets synthesized by powder metallurgy method and their biological evaluation","authors":"A. Shuaib, F. Mannan, Z. Ali, H. Rehman, M. H. Farooq, T. G. Shahzady","doi":"10.15251/djnb.2023.181.307","DOIUrl":"https://doi.org/10.15251/djnb.2023.181.307","url":null,"abstract":"ZnO is an important semiconductor due to its unique structural, mechanical and optical properties. In this study pure ZnO pallets and Co3O4 doped ZnO pallets with varying molar concentration of dopant i.e 2% 4% 6% 8% and 10% were prepared by using hydraulic press. X-ray diffraction (XRD), FTIR and Vickers indentation method is used for pallets characterization. The XRD analysis revealed that the pure ZnO and doped ZnO pallet samples have hexagonal wurtzite structure. Vickers Hardness test showed that pure ZnO pallet has maximum hardness as compared to the Co3O4 doped ZnO pallets. FTIR analysis used to examine the bonding properties of synthesized Co doped ZnO. Doped materials with varying concentration were applied against different gram positive and gram negative bacterial strains. A considerable increase in antibacterial activity was observed by increasing the concentration of Co3O4 dopant.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46298619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and anti-biological adhesion performance evaluation of ZNO@PSBMA super hydrophilic coating ZNO@PSBMA超亲水性涂料的制备及抗生物粘附性能评价
IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.15251/djnb.2023.181.315
G. Xu, C. Q. Li, C. Wang, Z. Xue, F. Liang, X. Shen, J. J. Wang, A. Amirfazli
In this study, zinc oxide (ZnO) nanoparticles were modified by means of dispersion using a γ-aminopropyl triethoxysilane coupling agent (KH550), obtaining KH550-ZnO. Then a certain amount of SBMA powder was put into the KH550-ZnO solution, and the ensuing polymerization reaction produced super hydrophilic PSBMA-KH550-ZnO powder. Finally, several polished aluminum sheets were immersed in the PSBMA-KH550-ZnO aqueous solution to start deposition. Upon completion of the deposition, the aluminum sheets were taken out and dried to obtain samples of the ZnO@PSBMA super hydrophilic coating. The structure, morphology and chemical composition of the powders and coatings were investigated by SEM, IR and EDS. The dispersion of KH550-ZnO in aqueous solution was analyzed. The results show that the particle size of KH550-ZnO decreases greatly in aqueous solution. The substrate can be superhydrophilic when deposited in PSBMA-KH550-ZnO aqueous solution for 130 minutes,After 48 hours of coating deposition, the compactness, roughness and friction resistance of the coating are greatly improved. ZnO@PSBMA superhydrophilic coating has good anti-protein, anti-bacterial and anti-algal adhesion properties.
本研究采用γ-氨基丙基三乙氧基硅烷偶联剂(KH550)对氧化锌纳米粒子进行分散修饰,得到KH550-ZnO。然后在KH550-ZnO溶液中加入一定量的SBMA粉末,聚合反应生成超亲水性PSBMA-KH550-ZnO粉末。最后,将几片抛光后的铝板浸入PSBMA-KH550-ZnO水溶液中开始沉积。沉积完成后,将铝板取出并干燥,以获得ZnO@PSBMA超亲水性涂层的样品。采用扫描电镜(SEM)、红外光谱(IR)和能谱仪(EDS)对粉末和涂层的结构、形貌和化学成分进行了表征。分析了KH550-ZnO在水溶液中的分散性能。结果表明:在水溶液中,KH550-ZnO的粒径明显减小;在PSBMA-KH550-ZnO水溶液中沉积130分钟后,涂层具有超亲水性,沉积48小时后,涂层的致密性、粗糙度和耐磨性均有较大提高。ZnO@PSBMA超亲水涂层具有良好的抗蛋白、抗菌、抗藻粘附性能。
{"title":"Preparation and anti-biological adhesion performance evaluation of ZNO@PSBMA super hydrophilic coating","authors":"G. Xu, C. Q. Li, C. Wang, Z. Xue, F. Liang, X. Shen, J. J. Wang, A. Amirfazli","doi":"10.15251/djnb.2023.181.315","DOIUrl":"https://doi.org/10.15251/djnb.2023.181.315","url":null,"abstract":"In this study, zinc oxide (ZnO) nanoparticles were modified by means of dispersion using a γ-aminopropyl triethoxysilane coupling agent (KH550), obtaining KH550-ZnO. Then a certain amount of SBMA powder was put into the KH550-ZnO solution, and the ensuing polymerization reaction produced super hydrophilic PSBMA-KH550-ZnO powder. Finally, several polished aluminum sheets were immersed in the PSBMA-KH550-ZnO aqueous solution to start deposition. Upon completion of the deposition, the aluminum sheets were taken out and dried to obtain samples of the ZnO@PSBMA super hydrophilic coating. The structure, morphology and chemical composition of the powders and coatings were investigated by SEM, IR and EDS. The dispersion of KH550-ZnO in aqueous solution was analyzed. The results show that the particle size of KH550-ZnO decreases greatly in aqueous solution. The substrate can be superhydrophilic when deposited in PSBMA-KH550-ZnO aqueous solution for 130 minutes,After 48 hours of coating deposition, the compactness, roughness and friction resistance of the coating are greatly improved. ZnO@PSBMA superhydrophilic coating has good anti-protein, anti-bacterial and anti-algal adhesion properties.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43484763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Digest Journal of Nanomaterials and Biostructures
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1